Surface Tension
Surface Tension
CONTENTS
8. Exercise - 1 ...................................................................... 14 – 18
9. Exercise - 2 ...................................................................... 19 - 22
Syllabus :
Ex.1 Calculate the energy released when 1000 small water drops each of same radius 10–7
m coalesce to form one large drop. The surface tension of water is 7.0 × 10–2 N/m.
Sol. Let r be the radius of smaller drops and R of bigger one. Equating the initial and final volumes,
we have
4 4
R 3 (1000) r 3
3 3
–7
or R = 10 r = (10)(10 ) m or R = 10–6 m
Further, the water drops have only one free surface. Therefore,
A 4R2 (1000)(4 r 2 )
Ex.2 A mercury drop of radius 1 cm is sprayed into 106 droplets of equal size. Calculates the
energy expanded if surface tension of mercury is 35 × 10–3 N/m.
Sol. If drop of radius R is sprayed into n droplets of equal radius r, then as a drop has only surface,
the initial surface area will be 4R2 while final area is n (4r2). So the increase in area
S = n(4r2) – 4R2
So energy expended in the process,
W = TS = 4T [nr2 – R2] ...(1)
Now since the total volume of n droplets is the same as that of initial drop, i.e.,
4 R
R 3 n[( 4 / 3 )r 3 ] or r 1/ 3 ...(2)
3 n
Putting the value of r from equation (2) in (1)
W 4R 2 T((n)1/ 3 – 1)
2T
Pin – P0 = = Excess Pressure
R
Pin
Pin
P0
P0
Since each half of bubble is in equilibrium (lower half shown in figure)
P0 R2 + 2T(2R) = Pin R2
4T
Pin – P0 = = Excess pressure
R
Note : (1) If we have an air bubble inside a liquid, a single surface is
formed. There is air on the concave side and liquid on the
convex side. The pressure in the concave side (that is in the
P2
air) is greater than the pressure in the convex side (that is in P1
the liquid) by an
2T
amount .
R
2T
P2 P1
R
The above expression has been written by assuming P1 to be constat from all sides of the bubble.
For small size bubbles this can be assumed.
(2) From the above discussion, we can make a general statement. The pressure on the concave
2T
side of a spherical liquid surface is greater than the convex side by .
R
1 1
3. For any curved surface excess pressure on the concave side = T R R where R1 & R2 are radius
1 2
of curvature of the surface in two perpendicular direction of instead of liquid surface, liquid film is
given then above exression will be
1 1
P 2T For spherical curved surface R1, R2
R1 R 2
Ex.3 What should be the pressure inside a small air bubble of 0.1 mm radius situated just below
the water surface. Surface tension of water 7.2 102 N/m and atmospheric pressure
1.013 105 N/m2 .
Sol. Surface tension of water T 7.2 10 2 N / m
Radius of air bubble R = 0.1 mm = 10–4 m
The excess pressure inside the air bubble is given by,
2T
P2 P1
R
2T
Pressure insde the air bubble, P2 P1
R
Substiting the values, we have
2 7.2 10–2
Pr = (1.013 × 105) + = 1.027 × 103 N/m2
10–4
Ex.4 A minute spherical air bubble is rising slowly through a column of mercury contained in a
deep jar. If the radius of the bubble at a depth of 100 cm is 0.1 mm, calculate its depth where
its radius is 0.126 mm, given that the surface tension of mercury is 567 dyne/cm. Assume
that the atmospheric pressure is 76 cm of mercury.
Sol. The total pressure inside the bubble at depth h1 is (P is atmospheric pressure)
2T
(P h1g) P1
r1
2T
and the total pressure inside the bubble at depth h2 is = (P + h2 g) + r = P2
2
2T 4 3 2T 4 3
Hence we get (P h1g) r 3 r1 (P h2 g) r 3 r2
1 2
2T 3 2T 3
or, (P h1g) r1 (P h2 g) r2
r1 r2
Given that : h1 = 100 cm, r1 = 0.1 mm = 0.01 cm, r2 = 0.126 mm = 0.0126 cm, T = 567 dyne/cm, P
= 76 cm of mercury. Substituting all the values, we get
h2 = 9.48 cm
2
2 T (2 R) + P0 R2 = Pin R2 + R 2
20
4T 2
Pin P0 –
R 20
Q
R Water
When the adhesive force (P) between solid and liquid molecules is more than the cohesive force
(Q) between liquid-liquid molecules (as with water and glass), shape of the meniscus is concave
and the angle of contact is less than 90º. In this case the liquid wets or adheres to the solid
surface. The resultant (R) of P and Q passes through the solid.
Glass
P
Q
R
Mercury
On the other hand when P < Q (as with glass and mercury), shape of the meniscus is convex and
the angle of contact > 90º. The resultant (R) of P and Q in this case passes through the liquid.
Let us now see why the liquid surface bends near the contact with a solid. A liquid in equilibrium
can not sustain trangential stress. The resultant force on any small part of the surface layer must
be perpendicular to the surface at that point. Basically three forces are acting on a small part of
the liquid surface near its contact with solid. These forces are,
(i) P, attraction due to the molecule of the solid surface near it i.e. adhesive force which acts
outwards at right angle to the wall of tube.
(ii) Q, attraction due to liquid molecules near this part and i.e. cohesive force which acts at an
angle of 45º to the vertical.
We have considered very small part, so weight of that part can be ignored for better understanding.
As we have seen in the last figures, to make the resultant (R) of P and Q perpendicular to the liquid
surface the surface becomes curved (convex or concave).
Note : The angle of contact between water and clean glass is zero.
4. CAPILLARY RISE
If a tube of very narrow bore (called capillary) is dipped in a liquid, it is found that the liquid in the
capillary either ascends or descends relative to the surrounding liquid. This phenomenon is called
capillarily.
In order to calculate the height to which a liquid will rise in a capaillary, consider a glass capillary of
radius R dipped in water as shown in Fig. shown. As the meniscus is concave and nearly spherical,
the pressure below the meniscus will be [p0 – (2T/r)] with p0 as atmospheric pressure and r as radius
of meniscus. Now as liquid flows from higher to lower pressure and at same level in a liquid pressure
must be same (this is because a liquid cannot sustain tangential stress), so the liquid will ascends in
the capillary till hydrostatic pressure of the liquid compensates for the decrease in pressure. i.e.,
r
R
h
p0 p0 p0
p0
2T
p0
t
2T 2T
p0 p0 – hg or h ...(1)
r rg
But from figure shown it is clear that radius of meniscus r is related to the radius of capillary through
the relation
(R/r) = cos , i.e., r = R/cos ...(2)
where is the anlge of contact. *So substituting the value of from Eqn. (2) in (1), we get
2T 2T cos
h ...(3)
rg Rg
• Alternate Method
T
As it can be seen from figure that T sin cancels out : T
The force due to T cos balances the weight of liquid (mg = vg)
vol. of the curve is negligible
vol. of liquid in r2h h
2T cos
T cos = 2r = r2hg h =
rg
Hg
(2) For a given liquid and solid at a given place as , T, and g are constant, (figure shown)
hr = constant
lesser the radius of capillary greater will be the rise and vice-versa. (figure shown)
(3) Here it is important to note that in equilibrium the height h is independent of the shape of capillary
if the radius of meniscus remains the same. This is why the vertical height h of a liquid column in
capillaries of different shapes and sizes will be same if the radius of meniscus remains the same and
also the vertical height of the liquid in a capillary does not change, when it is inclined to the vertical.
(figure shown)
h
2T
2T = hdg h d
dg
7. If two concentric tubes of radius 'r1' and 'r2' (inner one is solid) are placed in water reservoir, then
height of rise?
T[2r1 2r2 ] [r22h – r12h] g
2T
h
(r2 – r1 ) g
r1 r2
h
r2
T cos T cos
T sin T sin
r
8. If weight of the liquid in the meniscus is to be consider :
1
T cos × 2r = [r2h + r2 × r] g
3 h
r 2T cos
h 3 rg
9. When capillary tube (radius, 'r') is in vertical position, the upper meniscus is concave and pressure
2T
due to surface tension is directed vertically upward and is given by p1 = R
1
where R1 = radius of curvature of upper meniscus.
The hydrostatic pressure p2 = h g is always directed downwards.
If p1 > p2 i.e. resulting pressure is directed upward. For equilibrium, the
pressure due to lower meniscus should be downward. This makes lower
meniscus concave downward (fig a). The radius of
2T
lower meniscus R2 can be given by R (p1 – p 2 )
2
(a) (b) (c)
If p1 < p2 i.e. resulting pressure is directed downward for equilibrium, the pressure due to lower
meniscus should be upward. This makes lower meniscus convex upward (fig. b)
2T
The radius of lower meniscus can be given by R p 2 – p1
2
2T
If p1 = p2, then is no resulting pressure. then, p1 – p2 = R = 0 or, R2 = i.e. lower surface will be FLAT
T
2
(fig c)
Ex.5 A drop of water volume 0.05 cm3 is pressed between two glass-plates, as a consequence of
which, it spreads and occupies an area of 40 cm2. If the surface tension of water is 70 dyne/
cm, find the normal force required to seperate out the two glass plates in newton.
Sol. Pressure inside the film is less than outside by an amount,
1 1
P T , where r and r are the radii of curvature of
r1 r2 1 2
t
the meniscus. Here r1 =
2
and r2 = , then the force required r1= t/2
to separate the two glass plates, between which a liquid film t
2AT
is enclosed (figure) is, F = P × A = , where t is the thickness
t
of the film, A = area of film.
2A2 T 2A2 T 2 (40 10–4 )2 (70 10–3 )
F = 45 N
At V 0.05 10–6
O
C
R'
'
h
h
We know, the height through which a liquid rises in the capillary tube of radius r is given by
2T 2T
h or h R = = constant
R g g
When the capillary tube is cut an its length is less then h (i.e. h'), then the liquid rises upto the top
of the tube and spreads in such a way that the radius (R') of the liquid meniscus increases and it
becomes more flat so that hR = h' R' = Constant. Hence the liquid does not overflow.
r r
If h' < h then R' > R or
cos ' cos
cos < cos ' >
dv dv
FA or F – A ...(1)
dy dy
when is a constant called coefficient of viscosity or simply viscosity of the fluid. The negative sign
shows that viscous force on a liquid layer acts in a direction opposite to the relative velocity of flow
of fluid. The Eq. (1) is known as Newton's law of viscous force. Here y is taken from the layer of
which velocity is zero.
Regarding viscosity of fluid it is worth noting that :
(1) It depends only on the nature of fluid and is independent of area considered or velocity
gradient.
(2) Its dimensions are [ML–1 T–1] and SI unit poiseuille (PI) while CGS unit dyne-s/cm2 called
poise (P) with
1 Pl = 10 poise
(3) Viscosity of liquids is much greater (say about 100 times more) than that of gases
i.e., L > G
Ex.6 A boat of area 10 m2 floating on the surface of a river is made to move horizontally with a speed
of 2 m/s by applying a tangential force. If the river is 1 m deep and the water in contact with
the bed is stationary, find the tangential water in contact with the bed is stationary, find the
tangential force needed to keep the boat moving with same velocity. Viscosity of water is 0.01
poise.
Sol. As velocity changes from 2 m/s at the surface to zero at the bed which is at a depth of 1 m.
dv 2–0
Velocity gradient = = = 2 s–1
dy 1
Now from Newton's law of viscous force,
dv
|F| = A = (10–2 × 10–1) × 10 × 2 = 0.02 N
dy
Ex.7 The velocity of water in a river is 18 km/hr at the surface. If the river is 5 m deep, find the
shearing stress between the horizontal layers of water. The viscosity of water is 10–3 poiseuuille.
Sol. As velocity at the bottom of the river will be zero, velocity gradient
dv 18 10 3
1s –1
dy 60 60 5
Now as the viscous force F A(dv / dy ) is tangential to the area,
F11 dv
Shear stress = = 10–3 × 1 = 1 × 10–3 N/m2
A dy
Ex.8 A cylinder of mass radius r1 and length is kept inside another cylinder of radius r2 and length .
The space between them is filled with a liquid of viscosity . The inner cylinder starts rotating
with angular velocity while the other cyclinder is at rest. Find time when inner cylinder stops.
dv
Sol. Viscous force F = – A
dy
r12 r12
= – 2 r1 = – 2
r2 – r1 r2 – r1
r13
| F r1 | Fr1 sin 90 Fr1 –2 ...(1) R1
r2 – r1
Mr12 d r13
I –2
2 dt r2 – r1
a4r1 t 0
d
dt –
M(r2 – r1 ) 0
a4r1
t n
M(r2 – r1 )
6. STOKES LAW
When a body moves through a fluid, the flui in contact with the body is dragged with it. This estab-
lishes relative motion in fluid layers near the body, due to which viscous force starts operating. The
fluid exerts viscous force on the body to oppose its motion. The magnitude of the viscous force
depends on the shape and size of the body, its speed and the viscosity of the fluid. Stokes established
that if a sphere of radius r moves with velocity v through a fluid of viscosity , the viscous force
opposing the motion of the sphere is
F = 6 rv
7. TERMINAL VELCOITY (VT)
Consider a small sphere falling from rest through a large column of viscous fluid. The forces acting on
the shere are,
(i) Weight W of the sphere acting vertically downwards
(ii) Upthrust Ft acting vertically upwards Ft + Fv
(iii) Viscous force Fv acting vertically upwards, i.e., in a direction opposite to
velocity of the sphere.
Initially, Fv = 0 v
and W > Ft
and the sphere accelerates downwards. As the velocity of the sphere increases, Fv W
increases, Eventually a stage is reached when
W = Ft + Fv
After this net force on the sphere is zero and it moves downwards with a constant velocity called
terminal velocity (vT).
Substituting proper values in Eq. (i) we have,
4 3 4 v
r g r 3 g 6 rv T
3 3
Here, = density of sphere, = density of fluid
vT
and = coefficient of viscosity of fluid
2 r 2 ( ) g
From Eq. (ii), we get vT t
9 O
Figure shows the variation of the velocity v of the sphere with time.
Note : From the above expression we can see that terminal velocity of a spherical body is directly
proportional to the difference in the densities of the body and the fluid ( – ). If the density of fluid is
greater than that of body (i.e., > ), the terminal velocity is negative. This means that the body
instead of falling, moves upward. This is why air bubbles rise up in water.
Ex.9 Two spherical radindrops of equal size are falling vertically through air with a terminal velocity
of 1 m/s. What would be the terminal speed if these two drops were to coalesce to form a large
spherical drop ?
Sol. vT r 2
Let r be the radius of small rain drops and R the radius of large drop.
Equating the volumes, we have
4 4
R 2 2 r 3
3 3
R
R = (2)1/3. r or ( 2)1 / 3
r
2
vT R
( 2) 2 / 3
vT r
(A) (B) a x
t t
v v
(C) (D)
v t
(C) (D)
(JEE PROBLEMS)
Exercise - III JEE PROBLEMS
Paragraph for questions 4 to 6
1. When an air bubble rises from the bottom of a deep When liquid medicine of density is to be put in the
lake to a point just below the water surface, the pres- eye, it is done with the help of a dropper. As the bulb
sure of air inside the bubble on the top of the dropper is pressed, a drop forms at
(A) is greater than the pressure outside it the opening of the dropper. We wish to estimate the
(B) is less than the pressure outside it size of the drop. We first assume that the drop formed
(C) increases as the bubble moves up at the opening is spherical because that requires a
(D) decreases as the bubble moves up minimum increase in its surface energy. To determine
the size, we calculate the net vertical force due to
2. Assertion : A helium filled balloon does not rise
the surface tension T when the radius of the drop is
indefinately in air but halts after a certain height.
R. When this force becomes smaller than the weight
Reason : Viscosity opposes the motion of balloon.
of the drop, the drop gets detached from the dropper.
Choose any one of the following four responses :
[JEE 2010]
(A) if both (A) and (R) are true and (R) is the correct
4. If the radius of the opening of the dropper is r, the
explanation of (A)
vertical force due to the surface tension on the drop
(B) if both (A) and (R) are true but (R) is not correct
of radius R (assuming r << R) is
explanation of (A)
(C) if (A) is true but (R) is false 2r 2 T 2R 2 T
(A) 2 r T (B) 2 R T (C) (D)
(D) if (A) is false and (R) is true R r
3. A tiny spherical oil drop carrying a net charge q is 5. If r = 5 × 10–4m, = 103 kgm–3, g = 10 ms–2, T =
balanced in still air with a vertical uniform electric 0.11 Nm–1, the radius of the drop when it detaches
81 from the dropper is approximately.
field of strength 10 5 Vm 1 . When the field is (A) 1.4 × 10–3 m (B) 3.3 × 10–3 m
7
–3
(C) 2.0 × 10 m (D) 4.1 × 10–3 m
switched off, the drop is observed to fall with termi-
nal velocity 2 × 10 –3 ms–1 Given g = 9.8 ms–2, vis- 6. After the drop detaches, its surface energy is :
cosity of the air = 1.8 × 10–5 Ns m–2 and the den- (A) 1.4 × 10–6 J (B) 2.7 × 10–6 J
sity of oil = 900 kg m–5, the magnitude of q is : –6
(C) 5.4 × 10 J (D) 8.1 × 10–6 J
(A) 1.6 × 10–19C (B) 3.2 × 10–19C
–19
(C) 4.8 × 10 C (D) 8.0 × 10–19C
[JEE 2010]
:: ANSWER KEY : :
Exercise-I
1. D 2. C 3. C 4. B 5. B 6. C 7. B
8. C 9. D 10. B 11. A 12. C 13. D 14. A
15. A 16. C 17. D 18. B
Exercise-II
1. 1.44 × 10–5 J 2. 1.25 × 10–2 m 3. 7.2 × 10–2 Nm–1 4. 8.08 × 105 Nm–2
5. 0.004 m (common film will be concave towards the centre of the smaller bubble)
P(c3 a3 b3 )
6. 7. h = 1.5 cm 8. 1860 Nm–2 9. = 1 cm
4(a2 b2 c2 )
Velocity v0
Dist. moved H
Exercise-III
1. A,D 2. B 3. D 4. C 5. A 6. B