Q. No. 1 Which of the following contains equal to those in 12g Mg? (At. Wt.

Mg = 24)
Option 1 12 gm C
Option 2 7 gm N2
Option 3 32 gm O2
Option 4 None of these
Correct Answer 2
Explanation 12 1
Moles of Mg = =
24 2

1
 Atoms =  NA
2
7 1
Moles of N2 = =
28 4
1 N
No of atoms = NA  2 = A
4 2

Q. No. 2 1
If 1 moles of oxygen combine with Al to form Al2O3 ,the weight of Al used in the
2
reaction is (Al = 27)
Option 1 27 g
Option 2 54 g
Option 3 40.5 g
Option 4 81 g
Correct Answer 2
Explanation 3
2Al+ O2 
 Al2O3
2
3
2 mole mole
2
3
For mole of O2 , moles of Al required is 2 mole
2
 at = 2  27 = 54gm

Q. No. 3 Which has the highest mass?

Option 1 50 g of iron
Option 2 5 moles of N2
Option 3 0.1 mol atom of Ag
Option 4 1023 atoms of carbon
Correct Answer 2
Explanation 50 gm Fe
5 moles N 2 = 5  28 = 140gm
1 mole Ag = 0.1  108 = 10.8 gm
1023 1
1023 atomof C = 23
moles = moles
6.022 10 6.022
1
= 12 = 2 gm
6.022
Q. No. 4 The number of atoms present in 0.5 mole of nitrogen is same as the atoms in
Option 1 12 g of C
Option 2 64 g of S
Option 3 8 g of O
Option 4 48 g of Mg
Correct Answer 1
Explanation 0.5 mole N2contains 0.5  NA molecules
= 0.5  N A  2 = N A atom
This is same for 12 gm of C

Q. No. 5 Which of the following weighs the least?

Option 1 2 g atom of N (at. wt. of N = 14)
Option 2 3  1023 atoms of C (at. wt of C = 12)
Option 3 1 mole of S (at. wt. of S = 32)
Option 4 7 g silver (at. wt. of Ag = 108)
Correct Answer 2
Explanation 2 gm atom of N  28 gm
3 1023 1
3 1023 atomof C = = moles
6 1023 2
1
= 12= 6gm
2
1 mole of S = 32 gm
7 gm Ag

Q. No. 6 If NA is Avogadro’s number then number of valence electrons in 4.2 g of nitride ions
(N3–) is
Option 1 2.4 NA
Option 2 4.2 NA
Option 3 1.6 NA
Option 4 3.2 NA
Correct Answer 1
Explanation 4.2
Moles = = 0.3
14
0.3 mole contains 0.3 NA ions
One ion has 8 valence electron : total valence electro n = 0.3N A  8 = 2.4 N A

Q. No. 7 Hemoglobin contains 0.33 % of iron by weight. The molecular weight of hemoglobin is
approximately 67200. The number of iron atoms (at. wt. of Fe = 56) present in one
molecule of hemoglobin is
Option 1 6
Option 2 1
Option 3 4
Option 4 2
Correct Answer 3
Explanation 100 gm of Haemoglobin contains 0.33 gm of iron. Let there are x atoms of iron present
in one molecule.
100 1
Moles of Haemoglobin= =
67200 672
 x 0.33
Moles of Fe = = x  4
672 56

Q. No. 8 The number of molecules in 4.25 g of ammonia is about

Option 1 1.0  1023
Option 2 1.5  1023
Option 3 2.0  10 23
Option 4 2.5  1023
Correct Answer 2
Explanation 4.25
Moles = = 0.25
17
 No. of molecules = 0.25  6.023  1023
= 1.5  10 23

Q. No. 9 If 20% nitrogen is present in a compound, its minimum molecular weight can be
Option 1 144
Option 2 28
Option 3 100
Option 4 70
Correct Answer 4
Explanation For minimum molecular weight 1 mole of compound must contain 1 mole of atom.
 Moles of compound = Moles of atom
100 20
 = M= 70
M 14

Q. No. 10 The weight of molecule of the compound C60H122 is

Option 1 1.4  10 -21 g
Option 2 1.09  10-21 g
Option 3 5.025  1023 g
Option 4 16.023  1023 g
Correct Answer 1
Explanation (60  12 +122  1)
wt of one molecule = gm
6.022  1023
=1.4  10-21 gm

Q. No. 11 Choose the wrong statement :

Option 1 1 mole means 6.02  1023 particles
Option 2 Molar mass is mass of one molecule
Option 3 Molar mass is mass of one mole of a substance
Option 4 Molar mass is molecular mass expressed in grams
Correct Answer 2
Explanation Molar mass is the mass of one mole of molecules.

Q. No. 12 Which among the following is the heaviest?

Option 1 One mole of oxygen
Option 2 One molecule of sulphur trioxide
Option 3 100 amu of uranium
Option 4 44 g of carbon dioxide
Correct Answer 4
Explanation 1 mole O2 = 32 gm
1 molecule of SO3 = 80  1.66  10 -27
100 amu of U = 100  1.66  10-27 kg
44 gm of CO2

Q. No. 13 Rearrange the following I to IV in order of increasing masses and choose the correct
answer [At. wt. of N = 14 u, O = 16 u, Cu = 63 u]
I 1 molecule of oxygen
II 1 atom of nitrogen
III 1  10-10 mol molecule of oxygen
IV 1  10-10 mol atom of copper
Option 1 II  I  III  IV
Option 2 IV  III  II  I
Option 3 II  I  II  IV
Option 4 I  II  IV  III
Correct Answer 1
Explanation I. 1 molecule of O2 = 32 a.m.u
= 32  1.66  10-24 gm
II. 1 atom of nitrogen = 14 a.m.u
=14  1.66  10-24 gm
III. 10-10 mole of O2 = 10-10  32 gm
IV. 10 -10 mole of Cu = 10 -10  63.5 gm
 II  I  III  IV

Q. No. 14 The number of moles of SO2Cl2 in 13.5 g is

Option 1 0.1
Option 2 0.2
Option 3 0.3
Option 4 0.4
Correct Answer 1
Explanation 13.5
Moles = = 0.1
135

Q. No. 15 The largest number of molecules is in

Option 1 36 g of water
Option 2 28 g of carbon monoxide
Option 3 46 g of ethyl alcohol
Option 4 54 g of nitrogen pentoxide
Correct Answer 1
Explanation 36
36 gm water = moles = 2moles
18
 No. of molecules = 2N A
 28
28 gm CO = =1 mole
28
 No. of molecules = 1  NA
46
46 gm of CH3CH2OH= =1mole
46
 no of molecules = 1  N A
54
54 gmof N2O5 = moles
108
1 1
= mole = NAmolecules
2 2

Q. No. 16 Which of the following contains maximum number of atoms?

Option 1 6.023  1021 molecules of CO2
Option 2 22.4 L of CO2 at STP
Option 3 0.44 g of CO2
Option 4 None of these
Correct Answer 2
Explanation 6.023  1021 molecules of O2
6.023 1021
= 23
moles =10-2moles
6.022 10
No of atom =10-2  NA  3 atom
22.4
22.4 lit of CO2 = =1 mole
22.4
 Atom = 1  N A  3 = 3N A atom
0.44
0.44 gm CO2 = moles = 0.01 moles
44
 atom = 0.01  N A  3 atom

Q. No. 17 If 0.5 mol of BaCl2 is mixed with 0.2 mol of Na3PO4, the maximum number of mole of
Ba3(PO4)2 that can be formed is
Option 1 0.7
Option 2 0.5
Option 3 0.30
Option 4 0.10
Correct Answer 4
Explanation 3 BaCl2 +2Na3PO4 
 Ba3 (PO4 )2 + 6NaCl
0.5 mole 0.2 mole

2
0.5 mole BaCl2 requires =  0.5 mole Na3PO4
3
= 0.33 mole Na3PO4
 Na3PO 4 is the limiting reac tant
 moles of Ba3 (PO 4 )2  0.1 mole

Q. No. 18 One mole of a mixture of CO and CO2 requires exactly 20 gram of NaOH in solution for
 complete conversion of all the CO2 into Na2CO3. How many moles more of NaOH
would it require for conversion into Na2CO3 if the mixture (one mole) is completely
oxidised to CO2
Option 1 0.2
Option 2 0.5
Option 3 0.4
Option 4 1.5
Correct Answer 4
Explanation Total moles of mixture = 1 mole
Let moles of CO = x
 moles of CO2 = (1 - x)2  
CO2 + 2NaOH 
 Na2CO3 +H2O
20 1
Moles of NaOH= = mole
40 2
1 mole of CO2 requires 2 mole of NaOH
 (1 - x ) mole of CO 2requires 2 (1 - x ) mo le of NaOH
1
2(1- x) =
2
3
x =
4
3 3 1
 Moles of CO= , moles of CO2 =1- x =1- =
4 4 4
On oxidation only CO converts its CO2
3
 Moles of CO2formed=
4
 Total moles of CO 2 = 1 mole
 Moles of NaOH required = 2 mole
 Extra moles of NaOH required = 2 - 0.5
= 1.5

Q. No. 19 The number of water molecules present in a drop of water (volume = 0.0018 ml) at
room temperature is (density of H2O = 1 g/mL)
Option 1 6.023  1019
Option 2 1.084  1018
Option 3 4.84  1017
Option 4 6.023  1023
Correct Answer 1
Explanation Mass of water =   v
= 1  0.0018
= 0.0018 gm
0.0018
Moles = = 0.0001
18
No of molecules = 0.0001  6.022  1023
= 6.022  10 19

Q. No. 20 What is the weight of oxygen required for the complete combustion of 2.8 kg of
 ethylene?
Option 1 2.8 kg
Option 2 6.4 kg
Option 3 9.6 kg
Option 4 96 kg
Correct Answer 3
Explanation C 2H4 + 3O2 
 2CO2 + 2H2O
2.8  10 3
Moles of C 2H4 = = 100 moles
28
 Moles of O 2 required = 300 moles
 wt of oxygen = 300  32 gm
= 9.6 kg

Q. No. 21 A sample of pure calcium weighing 1.35 g was quantitatively converted to 1.88 g of
pure calcium oxide. Atomic mass of calcium would be:
Option 1 20
Option 2 40
Option 3 16
Option 4 35.5
Correct Answer 2
Explanation 1
Ca+ O2  CaO
2
1.35
Moles of Ca=
M
1.35
Moles of CaO =
M
1.88
Moles of CaO =
56
1.35 1.88
 = M= 40
M 56

Q. No. 22 30 g of magnesium and 30 g of oxygen are reacted, then the residual mixture contains
Option 1 60 g of Magnesium oxide only
Option 2 40 g of Magnesium oxide and 20 g of oxygen
Option 3 45 g of Magnesium oxide and 15 g of oxygen
Option 4 50 g of Magnesium oxide and 10 g of oxygen
Correct Answer 4
Explanation 2Mg + O2 
2MgO
30 gm 30 gm
30
Moles of Mg = =1.25
24
30
Moles of O2 = = 0.9375
32
1.25
1.25 moles of Mg requires moles of O2 = 0.625 moles
2
 Mg is the limiting reactant
Moles of MgO formed = 1.25
 Mass of MgO = 1.25  40 gm = 50 gm
 Moles of O2 left = 0.9375 - 0.625
= 0.3125
 wt of O2 = 0.3125  32 gm = 10 gm

Q. No. 23 Silicon carbide, is produced by heating SiO2 and C to high temperatures according to
the equation :
SiO2 (s) + 3C(s) 
 SiC(s) + 2CO(g)
How many grams of SiC could be formed by reacting 2.00g of SiO2 and 2.0 g of C?
Option 1 1.33
Option 2 2.56
Option 3 3.59
Option 4 4.0
Correct Answer 1
Explanation SiO 2 + 3C (s) 
 SiC + 2CO
2 gm 2 gm

2
Moles of SiO2 = = 0.033 moles
60
2
Moles of C = = 0.166 moles
12
C is in excess and the limiting reactant is SiO2
 Moles of SiC formed = 0.033
 wt of SiC formed = 0.033  40 gm
= 1.32 gm

Q. No. 24 Given the reaction

Pb(NO3 )2 (aq) + 2KI   PbI2 (s) + 2KNO3 (aq)
What is the mass of PbI2 that will precipitate if 10.2 g of Pb(NO3)2 is mixed with 5.73 g
of KI in a sufficient quantity of H2O?
Option 1 2.06 g
Option 2 4.13 g
Option 3 7.96 g
Option 4 15.9 g
Correct Answer 3
Explanation Pb(NO3 )2 + 2KI 
 PbI2 +2KNO3
10.2 gm 5.73 gm

10.2
Moles of Pb(NO3 )2 = = 0.0307
332
5.73
Moles of KI = = 0.0345
166
 L.R is K.I
 Moles of PbI2 formed = 0.0172
 wt of PbI2 = 0.0172  462
= 7.946 gm

Q. No. 25 If 9 moles of O2 and 14 moles of N2 are placed in a container and allowed to react
 according to the equation :
3O2 + 2N2   2N2O3
The reaction proceeds until 3 moles of O2 remain, how many moles of N2O3 are
present at that instant?
Option 1 6
Option 2 3
Option 3 4
Option 4 12
Correct Answer 3
Explanation 3O2 + 2N2  2N2O3
9 moles 14 moles
O2 is the limiting reactant ideally. When 3 moles of O2 remains at that instant moles of
O2 reacted = 6 moles
2
moles of N2O3 formed=  6 = 4mole
3

Q. No. 26 Iron (III) oxide can be reduced with CO to form metallic iron as described by
unbalanced chemical reaction
Fe2O3 + CO   Fe + CO2
The number of moles of CO required to form one mole of Fe from its oxide is
Option 1 1
Option 2 1.5
Option 3 2
Option 4 3
Correct Answer 2
Explanation Fe2O3 + 3CO   2 Fe + 3CO2
2 mole of Fe is formed from 3 moles of CO
3
 1 mole of Fe is formed from moles o f CO
2

Q. No. 27 The mass of CaO that shall be obtained by heating 20 kg of 90 % pure lime-stone
(CaCO3) is
Option 1 11.2 kg
Option 2 8.4 kg
Option 3 10.08 kg
Option 4 16.8 kg
Correct Answer 3
Explanation CaCO3 

 CaO + CO2 (g)
20,000  90
wt of pure CaCO3 =
100
= 18000 gm
18000
Moles of CaCO3 = =180 moles
100
 moles of CaO = 180
 wt of CaO = 180  56gm
= 10.08 kg

Q. No. 28 If potassium chlorate is 80 % pure, then 48 g of oxygen would be produced from

 (atomic mass of K = 39)
Option 1 153.12 g of KClO3
Option 2 122.5 g of KClO3
Option 3 245 g of KClO3
Option 4 98.0 g of KClO3
Correct Answer 2
Explanation 2KClO3 
2KCl(s) +3O2(g)
48
Moles of O2 = =1.5
32
3 moles of O2 is formed from 2 mole KClO3
2
 1.5 moles of O2 is form ed from  1.5 moles KClO3
3
= 1 mole KClO3

Q. No. 29 Antimony reacts with sulphur according to the equation

2Sb(s) + 3S(s) 
 Sb2S3 (s)
The molar mass of Sb2S3 is 340 g mol–1
What is the percentage yield for a reaction in which 1.40 g of Sb2S3 is obtained from
1.73 g of antimony and a slight excess of sulphur?
Option 1 80.9%
Option 2 58.0%
Option 3 40.5%
Option 4 29.0%
Correct Answer 2
Explanation 2Sb(s) + 3S 
 Sb 2 S 3
1.73 gm

1.73
Moles of Sb = = 0.0141
122
Moles of Sb2S3 ideally formed
0.0141
= = 0.00705
2
Ideal wt of Sb 2 S 3 = 0.00705  [340]gm
= 2.397
But actual wt of Sb2S3 = 1.40 gm
1.40
 % yield=  100 = 58%
2.397

Q. No. 30 NH3 is produced according to the following reaction :

N2 (g)+3H2 (g)  2NH3 (g)
In an experiment 0.25 mol of NH3 is formed when 0.5 mol of N2 is reacted with 0.5 mol
of H2. What is % yield?
Option 1 75%
Option 2 50%
Option 3 33%
Option 4 25%
Correct Answer 1
Explanation N2 (g) +3H2 (g) 
 2NH3 (g)
0.5 mole 0.5 mole
 H2 is the limiting reactant
 ideally the moles of NH3 formed
2
=  0.5 = 0.34
3
Actual moles of NH3 formed = 0.25
0.25
 yield= 100 = 75
0.34

Q. No. 31 What is the weight % sulphuric acid in an aqueous solution which is 0.502 M in
sulphuric acid? The specify gravity of the solution is 1.07.
Option 1 4.77%
Option 2 5.67%
Option 3 9.53%
Option 4 22.0%
Correct Answer 1
Explanation Molarity = 0.502 M
 502 moles of H2 SO 4 is present in 1 lit of solution i.e. 100 ml of solution
 Mass of solution =  V
= 1.07  1000
= 1070 gm
Mass of solute = 0.502  98 = 49.196 gm
49.096
 wt % =  100 = 4.77%
1070

Q. No. 32 Mole fraction of ethanol in ethanol-water mixture is 0.25. Hence, percentage

concentration of ethanol (C2H6O) by weight of mixture is
Option 1 25
Option 2 75
Option 3 46
Option 4 54
Correct Answer 3
Explanation 1
XC2H5OH = 0.25 =
4
 1 mole of C 2H5 OH is present in 4 mole of solution
 Moles of solvent = 4 - 1 = 3 mole
wt of C2H5OH = 46 gm
wt of solven t = 3  18 = 54 gm
Total wt of solution = 46 + 54 = 100 gm
46
% by wt =  100 = 46%
100

Q. No. 33 A molal solution is one that contains one mole of a solute in

Option 1 1000 g of the solvent
Option 2 One litre of the solvent
Option 3 One litre of the solution
Option 4 22.4 litres of the solution
Correct Answer 1
Explanation In a molal solution one mole of solute is present in 1000 gm of solvent.
Q. No. 34 An aqueous solution of ethanol has density 1.025 g/mL and it is 2 M. What is the
molality of this solution?
Option 1 1.79
Option 2 2.143
Option 3 1.951
Option 4 None of these
Correct Answer 2
Explanation 2M C2H5OH
2 moles of C2H5OH is present in 1 lit or 1000 ml of solution.
Mass of solution =   V
= 1.025  1000
= 1025 gm
Mass of solute = 2  46 gm = 92 gm
Mass of solvent = 1025 - 92 = 933 gm
2 1000
Molality = = 2.14
933

Q. No. 35 What volume of 0.4 M FeCl3.6H2O will contain 600 mg of Fe3+?

Option 1 49.85 mL
Option 2 26.78 mL
Option 3 147.55 mL
Option 4 87.65 mL
Correct Answer 2
Explanation Let volume V lit
 moles of solute = 0.4  V
moles of Fe3+ = 0.4V
600
moles of Fe3+ = 0.4V  56 =
1000
 V = 26.78 ml

Q. No. 36 A sample of H2SO4 (density 1.8 g/ml) is 90% by weight. What is the volume of the acid
that has to be used to make 1 litre of 0.2 M H2SO4?
Option 1 16 mL
Option 2 10 mL
Option 3 12 mL
Option 4 18 mL
Correct Answer 3
Explanation 100 gm of solution contain 90 gm of H2SO4
100 1
Vol. of solution=  lit
1.8 1000
1
= lit
18
90
Moles of H2SO4 =
98
90 18
Molarity = =16.53
98 1
Let volume of solution = V lit
16.53  V = 1  0.2 [Moles of solute will be same]
V  12 ml
Q. No. 37 The density (in g mL–1) of a 3.60 M sulphuric acid solution that is 29% H2SO4 (molar
mass = 98 g mol–1) by mass will be
Option 1 1.45
Option 2 1.64
Option 3 1.88
Option 4 1.22
Correct Answer 4
Explanation 3.60 moles of H2SO4 is present in 100 ml of solution. Let density = d gm/ml
M ass of solu tion = d  100 0
Mass of solute = 3.60  98 gm
= 352.8 gm
352.8
 by wt = 100 = 29
1000d
 d = 1.22 gm/ml

Q. No. 38 An antifreeze mixture contains 40% ethylene glycol (C2H6O2) by weight in the aqueous
solution. If the density of this solution is 1.05 g mL, what is the molar concentration?
Option 1 6.77 M
Option 2 6.45 M
Option 3 0.0017 M
Option 4 16.9 M
Correct Answer 1
Explanation 100 gm of solution contain 40 gm ethylene glycol (C2H6O2).
100
Vol. of solution= ml
1.05
1
= lit
10.5
40
Moles of solute =
62
40 10.5
Molarity = = 6.77M
62 1

Q. No. 39 What is the molarity of SO2-

4 ion in aqueous solution that contain 34.2 pp m of
Al2(SO4)3? (Assume complete dissociation and density of solution 1 g/mL)
Option 1 3 × 10-4 M
Option 2 2 × 10-4 M
Option 3 10-4 M
Option 4 None of these
Correct Answer 1
Explanation 34.2 gm of Al2(SO4)3 is present in 106 gm of solution
10 6
 Vol. of solution = ml
1
= 103 lit
34.2
moles of solute = = 0.1 mole
342
 2Al3+ + 3SO2-
Al2 (SO4 )3  4
0.1 mole 0.3 mole
 0.3
Molarity of SO2-
4 =
103
= 3 × 10-4 M

Q. No. 40 The mole fraction of a given sample of I2 in C6H6 is 0.2. The molality of I2 in C6H6 is
Option 1 0.32
Option 2 3.2
Option 3 0.032
Option 4 0.48
Correct Answer 2
Explanation 2 1
XI 2 = 0.2 = =
10 5
i.e. 1 mole of I2 is present in 5 mole of solution.
 mole of C 6H6 = 5 - 1 = 4
wt of C 6 H6 = 4  78 gm
= 312 gm
1  1000
molality = = 3.20
312

Q. No. 41 In which mode of expression, the concentration of a solution remains independent of

temperature?
Option 1 Molarity
Option 2 Normality
Option 3 Formality
Option 4 Molality
Correct Answer 4
Explanation Molality in values the wt. of solvent which does not changes with temperature.

Q. No. 42 With increase of temperature, which of these changes?

Option 1 Molality
Option 2 Weight fraction of solute
Option 3 Fraction of solute present in unit volume of water
Option 4 Mole fraction
Correct Answer 3
Explanation With increase of temperature volume changes.

Q. No. 43 Molarity and Normality changes with temperature because they involve:
Option 1 Moles
Option 2 Equivalents
Option 3 Weights
Option 4 Volumes
Correct Answer 4
Explanation But molarity and normality changes with temperature because they involve volume
and volume changes with temperature.

Q. No. 44 When 500.0 mL of 1.0 M LaCl3 and 3.0 M NaCl are mixed. What is molarity of Cl– ion?
Option 1 4.0 M
Option 2 3.0 M
Option 3 2.0 M
Option 4 1.5 M
Correct Answer 2
Explanation M illim oles of La Cl3 = 5 00  1
= 500
-
 m. moles of Cl = 1500
M illim oles of N a C l = 500  3 = 150 0
 m. moles of Cl- = 1500
Total m. moles of Cl- = 3000
Total volume = 100 ml
3000
 Molarity of C l- = =3
1000

Q. No. 45 When 50 mL of 2.00 M HCl, 100 mL of 1.00 M HCl and 100 mL of 0.500 M HCl are
mixed together, the resulting HCl concentration of the solution is
Option 1 0.25 M
Option 2 1.00 M
Option 3 3.50 M
Option 4 6.25 M
Correct Answer 2
Explanation 50  2+100  1+100  0.5
Mnet =
50+100+100
=1M

Q. No. 46 A sample of H2SO4 (density 1.8 g mL–1) is 90% by weight. What is the volume of the
acid that has to be used to make 1 L of 0.2 M H2SO4?
Option 1 16 mL
Option 2 18 mL
Option 3 12 mL
Option 4 10 mL
Correct Answer 3
Explanation 100 gm sample contain 90 gm of H2SO4
100 1
Vol. of sample = ml= lit
1.8 18
90  18
Molarity of solution= =16.53
98  1
Let the vol. of solution taken = V lit
 Moles of acid = V  16.53 = 1  0.2 or 0.12 ml
V = 0.012

Q. No. 47 What is the concentration of nitrate ions if equal volumes of 0.1 M AgNO3 and 0.1 M
NaCl are mixed together?
Option 1 0.1 M
Option 2 0.2 M
Option 3 0.05 M
Option 4 0.25 M
Correct Answer 3
Explanation AgNO3 +NaCl 
 AgCl+NaNO3
0.1  V 0.1  V
0 0 0.1V 0.1V
0.1V
[NO3- ]= = 0.05 M
2V

Q. No. 48 How many grams of NaBr could be formed if 14.2 g of NaI are reacted with 40.0 mL of
a 0.800 M Br2?
2NaI+Br2 
 2NaBr+ I2
Option 1 3.30
Option 2 4.80
Option 3 6.59
Option 4 9.75
Correct Answer 3
Explanation 2NaI + Br2 
 2NaBr+ I2
14.2 gm 40 ml of
0.8M
14.2
Moles of NaI = = 0.0946
150
0.8  40
Moles of Br2 = = 0.032
1000
0.0946
0.0946 moles of NaI will be reacting with mole of Br2 i.e. 0.0473 moles
2
 Br2 is limiting reactant
 Moles of NaBr formed = 0.32  2
= 0.064
w t of NaBr = 0.064  103 = 6.59

Q. No. 49 If AgBr is assumed to be completely insoluble, What mass of AgBr precipitates when
30.0 mL of a 0.500 mol/L solution of AgNO3 is added to 50.0 mL of an 0.400 mol/L
solution of NaBr?
Option 1 3.76 g
Option 2 1.28 g
Option 3 2.82 g
Option 4 3.76 kg
Correct Answer 3
Explanation AgNO3 +NaBr 
 Ag Br+NaNO3
30ml, 50ml,
0.500M 0.4M

M illim oles of AgN O 3 = 30  0. 5

= 15
Millimoles of NaBr  =50  0.4
= 20
 Limiting reactant is AgNO 3
 Millimoles of AgBr = 15
 15
Mass of AgBr =  [188] gm 
1000
= 2.82

Q. No. 50 In a titration, 15.0 cm3 of 0.100 M HCl neutralizes 30.0 cm3 of Ca(OH)2 . What is the
molarity of Ca(OH)2 solution?
Option 1 0. 0125
Option 2 0.0250
Option 3 0.0500
Option 4 0.200
Correct Answer 2
Explanation Milli eq. of HCl = mlli. Eq of Co(OH)2
(M V  'n'factor)HCl = (M V  'r'factor)Ca(OH)2
0.1 15 1 = 30 M 2
 M = 0.025

Q. No. 51 10 mL of 1 M BaCl2 solution and 5 mL 0.5 M K2SO4 are mixed together to precipitate
out BaSO4 . The amount of BaSO4 precipitate will be
Option 1 0.005 mol
Option 2 0.00025 mol
Option 3 0.025 mol
Option 4 0.0025 mol
Correct Answer 4
Explanation BaCl2 +K 2SO 4 
 BaSO 4 + 2KCl
m. moles of BaCl2 = 10
m. moles of K2SO4 = 2.5
 K 2 SO 4 is the limiting reac tant
 m. moles of BaSO 4 = 2.5
= 0.0025 mole

Q. No. 52 Mg of a substance when vaporised occupy a volume of 5.6 litre at NTP. The molecular
mass of the substance will be:
Option 1 M
Option 2 2M
Option 3 3M
Option 4 4M
Correct Answer 4
Explanation Mass of 5.6 lit at N.T.P is M gm
M
Mass of 22.4 lit at N.T.P is  22.4
5.6
=4M

Q. No. 53 Number of molecules in 1 litre of oxygen at NTP is :

Option 1 6.02  1023
32
Option 2 6.02  1023
22.4
Option 3 32  22.4
Option 4 32
22.4
Correct Answer 2
Explanation 1
Moles of O2 =
22.4
1
No. of molecular =  6.022 1023
22.4

Q. No. 54 The number of molecules in 89.6 litre of a gas at NTP are :

Option 1 6.02  1023
Option 2 2  6.02  1023
Option 3 3  6.02  1023
Option 4 4  6.02  1023
Correct Answer 4
Explanation 89.6
Moles = =4
22.4
No. of molecular = 4  6.022  1023

Q. No. 55 The mass of 112 cm3 of CH4 gas at STP is

Option 1 0.16 g
Option 2 0.8 g
Option 3 0.08 g
Option 4 1.6 g
Correct Answer 3
Explanation 112 1
Moles = =
22400 200
1
Mass = 16 = 0.08 gm
200

Q. No. 56 An oxide of metal (M) has 40% by mass of oxygen. Metal M has atomic mass of 24. The
empirical formula of the oxide is
Option 1 M2O
Option 2 M2O3
Option 3 MO
Option 4 M3O4
Correct Answer 3
Explanation Let the valency of metal = x
100 gm of oxide contain 40 gm of oxygen
 wt of metal = 100 - 40 = 60 gm
40 gm of oxygen combines with 60 gm of metal
60
 8 gm of oxygen combine s with  8 gm of metal
40
 Equivalent wt of metal = 12 gm
24
 Eq wt = 12 =  Valency = 2
Valency
 Formula = MO
Q. No. 57 What is the empirical formula of a compound composed of O and Mn in equal weight
ratio?
Option 1 MnO
Option 2 MnO2
Option 3 Mn2O3
Option 4 Mn2O7
Correct Answer 4
Explanation The wt. of Mn and O are equal
x
Moles of Mn=
55
x
Moles of O=
16
x x
Mole ratio of Mn : O = ;
55 16
 It empirical formula = Mn2O 7

Q. No. 58 Determine the empirical formula of Kelvar, used in making bullet proof vests, is
70.6% C, 4.2% H, 11.8% N and 13.4% O :
Option 1 C7H5NO2
Option 2 C7H5N2O
Option 3 C7H9NO
Option 4 C7H5NO
Correct Answer 4
Explanation Given :
C = 70.6%, H = 4.2%,
N = 11.8%, O =13.4%
Moles Simplest of ratio
C 70.6 5.88
= 5.88 = 7.02
12 0.8375
H 4.2 4.2
= 4.2 = 5.01
1 0.8375
N 11.8 0.842
= 0.842 =1.005
14 0.8375
O 13.4 0.8375
= 0.8375 =1
16 0.8375
 Empirical formula C 7H5NO

Q. No. 59 A compound contains atoms of three elements A, B and C. If the oxidation number of
A is +2, B is +5 and C is -2, the possible formula of the compound is:
Option 1 A(BC3)2 ☒
Option 2 A3(BC4)2 ☒
Option 3 A3(B4C)2 ☐
Option 4 ABC2 ☐
Explanation The sum of oxidation number of all the element, in a compound is equal to zero.
In (a) i.e. A(BC 3 )2 ,sum of oxidation number is + 2 + [5 - 6]  2 = 0
In (b) i.e. A3(BC4)2 sum of oxidation = 0

Q. No. 60 The carbonate of a metal is isomorphous (similar formula) with magnesium carbonate
 and contains 6.091% of carbon. The atomic weight of metal is
Option 1 24
Option 2 56
Option 3 137
Option 4 260
Correct Answer 3
Explanation The formula of carbonate of metal = MCO3
12
% C=  100 = 6.091
M+60
 M = 137

Q. No. 61 The Ew of an element is 13. It forms an acidic oxide which with KOH forms a salt
isomorphous with K2SO4. The atomic weight of element is
Option 1 13
Option 2 26
Option 3 52
Option 4 78
Correct Answer 1
Explanation Formula of salt will be M2SO4
 Valency of element is 1
M
 Equivalent w t =
1
M
13 =
1
 M = 13

Q. No. 62 A hydrate of Na2SO3 losses 22.2% of H2O by mass on strong heating. The hydrate is
Option 1 Na2SO3.4H2O
Option 2 Na2SO3.6H2O
Option 3 Na2SO3.H2O
Option 4 Na2SO3.2H2O
Correct Answer 4
Explanation Let the hydrate is Na2SO3. xH2O
100 gm of hydrate looses 22.2 gm of H2O on heating

Na2 SO3 .xH2O 
 Na2 SO3 + xH2O
100 gm 22.2

100
Moles of hydrate =
126+18x
100 x
It will gives moles of H2O
126+18x
22.2
mole of H2O=
18
100 x 22.2
 = x = 2
126+18x 18
 Na 2 SO 3 .2H 2 O
Q. No. 63 One of the following combinations illustrate law of reciprocal proportions
Option 1 N2O3, N2O4, N2O5
Option 2 NaCl, NaBr, Nal
Option 3 CS2, CO2, SO2
Option 4 PH3, P2O3, P2O5
Correct Answer 3
Explanation C S (in CS 2 )
12 gm 64 gm
C O (in CO 2 )
12 gm 32 gm
 wt ratio of S : O = 64 : 32 = 2 : 1 when S and O combines directly then they form SO 2 in
which weight ratio of S : O is 32 : 32 = 1 : 1. This illustrate the law of reciprocal
proportion.

Q. No. 64 If water samples are taken from sea, river, clouds, lake or snow, they will be found to
contain H2 and O2 in the approximate ratio 1 : 8. This indicates the law of
Option 1 Multiple proportion
Option 2 Definite proportion
Option 3 Reciprocal proportions
Option 4 None of these
Correct Answer 2
Explanation Any chemical compound always contain fixed ratio by wt of element in it no matter
they are prepared from any source or by any chemical method. This is law of definite
proportion.

Q. No. 65 The law of multiple proportion is illustrated by

Option 1 Carbon monoxide and carbon dioxide
Option 2 Potassium bromide and potassium chloride
Option 3 Water and heavy water
Option 4 Calcium hydroxide and barium hydroxide
Correct Answer 1
Explanation When two elements combine to for more than one compound then with a fixed wt. of
one element the wt. ratio of other elements combining bears a simple whole no
multiple. This is the law of multiple proportion.

Q. No. 66 The percentage of copper and oxygen in samples of CuO obtained by different
methods were found to be the same. This illustrates the law of
Option 1 Constant proportions
Option 2 Conservation of mass
Option 3 Multiple proportions
Option 4 Reciprocal proportions
Correct Answer 1
Explanation

Q. No. 67 Two samples of lead oxide were separately reduced to metallic lead by heating in a
current of hydrogen. The weight of lead from one oxide was half the weight of lead
obtained from the other oxide. The data illustrates.
Option 1 Law of reciprocal proportions
Option 2 Law of constant proportions
Option 3 Law of multiple proportions
Option 4 Law of equivalent proportions
Correct Answer 3
Explanation With a fixed mass of oxygen the wt of lead combining bears a simple whole no
multiple. This is the law of multiple proportion.
Q. No. 68 One part of an element A combines with two parts of another element B. Six part of
the element C combine with four parts of the elements B. If A and C combine together
the ratio of their weights will be governed by
Option 1 Law of definite proportions
Option 2 Law of multiple proportions
Option 3 Law of reciprocal proportions
Option 4 Law of conservation of mass
Correct Answer 3
Explanation If A and B combine directly to form a compound and if C and B combine to form and
compound if A and C combine directly to form a 3rd compound then wt ratio of A and C
will be governed by law of reciprocal proportion.

Q. No. 69 n g of substance X reacts with m g of substance Y to form p g of substance R and q g of

substance S. This reaction can be represented as follows.
X+Y=R+s
The relation which can be established in the amounts of the reactants and the
products will be
Option 1 n-m=p-q
Option 2 n+m=p+q
Option 3 n=m
Option 4 p=q
Correct Answer 2
Explanation X + Y = R + S
n gm m gm p gm g gm
Total wt of reactants = Total wt of products
n + m = p + q

Q. No. 70 Which one is the best example of law of conservation of mass?

Option 1 6 g of carbon is heated in vacuum, there is no change in mass
Option 2 6 g of carbon combines with 16 g of oxygen to form 22 g of CO2
Option 3 6 g water is completely converted into steam
Option 4 A sample of air is heated at constant pressure when its volume increases but there is
no change in mass
Correct Answer 2
Explanation During any chemical reaction total mass is conserved.

Q. No. 71 SO2 gas was prepared by (i) burning sulphur in oxygen, (ii) reacting sodium sulphite
with dilute H2SO4 and (iii) heating copper with conc. H2SO4. It was found that in each
case sulphur and oxygen combined in the ratio of 1 : 1. The data illustrates the law of :
Option 1 Conservation of mass
Option 2 Multiple proportions
Option 3 Constant proportions
Option 4 Reciprocal proportions
Correct Answer 3
Explanation

Q. No. 72 A sample of CaCO3 has Ca = 40% C = 12% and O = 48% If the law of constant
proportions is true, then the mass of Ca in 5 g of CaCO3 from another source will be:
Option 1 2.0 g
Option 2 0.2 g
Option 3 0.02 g
Option 4 20.0 g
Correct Answer 2
Explanation Any chemical compound always has same % of elements no matter it is obtained from
any source.
40
Mass of Ca = 5
100
= 2 gm

Q. No. 73 H2S contains 5.88% hydrogen, H2O contains 11.11% hydrogen while SO2 contains 50%
sulphur. These figures illustrate the law of:
Option 1 Conservation of mass
Option 2 Constant proportions
Option 3 Multiple proportions
Option 4 Reciprocal proportions
Correct Answer 4
Explanation In H2 S, H = 5.88 %  S = 94.12
In H2 O, H = 11.11 % ,O = 88.89
 wt ration S : O = 1 : 1
In SO 2 , S = 50  ,O = 50 
 wt ratio of S : O = 1 : 1
This illustrate the law of reciprocal proportion.

Q. No. 74 Hydrogen combines with chlorine to form HCl. It also combines with sodium to form
NaH. If sodium and chlorine also combine with each other, they will do so in the ratio
of their masses as:
Option 1 23 : 35.5
Option 2 35.5 : 23
Option 3 1:1
Option 4 23 : 1
Correct Answer 1
Explanation In HCl, wt ratio of H : Cl = 1 : 35.5
In NaOH, wt ratio of H : Na = 1 : 23
If Na and Cl combine directly then wt ratio = 23 : 35.5

Q. No. 75 x g of Ag was dissolved in HNO3 and the solution was treated with excess of NaCl when
2.87 g of AgCl was precipitated. The value of x is
Option 1 1.08 g
Option 2 2.16 g
Option 3 2.70 g
Option 4 1.62 g
Correct Answer 2
Explanation Ag + HNO3   AgNO3 
NaCl
 AgCl
Mole ratio is 1 : 1
 Moles of Ag = Moles of AgCl
x 2.87
=
108 143.5
 x = 2.16 gm
Q. No. 76 A 1.50 g sample of an ore containing silver was dissolved, and all the Ag+ was
converted to 0.125 g Ag2S. What was the percentage of silver in the ore?
Option 1 14.23%
Option 2 10.8%
Option 3 8.27%
Option 4 720%
Correct Answer 4
Explanation 0.125
Moles of Ag2S =
248
2  0.125
moles of Ag in Ag2S =
248
= 0.001
 wt of Ag = 0.001  108
= 0.1088
0.1088
 % of Ag =  100 = 7.2%
1.50

Q. No. 77 NaOH is formed according to the reaction

1
2Na + O2  Na2O
2
Na2 O + H2 O  2NaOH
To make 4 g of NaOH, Na required is
Option 1 4.6 g
Option 2 4.0 g
Option 3 2.3 g
Option 4 0.23 g
Correct Answer 3
Explanation 4
Moles of NaOH= = 0.1 mole
40
Mole ratio of Na and NaOH is 1 : 1
 Moles of Na = 0.1 mole
 wt of Na = 2.3 gm

Q. No. 78 2H3PO4 + 3Ca(OH)2 

Ca3 (PO4 )2 + 6 H2O Equivalent weight of H3PO4in this reaction
is
Option 1 98
Option 2 49
Option 3 32.66
Option 4 24.5
Correct Answer 3
Explanation 98
Equal = = 32.66 or H3PO4 has lost all root it
3

Q. No. 79 The Ew of H3PO4 in the reaction is

Ca(OH)2 + H3PO4   CaHPO4 + 2H2 O
(Ca = 40, P = 31, O = 16)
Option 1 49
Option 2 98
Option 3 32.66
Option 4 147
Correct Answer 1
Explanation Ca(OH)2 +H3PO4 
CaHPO4 +2H2O
In the reaction H3PO4 has lost 2H
 its 'n' factor = 2
M 98
Eq.wt = = = 49
2 2

Q. No. 80 What weight of a metal of equivalent weight 12 will give 0.475 g of its chloride?
Option 1 0.12 g
Option 2 0.24 g
Option 3 0.36 g
Option 4 0.48 g
Correct Answer 1
Explanation x
M + Cl2 
MClX
2
n factor of metal = valency of metal
Let the wt of metal = y gm
Gm - eq of metal = gm - eq of MClX
y 0.475
=
M M + x(35.5)
x x
M
 =12
x
 On solving y = 0.12 gm

Q. No. 81 How many grams of phosphoric acid would be needed to neutralise 100 g of
magnesium hydroxide? (The molecular weights are : H3PO4 = 98 and Mg (OH)2 = 58.3)
Option 1 66.7 g
Option 2 252 g
Option 3 112 g
Option 4 168 g
Correct Answer 3
Explanation Gm - eq of H3PO4 = gm - eq of Mg(OH)2
x 100
3 = 2
98 58
 x = 112 gm

Q. No. 82 0.116 g of C4H4O4 (A) is neutralised by 0.074 g of Ca(OH)2. Hence, protonic hydrogen
(H ) in (A) will be
Option 1 1
Option 2 2
Option 3 3
Option 4 4
Correct Answer 2
Explanation Gm - equivalents of C4H4O4
= gm - eq of Ca(OH)2
G m - eq of C 4 H 4 O 4 = moles  'n'factor
0.116
=  (x)
116
[where x is the no of H+ released]
0.074  2
Gm - eq of Ca(OH)2  =
74
0.116 0.074
 x= 2 x = 2
116 74

Q. No. 83 4.2 g of metallic carbonate MCO3 was heated in a hard glass tube and CO2 evolved was
found to have 1120 mL of volume at STP. The Ew of the metal is
Option 1 12
Option 2 24
Option 3 18
Option 4 15
Correct Answer 1
Explanation MCO3 
MO + CO2
4.2 gm 1120 ml
of S.T.P.
1120
Moles of CO2 = = 0.05
22400
4.2
Moles of MCO3 =
M + 60
4.2
 = 0.05  M=24
M + 60
24
Eq. wt of metal = =12
2

Q. No. 84 1.0 g of a monobasic acid when completely aceted upon Mg gave 1.301 g of anhydrous
Mg salt. Equivalent weight of acid is
Option 1 35.54
Option 2 36.54
Option 3 17.77
Option 4 18.27
Correct Answer 2
Explanation Let the monobasic acid = HA
Mg + 2HA 
 MgA2 + H2
1 gm 1.301 gm

 1  1.301
Moles of HA =  ,Moles of MgA2 =
 A +1  24+2A
As 2 moles of HA gives 1 mole of MgA2
 1  1 1.301
  moles of HA gives =
 A + 1 2(A + 1) 24 + 2A
  A = 35.54
 Molecular wt = 35.54 + 1 = 36.54
 Eq. wt = 36.54 / 1

Q. No. 85 0.1 g of metal combines with 46.6 mL of oxygen at STP. The equivalent weight of metal
is
Option 1 12
Option 2 24
Option 3 6
Option 4 36
Correct Answer 1
Explanation 46.6
Moles ofoxygen= = 0.0020
22400
wt of oxygen = 0.0020  32 = 0.064 gm
0.064 gm of O combines with 0.1 gm of metal
0.1
8 gm of O combines with=  8 =12 gm
0.064

Q. No. 86 When 100 ml of 1 M NaOH solution and 10 ml of 10 N H2SO4 solution are mixed
together, the resulting solution will be :
Option 1 Alkaline
Option 2 Acidic
Option 3 Strongly acidic
Option 4 Neutral
Correct Answer 4
Explanation milli - eq of NaOH = 1  1  100
= 100
m. eq of H2 S O 4   = 1 0  10
= 100
 Solution is neutral

Q. No. 87 Normality of 0.74 g Ca(OH)2 in 5 mL solution is

Option 1 8N
Option 2 4N
Option 3 0.4 N
Option 4 2N
Correct Answer 2
Explanation Gm - equivalents of Ca(OH)2
0.74 1
= =
74 50
2
1 1000
N= = 4N
50  5
Q. No. 88 Normality of a 2 M sulphuric acid is
Option 1 2
Option 2 4N
Option 3 N/2
Option 4 N/4
Correct Answer 2
Explanation N = M  'n' factor
= 2  2 = 4N

Q. No. 89 1 L of a normal solution is diluted to 2000 ml. The resulting normality is :

Option 1 N/2
Option 2 N/4
Option 3 N
Option 4 2N
Correct Answer 1
Explanation Gm - eq. of so lution = 1  1 = 1
1 1000
New normality =
2000
1 N
= i.e
2 2

Q. No. 90 What volume of 0.232 N solution contains 3.17 milliequivalent of solute?

Option 1 137 mL
Option 2 13.7 mL
Option 3 27.3 mL
Option 4 12.7 mL
Correct Answer 2
Explanation Milliequivalents of solute
= N V
= 0.232  V(mL) = 3.17
 V = 13.7 mL

Q. No. 91 1 L solution of NaOH contains 4.0 g of it. What shall be the difference between
molarity and the normality?
Option 1 0.10
Option 2 Zero
Option 3 0.05
Option 4 0.20
Correct Answer 2
Explanation For NaOH ‘n’ factor = 1
N and M are same
Difference is zero

Q. No. 92 100 mL of 0.3 N HCl is mixed with 200 ml of 0.6 N H2SO4. The final normality of the
resulting solution will be
Option 1 0.1 N
Option 2 0.2 N
Option 3 0.3 N
Option 4 0.5 N
Correct Answer 4
Explanation m. eq of HCl = 30
m. eq of H2 SO 4 = 200  0.6 = 120
Total gm - eq = 150
Total volume = 300 ml
150 1
NFinal = = = 0.5N
300 2

Q. No. 93 Normality of a mixture of 30 mL of 1 N H2SO4 and 20 mL of 4 N H2SO4 is

Option 1 1.0 N
Option 2 1.1 N
Option 3 2.0 N
Option 4 2.2 N
Correct Answer 4
Explanation Total m. eq= 30  1 + 20  4
= 30 + 80
= 110
Total volume = 50 ml
110
N= = 2.2N
50

Q. No. 94 Normality of solution obtained by mixing 10 mL of 1 N HCl, 20 mL of 2 N H2SO4 and

30 mL of 3 N HNO3 is
Option 1 1.11 N
Option 2 2.22 N
Option 3 2.33 N
Option 4 3.33 N
Correct Answer 3
Explanation 10 1+20  2+30  3
Nnet =
60
= 2.33 N