TUGAS NERACA ENERGI

Ahmad Zaenal Arif (2311161095)

Gilman Zaki Mahda Sabila (2311171048)

8.12

T=600 F = 58 8,5 K
850 F = 727,4 K
F1 = 1 MOL F2 = ?
CO(g) + H2O(g) ⇌ CO2(g) + H2(g)
CO = 0,3 CO = ?
H2 = 0,2 H2 = ?
H2O = 0,5 H20 = ?
CO2 = ?

F3 = ?
550 F = 560,7 K
r=
Xco.Fco
=
0,9 . 0,3
= 0,27  H2O
−σ − (−1)
1 x F2 – 27 = 23
Neraca Masa Total F2 = 50 mol/jam
 F3 = F1 + F2
F1 + F2 = F3 = 100 + 50
= 150 mol/jam
100 + F2 = F3
Neraca Massa Komponen (Aliran 3)

 CO  C02
= 0,3 x 100 – r =0+r
= 30 – 27 =27
=3  H2
 H2O = 0,2 x 100 + r
= 0,5 x 100 – r = 20 + 27
= 50 – 27 = 47
= 23
8.13
A.

T3 = ?
F3 = ?
Q=0

CO2 = 0
F1 = 1MOL H20 = ?
2H2 + 02 JD 2H20
H2 = 100% SO2 = 0
298 K N2 = ?

F2 = ?
02 = 0,21
N2 = 0,79
298 K

∆HR(25oC)= 2∆Hf H2O - ∆Hf H2 - ∆Hf O2

= 2 (- 57,8) – 0 -- 0
= - 115,6 kcal/mol
=483,21x103J/mol
H2o=H2 + ro
1 = 1-2r
r = 0,5 mol/s
O2’ = 0,5 mol
𝑚𝑜𝑙 𝑂2
Mol udara = = 2,4 mol
0,21

Mol N2’ : mol N2o = 2,4 – 0,5 = 1,9 mol

H2O: 0 +2(0,5) = 1 mol
Tref = Ti , maka ∑Fi Hi =0
𝑇 𝑇
0=∫298 34,5 𝑑𝑇 + 1,9 ∫298 29,4 𝑑𝑇 + 0,5 (−483,21)

( 34,05(T - 298)) + (1,9x 29,4 (T – 298)) = 0,5(483,21)x103

T= 2985,2K
B.

Q=0

F1 = 1MOL CO2 = 0
H2 = 100% C2H6 + 7/202 JADI 2C02 + 3H20 H20 = ?
298 K SO2 = 0
N2 = ?

F2 = ?
02 = 0,21
N2 = 0,79
298 K

∆HR(25oC)= 2∆Hf CO2 + 3∆Hf H2O - ∆Hf C2H6 -7/2 ∆Hf O2

=2(-94,05) + 3(-57,8) – (-20,24) – 0
= -341,26 kcal/mol
= -1426,5 x 103 J/mol
C2H6o= C2H6 + ro
1 =1–r
r =1 mol/s
O2 =3,5 mol/s
3,5
Mol udara = 0,21 = 16,6 mol

Mol N2’ : mol N2o = 16,6 – 3,5 = 13,1 mol

CO2o: 0 + 2(1)= 2 mol
H2O: 0 +3(1)= 3 mol
 Tref = Ti , maka ∑Fi Hi =0
𝑇 𝑇 𝑇
0=13,1 ∫298 29,4 𝑑𝑇 + 3 ∫298 34,05 𝑑𝑇 + 2 ∫298 19,02 𝑑𝑇 + 1(−1426,5)

(13,1x 29,4(T - 298)) + (3x 34,05 (T – 298)) + (2x19,02 (T – 298 ))= 1426,5x103
T3 = 3013,43 K

C.

F1 = 1MOL
298 K T3 = ?
F3 = ?

S + 02 JADI SO2 (1) CO2 =

ASH = 0,07 SO2 =
S = 0,03 C + 02 JADI C02 (2) H20 = 0
O = 0,02 N2 = 0
H = 0,08
C = 0,8

F2=?
O2 = 0,21
N2 = 0,79
298 K
Reaksi 1 :
∆HR(25oC) – (-70,95) – 0 – 0 = -70,95 kcal/mol
= -296,6 x103J/mol
S: S’+ rⱴ
O: 0,03 – r
r = 0,03
SO2 o= 0,03 mol
Mol O2 = 0,03 mol
0,03
Mol udara = = 0,14
0,21
Mol N2o =0,14 – 0,03 =0,11

Reaksi 2 :
∆HR(25oC) – (-94,05) – 0 + 0 = -94,05 kcal/mol
= -393,13x103J/mol
C: C’+ rⱴ
r= 0,8
O2 o= 0,8 mol
 0,8
Mol udara =0,21 = 3,81
Mol N2o =3,81 – 0,8 = 3,01 mol
O2’ tot = 0,8 + 0,03 = 0,93 mol
Udara = 3,95 mol
N2 = 3,12 mol
q = ∑ F0 H0 - ∑ Fi Hi +∆ Hr
𝑇 𝑇 𝑇
0=0,3 ∫298 19,02 𝑑𝑇 + 0,03 ∫298 25,8 𝑑𝑇 + 3,12 ∫298 29,4 𝑑𝑇 + 0,03 ( -296,6x 103)+ 0,8 (-
393,13x103)
(0,8x19,10(T-298)) + (0,03x25,8(T-298)) +(3,12X29,4 (T-298)= 0,03 ( 296,6x 103)+ 0,8
(393,13x103)
T=3300,3 K

8.15
Q

F2 =
F1 = 1000 Kmol/jam 2 C2H4 + O2  2C2H4O (C1) C2H4=
C2H4 = 0,1 O2 =
C2H4 + 3O2  2C02 + 2H2 (C2)
H20 =0.9 N2 =
373 k C2H4o=
CO =
H2O =513 k
FC2H4 = 1000 X 0,1 = 100 Kmol/jam

Yang bereaksi : 0,25 x Fc2H4 = 25 Kmol/jam

Reaksi 1 : 25 x 0,8 = 20 kmol/jam
2 : 5 kmol/jam

 reaksi 1
2C2H4 + 02  2C2H40
∆HR : 2(-12,58) – 1(12,5) – 0 = -37,66 Kcal/mol
= -157,42 kj/mol = -157,42 x 106 j/kmol

R : 10 kmol/jam
C2H4O = 0 + 2(10) = 20 Kmol/jam
02 = 10 kmol/jam
  reaksi 2

C2H4 + 3 O2  2 CO2 + 2 H2O

∆HR : 2(-94,05) + 2(-57,8) – 0 – 12,3 = -316,2 Kcal/mol
= -1321,72 kj/mol = -1321,72 x 106 j/mol

R = 5 kmol/jam
02 = 15 kmol/jam
C02 = 0 + 5(2) = 10 kmol/jam
H2O = 0 + 5(2) = 10 Kmol/jam

 udara
= 1000 x 0,4 = 900 kmol/jam
 o2 = 0,21 x 900 = 189 kmol/jam
 N2 = 711 Kmol/jam = N2
 02 = 189 – 15 – 10 = 164 kmol/jam

373 373 373

∑F1H1 = 100 ∫298 16,8 𝑑𝑡 + 189 ∫298 29,88 𝑑𝑡 +711 ∫298 29,41 𝑑𝑡

=2118,062 J/Kmol

5,3 5,3 5,3 5,3

∑F1H0 = 75 ∫298 16,8 𝑑𝑡 + 164 ∫298 29,88 𝑑𝑡 +711 ∫298 29,41 𝑑𝑡 + 20 ∫298 17,57 𝑑𝑡 + 10
5,3 5,3
∫298 19,62 𝑑𝑡 + 10 ∫298 34,64 𝑑𝑡

= 5944,6 x 106 j/mol

Q = ( 5944,6 – 2118,062 + 10 (-157,42) + 5 (-1323,723) x 106

= -4556,26 x 10 3 kj/jam
8.16

T2 = 900°F
C3H8 =100% P = 400 psia
T1 = 500°F C3H8 = 0,45
P = 400 psia C3H8 = 0,2
F1 = 100 mol/s C2H4 = 0,05
C2H6 = 2xCH4
CH4 =
H2 =

Neraca Massa
C = 3.yC3H8,i .F1 = 3.yC3H8,2 F3 + 3.yC3H6,iF3 + 2yC2H4,2F3 + 2.yC2H6.F3 + 1yCH4.F3
H = 8.yC3H8,i .F1 = yC3H8,2 F3 + yC3H6,iF3 + yC2H4,2F3 + yC2H6.F3 + yCH4.F3 + yH2.F3

C = 3(1)(100) = 3(0,45)(100) + 3(0,2)(100) + 2(0,05)(100) + 2CH4 (100) + yCH4 (100)

300 = 205 + 200CH4 + 100CH4
95 = 300CH4
CH4 =0,31667

ΔH1 = 1(-24,82[11107,4865 - 12836,96183 + 48732,7795 – 30893,1484 + 6660,44445])

= - 565766,2987 j/kg

CpC2H4 = (7693,4122 + 12396,08453 + 29128,57193 – 27393,88575 +

7716,465653).yC2H4
= 29540,64856 χ 12,50
= 369258,107 j/kg
CpH2 = 0 j/kg
CpC2H6 = (15462,0923 – 3733,6734 + 50742,8899 – 32637,1321 + 6749,2469).yC2H6
= 36583,4236.yC2H6
= 36583,4236 χ -20,24
 = - 740448,4937 j/kg
CpCH4 = (17542,859 – 17724,3078 + 39176,2543 – 20912,8267 + 3890,8346).yCH4
= 21972,8134 χ -17,89
= -393093,6317 j/kg
CpC3H6 = 56773 χ 4,88
= 277052,24 j/kg

ΔH2 = 369258,107 + 0 – 749448,4937 – 393093,6317 + 277052,24

= -487231,7784 j/kg

Q = F2 . ΔH2 – F1 . ΔH1
= 100(-487231,7784) – 100(-565766,2987)
= 7853452,03 j/kg
 8.23 A catalytic reactor is charged with a feed consisting of 5 mol H2 to 1 mol CO2 at 400o C and
5 bar (Figure P8.23). in the reactor the reactions
CO(g)+ 3H2(g) CH4(g) + H2O(g)
CO2(g)+ H2(g) CO(g) + H2O(g)

take place with 90% conversion of CO2. If the reactor operates adiabatically and the exit stream is
at 400o C, calculate the composition of the exi stream.

𝑑𝑄
=0
𝑑𝑇

H2 =5MOL
673 K
CO2 = 1MOL
673K

X = 0,9
analisis derajat kebebasan NM NE
variabel aliran NM 5 5
variabel aliran NE 0 5
persamaan reaksi 2 2
Persamaan TTSL 5 5
persamaan NE 0 1
variabel NE 0 4
komposisi 1 1
laju alir 1 1
hub pembantu 0 0
DK 0 0

XCO2 = 90%
𝑟2
0,9 =0,9×1

r 2 = 0,81
Adiabatik, Isotermal, Tref= 25oC , ∆H1 =0, ∆H2=0
Q=0
Q= r1∆HR (400oC)+ ro∆HR2 (400oC)
∆HR(Tref) =‫ס‬CO ∆Hfco+‫ ס‬H2∆HfH2 +‫ ס‬CH4∆HCH4+‫ ס‬H2O ∆HH2O
= -1 (126,42)+ (-3)(0) + 1(-17,89) +1(-57,80)
= -49,27 kcal/gmol = -206,14568 KJ/mol

673
∫ 𝐶𝑂 = 11615,34
298

673
∫ 𝐻2 = 11050,93
298

673
∫ 𝐶𝐻4 = 17469,99
298

673
∫ 𝐻2𝑂 = 15117,11
298

673
∆HR1 =∆HR(Tref) +∑‫ס‬1∫298 𝐶𝑃 (𝑇)𝑑𝑥

= -206,14568 + (-11615,34 – 3(11050,93) +17469,99 + 15117,11)

= -12387,18 KJ/mol
673
∆HR2 =∆HR(Tref) +∑‫ס‬1∫298 𝐶𝑃 (𝑇)𝑑𝑥

= -206,14568 + (-11615,34 – (11050,93) +17469,99 + 15117,11)

= 9714,68 KJ/mol
Q=0
0= r1∆HR1(400oC) + r2∆HR2(400oC)
r2∆HR2(400)
r1= ∆HR1(400)

0,81 𝑥 9714,68
r1= (−12387,18) = -0,64

CO = -r1 – r2= yCO2. F2

H2 = y H2,1 . F1 – 3r1 – r2 = y H2,2 . F2
CH4=r1=yCH4 . F2
H2O= r1 + r2= y H2O,2 . F2
CO2= yCO2,1 . F1 – r = yCO2,2 . F2
H2 = 0,83(100) – 3(-0,64) – (0,81)= yH2,2. 100
yH2,2 =0,8411
H2O= -0,64+ 0,81 = yH2O,2. 100
yH2O,2=0,0017