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SAFETY DATA SHEET Revision Date: 10.03.2009

Print Date: 29.12.2009
MODAR® 835 S RESIN MSDS Number: R0528578
Version: 1.1

Conforms to Regulation (EU) No. 1907/2006 - MSDS_GB

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE

COMPANY/UNDERTAKING

Ashland Emergency telephone

P.O. Box 8619 +1-800-ASHLAND (+1-800-274-5263/+1-606-329-
NL3009 AP, Rotterdam 5701) , or contact your local emergency telephone
The Netherlands number at 112

[email protected] Product Information

+31 10 497 5000 (in the Netherlands), or contact your
local CSR contact person

Product name MODAR® 835 S RESIN

Product code 337752
Product Use Description no data available

2. HAZARDS IDENTIFICATION

Hazard Summary Highly flammable

Irritant

Risks Highly flammable.

May cause sensitization by skin contact.
Irritating to respiratory system and skin.
Harmful by inhalation.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Components CAS-No. EINECS-No. Concentration Symbol(s) R-phrase(s)

Methyl methacrylate 80-62-6 201-297-1 >=25 - <40% F Xi R11 R37/38 R43
Styrene 100-42-5 202-851-5 >=5 - <10% Xn Xi R10 R20 R36/38

For the full text of the R-phrases mentioned in this Section, see Section 16.

4. FIRST AID MEASURES

General Information
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MODAR® 835 S RESIN MSDS Number: R0528578
Version: 1.1

Move out of dangerous area. Consult a physician. Show this safety data sheet to the doctor in
attendance.

Eyes
Flush eyes with water at least 15 minutes. Get medical attention if eye irritation develops or persists.
Remove contact lenses.

Skin
Take off contaminated clothing and shoes immediately. Wash off immediately with plenty of water.
Wash contaminated clothing before re-use. If skin irritation persists, call a physician.

Ingestion
Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious
person. Consult a physician if necessary.

Inhalation
Move to fresh air. If symptoms persist, call a physician. In case of shortness of breath, give oxygen.

Notes to physician
Hazards: This material is an aspiration hazard. Potential danger from aspiration must be weighed
against possible oral toxicity (See Section 2 - Swallowing) when deciding whether to induce vomiting.

5. FIRE-FIGHTING MEASURES

Suitable extinguishing media

ABC powder, Water mist, Carbon dioxide (CO2), Dry chemical

Unsuitable extinguishing media

DO NOT USE: Halons

Hazardous combustion products

carbon dioxide and carbon monoxide, toxic fumes, Hydrocarbons

Thermal decomposition
no data available

Precautions for fire-fighting

Do not allow run-off from fire fighting to enter drains or water courses. Use water spray to cool
unopened containers. Prevent fire extinguishing water from contaminating surface water or the ground water
system. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with
local regulations. For safety reasons in case of fire, cans should be stored separately in closed containments.

Personal protective equipment

In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment.
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SAFETY DATA SHEET Revision Date: 10.03.2009
Print Date: 29.12.2009
MODAR® 835 S RESIN MSDS Number: R0528578
Version: 1.1

6. ACCIDENTAL RELEASE MEASURES

Personal precautions
Persons not wearing protective equipment should be excluded from area of spill until clean-up has
been completed. Beware of vapours accumulating to form explosive concentrations. Vapours can
accumulate in low areas. Ensure adequate ventilation. Eliminate all ignition sources (flares, flames including
pilot lights, electrical sparks). Pay attention to the spreading of gases especially at ground level (heavier than
air) and to the direction of the wind. Evacuate personnel to safe areas.

Environmental precautions
Prevent further leakage or spillage if safe to do so.

Methods for cleaning up

Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth,
diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations
(see section 13). Keep in suitable, closed containers for disposal.

Other information
Comply with all applicable federal, state, and local regulations.

7. HANDLING AND STORAGE

Handling
Avoid formation of aerosol. Do not breathe vapours or spray mist. Avoid contact with skin and eyes.
For personal protection see section 8. Provide sufficient air exchange and/or exhaust in work rooms. Avoid
exceeding of the given occupational exposure limits (see section 8). Smoking, eating and drinking should be
prohibited in the application area. Take measures to prevent the build up of electrostatic charge. Preparation
may charge electrostatically: always use earthing leads when transferring from one container to another.
Keep product and empty container away from heat and sources of ignition. No sparking tools should be
used.

Storage
Store in original container. Keep containers tightly closed in a dry, cool and well-ventilated place.
Containers which are opened must be carefully resealed and kept upright to prevent leakage. Electrical
installations / working materials must comply with the technological safety standards. Stable under
recommended storage conditions.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure Guidelines
Methyl methacrylate (CAS 80-62-6)
EH40 WEL time weighted average 50 ppm
EH40 WEL time weighted average 208 mg/m3
EH40 WEL Short term exposure limit 100 ppm
EH40 WEL Short term exposure limit 416 mg/m3
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SAFETY DATA SHEET Revision Date: 10.03.2009
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MODAR® 835 S RESIN MSDS Number: R0528578
Version: 1.1

Styrene (CAS 100-42-5)

EH40 WEL time weighted average 100 ppm
EH40 WEL time weighted average 430 mg/m3
EH40 WEL Short term exposure limit 250 ppm
EH40 WEL Short term exposure limit 1,080 mg/m3

General advice
These recommendations provide general guidance for handling this product. Personal protective
equipment should be selected for individual applications and should consider factors which affect exposure
potential, such as handling practices, chemical concentrations and ventilation. It is ultimately the
responsibility of the employer to follow regulatory guidelines established by local authorities. Keep away
from food, drink and animal feedingstuffs. When using do not eat, drink or smoke. Ensure that eyewash
stations and safety showers are close to the workstation location.

Exposure controls
Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below
level of overexposure (from known, suspected or apparent adverse effects).

Eye protection
Safety glasses with side-shields

Skin and body protection

Wear as appropriate:
Safety shoes
Flame-resistant clothing
Wear resistant gloves (consult your safety equipment supplier).

Respiratory protection
When workers are facing concentrations above the exposure limit they must use appropriate certified
respirators.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state liquid

Form liquid
Colour coloured
Odour pungent
Boiling point/boiling range 100.50 °C @ 1,013.23 hPa, Calculated Phase Transition
Liquid/Gas
Melting point/range no data available
pH no data available
Flash point 12.80 °C, Seta closed cup
Evaporation rate no data available
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SAFETY DATA SHEET Revision Date: 10.03.2009
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MODAR® 835 S RESIN MSDS Number: R0528578
Version: 1.1

Lower explosion limit/Upper explosion no data available

limit
Vapour pressure 51.32 hPa @ 25 °CCalculated Vapor Pressure
Vapour density no data available
Density no data available
Solubility no data available
Partition coefficient: n-octanol/water no data available
log Pow no data available
Autoignition temperature no data available
Viscosity, dynamic 500 mPa.s
Viscosity, kinematic no data available

10. STABILITY AND REACTIVITY

Stability
Stable under recommended storage conditions.

Conditions to avoid
Heat, flames and sparks. Exposure to moisture., Exposure to sunlight., Exposure to air.

Incompatible products
Acids, Amines, alkalis, aluminum, aluminum chloride, Bases, Copper, Copper alloys, halogens, iron
chloride, metal salts, nitrates, Peroxides, reducing agents, Strong oxidizing agents, UV light

Hazardous decomposition products

carbon dioxide and carbon monoxide, toxic fumes, Hydrocarbons

Hazardous reactions
Hazardous polymerisation may occur. Vapours may form explosive mixture with air.

11. TOXICOLOGICAL INFORMATION

Routes of exposure
Skin contact, Eye Contact, Ingestion, Inhalation

Eye contact
May irritate eyes.

Skin contact
Causes skin irritation. May cause allergic skin reaction.Causes skin irritation.

Ingestion
Not known to be harmful if swallowed.
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MODAR® 835 S RESIN MSDS Number: R0528578
Version: 1.1

Inhalation
Irritating to respiratory system.

Aggravated Medical Condition

Preexisting disorders of the following organs (or organ systems) may be aggravated by
exposure to this material: Skin, Upper respiratory tract, lung (for example, asthma-like conditions), Liver,
kidney, auditory system, male reproductive system, Central nervous system

Symptoms
Signs and symptoms of exposure to this material through breathing, swallowing, and/or passage of
the material through the skin may include: irritation (nose, throat, airways), Cough, Shortness of breath,
Difficulty in breathing, loss of appetite, stomach or intestinal upset (nausea, vomiting, diarrhea), irritability,
Lack of coordination, confusion, effects on memory, pain in the hands and feet, Lowered blood pressure,
kidney damage, liver damage, central nervous system depression (dizziness, drowsiness, weakness, fatigue,
nausea, headache, unconsciousness) and other central nervous system effects, Exposure to this product (or a
component) may cause an allergic reaction (narrowing of the air passages of the lungs resulting in difficult
breathing, tightness in the chest, coughing and wheezing) in some sensitive individuals. Other symptoms of
an allergic reaction may include itchy and watery eyes, runny and stuffy nose, sweating, flushing, hives,
rapid heart rate, and lowered blood pressure.

Target Organs
Overexposure to this material (or its components) has been suggested as a cause of the
following effects in humans: mild effects on color vision, effects on hearing, respiratory tract damage (nose,
throat, and airways), central nervous system effects

Component data

Acute oral toxicity

Methyl methacrylate LD 50 Rat: 7,800 mg/kg

Styrene LD 50 Rat: 2,650 mg/kg

Acute inhalation toxicity

Methyl methacrylate LC 50 Rat: 3,750 mg/l , 8 h

Styrene LC 50 Rat: 2800 ppm, 4 h

Acute dermal toxicity

Methyl methacrylate no data available

Styrene no data available

12. ECOLOGICAL INFORMATION

Product information

Aquatic toxicity
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MODAR® 835 S RESIN MSDS Number: R0528578
Version: 1.1

no data available

Environmental fate and pathways

Biodegradation
no data available

Bioaccumulation
The bioaccumulation potential cannot be determined.

13. DISPOSAL CONSIDERATIONS

Waste disposal methods

Dispose of in accordance with the European Directives on waste and hazardous waste. Dispose of in
accordance with local regulations. Container hazardous when empty. Do not contaminate ponds, waterways
or ditches with chemical or used container.

Empty packaging
Empty remaining contents. Dispose of as unused product. Empty containers should be taken to an
approved waste handling site for recycling or disposal. Do not re-use empty containers. Do not burn, or use
a cutting torch on, the empty drum.

European Waste Catalogue

The Waste code should be assigned in discussion between the user and the waste disposal company.

14. TRANSPORT INFORMATION

ADR
UN 1866 RESIN SOLUTION 3 II
ADNR
UN 1866 RESIN SOLUTION 3 II
RID
UN 1866 RESIN SOLUTION 3 II
INTERNATIONAL MARITIME DANGEROUS GOODS
UN 1866 RESIN SOLUTION 3 II
INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO
UN 1866 Resin solution 3 II
INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER
UN 1866 Resin solution 3 II
Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific
exceptions that can be applied. Consult shipping documents for descriptions that are specific to the
shipment.
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MODAR® 835 S RESIN MSDS Number: R0528578
Version: 1.1

15. REGULATORY INFORMATION

Product Use Description

no data available

Hazard symbols

Highly flammable Irritant

R-phrase(s)
R11 Highly flammable.
R37/38 Irritating to respiratory system and skin.
R43 May cause sensitization by skin contact.

S-phrase(s)
S9 Keep container in a well-ventilated place.
S16 Keep away from sources of ignition - No smoking.
S23 Do not breathe vapour.
S24 Avoid contact with skin.
S37 Wear suitable gloves.
S51 Use only in well-ventilated areas.

Contains
Methyl methacrylate CAS 80-62-6

16. OTHER INFORMATION

Full text of R-phrases referred to under sections 2 and 3

R37/38 Irritating to respiratory system and skin.
R43 May cause sensitization by skin contact.
R11 Highly flammable.
R20 Harmful by inhalation.
R10 Flammable.
R36/38 Irritating to eyes and skin.
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SAFETY DATA SHEET Revision Date: 10.03.2009
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MODAR® 835 S RESIN MSDS Number: R0528578
Version: 1.1

The information accumulated herein is believed to be accurate but is not warranted to be whether originating
with the company or not. Recipients are advised to confirm in advance of need that the information is
current, applicable, and suitable to their circumstances. This MSDS has been prepared by Ashland's
Environmental Health and Safety Department (+31 10 497 5000).