Source rocks at Svalbard: An overview of Jurassic & Triassic Formations and

Comparison with Offshore Barents Sea time-equivalent source rock Formations

Tesfamariam Berhane Abay1*, Dag Arild Karlsen1 and Jon Halvard Pedersen2
1. Department of Geosciences, University of Oslo, Postbox 1047 Blindern, N-0316 Oslo, Norway, *: contact: [email protected]
2. Lundin Norway As, Lysaker, Norway, Postbox 1172 Blindern, N-0318 Oslo, Norway

Introduction Study area

The Svalbard Archipelago, located in the Arctic region, holds source rocks of great
importance to the understanding of the Petroleum systems in the Barents Sea and B
the Circum-Arctic Region. Vast Mesozoic sedimentary successions are exposed on
the major islands. A
The key targets of this study were to identify the source rock potential and describe
the organic matter (OM) in terms of total organic carbon contents (TOC),
hydrocarbon potential, organic facies, and level of maturity in more detail and from SD BP
more varied localities than previously accomplished. Forty-nine outcrop samples (38
Triassic, 10 Upper Jurassic, and 1 Lower Jurassic), mostly shales and mudstones,
from 4 different locations at Svalbard have been analysed geochemically by Rock-
eval, gas chromatography - flame ionization detection (GC-FID), mass spectrometry
(GC-MS) and stable isotope.

The outcrops represent the following Formations (Fms): Botneheia, Tschermakfjellet, Map of Svalbard and location of the samples

De Geerdalen, Vikinghøgda (all Triassic) and Agardhfjellet (Upper Jurassic). Some of

the results from these Fms were compared with time equivalent Offshore Barents Fig. 1: Svalbard (A) and its position in the Arctic Ocean and Barents Sea (B). Sample localities are indicated by numbers. Most samples originate
from Edgeøya (location 1 and 2), south-eastern of the Svalbard archipelago. Structural elements in the Barents Sea (B): LH: Loppa High, HFB:
Sea Steinkobbe (1.5-9% TOC) and Hekkingen (3-16% TOC) Fms. Hammerfest Basin, NKB: Nordkapp Basin, SD: Svalis Dome, BF: Bjarmeland Platform, FP: Finnmark Platform, AH: Admiralty High, NBB: North
Barents Basin, SBB: South Barents Basin, TP: Timan Pechora Region.

Hydrocarbon potential
A

B
Fig. 3 : Plot of total organic carbon (TOC, wt. %) vs S2 (mg HC/g Fig. 4: Modified van Krevelen diagram with hydrogen Index (HI) plotted vs Fig. 5: Modified van Krevelen diagram with hydrogen
rock), showing the source rock potential of the samples. Most oxygen Index (OI). Most samples from the Blanknuten locality of the Index (HI) plotted vs Oxygen Index (OI) for Middle Triassic
samples from the black shale Botneheia Fm contain higher S2 and Botneheia Fm show high HI values (HI = greater than 300), early to steinkobbe Fm at Svalis Dome, Offshore Barents Sea. The
TOC content, suggesting very good to excellent source rocks. Most moderate maturity, Type II kerogen and thus oil potential. The rest of the samples from core 2 (Dia 84-2, IKU) show wide variation in
of the rest samples are fair to good hydrocarbon source rocks. samples show lower HI, high maturity and thus capable of generating gas. HI and OI ranging from Type II to Type III kerogen.

Maturity

Fig. 2: (A) Triassic succession outcropping at Edgeøya, southeastern

Svalbard (from Krajewski, 2008). Vikinghøgda Fm (Early Triassic,
dominantly dark grey shales, mudstones and siltstones); Botneheia Fm
(Middle Triassic, darker, mostly black shales and mudstones, phosphatic in
the upper part); Tschermakfjellet Fm (Late Triassic, marine dark grey to
black shales and siltstones with common clay−ironstone (sideritic) Fig. 6: HI vs Tmax. All samples are within oil Fig. 7: X-Y plot of production index (PI) vs Tmax Fig. 8: Cross plot of two vitrinite reflectances Fig. 9: Plot of diasteranes/(diasteranes+regular
concretions); De Geerdalen Fm (deltaic sandstone). The Upper Jurassic window maturity. Samples from Blanknuten for samples at Muen and Blanknuten areas. The calculated from peak heights of phenanthrene steranes) vs Ts/(Ts+Tm) indicating maturity. The
Agardhfjellet Fm is not shown in the succession. (B) Soxtec extracts show early to medium maturity. Agardhfjellet, maturity at Muen is higher than maturity at and its methylated isomers. On y-axis, F1 = (3+2- ratios increase with maturity, and are valid for the
sorted according to the color of the extractable organic matter (EOM). The Tschermakfjellet and most of the samples from Blanknuten. The plot indicate excellent MPs)/(3+2+1+9-MPs) (Kvalheim et al., 1987); on whole oil window. This Fig indicates same maturity
Middle Triassic Botneheia Fm at the Blanknuten locality show darker EOM Festningen and Muen localities contain OM of correlation between, PI = S1/(S1 + S2) and x-axis, MPI1 = 1.5(3+2-MPs)/(P+9+1-MPs) trend as Figs 6-8, thus good maturity correlation
and is clearly the best source rock at Svalbard. high maturity (0.88<Ro<1.35). Tmax. (NB: Hunt, 1996 used used depth instead of Tmax). (Radke et al., 1982). from biomarker, Rock-Eval and aromatic HCs.

LU-33 (Botneheia Fm @ Blanknuten)

Facies
LU-02 (Botneheia Fm @ Muen) Pr/Ph = 1.70
Pr/Ph = 1.74 Pr/n-C17 = 0.99
Pr/n-C17 = 0.80 Ph/n-C18= 0.69
Ph/n-C18= 0.51

Hekkingen
LU-52 (Agardhfjellet Fm @ LU-33 (Lower Jurassic @ Festningen) Snadd and Kobbe
Myklegardfjellet) Pr/Ph = 1.73 Agardhfjellet
Pr/Ph = 2.11 Pr/n-C17 = 0.45
Pr/n-C17 = 0.81 Ph/n-C18= 0.23
Ph/n-C18= 0.43

Steinkobbe
Botneheia

Fig. 11: Plot of pristine /phytane (Pr/Ph) ratio versus the sum of methyl-dibenzothiophenes Fig. 12: Stable carbon isotope abundance of the saturated
(MDBT)/the sum of methyl-phenanthrenes (MP), suggesting variation in depositional setting of the and aromatic hydrocarbon components indicating the
OM at Svalbard and in the Norwegian Barents Sea. The Upper Jurassic Agardhfjellet Fm at Svalbard
depositional setting of the OM that yielded the HC in the
Fig. 10: Examples of gas chromatograms for Triassic and Jurassic Fms at Svalbard. Pr = Pristane, Ph = Phytane, n-alkanes are is more oxic than its time equivalent Hekkingen Fm in the Barents Sea. Likewise, the OM in the the
Middle Triassic Botneheia Fm is more oxic compared to the Steinkobbe Fm at Svalis Dome. studied samples ( after Sofer, 1984).
indicated. The Pr/Ph ratio of the Agardhfjellet Fm is higher than those for Triassic Fms.

Conclusions References
•Hughes, W.B., Holba, A.G., and Dzou, L.I.P., 1995, The ratios of dibenzothiophene
 Both Jurassic and Triassic sediments have potential for oil and gas generation, and the best source rocks at Svalbard lie within the Triassic Botneheia Fm. to phenanthrene and pristane to phytane as indicators of depositional environment
and lithology of petroleum source rocks: Geochimica et Cosmochimica Acta, v. 59,

 Most samples from the Botneheia Fm at the Blanknuten locality are characterized by high TOC (5-10%), high hydrogen index (HI) (400-600 mg HC/g TOC),
p. 3581-3598
•Krajewski, K. P. 2008. The Botneheia Fotmation (Middle Triassic) in Edgeøya and
Barentsøya, Svalbard: Lithostratigraphy, Facies, Phosphogenesis,
low PI (0.04-0.1), Tmax (439-446 ºC), suggesting that these source rocks are early- to mid-mature and composed of oil-prone Type II kerogen. Paleoenvironment. Polish Polar Research, 29, 319–364.

 Most samples from the Botneheia Fm at the Muen locality have also very good TOC (2.4-6.2%) but lower HI (124-184 mg HC/g TOC), higher PI (0.12-0.32), •Kvalheim, O. M., Telnaes, N., Bjorseth, A. and Christy, A. A., 1987: Interpretation
of multivariate data; relationship between phenanthrenes in crude oils. Multivariate
higher Tmax (448-457°C) , indicating that the samples are at late oil maturity stage and have probably generated and expelled significant oil, and that they statistical workshop for geologists and geochemists., Kvalheim, O. M., Ed.,
Elsevier, 149-153.

are still capable of generating gas (i.e., currently gas prone Type III kerogen). •Peters, K.E., and Moldowan, J.M., 1993, The biomarker guide: interpreting
molecular fossils in petroleum and ancient sediments: Englewood Cliffs, N.J.,
 The samples from the Upper Jurassic Agardhfjellet Fm at the Myklegardfjellet/Agardhbukta locality show values of TOC (2.2-5.9%), HI (77-121 mg HC/g Prentice Hall, XVI, 363 s. p.

TOC), and Tmax (452-465°C), implying type III gas prone OM that is presently within the late oil window maturity stage. •Radke, M., Welte, D. H. and Willsch, H., 1982a: Geochemical study on a well in
the western Canada Basin; relation of the aromatic distribution pattern to maturity
 Isotope and biomarker data suggest shallow/open marine facies for most samples from Middle Triassic Fms and marine but with great input from terrestrial of organic matter. Geochimica et Cosmochimica Acta, 46, 1-10.

for Upper Jurassic Agardhfjellet Fm. •Hunt, J.M., 1996, Petroleum geochemistry and geology (2nd edn): W. H. Freeman
& company, New York, 743pp.

 Comparison with Offshore Barents Sea data show variation in both HC potential and organo facies source. The Steinkobbe Fm (1.5-9% TOC) and the
Hekkingen Fm (3-13% TOC) from offshore Barents Sea contain organic matter derived from more anoxic depositional facies compared to the Botneheia Fm Acknowledgements
at Muen and the Agardhfjellet Fm, respectively. Lundin Norge AS is thanked for projec funding and constructive cooperation.

 Samples from Svalbard are more mature compared to their time-equivalent Formations Offshore Barents Sea. Idemitsu and RWE Dea, license partners of Lundin are also greatly acknowledged.