Kitchen Improvised Fertilizer

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KITCHEN IMPROVISED

FERTILIZER EXPLOSIVES

By Tim Lewis
COPYRIGHT 1985

INFORMATION PUBLISHING CO.


P.O. Box 10042
Odessa, Texas 79767-0042

All rights reserved!!!


Absolutely no part may be reproduced in
any manner or form without the express
written consent of the author and
Information Publishing Co.!!
TABLE OF CONTENTS
P R I L L E D FGAN - #2 FUEL OIL. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . l
P R I L L E D FGAN - #2 FUEL OIL (Cap sensitive) ... . . . . . . . . . . . . . . . . . . . . . 9
P R I L L E D FGAN - POWDERED COALOR CHARCOAL . . . . . . . . . . . . . 11
P R I L L E D FGAN - GASOLINE. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13
P R I L L E D FGAN - ANTIFREEZE. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15
P R I L L E D FGAN - MAGNESIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17
P R I L L E D FGAN - NITROGLYCERIN . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19
P R I L L E D FGAN - METHANOL OR ETHANOL . . . . . . . . . . . . . . . . . . . . . . 23
P R I L L E D FGAN - ALUMINUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25
P R I L L E D FGAN - MONONITRONAPTHALENE . . . . . . . . . . . . . . . . . . . . . . 27

POWDERED FGAN - #2 FUEL OIL . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31


POWDERED FGAN - ALUMINUM POWDER . . . . . . . . . . . . . . . . . . . . . . . . . . 33
POWDERED FGAN - DIETHYLENE GLYCOL (Antifreeze) . . . . . . . 35
POWDERED FGAN -
HEXAMETHLYENETETRAMINE ADDUCT . . . . . . . . . . . . . . . . . . . . . . . 37
POWDERED FGAN - NITROGLYCERIN . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 39
POWDERED FGAN - NITROMETHANE (Astrolite) . . . . . . . . . . . . . . . . . . . . 43
POWDERED FGAN - METALLIC NITRATE . . . . . . . . . . . . . . . . . . . . . . . . . . 45
POWDERED FGAN - RED PHOSPOROUS - COFFEE . . . . . . . . . . . . . . . . . 47

FGAN-HEXAMINE-NITRIC ACID GELATIN . . . . . . . . . . . . . . . . . . . . . . . . . . . 49


FGAN-HEXAMINE OR UREA GELATIN . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 51
FGAN-ANTIFREEZE-SMOKELESS POWDER GELATIN . . . . . . . . . . . . . . . 55
FGAN-MONOMETHYLAMINE NITRATE GELATIN . . . . . . . . . . . . . . . . . . . 57
FGAN-SLURRY COMPOSITION #1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 59
FGAN-SLURRY COMPOSITION #2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 61
FGAN-SLURRY COMPOSITION #3 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 63
FGAN-SLURRY COMPOSITION #4 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 65

CAST FGAN-WAX FOAMED CHARGE (Cap Sensitive) . . . . . . . . . . . . . . . . 67


CAST FGAN-FUEL OR CHNO EXPLOSIVE ("Ammonex") . . . . . . . . . . . . 71
CAST FGAN-MONOMETHYLAMINE NITRATE ("FORMIT")................ 73

FGAN-HYDRAZINE (HYDRAZINE NITRATE) . . . . . . . . . . . . . . . . . . . . . . . . 75


FOREWARD

The U.S. standard of living is falling slowly. At the bottom of this fall are
countries like Kenya and Pakistan. The youth of America is not interested in
bettering themselves and their country, but just in partying and having a good
time. What they don't realize is that this advancement of our culture is necessary.
Time after time I have heard them say, "But I CAN'T" There is not such thing as
can't. Instead what they mean is they won't. Quite a difference in my book. It
saddens me greatly to see this. 1 will partly put the blame on our educational
system. Of course, the American people should receive the bulk of the blame.
This should also be placed on the parents of Americans, as they let themselves
and their kids be brainwashed on T.V. I personally know I have never learned
anything of real value on T.V. that can't be thought of off hand. Every day we see
liberal programming on the "tube" with a one sided slant. I don't believe the
people should allow themselves to be brainwashed. With the advent of
subliminals and their use on T.V. (yes, they use them today on most commercials
contrary to popular belief) proves the desire of a few to control the populace.
Stupid people (brainwashed) or people sheltered from reality as in the
U.S.S.R. are the easiest to control. They can do this. Reams of government
research on the subject of control of minds have been carried out.
IT'S YOUR RESPONSIBILITY TO KNOW WHAT'S GOING ON, NOT
SOMEONE ELSE'S. YOUR M I N D IS YOURS TO ENJOY AND USE, NOT
FOR SOMEONE ELSE TO GET I N S I D E OF AND CONTROL. THIS IS
THE WORST TYPE OF THEFT!!

WARNING!!!

The procedures in this book can be dangerous. The compounds produced in


these procedures are or can be dangerous. The actual manufacture of explosives
is illegal and classified as a felony. These processes are given as information and
information only! The actual use of this information by persons not familiar
with proper laboratory procedures and. safety can be dangerous if not fatal.
Students of explosives should obtain a good college level chemistry book and
laboratory procedure handbook. Reasonable care has been used in the
compilation of this book and this information has been presented for it's
educational value only. Due to the nature of these explosive compounds, neither
the publisher or the author can or will accept any responsibility for this
information and it's subsequent use. All responsibility is assumed by the
reader!!!!!!
PRILLED FGAN-#2 FUEL OIL (Diesel)
DETONATION RATE - 2,000-4,400 M/sec ... 6,550-14,410 Ft./sec.
DETONATION PRESSURE - 565,000, 900,000 P.S.I.
DENSITY OF LOADING - .98 to 1.2 G/cc.. Density is controlled by the
prills size and bulk density. Users need not worry, as this is already controlled for
them.

SENSITIVITY - requires a 1/4 to 1/2 stick of dynamite, 50-100 G. high explosive


(T.N.T., P.E.T.N., Picric acid, etc.), Detonating cord ("Primercord" or
equivalent), 200 G. of other cap sensitive AN explosive (powdered, foamed case,
red phosporous-AN, etc.). Shock sensitive to a 30 cm. drop of a 2 Kg. weight.

USE-
BLASTING - It's use is very versatile due to the very pourable nature of the
finished product. It must be used in large diameter bore holes (4 inches and
larger) that are dry. If wet bore holes are encountered, the charges can be loaded
in plastic containers (polyethylene bags or trash bags or equivalent). Good earth
mover and finds a great use as a ditching or earth-pond blasting.
DEMOLITIONS - It's use is limited. It can be used to blow foundations,
bridge and building substructures with below ground charge placement next to
the target.
MUNITIONS - Again it's use is limited as very heavy cases are required with
good charge containment. Fragmentation is 30-50% as good at T.N.T.. It will,
however, work in this role, but very large charges are required, as the the user
must count on the large long duration blast wave to kill by concussion alone as
fragment generation is considered poor. As a grenade filler, it will work, but
other explosives would be a better choice.
SAFETY PRECAUTIONS - Very stable, but should be made up as needed.
AN should be kept dry to ensure proper detonation. This explosive is a definite
fire hazard. Flame and heat should be avoided. Not shock sensitive as explosives
go, but can be detonated by a very sharp blow (30cm drop of a 2 Kg. weight will
detonate). Copper and brass should be avoided in manufacture and all
munitions loading and finished products.
Ammonium nitrate fuel oil explosives are without a doubt the most widely
used explosive on the face of the earth. It has gained this title by it's low price,
ease of on site manufacture and it's good blasting characteristics. Ease of
acquisition and relative high power, make this explosive very desirable to home
or calindistine manufacture. Being comparable to 40% dynamites, their blasting
efficiency can be considered the same for all practical purposes and charge
computation figures for 40% dynamite can be used to begin calculations.
To manufacture these ANFO (prilled) explosives, the procedure is very
simple. The AN prills are placed in a container. The proper amount of fuel oil or
diesel is added and the mixture is intimately mechanically mixed. For smaller
batches of the explosive, an empty, clean and dry coffee can may be used. The
mixing in this type of small batch is best done by hand by simply rolling the
explosive mixture on the floor after the plastic lid is firmly in place. This should
be done for fifteen to twenty minutes. Larger coffee cans may be used for slightly
larger batches. Clean and dry empty five gallon cans could be used to make even
larger batches with slightly longer mixing times. With large blasting operations
the ideal manufacture technique is to use a cement mixer. A small portable type
will work very satisfactorily. With these larger size batches, mixing times should
be increased to 1 hour. Another trick to obtaining a good stable standardized
explosive is to paint the outside of the cement mixer black. Since operations of
this magnitude will always be performed outside and on site, sunlight will heat
the mixture and promote the best dispersion of the fuel oil throughout the prilled
AN. Of course, all AN explosives should be kept dry and all containers and
mixing apparatus should be completely free of moisture and contact with the
atmosphere (humidity) should be avoided.
The mixture's proportions can vary somewhat with the desired purpose.
Lesser fuel percentages down to 1% total weight will give an explosive that is a
little easier to detonate and has the higher detonation rates. Mixtures with a fuel
concentration of over 5% will give more power and a greater heaving force and a
lower detonation rate, but require heavier boosters. Addition of 1-5% "Bullseye"
smokeless powder, give a composition of greater strength and more detonation
sensitivity and greater detonation rate than figures at the beginning of this
section. Also a .25-1% addition of "Tide" or "Mr. Bubble" soaps, as with other
AN explosives, will increase the performance of the finished explosive mixture.
The percentages by weight are as follows for ANFO (prilled) explosives:

AMMONIUM NITRATE (fert. grade) . . . . . . 94.5%


FUEL OIL or DIESEL . . . . . . . . . . . . . . . . . . . . . 5.5%

This explosive is the best and safest of the blasting explosives! For all general
blasting work, dollar for dollar, it is the best explosive for 85% of all blasting
operations.
PRILLED AN-FUEL OIL (Cap sensitive)
DETONATION VELOCITY
Confined - 4600 M/sec.
Unconfined = 3200-4600 M/sec.
DETONATION PRESSURE - 490,000-1,000,000 P.S.I.

SENSITIVITY - One #8 blasting cap will initiate detonation in charges larger


than 2.25 inches, but similar untreated prills will not detonate.

USE-
BLASTING - Useful in blasting due to the fact that it is easy and very
inexpensive to prepare. This prilled form of the usual ANFO explosives is
attractive to the blaster because in nearly all applications this type of prilled
ANFO explosive will have a higher detonation rate and therefore an increased
performance over it's counterpart.
DEMOLITION - See PRILLED AN-FUEL OIL
MUNITIONS - See PRILLED AN-FUEL OIL
This is a very interesting development of the ANFO explosives. While being
very simple, it effectively sensitizes the fertilizer grade of AN when mixed with
diesel, so that one blasting cap will detonate the resulting mix. It makes use of the
tendancy of even small amounts of water to effect the crystalline structure of the
prills in such a way that effective density is lowered. This, in conjunction with
available fuel, yields an explosive that is cap sensitive. This is one of the most
simple cap sensitive explosive compositions in this book.
This procedure really should be performed of all prilled AN explosives. This
lowers the actual density of the prills. Giving an optimum density for the proper
absorbtion of most ANFO. Compositions with 94.4% AN and 5.6% fuel oil are
considered optimum. These will also be cap sensitive. The fuels in the
compositions below are considered slightly higher than the AN FO explosive due
to sensitivity and performance respectively. Take 40 G. of ammonium nitrate
prills (fertilizer grade) and to them add 10 G. (lOcc) water. This mixture is heated
to 90 degrees C. (195 degrees F.). All of the prills should dissolve. If not stir the
liquid until they do. This liquid (saturated AN-water solution) is then added to a
mixture of 14 G. #2 diesel and 186 G. ammonium nitrate prills (fert. grade). This
mixture is stirred and poured into a suitable container (stainless steel pan) and
placed in an oven with the thermostat set at 150 degrees F. for 2.5 hours with
constant supervision. Ammonium nitrate when mixed with fuels are dangerous
when heated. Better and safer than this is to place these wetted prills in a
desicator (laboratory drier) or in a container with a vacuum drawn on it and it's
contents so as to remove the water. This vacuum method of water removal is best
and will yield the highest performance mixtures. In boiling water off the AN
prills under reduced pressure porous prills are produced by the water vapor
escape from inside the prills.
These prills will produce cap sensitive mixtures easily with almost any liquid
hydrocarbon. Fuel oil, naptha, gasoline, carbondfdisulfide and almost anything
liquid that will combust will work.
AMMONIUM NITRATE (Fert, prills) . . . . . . . . . 40 G. or 14.6%
WATER . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10.cc or 4.0%

AMMONIUM NITRATE (Fert, prills) . . . . . . . 186 G. or 74.4%

GASOLINE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 G. or 2.5%
WAX (PARIFFIN) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9 G. or 3.1%
or
DIESEL . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7 G.
ALUMINUM POWDER (400 Mesh) . . . . . . . . . . . . . . . . . . . 14 G.

This procedure should work on other liquid fuels except the very volatile ones
such as gasoline and the alcohols giving easily prepared cap sensitive explosive
compositions. Also the substitution of 14 G. of powdered aluminum for 7 G. of
the diesel will give a slightly higher performance explosive.

Untreated prills. Treated prills.


PRILLED AN-POWDERED COAL OR CHARCOAL
DETONATION VELOCITY - 2400-3500 M/sec.
DETONATION PRESSURE - 390,000-800,000 P.S.I.

USE-
BLASTING - Limited to earth moving and other blasting operations where
high "heaving" value and not high velocity are the factors influencing explosive
choice. A very cheap easily manufactured blasting agent with a cost effectiveness
not easily surpassed in most bulk blasting operations.
DEMOLITIONS - Not a good choice due to the very low detonation rate and
relative bristance.
MUNITIONS - Not a good choice here either due to the low velocity and low
bristance or shattering power.
A good cheap blasting agent. This explosive should be limited to earth moving
applications and with a preference for the prilled AN-fuel oil explosive over this
explosive. In all, with easy acquisition of the sensitizer, this composition is one of
the better home concocted explosives for a blasting application. Coal or
charcoal is readily available and cheap. This explosive is manufactured by the
addition of the powdered charcoal to the prills and subsequent tumbling or
shaking to ensure an intimate mixing of the components. A major drawback of
this mixture is the tendancy for the charcoal and the AN to separate out due to
the different actual densities of the two ingredients. A small percentage (1-2%) of
fuel oil substituted for part of the charcoal, causes the charcoal to adhere to the
prills and virtually eliminate this problem. Actual composition of these
explosives are given below:

#1
PRILLED AN . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 94%
CHARCOAL (powdered dust) ..................... 6%

#2
PRILLED AN . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 94%
CHARCOAL (powdered dust) . . . . . . . . . . . . . . . . . . . 5%
#2 FUEL OIL OR DIESEL . . . . . . . . . . . . . . . . . . . . . 1%

Minimum charge diameter of the first formula should be around 8 inches.


Whereas the 2nd formulation can be used in bore holes 6 inches or greater in
diameter. Water and wet blasting condition should be avoided with the first
composition due to the lack of water tolerance. The 2nd explosive has a slightly
greater tolerance, but with all AN explosives, unless they are designed for wet
applications, water and wet conditions should be avoided.
PRILLED AN-GASOLINE
DETONATION RATE - 2700-4650 M/sec.
DETONATION PRESSURE - 190,000-1,100,000 P.S.I.

SENSITIVITY - Same as prilled An-Fuel oil. Perhaps slightly more sensitive,


but adequate boosters are required to ensure an efficient detonation.

USE-
BLASTING - Not suitable due to the volatility of the fuel sensitizer. Could be
used if the volatile nature were taken into account and steps taken to counter act
this fuel sensitizer loss due to evaporation. A powerful higher velocity explosive
as opposed to AN-fuel oil explosives. Also cost effective due to the ready access
and low cost of the sensitizer.
DEMOLITIONS - Not suitable due to the volatile nature and relative low
velocity of detonation. For more about usage, see prilled An-fuel oil explosive.
Volatility could be overcome to some extent if necessary by on site mixing and
immediate use!!
MUNITIONS - Unsuitable!!
This explosive is limited in use due to it's volatile nature. The gasoline will
evaporate with time, giving erratic performance and detonation sensitivity. It is
easier, however, to make than the prilled AN-fuel oil composition. The lower
density of the fuel makes for better penetration of the AN prills and also gives an
explosive of higher detonation velocity and consequently slightly higher actual
power. It is easily prepared by simply pouring the gasoline over the AN prills in a
container impervious to gasoline and tumbling until a homogeneous mixture is
obtained. As with the other prilled AN explosives, higher performance can be
obtained by the addition of .5 to 1% total explosive weight of sodium dodecyl
benzene sulfonate ("Tide", "Mr. Bubble" soaps or Connaco 50 detergent). The
explosive consists of the following mixture:

PRILLED AN . . . . . . . . . . . . . . . . . . . . . . . . . . . . 94%
GASOLINE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6%

This explosives volatile nature can be overcome to some extent by enclosing


the mixed explosive composition in something impervious to gasoline. Large
trash bags would serve this purpose. The explosive would need to be used
quickly, however, as this measure would not be enough to ensure the explosives
loss of sensitizer to evaporation. Better explosive composition can be had, but
this one would work and is powerful!!
PRILLED FGAN-ANTIFREEZE
DETONATION RATE - 2700-4500 M/sec.
SENSITIVITY - See FGAN-Fuel oil.

USE-
BLASTING - Use is limited due to the high cost of the diethylene glycol
(antifreeze). It is also very hygroscopic. Good power and slightly greater
detonation rate than the FGAN-Fuel oil composition. Good for earth moving
and other similar uses. Cost effectiveness less than that of FGAN-Fuel oil.
DEMOLITIONS - See Prilled FGAN-Fuel oil.
MUNITIONS - Hygroscopic. See Prilled FGAN-Fuel oil.

A good explosive if the ethylene glycol or antifreeze is all the manufacturer has
available. It is slightly easier to detonate than the FGAN-Fuel oil composition
and has a greater detonation rate, all things being equal. Boosters would not
need to be quite as large as the FGAN-Fuel oil mixture would require. It is also
very hygroscopic and steps should be taken to ensure that the contamination of
the mixture with unwanted moisture is avoided.
This explosive is manufactured in essentially the same way as all the other
explosive compositions in this book so far. For details of these manufacture
techniques, see Prilled FGAN-Fuel Oil. The composition is as follows:

PRILLED FGAN . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 95.0%


DIETHYLENE GLYCOL (Antifreeze) . . . . . . . . . . . 5.0%

This glycol-AN explosive like the methanol and ethanol compositions are
very efficient. Since the glycols and glycerins are in effect forms of alcohols, they
perform similarly. Glycerin could be substituted for the glycol, but it's cost is
even higher than glycol. Addition of a small amount of "Tide" or "Mr. Bubble"
(e.g. sodium dodecyl benzene sulfonate) will increase the performance and
detonation rate by 15-35%.
PRILLED FGAN-MAGNESIUM
DETONATION RATE - 2600-4200 M/sec. 8536-13,790 Ft./sec.
DETONATION PRESSURE - 400,000-1,000,000 P.S.I.
SENSITIVITY - See Prilled FGAN-Aluminum.

USE-
BLASTING - See Prilled FGAN-Aluminum
DEMOLITIONS - See Prilled FGAN-Aluminum
MUNITIONS - See Prilled FGAN-Aluminum
This explosive composition is nearly identical to the Prilled FGAN-
Aluminum explosive. It is, however, a slightly more bristant, more powerful
explosive. This is due to the higher temperature of the combustion of the
magnesium powder as opposed to the aluminum powder. As with the FGAN-
Aluminum composition, this explosive gives an abnormal gas volume on
detonation. This will give this explosive a greater blast effect than most of the
explosives in the ammonium nitrate family. As with all good aluminum
containing explosives, they are oxygen deficient. This allows an after burning
effect. By this I mean the unreacted or oxidized fuel (Magnesium), preheated to
combustion temperature, is allowed to finish its combustion with the
atmospheric oxygen. This gives these explosives a high blast rate due to the long
pulse of positive pressure generated by the detonation. Aluminum is really
preferable to magnesium, due to its much lower cost. It will, however, on
detonation at night give a much brighter flash than will the aluminum. This is, of
course, due to the greater temperature of detonation, which causes a more
luminous candescence of the gases in the fireball. This boils down to a very
bright flash upon detonation in low light conditions. It should cause temporary
night blindness too!! Its composition is as follows:

PRILLED FGAN . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 80%


MAGNESIUM POWDER (300+mesh) . . . . . . . . . . . . . . . . . 20%
PRILLED AN-NITROGLYCERIN
DETONATION RATE - 2800-4800 M/sec.
DETONATION PRESSURE - 450,000-1,000,000 P.S.I.
Depending on % of nitroglycerin
SENSITIVITY - This factor depends on the % of nitroglycerin. A 4%
composition requires a 1/4 stick of dynamite or equivalent. An 8-15%
composition requiring only a #6 blasting cap.

USE-
BLASTING - A good explosive for this purpose with a high bristance and
detonation rate. Very sensitive to the impulse from a reasonably small #6
detonator. However, this explosive due to the nature of the explosive sensitizer
would be limited to someone with prior chemistry experience. There is danger in
manufacture of this explosive!! While millions of gallons of nitroglycerin have
been manufactured since its introduction into the explosive field, home
manufacture by the unknowing, stupid, careless and suicidal WILL RESULT
MOST LIKELY IN DEATH!! This explosives manufacture should never be
undertaken unless the procedure is completely understood. THERE IS NO
ROOM FOR ERROR OR CARELESSNESS!!!! This explosive will, with
contact to the skin, cause the most tremendous migrain headache. Repeated and
continuous exposure to the skin and subsequent absorbtion will cause "nitro
heart" and possible future coronary problems and risks. Also contact with
detonation residues and gases will cause these same headaches and risks. The
powdered form of this explosive is a better choice as larger amounts of "nitro"
can be absorbed safely. For charge computation use 50% ammonia dynamite.
DEMOLITIONS - This explosive could be good for cratering charges, but is
not as cost effective as ANFO explosives. The powdered form of this explosive
would be a better choice, as it is more easily packaged and will hold a higher
percentage of "nitro".
MUNITION - The only munition this explosive would even be remotely good
for, would be some type of homemade fragmentation grenade.
First usage of this type explosive was made by the famous father of modern
explosives, Alfred Nobel. He purchased the patent from C.J. Ohlsson and J.H.
Norrbin in the early 1870's. This should give you some idea of how long these
explosives have been in use. They are powerful, primarily blasting explosives.
They have been supplemented in the modern explosives industry due to the cost
advantage of AN fuel oil explosives. These, however, are more powerful, due to
the higher heat of explosion which is a side effect of the "nitro" compounds
addition to the prilled ammonium nitrate. The "nitro" makes the explosive
resistant to water, which in some applications is advantageous. As the
nitroglycerin is added to the AN prills it forms a gel of AN and nitroglycerin on
the surface of the prill. This serves in the carrying of the shock wave generated by
the detonator throughout the explosive charge. This of course gives the
ammonium nitrate a higher detonation rate with only the addition of a small
amount of the high explosive sensitizer.
NITROGLYCERIN MANUFACTURE - The manufacture of nitroglycerin
is really a simple affair. The tendancy of nitroglycerin to explode from a shock (a
slight jar), heat (overheating of the acids during manufacture) and decompose
(explosively) from impurities make the manufacture a testing one. It can be done
with a good deal of safety by eliminating as many of the above problems in
manufacture. Only reagent or U.S.P. grade chemicals should be used. This will
eliminate the possibility of explosive decomposition from impurities. The
explosive oils sensitivity to shock can be reduced by careful control of the
temperature and avoiding bumps and jars of the containers during the
"nitration" process. The process below will not give as good a yield as the process
in "KITCHEN IMPROVISED PLASTIC EXPLOSIVES". It is, however, in
my opinion, a simple relatively safe process for the person not inept in chemistry
and laboratory processes.
CAUTION: Eye protection and viton gloves and apron should be worn during
this lab type process. Hash facilities (a shower) should be quickly accessable.
This process should be done in a well ventilated area!!
Take 100 ml. (CC) of nitric acid (specific Gravity 1.42, 70%, obtained from a
chemical lab. supply house) and place in a 1 pint fruit canning jar. 150 m. (CC) of
sulfuric acid (specific gravity 1.8, 98% / obtained from janitorial supply) is then
slowly poured into the nitric acid. This acid mixture will become hot when this
addition takes place. This container should be placed in a bath of salted ice
water. Care should be taken to ensure that none of the water gets into the acid
mixture. That would cause spattering of the hot acid mixture and big problems
for the person with the acid shower. A thermometer is placed into the mixed
acids. The temperature of the mixed acid should be allowed to drop to 0 degrees
C. (32 degrees F.). While the acids cool, place 80 ml. (CC) anhydrous glycerin in
a measuring cup. This cup should be placed in the freezing compartment of a
refrigerator or cooled in someway taking care to ensure water is not absorbed by
the glycerin. A quart canning jar is then filled to 1/2 its volume of crushed ice and
clear clean cold water. When the acids are at 0 degrees and the glycerin is as thick
as cold molasses or "Karo" syrup, the glycerin is slowly poured in to the acid
mixture in a manner that it floats on top of the cold mixed acids.
CAUTION: If at any time red fumes begin to issue from the acid-glycerin
combination, pour immediately with a gloved hand into the water and cracked
ice previously prepared!!!!!!!
With a teflon stirrer carefully stir the mixed acid and glycerin combination
TAKING GREAT CARE NOT TO CONTACT THE SIDES OR BOTTOM
OF THE CONTAINER!!! This stirring should be done vigorously and carefully
for 15 seconds and the whole mixture then immediately poured in to the cracked
ice. The nitroglycerin will fall out as a whitish oil in the bottom of the container.
Care should be taken to avoid bumping the lip of the jar with anything and the
container kept completely free of shocks and bumps. The acid-water is then
poured off the nitroglycerin oil in the bottom of the container. Cold water is then
added to the "nitro" in the bottom of the quart canning jar. The liquids are
carefully swirled and as much water poured off as possible. This washing is
carried out one more time with the excess water being poured off. The resulting
oil and small amount of water is then treated with small amounts of sodium
bicarbonate (baking soda). The soda at first will effervesce (fizz). These
additions should be made until the effervescent reaction ceases with new small
additions of soda. The remaining water can then be removed with a syringe
carefully. Care should be taken not to bump the bottom of the container with the
syringe. The nitroglycerin should now be incorporated into the explosive.
ADDITION OF 25% ACETONE TO THIS EXPLOSIVE OIL WILL
RENDER IT MUCH LESS SENSITIVE TO SHOCK AND IS ADVISED!!!
To manufacture this explosive simply add the nitroglycerin to the AN prills
with gentle kneading with gloved hands (dishwasher gloves will work, but
should be discarded afterwards). The charcoal or other ingredient is added to the
AN before this nitro addition if desired. This addition will give a more powerful
explosive and is very desirable. If explosive is to be used immediately, the
addition of the fuel will not be necessary as the acetone will serve this purpose.
Below several compositions are given:

#1
PRILLED AN . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 88%
ONE OF THE FOLLOWING: CHARCOAL, DIESEL OIL
ANTIFREEZE, SULFUR, MOTOR OIL . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7%
NITROGLYCERIN . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5%

#2
PRILLED AN . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 83%
ALUMINUM OR MAGNESIUM POWDER (400 MESH) . . . . . . . . . . . . . 10%
NITROGLYCERIN . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7%

#3
PRILLED AN
.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 79%
FUEL (ONE FROM COMPOSITION #1) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6%
NITROGLYCERIN . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15%

#4
PRILLED AN .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 72%
ALUMINUM OR MAGNESIUM POWDER (400 MESH) . . . . . . . . . . . . . 13%
NITROGLYCERIN . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15%

These explosives should be safe and very powerful for the compositions
containing higher percentages of nitroglycerin. The last two explosive formulas
will be the most easily detonated by a blasting cap. The last two will not need
confinement to achieve a good explosion, but the first formulations are
primarily for blasting purposes. The compositions containing aluminum should
have nitroglycerin additive containing as little water as possible which will give a
better performance and longer storage life.
PRILLED FGAN-METHANOL OR ETHANOL
DETONATION RATE - 2800-4500 M/sec. 9193-14775 Ft./sec.
SENSITIVITY - Same as prilled FGAN-#2 fuel oil.

USE-
BLASTING - Practically the same as prilled FGAN-#2 fuel oil. This explosive
is less water tolerant as the FGAN-FO mixture. It also has a slightly higher
detonation rate for all practical purposes. But has a higher cost due to the
increased cost of the sensitizer.
DEMOLITIONS - See Prilled FGAN-Fuel Oil.
MUNITIONS - Not desirable due to the very volatile nature of the sensitizer.
For performance see Prilled FGAN-Fuel oil.
This explosive is a good explosive, but the tendancy of the sensitizer to
evaporate before the charge is ready for detonation is a major problem. This can
be over come by sealing the prepared charges in an impervious container to
avoid this evaporation. It also has a characteristic of being very hygroscopic,
which is the tendancy to take water from the air which makes detonation more
difficult. It is, however, a good powerful explosive composition. Its higher
detonation rate over the AN-fuel oil composition is a definite plus. The figures
above do not really reflect this however. This greater detonation rate is realized
in charges that are not so well confined. An explanation of this is the less viscous
(thick) shorter simpler molecule is more easily transformed under the impulse of
the detonation wave as it moves through the explosive triggering the rapid
transformation from solid to gaseous state.
This explosive is more quickly manufactured due to the less dense fuel
sensitizer. This gives a more rapid and uniform absorbtion into the fertilizer
prills. The manufacture is accomplished by placing the proper amount of AN
prills in a container. Addition of the proper ratio of alcohol is the next step.
These are stirred or tumbled together until a complete uniform mixture is
obtained. The percentages are as follows:

P R I L L E D FGAN . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 94%
METHANOL or ETHANOL ALCOHOL . . . .. ... .. .. .. ... .. .. .. ... .. 6%
This explosive is, as we stated earlier, sensitive of moisture and this should be
avoided in any storage or usage. One advantage of this explosive is the fact that it
produces very modest amounts of harmful gaseous detonation products, this
explosive would be the explosive of choice if usage in a semi-confined area where
work would need to commence right after the shot is fired! It is not permissable
in a coal mine due to the heat and longer period of high detonation product heat.
This can be overcome by the following composition:

P R I L L E D FGAN . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 82.5%
METHANOL or ETHANOL ALCOHOL . . . . . . . . . . . . . . . . . . . . . . . . . 7.5%
SODIUM CHLORIDE (table salt) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10.0%

This deviation from the composition above above, gives the explosive an
excess of fuel which lowers the flame temperature and the sodium chloride
further cools the flame temperature. This composition will give a higher
percentage of carbon dioxide in the gaseous products yield, but you can't have
your cake and eat it too!!!
AMMONIUM NITRATE-ALUMINUM EXPLOSIVE
DETONATION RATE - 2600-3700 M/sec.
DETONATION PRESSURE - 650,000-1,320,000 P.S.I.
SENSITIVITY - Same as Prilled FGAN-#2 fuel oil explosive

USE-
BLASTING - Its use in blasting is limited due to the increased cost of the
aluminum component which drives up the cost per c u / f t earth moved. It is,
however, better at most tasks than AN-FO explosives. It has a definite potential
in blasting very hard rock and in usages where the bore holes are time consuming
to prepare. For charge computation, a reduction of 20% in total charge weight
can be utilized from FGAN-Fuel oil explosives.
DEMOLITIONS - Surpassed by the powdered AN-AL explosives and other
explosive formulations in this book. Best used in below ground usage although
in a thin case (6 inch and greater diameter pipe having a thick wall) it can find
above ground demolition use. Another interesting use would be in large scale
(washtub sized) shaped charges. Most targets could be defeated easily with the
exceptions of thick steel or armor plate and very heavily reinforced concrete
using 200 Ib. charges with good tamping (surrounding explosive on all sides with
the exception of the side of the charge facing the target) and with the correct
stand-off distance (distance from target to the face of the explosive). Multipoint
detonation would be a must for maximum efficiency.

MUNITIONS - This explosive should be a relatively good choice for loading


larger munitions. While none of the ammonium nitrate explosives with the
exception of some case AN explosives, some pressed AN explosives and AN
explosive containing CHNO explosives are very good choices for munitions this
could be used and as a concussion munitions filler. A fifty five gallon drum filled
with this explosive should produce blast overpressures in excess of 1000 P.S.I..
This should kill in excess of a 300 meter radius of the point of detonation if laced
with detonation cord which would raise the detonation rate of the entire charge.
It would also be audible for 5 to 10 miles depending on the conditions existing at
the time of detonation (i.e.-atmospheric/ temperature inversion etc.).
This explosive is another composition utilizing the AN in the prilled fertilizer
grade. It is a powerful explosive utilizing the great heat of the transformation ot
aluminum into its oxidized state. Most people have heard of "Thermite" and the
same oxidation which generates the 4000 degree heat in thermite give this
ammonium nitrate explosive its greater power and blast coefficient. Ideally
these explosives should be mixed with a 20% negative oxygen balance to ensure
the afterburning affect of the aluminum powder in the air. This will lengthen the
pressure pulse created by detonation. Its manufacture is simple. Prilled
ammonium nitrate (fertilizer grade) and aluminum (preferably fine powdered
e.g. black German "pyro"grade) are mixed together in a suitable container in the
following proportions:
AMMONIUM NITRATE (fertilizer grade 32%+ nitrogen) . . . . . . . . . . . 82%
ALUMINUM POWDER (200 mesh or greater) . . . . . . . . . . . . . . . . . . . . 18%

The aluminum powder used ideally should be of a flaked grade (paint grade)
which is cheaper than the "black" pyro grade and even the atomized will work
well. A lower performance but workable substitution could be made for part of
the aluminum powder with small chips (oilfree) of aluminum as produced in a
machine shop in turning or bandsawing operations. These components are
mixed in a clean dry container. The mixing should be carried out until an
intimate mixture is obtained. The different densities of the two components will
make this mixing difficult, so the addition of 1% total weight of diesel oil will
cause tha aluminum to stick to the granules of ammonium nitrate and raise
charge sensitivity. This fuel oil addition will also make the mixture propagate
detonation a little better. This explosive composition should be kept dry and free
from moisture, as moisture in this composite explosive will start an almost
immediate but slow break down yielding hydrogen as a by product. This
presence of moisture will also make the explosive difficult, if not impossible to
detonate without the use of a very heavy booster charge or charges. One last
note, as with the FG AN-FO explosives, this explosives' properties are improved
up to 30% by the addition of .5 to 1% "Tide" or "Mr. Bubble" or any detergent
containing Sodium dodecyl benzenesulfonate.

(L) Atomized aluminum powder


(R) German flake aluminum powder
PRILLED FGAN-MONONITRONAPATHENE
DETONATION RATE - Dependant on amount of MNN 4200-5700 M/sec.
DETONATION PRESSURE - 725,000-1,600,000 P.S.I.
SENSITIVITY - One #8 cap will detonate but use of a booster (50
G. P. E. T. N., 1/2 stick hi-vel dynamite) will obtain maximum performance.
Higher loading densities (1.4 and greater) will require large boosters and good
confinement to perform correctly.

USE-
BLASTING - A good explosive for blasting, but for most purposes ANFO
explosives will do as good a job with less work and less cost per Cu/ft. earth
moved. Good for blasting tunnels, hard rock and other uses where a shattering
effect is required and smaller charges would be more advantageous.
DEMOLITIONS - A better shaped charge explosive than some other
explosives listed in this publication due to its higher detonation rate. Not as good
as T.N.T. in this respect, but it is a usuable explosive nonetheless. For this
purpose, a mold would have to be made to produce suitable charges. Also a good
demolition explosive in a stick or cylindrical form. Can be used in the place of a
good gelatin dynamite for demolition purposes.
MUNITIONS - One of the better explosives in this book for this purpose. Can
be used to load grenades, morter rounds and large caliber shells. Armor piercing
("heat") use should be avoided as the detonation velocity is not quite high
enough for good formation of a suitable "linear jet" capable of penetrating thick
armor plate. For use, this explosive is loaded while still hot and pressed into the
shell or munition desired. Can be hand stemmed (packed) with a wooden or
"Teflon" or heat insensitive plastic rammer rod while hot in most munitions with
the exception of shells and morter rounds with

Approximate pressure required:


DEMOLITION CHARGES . . . . . . . . . . . . . . . 2000 P.S.I.
GRENADES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2000 P.S.I.
MORTER AND SHELLS . . . . . . . . . . . . . . 8000+P.S.I.

This explosive is powerful and stable. It should find


a good use as its properties are preferable over other explosives in this book. The
drawbook of this explosive is the preparation of the mononitronapthalene
While it is a simple and safe process, to manufacture this product is not
expediant. All in all the process is worth the trouble due to the great increases of
the explosives performance over other explosives in this book.

MONONITRONAPATHENE MANUFACTURE
Mononitronapthalene is the product of the nitration of napthalene with a
mixed acid mixture of nitric and sulfuric acids at 50 degrees centigrade.
Napthalene is a common coal tar chemical. It should be available in the form of
moth balls. Check the ingredient lable of moth balls to find the active ingredient.
When the correct mothballs are found with a napthalene active ingredient, they
should be acquired. They will then need to be purified. This is not entirely
necessary, but will increase the yield on MNN. This can be done by powdering
the mothballs and placing the powder in four times the powders weight of
petroleum ether or chloroform.
CAUTION: Avoid breathing the dust or fumes and contact with the skin with
the acids, mothballs, napthalene and the finished product as they are all
dangerous'!!!1
The powder will all or nearly all dissolve. This liquid should then be allowed to
evaporate.
CAUTION: This should be done in a place with good ventilation away from all
sparks and flame as petroleum ether is unbelievably flammable!!!!
The yellowish crystals remaining after evaporation should be napthalene that
is relatively pure. These crystals are then weighed. In a separate beaker a mixture
of 48% Nitric acid and 52% sulfuric acid is prepared. The nitric acid can be the
70% grade which is readily available and the sulfuric should be the 98% grade
with specific gravities of 1.42 and 1.8 respectively. All percentages are by weight.
To mix these acid care should be taken and they should be poured together
slowly. CAUTION: Eye protection is a must!!!! The total weight of the acid will
need to be known. Per 100 G. of mixed acid will nitrate 100 G. napthalene. The
correct amount of napthalene is then added to the mixed acid eg. 250 G. mixed
acid will nitrate 250 G. napthalene. The acid nitration mixture is stirred. A
thermometer is placed in the mixture. The beaker is placed on a heat source. An
electric hot plate would work fine. The mixture is heated to 75 degrees centigrade
while stirring. It is held at this temperature for 30 minutes while stirring is
continued. The contents of the beaker is then poured into 3 times its volume of
cold water. The mononitronapthalene will immediately drop out of the solution.
It is then filtered out and washed twice with cold water and once with warm
water. It can be used as is or purified by dissolving in chloroform, diethyl ether or
methyl alcohol and allowing the liquid to nearly evaporate completely. The
crystals are then filtered out and dried and are ready for use.
One would now be ready to manufacture the finished explosive. The
percentages of aluminum powder and MNN can be varied with greater
percentages of aluminum giving a greater blast effect. Powdered charcoal can be
used in place of the aluminum with lesser performance. Greater percentages of
MNN giving higher detonation velocity. Explosive composition is as follows:

FGAN (prilled) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 80%


MONONITRONAPTHALENE . . . . . . . . . . . . . . . . . . . . . . . . 10%
ALUMINUN or POWDERED CHARCOAL . . . . . . . 10%
This FGAN is gently heated in a suitable container (stainless steel, Enameled
steel, pyrex glassware) with a thermometer in place. The prills should be stirred
to prevent uneven heating in the container. The MNN is placed in a container as
above and heated until melting. When the temperature reaches 115 degrees
centigrade, the MNN is added and will melt. This mixture is stirred until a
uniform coating of the prills with MNN occurs. The temperature is then reduced
to 100 degrees C. while the stirring is continued. The flaked or atomized
aluminum powder is added while the stirring is continued. The stirring is kept up
until a uniform coating with the aluminum powder is achieved and the explosive
is then ready to press in the desired munition.
POWDERED AN-FUEL OIL OR DIESEL
DETONATION RATE - 3600-4750 M/sec.
DETONATION PRESSURE - 578,000-1.087,000 P.S.I.
SENSITIVITY - Cap sensitive when loaded at a density of .86 G/cc or less.
Sensitive to a small dynamite booster (1/4 stick) to loading density of 1.2 G/cc.
These figures are for a slightly confined charge (can, bottle or paper tube) at 5
cm. in diameter. Lower loading densities with the "soap" additive will allow a
reduction of the useable charge diameter to 4 cm. while retaining #8 cap
sensitivity.
LOADING DENSITY - Cap sensitive-.86 G/cc. with addition of .5% "Tide",
"Mr. Bubble" or sodium dodecyl benzene sulfonate will allow a higher loading
density of .96 G/cc. with #8 cap sensitivity. Loading densities of up to 1.55 G/cc.
can be achieved by pressing the explosive into the proper container. At this
density these charges will require a large booster (1/2 stick of gelatin dynamite, 50
grams of either R.D.X., C-4, T.N.T., P.E.T.N. (from det. cord), Picric acid, or
other explosives of similar power and detonation velocity).

USE-
BLASTING - Comparable to 40% ammonia dynamite. High gas yield and
decent "shattering power". Low cost makes this explosive attractive for this
purpose. Also of importance is the ability of this explosive in a cap sensitive
loading density to perform the initiation of Prilled AN-fuel oil explosives and
other prilled explosives.
DEMOLITIONS - Comparable to 40% ammonia dynamite. With detonation
pressures in excess of 800,000 P.S.I, and its low cost this explosive could be
useful in demolition in special applications. The powdered AN-AL would be a
better choice but the addition of 10-20% total explosive weight of "Bullseye"
smokeless powder would bring this explosive into an equivalent of 70% straight
dynamite (see formulas below). This would be a better choice for demolition
application, but would also increase the cost of the finished explosive by
approximately 2000%.
MUNITION - Not really suitable. The powdered AN-AL explosive is a much
better choice. Can be used, but better explosive formulations are available.
This explosive has good power and is very cost effective. Its components are
readily available and could be obtained without any question. The charge
diameter is important as it is with all AN explosives. Charge diameters of 40 mm
should be contained in light containers such as beer bottles, empty cans (steel),
cardboard shipping tubes or something of similar strength. The 500 ml plastic
"Coke" bottles would work fine and are cheap and easily available in useable
quantities by a little late night garbage can scrounging. The advantage of these 1/2
liter bottles is the easy attaching of a handle (broomstick) and simple ringing of
the outside of the bottle with nails taped or otherwise attached to the
circumference of the bottle. This would produce a grenade with a good throwing
range and a 3.5-8 meter lethal radius. Varying the size of the nails gives the
variations in lethal radius. The explosive filler if the grenade where to be thrown
would need some protection to ensure the loading density would not go past the
cap sensitive range upon impact with the ground which would cause a dud. This
could be overcome by either using a booster with the cap which would be ideal or
the addition of fine saw dust equivalent to 5% total explosive weight in
conjunction with the soap additive composition below. This would lessen the
tendancy of the explosive filler to pack but would also lower the detonation
velocity and effectiveness. The AN-AL powdered explosive would be a good
choice also for filling this type of munition.
To manufacture this explosive, take AN which has been previously powdered
to a very fine consistancy (see Powdered AN-AL explosive for methods of
particle size reduction). To this is added the fuel oil or diesel in the proper
amount. This is thoroughly mixed. If desired, the small amount of "Tide" is
added to this mixture after it has been reduced to the consistancy of flour. This
addition is highly recommended due to the enhancement of the detonation and
sensitivity characteristics of the explosive and decreasing somewhat the
sensitivity when packed or "dead pressed" with the subsequent loss of sensitivity.
Of course this mixture should be kept from all moisture and stored in a
waterproof container until ready for use. The explosive consists of the following:

#1
AMMONIUM NITRATE (Fertilizer grade)
Fine powdered . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 94.5%
F U E L O I L or DIESEL . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5.5%

#2
AMMONIUM NITRATE (Fertilizer grade)
Fine powdered . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 94.5%
FUEL OIL or DIESEL . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5.5%
"TIDE", "MR. B U B B L E " or S O D I U M DODECYL
BENZENE SULFONATE (added to the explosive mixture
above so that is consits of .5% of the total explosive weight)

#3
AMMONIUM NITRATE (Fertilizer grade)
Fine powdered . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 94.5%
FUEL O I L or DIESEL . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5.5%
"BULLSEYE" SMOKELESS POWDER (added to the
above explosive mixture so that it consists of 20% total
explosives weight)

These explosives are in order of power and detonation velocity. #1 being the
lowest and #3 being the highest. The addition of the smokeless powder to the
explosive formula gives a high explosive of greater detonation velocity than the
figures given at the beginning of this section.
POWDERED AN-ALUMINUM
DETONATION RATE - 3400-4600 M/sec.
DETONATION PRESSURE - 700,000-1,350,000 P.S.I.
SENSITIVITY - Sensitive to one#8 cap at a density of .95 G/cc.. Sensitive to
1
/4 stick of dynamite or equivalent to density 1.25.
LOADING DENSITY - Cap sensitive .95 G/cc. or less. Booster sensitive
density .96-1.25. Density related to detonation velocity up to 1.2 G/cc.

USE-
BLASTING - Comparable to 50% straight dynamite. High shattering effect
and long duration pressure pulse. Comparable to AN blasting slurries not
containing nitro compounds.
DEMOLITIONS - Comparable to 50% straight dynamite. Good pressure
curve but for some demolition purposes is unsatisfactory. Not as high a
detonation pressure but has a longer duration. The higher densities of loading
even though requiring a booster are the most efficient charges for this useage.
Nitro additives would make this explosive a better choice for this field of use.
MUNITIONS - Pressed to a high density (1.35-1.5 G/cc.) this is a good
munition filler. Requires a very heavy charge for a booster (R.D.X., P.E.T.N.,
Comp. B) to ensure a good detonation. Should be pressed into the munition
(shell, grenade or bomb). Addition of 10% to the total weight of the explosive
below of P.E.T.N. (detonation cord filler), R.D.X. or T.N.T. will give a better
shell filler. It will also give an explosive with better less demanding detonation
cap requirements. A good filler for offensive grenades due to the tremendous
concussive effect.
This explosive has a great blast effect due to the huge amount of high
temperature gases (1400-1800 degrees celsius) produced by the detonation
process. The pressure wave goes out from an explosion like a ripple from a
pebble thrown into a pool of water. The difference in this explosive to others in
this book and unaluminized explosives is this wave presses on the target up to
four times as long as other explosives. A lower pressure for a longer amount of
time will nearly always do more work or damage. The detonation of atomic
weapons uses the same long duration lower pressure pulse that we are talking
about here. This pulse or shock front is visible at a distance from the point of
detonation. If the reader has ever watched films from WWII or the Vietnam
police action showing airborne camera footage and noticed the white area of
compressed air radiating from the point of detonation of a bomb, you saw a
visible shock wave. Imagine this white area 4 times as thick and you'll get "the
picture".
This explosives manufacture is simple. The fertilizer grade ammonium nitrate
is powdered with a mortar & pestle or ground in a similar manner. This should
be done until the consistancy of face powder is obtained. This powdering can
also be accomplished by dissolving the AN prills in boiling water (30% water,
70% AN). This liquor might need to be gently heated to get the AN to completely
dissolve. This should be done in a pyrex or preferably stainless steel container.
This liquor is then poured in a stainless steel cookie baking tray so that it is 1 / 8 to
3/16 inch deep This tray is then placed in an oven set on the lowest temperature
that the oven will operate (160 degrees F, 70 degrees C ideally) This
temperature should be checked with a oven thermometer or candy thermometer
before the AN liquor is placed in the oven When the proper temperature is
achieved, the cookie sheet is placed in the oven with the door slightly ajar to
allow the water being driven off to escape This liquor should be allowed to
remain in the oven for 18-22 hours The remaining crystals will be very easily
b r o k en up and are the ideal crystal structure and size for explosives
manufacture
To this powder the aluminum powder is added Pyro grade 400 mesh is the
best aluminum for this explosive Atomized grades of aluminum will work, but
the highest performance is realized with the pyro aluminum This mixture is
tumbled in a sealed container until a uniform mix is obtained
CAUTION Breathing of aluminum dust is hazardous and should be avoided
Respirators are cheap and well worth the trouble and expense
This explosive can be initiated with a blasting cap if the lower densities can be
obtained The addition of sawdust is given in one formula below so that the
lower densities are ensured The last formulas are given for munition loading
The addition of 25- 75% total explosive weight of "Tide" will give an explosive
less sensitive to density changes and more sensitive to detonation

#1
AMMONIUM NITRATE (Fert grade powdered) . . . . . . . . . . . . . . . . . . . 80.0%
ALUMINUM POWDER
(Flaked prefered, but atomized will work) . . . . . . . . . . . . . . . . . . . . . . . 20.0%

#2
AMMONIUM NITRATE (Same as in #1) . . . . . . . . . . . . . . . . . . . . . . . . . . 80.0%
A L U M I N U M POWDER (Same as in #1) . . . . . . . . . . . . . . . . . . . . . . . . . . 15.0%
SAW DUST ... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5.0%

#3
AMMONIUM NITRATE (Same as in #1) . . . . . . . . . . . . . . . . . . . . . . . . . . 85.0%
A L U M I N U N POWDER (Flaked only) . . . . . . . . . . . . . . . . . . . . . . . . . . . 9.0%
STERIC ACID .... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6.0%
POWDERED AN-DIETHYLENE GLYCOL
DFTONATION RATE - 3400-4600 M/sec
DETONATION PRESSURE - 650,000-1,040,000 P S I
SENSITIVITY - 95 G/cc is the ideal density to load this explosive At this
density the ability to take a detonation impulse from a #6 cap is excellent at a
minimum charge diameter of 4 0 cm (1 6") Higher densities while still
detonatable will require a 50 G dynamite or other high explosive booster
charge

USE-
BLASTING - A good cheap blasting explosive comparable to 50% ammonia
dynamite Alcohols and glycols are some of the best fuels for AN explosives The
only drawback of this explosive is its relative sensitivity to moisture which can
cause charges to become insensitive to a blasting caps' impulse This can be
overcome by proper packaging of the final explosive in such a way that moisture
imperviation can be obstructed ( e g P V C pipe, polyethylene tubes, empty
coffee cans, etc )
DEMOLITIONS - Limited in this useage by low velocity and proportionately
low bnstance (shattering power) as opposed to other demolition explosives
M U N I T I O N S - Unsuitable due to sensitive nature and hygroscopic
properties
This composition is an interesting one It has good power and is very
inexpensive to manufacture One of the attractive properties of the explosive is
its high cap sensitivity One #6 blasting cap will detonate this explosive The
disadvantages are the relatively hygroscopic nature of the formula The addition
of guar gum or other high mole weight polysaccharide will reduce the tendancy
for this to occur but this only gives a slow protection from moisture Guar gums
are available (eg "Guartec"&"Gengel"TM'S of the Henkel Corp Minneapolis
M I N N ) that will effectively block the migration of moisture into the finished
explosive formulation These products find an almost exclusive use in the
explosive industry and could possibly arouse suspicion in their acquisition The
use of diethylene glycol (antifreeze) as the fuel in the explosive is a good choice
This is due to the fact that glycol is a form of alcohol and alcohol is one of the
best fuels for AN explosives Also the addition of 1% aluminum raises the total
heat of the gases formed on detonation which subsequently give the explosive a
greater bnstance As with most of the explosive formulas in this publication the
manufacture of this explosive is a simple affair The AN is powdered and the
diethylene glycol (antifreeze) is added in the proper proportions and throughly
mixed To this mixture the a l u m i n u m powder and guar gum are added and
mixed to obtain a well blended mixture To this the proper amount of paraffin
wax, that has been previously reduced to as small a particle size as possible, is
added This particle size reduction can be obtained by rubbing a block of wax
against a cheese grater or chopping in a food processor The mixture is t h e n
mixed until a uniform composition is obtained This explosive is then loaded
into the charge configuration desired (16" or 40mm diameter or greater) at a
loading density of 95 G/cc or less The percentages of the ingredients are given
below
POWDERED AN (Fert, grade) . . . . . . . . . . . . . . . . . . . . . 90.0%
ETHYLENE GLYCOL (Antifreeze) . . . . . . . . . . . . . . . . . . 5.0%
ALUMINUM POWDER (400 mesh) . . . . . . . . . . . . . . . . . . 1.0%
G U A R G U M . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.0%
PARAFFIN WAX (small part, size) . . . . . . . . . . . . . . . . . 2.5%

This will give a strange semi-gelatin explosive that is somewhat powdery. It is


simply pressed into the container and the explosive is ready to use. Below is
another explosive formula that should work well and have a slightly higher
performance parameter:

POWDERED AN (Fert. grade) . . . . . . . . . . . . . . . . . . . . . 90.0%


ETHYLENE GLYCOL . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5.0%
A L U M I N U M POWDER (400 mesh) . . . . . . . . . . . . . . . . 2.5%
G U A R G U M . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.0%
PARAFFIN WAX (small part, size) . . . . . . . . . . . . . . . . . 1.0%

This should be a little less cap sensitive, but will still most likely detonate from
a #6 cap except at low temperatures (0 degrees C. and below).
POWDERED
AN-HEXAMETHYLENETETRAMINE ADDUCT
DETONATION RATE - 4050 M/sec.
DETONATION PRESSURE - 725,000 P.S.I, (est.)
SENSITIVITY - Sensitive at a density of .95 G/cc to one #6 cap. Higher
densities yield higher detonation rates but are not cap sensitive and require a 1A
stick of dynamite booster or equivalent.
LOADING DENSITY - For cap sensitive mixtures loading D. should be held
below .95 G/cc. Higher densities up to 1.3 G/cc can be loaded, but detonation
sensitivity is such to require heavy boosters.

USE-
BLASTING - Comparable to 40% ammonia dynamite. High toxic fume
production of this explosive limits its use to one where prevalent winds can carry
these toxic fumes in a safe direction, away from the user.
DEMOLITIONS - Can be used as a 40% ammonia dynamite substitute.
Detonation rate is not really high enough for good demolition use.
MUNITION - Required low density for reliable detonation is a limiting
factor. For more use information, see Powdered AN-Aluminum.
This explosive is cheap and cap sensitive and these are the major reasons for its
place in this publication. It is a powerful explosive and would be an excellent
choice for a home blaster.
Hexamethlyenetetramine is quite a mouthful to say but is a perfect fuel for AN
explosives due to its high stability. For its manufacture from ammonia water
and formaldehyde solution see KITCHEN I M P R O V I S E D PLASTIC
EXPLOSIVES. It can also be bought as ration heating tablets from any army
surplus store (eg. Hexamine fuel tabs). Also available under the following
names: "Ammoform", "Hexamethylenamine", "Aminoform", "Ammoform",
"Formin", "Urotropin".
The adduct used in the explosive is simple. Two molecules of AN links with
one of hexamine. The adduct is manufactured by simply evaporating the water
from 700 G. hexamine/800 G. AN/600 ml. water solution. This evaporation
should be done by placing a shallow pan of the dissolved salts in water solution
under an electric fan for 24 hours. A slush of crystals with the remainder of the
solution should then be filtered. A buchner filter (vacuum filter) is ideal but not
necessary. The crystalline substance remaining on the filter should be washed
with anydrous acetone. This should remove most of the water remaining in the
adduct. The adduct should then be ground with a mortar and pestle to a very fine
consistancy. After the grinding or powdering is complete the adduct should be
washed once more with fresh anhydrous acetone. This should remove the
remaining water from the crystals. They are then pressed, to remove as much
acetone as is possible and the adduct is then ready to be incorporated into the
final explosive mixture.
The adduct produced is a weak molar explosive and until mixed with AN is
very safe to handle. This adduct is then mixed with the proper amount of
powdered ammonium nitrate and the mixture loaded into the form in which it is
to be used. The explosive composition is as follows:

AMMONIUM NITRATE (Fert, grade)


Finely powdered . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 80%
ADDUCT (Hexamine-AN) . . . . . . . . . . . . . . . . . . . . . . . . . 20%

The explosive should be used in explosive cartridge diameters greater than


1.25 inch or 32 mm.

Simple adduct acetone wash set-up.


POWDERED AN-NITROGLYCERIN
DETONATION VELOCITY -
20% NG-4400 M/sec.
30% NG-5150 M/sec.
40% NG-5700 M/sec.
DETONATION PRESSURE - 400,000-3,500,000 P.S.I.
SENSITIVITY - Sensitive to one #6 cap. Highly shock sensitive. This shock-
sensitivity becomes greater the higher the ambient temperature and percentage
"nitro". Explosives containing this high a percentage of nitroglycerin are prone
to extrude or "sweat" the oily nitroglycerine. This is very dangerous. This
extrudation can seep through containers and yield an explosion looking for an
unknowing or foolish person to kill. Explosives should be made as needed and
not stored. This explosive looses sensitivity as the temperature drops and will
become insensitive to one #6 blasting cap at 42 degrees F. or 5.5 degrees C..
Larger booster explosives would be needed to detonate these explosives at this
lower temperature.

USE-
BLASTING - Can be used as a dynamite, as in essence that is what this
formula is. The formulas below are high velocity, high power explosives. They
are great for shattering the hardest rock. For earth moving much cheaper
explosives (ANFO) can be used with almost as good a result. The explosive
containing the least amount of nitro sensitizer is equivalent to 70% ammonia
dynamite and the last composition is equivalent to 80% dynamite.
DEMOLITIONS - Good!!!! For relative powers see the blasting section
above.
MUNITIONS - POOR!!!!!!!!!!
These explosives are extremely powerful and dangerous due to the high
percentage of nitroglycerin in them. Only a person with experience with
explosives would be wise to attempt this manufacture and use of the explosive
produced. The manufacture of nitroglycerin can be found in the prilled AN
explosive section of this book under PRILLED AN-NITROGLYCERIN. To
manufacture these explosives the powdered AN and fuel are mixed. The
nitroglycerin is added to the powder and kneaded until a good uniform mixture
is obtained. The formulas are as follows:

#1
AMMONIUM NITRATE (Fert. grade)
Finely powdered . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 72%
POWDERED CHARCOAL . . . . . . . . . . . . . . . . . . . . . . . . . . 8%
NITROGLYCERIN . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20%

#2
AMMONIUM NITRATE (Fert. grade)
Finely powdered . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 63%
POWDERED CHARCOAL . . . . . . . . . . . . . . . . . . . . . . . . . 7%
NITROGLYCERIN . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 30%
#3
AMMONIUM NITRATE (Fert, grade)
Finely powdered . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 54%
POWDERED CHARCOAL . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6%
NITROGLYCERIN . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 40%

The addition of 2-4% total explosive weight of I M R smokeless powder will


give an explosive that will not extrude nitroglycerin and is the best way to
manufacture this explosive. The substitution of aluminum powder for the
charcoal will give higher performance. These explosives are basic dynamites, but
have the advantage, that commercial dynamites do not have this much "nitro" in
them. These explosives should be pressed gently into a tube with a wooden
dowel. P.V.C. pipe available at hardware or plumbing supply stores are a good
inexpensive choice for this. Wood dowel must be the only thing used to "press"
the exlosive into the pipe for safety's sake. These explosives can also be used to
fill shaped charges by very gently pressing them into the molds. For this purpose
the addition of I M R smokeless powder should be undertaken.
DETONATON VELOCITY X 1OOO (M./Sec.)
POWDERED AN-NITROMETHANE
DETONATION VELOCITY - 5700-6900 M/sec
DETONATION PRESSURE - 2,250,000-2,750,000 P S I
SENS IT IV I TY - One #6 blasting cap will reliably detonate even at low
temperatures Loading Density should be around 1 1-1 3 G 'cc

USE-
BLASTING - Too expensive to really be effective for blasting except for
special applications requiring the high shattering ability of this explosive
DEMOLITION - Great for most applications Can be considered a T N T
equivalent This explosive can be used in shaped charges to penetrate armor
plate and heavily reinforced concrete Bristant and very powerful
MUNITION - Unsuitable due to the volatile nature of the nitromethane
sensitizer and high sensitivity
This explosive is one of the more interesting binary AN explosives With
actual power greater than that of T N T , this explosive could find multiple
useages One of the aspects of this binary explosive is its ability to be used in high
performance shaped charges Of course, this explosive can not approach the
performance of C-4 or other R D X based explosives, but its simple
manufacture and location of the components for manufacture make it an
attractive alternative The high gas yield of this composition actually gives it
greater power than T N T and puts it in the Picric Acid class With the easy
manufacture process this explosive would be a good choice for many uses The
drawbacks of this explosive are the volatile nature of the nitromethane and the
subsequent expense of the nitromethane Both would need to be taken into
account The nitromethane could be obtained from a racing supply house as it is
a high performance fuel additive A useable form could also be obtained from a
hobby store as a high performance model airplane fuel (35% nitromethane) This
racing model airplane fuel would of course give a lower performance explosive
than the pure nitromethane product This model airplane fuel could be
separated by the vacuum distilling of the fuel with two stages in the system The
last stage would be super cooled to catch the methanol and nitromethane The
changes in pressure would also signal the boiling point changes due to liquid
remaining in the flask The first 30% of this liquid can be discarded The
remaining liquid to be caught in the second flask should be used to make the final
explosive in place of nitromethane that is called for Remaining in the second
stage flask is a liquid containing 75% plus nitromethane that would work well in
the first formula below A process such as this would take some working with but
would give an unlimited supply of surpentuous nitromethane See the diagram
that has a flow chart of this process The model airplane fuel could be used as is
and would still give good results the formulas below will give a formula for the
straight model airplane fuel as the percentages would not be the same
The ammonim nitrate is ground to a very fine consistancy The nitromethane
is added and stirred until a uniform mix is obtained This is then loaded by gently
pressing in the munition desired A different method can be used and will reduce
the above mentioned volatility and subsequent evaporation problems. The
powdered AN is pressed in the desired munition (shaped charge, etc.) or
container. Prior to detonation the correct amount of nitromethane is poured on
the pressed AN powder and allowed to soak for five minutes and then would be
ready to detonate. The explosives consist of the following:

AMMONIM NITRATE (Powdered) . . . . . . . . . . . . . . . . . 72%


NITROMETHANE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 28%

AMMONIUM NITRATE (Powdered) . . . . . . . . . . . . . . . 85%


NITROMETHANE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15%

A M M O N I U M NITRATE (Powdered) . . . . . . . . . . . . . . . . 70%


MODEL AIRPLANE FUEL
(35% m Nitromethane) . . . . . . . . . . . . . . . . . . . . . . . . . . . 30%

Of the compositions listed, the first is the highest performing of the three. The
last will be the lowest with detonation velocities of 6900, 6400, 5700 M/sec.
respectively. These are neat explosives that are very cap sensitive and will
detonate at high velocities and with great bristance.
POWDERED AN-METALLIC NITRATE
DETONATION RATE - 2900-3900 M/sec.
DETONATION PRESSURE - 700,000-980,000 P.S.I.
SENSITIVITY - One #6 ASA detonator will cause detonation in a 25 mm (1")
diameter at loading densities between .9-1 G/cc.

USE-
BLASTING - Great for any use calling for 40% dynamites. Great cap
sensitivity and low cost make this explosive very attractive for the home blaster.
Also could be used as a booster for prilled AN-fuel oil explosives. This explosive
would find use in stumping and other similar applications.
DEMOLITIONS - Very limited in this field due to the low detonation velocity
and pressure. Could find specialized uses!
MUNITIONS - Not a good choice as loading density is critical.
A simply prepared explosive with superb cap sensitivity within the proper
loading densities. The loading density will need to be closely controlled. This is
easily done by loading the explosive in a container of known volume with the
correct amount of the sensitized mixture. The manufacture involves simply
powdering all the ingredients separately and mixing together until a uniform
mixture is obtained. Several different sensitizers with their respective best
loading densities will be given below:

#1 LOADING DENSITY-0.93 G/cc.


POWDERED AN (Fert, grade) . . . . . . . . . . . . . . . . . . . . . . . 90%
HEAVY FUEL OIL . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4%
SAW DUST . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4%
CHROMIUM NITRATE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2%

#2 LOADING DENSITY - 1.0 G/cc.


POWDERED AN (Fert, grade) . . . . . . . . . . . . . . . . . . . . . . . . 90%
HEAVY FUEL OIL . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4%
SAW DUST . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4%
FERRIC OR IRON NITRATE
OR COBALT NITRATE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2%

#3 LOADING DENSITY-0.99 G/cc.


POWDERED AN (Fert, grade) . . . . . . . . . . . . . . . . . . . . . . . . 91%
HEAVY FUEL OIL . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4%
SAW DUST . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4%
LEAD NITRATE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1%

These loading densities are the maximums that these charges will take a
detonation wave from a #6 cap. Lower density loadings will still detonate, but
will give lower performance due to their detonation velocities. These are simple
to make and use and would be a good choice for a home manufacturer to "whip
up" on short notice for special blasting jobs around the farm or ranch.
POWDERED AN-RED PHOSPOROUS COFFEE
DETONATION RATE - 4600-5600 M/sec.
DETONATION PRESSURE - 800,000-1,250,000 P.S.I.
SENSITIVITY - One #6 blasting cap will reliably instigate detonation even at
temperatures as low as -10 degrees F.. Sensitive to shock impact and
friction!!!!!!!
LOADING DENSITY - Should be around .9-1.0 G/cc. for maximum
performance with charges in the 1.5 inch diameter or greater will propagate
detonation.

USE-
BLASTING - Equivalent to 60% dynamite for which charge computation
figures can be used. Very sensitive to detontaion due to the low shock threshold.
MUNITIONS - Can be used for this purpose but since the loading density of
this explosive needs to be low, it would not be a good choice. However, the
detonation releases phosphorous pentoxide, a nasty poison which would, in
certain, instances give a secondary poison gas effect to the detonation of this
explosive in munitions. Its shock sensitivity limits its use to hand propelled
munitions such as grenades.
A simple and powerful explosive easily made in a calindistine setting or by
home blasters. While being more expensive than other explosives in this book
the speed of manufacture and cap sensitivity tend to offset this expense to some
extent. It is not clear exactly what the coffee does to the explosive to positively
change the performance, but its addition is a definite plus. This addition of
"Instant" coffee to the explosive gives the explosive 50% more power than
similar compositions containing only red phosphorous. The manufacture is a
simple affair. The ingredients are powdered separately to a very fine consistancy.
This can be accomplished by heating the coffee in the oven with the door slighty
ajar at 200 degrees F. for 1 hour before grinding it. These finely powdered
components are mixed by tumbling together until an intimate mixture is
obtained. This should be done in a plastic container to ensure the safety of the
mixture!!!!
CAUTION: Red phosphorus is a dangerous compound. Respirators should be
worn while handling this component and care taken to ensure that the dust is not
ingested, breathed or allowed contact with the skin. DO NOT use any container
or other utensil that has at any time been used with potassium chlorate or any
chlorate salt. An explosion is a certainty. I have a picture of a bomb squad
crewmember with his hand turned into a mist by this compositions'detonation
and it does not look at all pleasant.
This explosive formula is composed of the following:

AMMONIUM NITRATE (Fert, grade)


Finely powdered . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ...95.0%
REDPHOSPHORUS. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.0%
SOYBEANOIL. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3..5 %
DEHYDRATED GROUND COFFEE . . . . . . . . . . . . . . . . . 0.5%

Care should be taken to avoid breathing the detonation products or gases as


they contain highly poisonous phosphorus pentoxide. Although this is a strange
concoction for an explosive it is powerful and seemingly a good explosive. It is
strange that the addition of "Instant" coffee increases this explosives power by
50%. This is most likely due to the lowering of the loading density brought on by
the addition of the low density of dried coffee.
GELLED AN-HEXAMINE-NITRIC ACID
DETONATION RATE - 4400 M/sec. at 3"-5200 M/sec. at 5"
DETONATION PRESSURE - 750,000-1,800.000 P.S.I.
SENSITIVITY - One #8 blasting cap will detonate this explosive.
USE-
BLASTING - Good explosive which is comparable to 70% ammonia
dynamite. A good choice for blasting. Storage stable for up to one year in
average magazine conditions.
DEMOLITIONS - Good for this use if the charge diameters do not pose a use
problem. Good bristance and blast characteristics. Some of the nitroglycerin
explosives in this book and the AN nitromethane explosives are better choices
but this explosive will work. For shaped charge applications, this explosive does
not possess a high enough detonation rate for proper collapse of the liner and
subsequent formation of a good high velocity linear jet.
MUNITIONS - Not a good choice due to the highly corrosive nature of the
composition.
This is an excellent explosive choice for a "home" type manufacture. The only
drawbacks of this explosive are its highly corrosive nature and subsequent
danger involved in handling nitric acid. It is a gell and was originally developed
as an explosive that could be extruded into a plastic tube much like sausage is
manufactured. This explosive does need to have a rather large charge diameter
for it to reach its maximum potential as an explosive. Larger diameters than 5"
will no doubt raise the detonation rate slightly higher than the figures given at
the beginning of this section. A seven inch charge diameter could possibly give a
detonation rate of over 6000 M / sec.. The manufacture is not as simple as some
of the others in this publication. To manufacture, place 1000 G. of prilled
ammonium nitrate and 28 G. guar gum in a stainless steel container of 1.5 gallon
capacity. Guar gum is a high mole weight poly saccaride which, when mixed
with water at low percentages gives a stable and water resistant gell. It is used
extensively in food processing (e.g. ice cream, dairy products, chewing gum etc.)
and as a thickening agent in oil well drilling fluids. It is obtained locally if
possible, but major sources are given in the pages of this publication. These
should be stirred together until uniformly mixed. To this is added 340 cc of
water, 240 G. hexamine (methenamine, see AN-Hexamethylenetetramine
adduct), 1 1 7 m. 54% nitric acid (90 ml. 70% nitric acid and 27 ml. water will
work). CAUTION: Wear gloves and eye protection and work with good
ventilation and be prepared to wash any composition off as soon as possible. To
this add an additional 2240 G. of ammonium nitrate prills. This is blended
together and allowed to stand. The mixture will begin to gell. After is has started
to thicken noticeably, add 120 G. chromic acid, 280 G. zirconium sulfate and 120
G. aluminum sulfate. This will produce 9.94 Ibs. of explosive gell at a density of
1.3 G/cc.. This explosive is cap sensitive, but the explosive should be capped
only immediately before actual detonation due to the corrosive nature of the
composition on the detonator shell. This is an interesting explosive due to the
balancing of the positive and negative heats of solution. The hexamine forms
with the nitric acid, a sensitizer which is in the fammily of R.D.X. explosives.
This explosive is cheap and storage stable for 9-12 months at standard
temperature (70 degrees F.). For use, it can be packed into a suitable container
with an inside diameter of 3" or greater. If any amount of time is expected to pass
before the charge is to be detonated, care should be taken to ensure that the
co n t ai n er will not be affected by the corrosive nature of the explosive
for mul atio n. Below once again is the composition of the explosive in
percentages, instead of the particular batch weights given above:

POWDERED AN (Fert. grade) . . . . . . . . . . . . . . . . 25.0 parts


GUAR G U M . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7 parts
WATER . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8.5 parts
HEXAMETHYLENE (Hexamine) . . . . . . . . . . . . . . . 6.0 parts
N I T R I C ACID (HNO3) . . . . . . . . . . . . . . . . . . . . . . . 3.8 parts
POWDERED AN (Fert. grade) . . . . . . . . . . . . . . . . 56.0 parts

CHROMIC ACID . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3%
Z I R C O N I U M SULFATE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7%
A L U M I N U M SULFATE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3%

The last three ingredients are given in percentages as they comprise a ratio of
gelled explosive to their interligation properties. The first six ingredients are
prepared with the total weight known, then the percentages of the last three
ingredients will give the correct amount of these ingredients to add to finish the
explosive composition.

Water gelled with 3% guar gum.


POWDERED AN-HEXAMINE OR UREA GEL
DETONATION RATE - 4850-5600
DETONATION PRESSURE - 1,000,000-1,300,000 P.S.I.
SENSITIVITY - One #8 blasting cap will detonate this explosive in 1.5 inch (4
cm.) diameter columns but 25 G. boosters of dynamite will give the higher
detonation velocity figures.

USE-
BLASTING - A high performance explosive that compares favorably with
high velocity gelatin dynamites in power. While velocity is not as high, the actual
ability to do work is slightly higher. Not quite as bristant (shattering power) as
high velocity gelatin dynamites, this is not really as good a hard rock blasting
explosive but will work very well at this usage.
DEMOLITION - A good choice for ammonium nitrate explosive not
containing "nitro" compounds from this book. Good velocity for a dynamite
type explosive. While the detonation rate is not as high, the blast pressures set up
by detonation of this explosive will do more actual work. Charges will need to be
stemmed for best results and a well stemmed charge will perform as well as the
better high velocity dynamites. This explosive will give a longer duration high
pressure detonation zone than will the higher "nitro" containing dynamites
MUNITIONS - Not a good choice.
This is a good explosive, but the manufacture method is a little more
dangerous than the others in this publication. The danger rises from the fact that
heating ammonium nitrate in the presence of fuels can cause the premature
detonation of the charge or explosive therein. The basic idea behind this
explosive is the intimacy of the oxidizer (ammonium nitrate) with the fuel
(hexamethylene - "hexamine" or urea). The urea fuel sensitizer is the best all
around choice, although performance is somewhat lower. Urea fertilizer will
work and is relatively cheap and easily obtainable. This fertilizer would be
obtained by asking the nursery or feed store for some 45-0-0 urea fertilizer which
they would be more than happy to sell to a customer for his yard. The urea could
also be had by urinating in a shallow pan and allowing this to completely
evaporate. The urine of a person eating a high percentage of proteins and a low
amount of sugars and carbohydrates gives the best urine for this purpose. Not
really liking the smell of urine, I would tend to want to purchase my urea, as it
should cost around $10.00 U.S. which would be worth the price. The hexamine
sensitizer, while giving the highest performance, is also the most dangerous to
work w i t h , as it requires hi gh er "melt" temperatures. Two different
compositions will be given for each of these explosives.
The procedure is simple. The first addition of AN and fuel (urea or hexamine)
and the "Tide" (sodium dodecyl benzenesulfonate) are powdered and mixed
together. These are placed in a stainless steel pan. A candy thermometer is placed
in the mixture so that it will go completely to the bottom of the mixture. The
container is then place on a heat source that is easily and accurately controlled
(e.g. electric hot plate). This is heated slowly until it begins to melt (100 degrees
C. urea, 170 degrees C. Hexamine). This is where the danger lies. At this
temperature, 170 ammonium nitrate has been known to explode on rare
occasions. The temperature should never be allowed to go higher than 175
degrees C.. The urea should be safe throughout this manufacture step due to its
lower melt temperature. When the mixture has completely melted it is then
poured on a stainless steel cookie sheet or similar corrosion resistant surface.
The cookie sheet should be set in a shallow pan of water to make the molten salts
cool as they are poured into the pan. The thinner the layer of crystals in the
bottom of the pan the better. After these crystals cool, they should be powdered
in small amounts by some method (morter and pestle, rolling pin on hard
surface, etc.). Then, to the correct percentage of this mixture, is added the
following powdered ingredients: Ammonium nitrate, saw dust and sodium
nitrate. These are mixed well. To complete, the explosive guar gum is added and
mixed well. Water is added in which the potassium chromate is dissolved and the
whole mess is mixed well. The ingredients are as follows:

#1
67%
AMMONIUM NITRATE (Fert, grade)
Finely powdered . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 91.2%
HEXAMINE (Methenamine) . . . . . . . . . . . . . . . . . . . . . . . . . 8.5%
"TIDE" laundry detergent (sodium dodecyl)
(Benzene sulfonate) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 0.3%

33%
AMMONIUM NITRATE (Fert, grade)
Finely powdered . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8.9%
SAW DUST (Wood flour) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7.4%
SODIUM NITRATE (Powdered) . . . . . . . . . . . . . . . . . . . . . 11.9%
GUAR GUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 0.3%
POTASSIUM CHROMATE (Dissolved in H20) .. . . . . . . . 0.2%
WATER . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4.4%

#2
67%
AMMONIUM NITRATE (Fert, grade)
Finely powdered . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 80.0%
UREA (Fert, grade or other source) . . . . . . . . . . . . . . . . . . . . 20.0%
"TIDE" laundry detergent
(Sodium dodecyl) (Benzene sulfonate) . . . . . . . . . . . . . . . . 0.3%

33%
AMMONIUM NITRATE (Powdered) . . . . . . . . . . . . . . . . . . 8.9%
SAW DUST (Wood flour) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7.4%
SODIUM NITRATE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11. 9 %
GUAR G U M . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 0.3%
POTASSIUM CHROMATE (Dissolved in H20) . . . . . . . . . . . 0.2%
WATER . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4.4%
These explosives, # 1 & #2, should have a density of around 1.2 G/cc. and have
detonation rates of 5600 M/sec. and 5100 M/sec. respectively. As stated above,
caps will detonate, but boosters of 25 G. are recommended and will give the
higher detonation velocities. While these explosives are really a wet blasting
agent they do not really fall into the category of slurry explosives either. A good
explosive choice and the urea formulation is recommended due to the much
safer nature of its manufacture.
GELLED AN-ETHYLENE GLYCOL
SMOKELESS POWDER
DETONATION RATE - 5400 M/sec.
DETONATION PRESSURE - 1,300,000 P.S.I.
SENSITIVITY - Not cap sensitive, requires a booster (1/4 stick of dynamite or
equivalent).

USE-
BLASTING - A good explosive which can be extruded into a polyethylene
tube to form ready made dynamite sticks. Also a useable explosive in that it can
be pumped directly into the bore hole if excess moisture is not present.
Comparable in power to 60% gelatin dynamite.
DEMOLITIONS - Useable in this field but definitely limited in its
application. Best used in the form of sticks (polyethylene tubes or P.V.C. pipe).
Comparable to 60% gelatin dynamite, but charge weights should be increased by
15% to make up for the lower rate of detonation.
MUNITIONS - Unsuitable!!
This is a gelled aqueous slurry explosive, this formulation contains a metallic
nitrite which generates small gas bubbles in the explosive gel matrix. This lowers
the specific gravity or density of the explosive and the gas bubble takes
advantage of the "hot spot" theory of detonation. This gives a much more
sensitive and higher detonation velocity explosive. Again guar gum is used as the
thickening agent o/gelling agent. This slurry explosive is manufactured in a
simple process. The ammonium nitrate, sodium nitrate and smokeless powder
are slurried with water at 100 degrees F. (38 degrees C.). To this slurry is added
the sodium nitrite. Then with a dropper and P.H. paper acetic acid is added until
the P.H. is between 4.5 and 5.0. (NOTE: E. MERRICK makes a very accurate
and easily read P.H. paper with which you simply dip and read by comparing the
four colors with a chart). The first addition of guar gum and ethylene glycol
(antifreeze) is then made. This is followed by another addition of ethylene glycol
and guar gum. The thickened explosive is stirred until uniform and is then ready
for either loading into cartridges or directly into the bore hole or target. The
composition is as follows:

AMMONIUM NITRATE (Fert, grade) . . . . . . . . . . . . . . . . . . . . 41.7%


SODIUM NITRATE (NaNO3) . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13.0%
WATER . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17.0%
SMOKELESS POWDER ("Bullseye") . . . . . . . . . . . . . . . . . . . . . 25.0%
SODIUM NITRITE (NaNO2) . . . . . . . . . . . . . . . . . . . . . . . . . . . 0.065%
ACETIC ACID . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Add to adjust P.H.

GUAR GUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 0.7%


ETHYLENE GLYCOL (Antifreeze) . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2.1%
GUAR GUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 0.08%
ETHYLENE GLYCOL (Antifreeze) . . . . . . . . . . . . . . . . . . . . . . . . . . 0.4%

This is a good slurry explosive. It has a higher cost, as the smokeless powder it
contains drives the cost up. It has good shattering characteristics and high
performance for a slurry and is easily prepared in a short amount of time by
anyone that would desire to do so.

Spooning a mixture into a P.V.C. pipe.


GELLED AN-MONOMTETHYLAMINE
NITRATE GELATIN
DETONATION VELOCITY - 5600-6400 M/sec.
DETONATION PRESSURE - 1,500,000-2,200,000 P.S.I.
SENSITIVITY - One #8 cap will reliably detonate these compositions.

USE-
BLASTING - These are the basic explosives of Du-Ponts "Tovex" series of
explosives. They are cheap and powerful with good magazine life. These, while
not the perfect explosives, would find many uses in blasting.
DEMOLITIONS - Powerful and good sensitivity make these explosives good
choices for some "demo" applications. Their water gell tendancies limit usage,
but they are easily made and cap sensitive.
MUNITIONS - Unsuitable for most applications. Perhaps large antipersonal
bombs could be fabricated and would kill on blast alone.
These are very similar in composition to DuPont's "Tovex" explosives. The
"Tovex" line of explosives are water gells that are sensitized with the addition of
monomethylamine nitrate. This gives sensitive compositions with very high
detonation rates for AN explosives. The MMAN is very stable in heat and
storage tests, the only problem with these explosives would be the creation of a
stable gell matrix. Most water gells have poorer storage life than other
explosives but their low cost and good performance are unequalled for the cost.
This explosive in DuPont's eyes is as good as any dynamite and many different
grades are available. They were so impressed with them that they dropped their
nitroglycerin based dynamites in favor of this explosive group. Of course, I am
sure that these are cheaper to manufacture than the "Nitro" based dynamites.
They also are very easy for the home manufacturer to make.
The process to make the MMAN is given on page 67. The cast explosive in
that chapter is some 30% MMAN and 70% AN. This process would be used to
produce the clear liquor containing the two major products. Removal of all the
water is not necessary. 10% of the water should remain in the liquid. This can be
achieved by removing water until a density of 1.45 is reached. This will give 10%
water roughly. To this is added the guar gum and aluminum powder. This
should all be mixed very well. This explosive will require a large booster as its
density is too high to be cap sensitive. To make this explosive cap sensitive, add
resin microballons, glass microballons, powdered styrafoam or pearlite. Resin
microballons are hard to come by, but pearlite and styrafoam are not.
Styrafoam packing "peanuts" could be used or pearlite which is available at local
gardening centers. This addition will lower the density. Enough should be added
to lower the density to between 1.1 and 1.25 G./cc. Resin microballons are hard
to find, but for information on powdering styrafoam see page 56 and 57 (e.g.
Prod. # C-15/250, 3M Corp. Minneapolis, MN).
#1
LIQUOR FROM PAGE 68 (10% H20) . . . . . . . . . . . . . . . . . . . . 95%
ALUMINUM POWDER . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3%
GUAR G U M . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2%
#2
LIQUOR FROM PAGE 68 (10% H20) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 94%
ALUMINUM POWDER . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3%
G U A R G U M . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2%
10% POTASSIUM CHROMATE AQUEOUS SOL. ........................... 1%

The first composition will not have a long storage life due to the break down of
the gel matrix. The second formula is crossed linked with potassium chromate
which will give a storage stable explosive. The density, as mentioned earlier, is
critical if cap sensitivity is needed. The manufacturer would have to control this
density in a batch by batch process.
AN SLURRY COMPOSITION #1
DETONATION VELOCITY - 4800 M/sec.
DETONATION PRESSURE - 580,000-1,100,000 P.S.I.
SENSITIVITY - Requires at least a one pound high explosive booster.
Critical charge diameter (unconfined) 6 inches. Addition of 2% aluminum
powder will give a slurry that will still detonate at 5 degrees C..

USE-
BLASTING - Good cheap explosive slurry. Good power and decent
propagation at lower temperatures. Easy to load and use, but requires a good
sized booster to ensure detonation. A good choice.
DEMOLITION - Little or no use, except in very special circumstances.
MUNITIONS - Good filler for large (200-15,000 pound) concussion bombs
like the "Big Blue 62" or "Daisy Cutter" munition.
A good, easily prepared high explosive slurry. Cheap and easily
manufactured. A good choice for most earth moving, pond blasting, ditching
(large) and other similar applications. For more information see the DuPont
"Blaster's Handbook". This slurry is "cooked up" in the following procedure.
The ammonium nitrate and the sodium nitrate are dissolved in water at 60
degrees C. to form a thich solution. To this is added sulfur, powdered gilsonite
(uintaite a form a asphalt obtained from the Unita Valley in Utah) and starch. I
believe that any form of asphalt will work if the particle size is reduced enough.
Then the guar gum (thickner) is added and the mixture is well mixed. This will
give a thick slurry in approximately 5 minutes. This explosive is composed of the
following:

AMMONIUM NITRATE (Fert. grade) . . . . . . . . . . . . . . . . . . . . . . . . . . . . 54.0%


SODIUM NITRATE .... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19.0%
WATER .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13.5%
SULFUR (Flowers powdered) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4.0%
GILSONITE (Asphalt powdered) ........ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4.5%
STARCH (Corn starch) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3.0%
A L U M I N U M POWDER (400 mesh-optional) . . . . . . . . . . . . . . . . . . . . . . . 1.5%
GUAR G U M .......... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 0.5%

This explosive can be just poured into the bore hole if water is not present. It
will work in a wet environment, but the longer the exposure to moisture, the less
performance can be expected. The best application in a wet bore hole is to place
the slurry in a poly ethylene tube or a trash bag to protect the explosive from the
adverse affects of the water.
AN SLURRY #2
DETONATION VELOCITY - 400-4600 M/sec. at Density 1.3 G/cc.
DETONATION PRESSURE - (est.) 1,000,000 P.S.I.
SENSITIVITY - 25 g. of dynamite are required for detonation when prepared
with small particle size aluminum powder (300 mesh). Larger aluminum powder
yields an explosive that requires more than 100 g. dynamite for detonation.
USE-
BLASTING - Great for blasting high detonation rate and comparable in
power for 60% ammonia dynamite. Not water resistant. Requires protection
from moist boreholes. Powerful and cheap. Must be used in 5" diameter charge
or greater.
DEMOLITIONS - Very limited use.
MUNITION - Limited if any.
A simple slurry like explosive without guar additives. The lack of guar gives a
slurry with less viscosity and more fluid characteristics. One of the more simple
slurry explosives - it is a good, powerful explosive. Detonation propagation is
good in larger charge diameters.
The water and starch are mixed together. To this is added the ammonium
nitrate (fine powder), '"Bullseye" smokeless powder and 400 mesh aluminum
powder. The slurry like mixture is mixed until uniform and is then ready for use.
The composition is as follows:

WATER . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17%
FLOUR (Wheat, common bleached) . . . . . . . . . . . . . . . . . . . . . . . . . . . 4%
AMMONIUM NITRATE (Fert, powdered) . . . . . . . . . . . . . . . . . . . . 66%
"BULLSEYE" SMOKELESS POWDER . . . . . . . . . . . . . . . . . . . . . . 10%
ALUMINUM POWDER (400 Mesh) . . . . . . . . . . . . . . . . . . . . . . . . . . 3%

This explosive has propagated detonation in 1.375" I.D. (35mm) pipe with a %
inch wall. Therefore this explosive will work fine in this size or larger bore hole.
A good choice for small blasting jobs requiring a small bore hole explosive
slurry.
AN SLURRY #3
DETONATION VELOCITY - 4500 M/sec. at 32 degrees C.
DETONATION PRESSURE- 1,100,000 P.S.I.
SENSITIVITY - One #8 blasting cap in a density of 1.2 G/cc..

USE-
BLASTING - Similar to slurries # 1 and #2. A good, cheap blasting agent that
is sensitive to conventional caps.
DEMOLITIONS - Limited.
MUNITIONS-Limited.
A cap sensitive slurry in which the density is controlled by the addition of gas
encapsulating substances (Marrow of sugar cane). This slurry has fairly good
storage properties and decent shelf life due to the "crosslinking" of the slurry
with the potassium chromate solution. This "crosslinking" simply locks the
gellitizing agent into its gelled state by not allowing the hydration of the
polysaccharide gum to loose its hydrogen attraction. This is what gives this
explosive a good storage life. The fuel in this slurry is sugar (sucrose or cane
sugar). This slurry is attractive as it does not require expensive aluminum
additives, yet it loses very little performance due to this change. This explosive
slurry has good water resistance due in part to the crosslinking of the aqueous
blasting agent. This is a very good choice from the point of manufacture,
sensitivity, stability and ease of acquisition of the main ingredients.
The ammonium nitrate (Fert, grade) and sodium nitrate are dissolved in the
water, which is heated until all of the ammonium nitrate dissolves and the
heating slowed. To this is added the cane sugar. The temperature of the mixture
should be kept at 65 degrees C. throughout the remainder of the mixing process.
The sugar cane marrow, "Tide", stearic acid and guar gum is added. The mixing
is continued until the composition is uniform. To this is added the 5% aqueous
solution of potassium chromate in an amount of 450 CC to every 50 KG. of
finished explosive. It does not take much! The sugar cane marrow can have
styrafoam beads as a substitution. These beads could be made by rolling or
tumbling common styrafoam until it breaks up into small pelleted size (1 mm).
Perhaps the best way to reduce the styrafoam to small sizes is by placing
styrafoam pieces in a blender and the blender turned on to high until the
styrafoam is chopped into very fine pieces. Addition of pearlite in place of the
sugar cane marrow would also work, but its particle size might need to be
reduced in the same manner as the styrafoam. Pearlite can be obtained from a
garden store or nursery at a very low cost. The composition of the slurry is as
follows:
A M M O N I U M NITRATE (Fert.). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 56%
WATER . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14%
S O D I U M NITRATE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15%
CANE SUGAR ... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8%
SUGAR CANE MARROW OR STYRAFOAM . . . . . . . . . . . . . . . . . 3%
"TIDE". . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1%
STEARIC A CID. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3%
GUAR GUM ................................................. 1%

This slurry, when loaded in 150 mm cylinders (5.9 inches), can be exploded by
standard blasting caps at temperatures as lows as 4 degrees C.. Detonation
velocities at 32 & 4 degrees C. are 4500 M/sec. and 4150 M/sec. respectively.

Setup to powder styrafoam in a blender.


AN SLURRY #4
DETONATION VELOCITY - 4600-5500 M sec.
DETONATION PRESSURE - 800.000-1,300,000 P.S.I.
SENSITIVITY - Requires a 50-100 G. booster of hig h explosive such as
Comp. "B", T.N.T. or high velocity dynamite at density 1.4 G/cc. and in a 6 inch
diameter charge.

USE-
BLASTING - Similar to "Aquanal" slurry in power and useage. This slurry is
not quite as resistant to water as is the "Aquanal" slurry. Good water resistance
can be had and high densities are also attainable allowing this slurry to be used in
wet bore holes. Charges should be fired as soon as possible.
DEMOLITIONS - Limited.
MUNITIONS- Limited.
This is a neat blasting slurry that makes use of the ability of water to furnish
oxygen to the explosive reaction. The fact that water and aluminum powder will
detonate, reinforces this statement. Aluminum has a great tendancy to oxidize
especially in the presence of water. This is overcome in t h i s formulation by
coating the metal additive with a substance that gives a water repellant tendancy
to the aluminum. Uncoated aluminum containing slurry ty pe explosives will
have a very short storage life and during storage tend to evolve or "give off
hydrogen gas which is not very desirable. Generally the percentage of coating
agent is very small (e.g. 1%). This coating seems to give this slurry the ability to
detonate, even in charges as small as 2.5 inches (6.3 cm), but the highest
detonation velocity will not be achieved at this small diameter loading. This
gives this explosive an added ability of being loaded in small diameter boreholes
directly and should be pumpable with a diaphragm type pump.
The aluminum is coated by either tumbling the coating agent with the
aluminum (Gilsonite, stearic acid or calcium stearate) or by dissolving the
coating agent in a solvent and mixing with the aluminum and allowing the
solvent to evaporate ("Bullseye" smokeless powder-acetone or p a r a f f i n -
gasoline). The amount of coating should be 1/2 to 1% total weight of the
aluminum powder, thus the powdered ammonium nitrate, sodium nitrate and
sulfur are mixed together. To this is added the water and aluminum that has been
previously mixed together. This solution is heated to 45 degrees C. ( 1 1 3 - 1 1 5
degrees F.). To this solution is added the remainder of the sulfur. Then the
powdered coal and the guar gum are added and the viscous liquid mixed well.
The slurry consists of the following:
AMMONIUM NITRATE (Fert, grade) ................................ 42.0 %
S O D I U M NITRATE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11.1%
SULFUR (powdered)
1st addition . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7.0%
2nd addition... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6.0%
WATER . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15.0%
A L U M I N U M (powder 300 mesh) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16.2 %
POWDERED COAL ... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2.2%
GUAR G U M ........ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 0.5%

This will provide a thick slurry, sensitive in small diameters. Good power and
water resistance are also advantages. This slurry requires heavy boosters, but
one stick of gelatin dynamite will work well.
CAST AN EXPLOSIVE-FOAMED
DETONATION RATE - 4300-4700 M/sec.
DETONATION PRESSURE - 800,000-1,400,000 P.S.I.
SENSITIVITY - Sensitive to one #6 blasting cap at densities of .95 G/cc or
less. This foamed cast explosive is sensitive to a dynamite booster at a density of
1.25 or less. These figures are applicable at a charge diameter of 2 inches (5 cm.)
or greater.

USE-
BLASTING - Very useful in blasting due to the ability to lend itself to multi
charge diameter and a variety of charge configurations. Also a good choice for a
booster type explosive for the prilled AN-fuel oil type explosives at a low cost.
Charge diameter should be 2" or greater. Comparable to 50% ammonia
dynamite.
DEMOLITIONS - A useable explosive for some "demo" applications. The
ability to conform to a variety of shapes and its relative ability to resist "dead
pressing" or packing to an insensitive and undetonatable density. While the
detonation rate is not as high as could be obtained, this explosive is cheap and
could be produced in a great bulk. It does not have a shaped charge application
in modern terms (e.g.: concrete breaching, steel plate perforations, etc.). but in
large quantities it could be used effectively. However, the greater bulk (washtub
sized shaped charges) and weight of the demolition charges would not be
feasable for an underground group, except in special instances, as they would
depend upon hit and run tactics.
MUNITIONS - Could very easily be used in cast iron or similar fragmentation
charges. Any application of AN explosives metal fragmentation ordinance
needs to be painted inside with asphalt or an epoxy type paint to eliminate the
corrosive action of the salt on the container.
CAUTION: Ammonium nitrate should never be in contact with copper or brass,
as potentially dangerous salts could be formed which could result in the
premature detonation of the charge!!!!
This explosive, of course, is not as good a fragmentation explosive as T.N.T.,
due to its lower detonation rate. Although prefragmented explosive devices
could be fabricated easily with something like roofing nails or some other
potentially lethal projectiles. This explosive is unsuitable for projectile loading
of any sort.

Cast AN explosives have always had a bad reputation for their tendancies to
be overly insensitive to even rather large boosters. This seeming inability to
achieve a complete or efficient detonation is a curse of cast AN explosives. This
composition and its manufacture procedure seems to give a cast charge that is
sensitive to a blasting cap and will propagate detonation in a container of very
little strength (e.g.; tin can, bottles, paper tubes, etc.). This great increase of
sensitivity is achieved by lowering the density of the explosive charge. This is
accomplished by the addition of small bubbles of gas in the molten AN-fuel as it
cools. The bubbles of gas are formed in a reaction between the AN and a
carbonate, bicarbonate, peroxide, metallic oxide or one of two gas generating
nitrates. When the manufacturer "gets the hang" of pouring at the proper
temperature, the bubbles dispersed throughout the cast explosive will be of
surprising uniformity. Since most shaped charges are formed by casting, this will
give the home manufacturer a way to make "homemade" shaped charges. Of
course, the detonation velocity is too low for a good effective shaped charge, but
the low cost of the explosive allows the use of charges much larger (washtub
sized) than would be needed with equivalent CHNO explosives (T.N.T., R.D.X.,
comp "B", etc.). A washtub shaped charge of this type would be in the 50 to 80 Ib.
size range and would be large enough to do a great deal of destruction. Also this
size munition could be used by filling the shaped charge cavity with nails, bolts,
nuts, glass, wire, ball bearings, BB's and anything else that would make good
fragments. This would, in effect, create a huge claymore mine with several
hundred meter effective range. To manufacture this explosive, proceed as
follows:

The volume of the container, in which the charge is to e cast into, should be
measured. This can be done easily by filling it with water, making note of how
much water it takes to fill it. Since water is a standard for density and one cc
weights equals one gram, this is easy to do:

One gallon = 3584 grams = 3584 cc.


One quart = 896 grams = 896 cc.
One pint = 448 grams = 448 cc.
One fluid ounce = 28 grams = 22 cc.

After the volume of the container has been figured, the amount of explosive
would be figured, this is done by multiplying the number of cc. in the container
by the density desired as done below:

EXAMPLE:
V = Volume of container = 454 cc.
D = Density of charge desired - .95 G/cc
V x D = Amount of explosive required
454 x .95 = 431.3 G. explosive

It is a good rule of thumb in calindistine explosive manufacture to


manufacture only one device at a time. Of course, it would go without saying, the
container should be dried out after the water measuring and would be clean
enough to "eat out of".
The explosive weight is known and the proportions should be figured from
this. The ammonium nitrate (87.9%) is placed in a stainless steel container. The
water (5.15%) is then added with distilled water being used whenever possible. A
candy thermometer is placed in the container so that it goes all the way to the
bottom of the stainless steel melting pan. Place the pan on a heat source which
can be controlled easily. A good heat source is an electric hot plate. The hot plate
is turned on and the mixture heated to 130 degrees centigrade (266 degrees F.).
This heating should be done slowly so that potentially explosive "hot spots" will
not form due to uneven heating. A slow and even heat will work best.
CAUTION: The hot salt is a burn hazard and contact with is should be avoided
and safety goggles, gloves and appropriate clothing should be worn.
After the temperature of 130 degrees C. has been reached, this temperature is
held for 5 minutes to ensure the complete solution of the AN in the hot liquid.
The temperature is then allowed to fall to 110 degrees C. and at this temperature
a thick slurry or mush about the consistancy of thin oat meal will form. To this
slurry is added the wax fuel (5.72%) and n-Octadecylamine, "Mr. Bubble" or
"Tide" (0.25%). This is stirred rapidly to form an emulsion or intimate mixture
of the AN-water solution with the molten wax. The foaming agent will aid in the
formation of a good emulsion with good stability and will hold this emulsified
state until the explosive is cooled in the mold. The molten explosive is then taken
off the heat source and the foaming agent (1 %) added. The foaming agent can be
one of the following substances:

H2O2 - Hydrogen peroxide 30%


Na2O2 - Sodium peroxide
BaO2 - Barium peroxide
NaNO3 - Sodium nitrate
Ba (NO3) 2 - Barium nitrate
NH4HCO3 - Ammonium bicarbonate
Na2CO3 - Sodium carbonate
NaHCO3 - Sodium bicarbonate

Of the foaming agents the sodium nitrate and the sodium bicarbonate (baking
soda) are the most attractive from the standpoint of easy acquisition. As the
foaming agent is added, the mixture will begin to foam. Immediately after this
addition, the pouring should be done. Then the explosive should foam up and
cool before it has time for the bubbles within to escape. Varying the pour
temperature may help control this. This will not help as much as keeping the
mold cold or surrounded by ice water or cold water. This will cause the explosive
melt to solidify more rapidly, thus trapping more gas in the explosive charge.
The wax fuel could be replaced with aluminum powder (400 mesh) and a higher
power more bristant explosive can be had. Again the ingredients of this
explosive will be listed below:

#1
AMMONIUM NITRATE (Fert, prills) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 87.9%
WATER .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5.15%
WAX .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5.72%
EMULSIFIER . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 0.25%
FOAMING AGENT . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.0%
#2
AMMONIUM NITRATE (Fert, prills) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 83.0%
WATER..... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4.86%
ALUMINUM POWDER (400 mesh) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10.9%
EMULSIFIER (Not essential) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 0.25%
FOAMING AGENT .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.0%

The second formula is the best, performance wise, but is not as stable in even
short term storage as is the first. In the second formula the emulsifier is not
essential, but will yield a more cap sensitive explosive and will ensure a better
mixture of the molten salt and the aluminum fuel. This process will produce cast
charges of a densities 0.68-1.34 and in a 2" diameter charge will be sensitive to a
blasting cap at a density of .95 G/cc or less. Similar compositions, that are
unfoamed, will not be cap or even booster sensitive, unless strong confinement
and very large boosters are used.

Melt apparatus set-up.


CAST AN-FUEL (high density "AMMONEX")
DETONATION VELOCITY - (well confined) 3900-6600 M/sec.
DETONATION PRESSURE - 1,200,000-3,500,000 P.S.I.
SENSITIVITY - Very insensitive. Requiring heavy boosters with very strong
confinement.

USE-
BLASTING - Would be a good blasting explosive, but other formulations in
this book would be a better choice due to their easier method of manufacture and
lack of high confinement requirement.
DEMOLITION - The last two formulas will be comparable to T.N.T. in
shaped charge application, but require very large boosters. The last two charge
compositions would be the only explosive "Ammonexes" suitable, as the other
two have much too low of a detonation rate.
MUNITION - Superb munitions loading explosive. These ammonex type
explosives were developed in WWII as a replacement for T.N.T.. The U.S. had
an adequate supply of T.N.T. and these explosives never came into use. The last
two formulas given are the best and should have storage stability similar to
military T.N.T. The first two will tend to extrude from the loaded munitions at
elevated temperatures (60-70 degrees C. for seven days). They also possess lower
detonation velocities, but are easier to manufacture than are the last two. These
ammonex explosives would all find excellent application as cast iron body (e.g.
"pineapple") grenade fillers, but would require four to eight gram boosters of
picric acid, R.D.X., tetryl or other similar explosives.
The ammonex explosives were developed at the famous PICTINNY
ARSENAL in Dover, New Jersey during the second world war. The adequate
supply of T.N.T. in the U.S. made this development one of obsolescence. The
ammonex cast explosives are really below T.N.T. performance, unless they
contain CHNO explosive additives, they are useful none the less due to their
simple ingredients and manufacture. The curse of cast AN explosives up to this
development was the very high melt temperature (169 degrees C.) required to
bring them to "pour point". This tended to cause premature detonation and
subsequent short plant life!!! The ammonexes make use of a simple idea. That
addition of a combustable that will lower the melting temperature of the AN and
form an eutectic mixture of AN and fuel. The addition of urea gave the
explosives the low melt temperatures, but tended to be unstable in storage
(extrudation). The addition of calcium nitrate (anhydrous), gave its mixture
with AN a low melting point, allowing the manufacturer to add a higher
detonation velocity explosive (Tetryl or ammonium picrate). This gives an
explosive with performance comparable to T.N.T.. The molten explosive is cast
into the munition intended. The first two explosive formulas (# 1, #2) should give
fragmentation performance compared to T.N.T. 24% and 41% respectively. The
last two formulas (#3, #4) should give comparative performance to T.N.T. of
85% and 100% respectively. The munitions to be loaded should be coated inside
with high temperature paint (epoxy base) or asphalt. And of course, the use of
AN with any copper or copper containing alloy (brass etc.) should be avoided.
The melting is simple. The ingredients are heated in a stainless steel pan with a
candy thermometer in place. The heating should be done slowly and evenly. The
explosive should melt between 90-100 degrees C.. The molten explosive is stirred
and then poured into the munition.
CAUTION: The molten explosive is very hot and would cause severe burns if
handled carelessly. Protect any part of your body, unless you do not mind getting
burned.
As this molten explosive cools it will solidify. The munitions should be
protected from extremes of temperature. With the first two compositions this
rule is crucial. The ingredients of the four different compositions are as follows:

AMMONIUM NITRATE (Fert, grade) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 78.0%


UREA (Powdered) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11.0%
A L U M I N U M POWDER (400 mesh) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11.0%

#2
AMMONIUM NITRATE (Fert, grade) . . . . . . . . . . . . . . . . . . . . . . . . . . . 78.0%
UREA (Powdered) .... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11.0%
CALCIUM SILICIDE (Powdered) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11.0%

#3
AMMONIUM NITRATE (Fert, grade) . . . . . . . . . . . . . . . . . . . . . . . . . . . 36.0%
SODIUM NITRATE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5.5%
CALCIUM NITRATE (Anhydrous) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8.0%
DYCYANDIAMIDE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5.5%
TETRYL . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 45.0%

#4
AMMONIUM NITRATE (Fert, grade) . . . . . . . . . . . . . . . . . . . . . . . . . . . 36.0%
S O D I U M NITRATE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5.5%
CALCIUM NITRATE (Anhydrous). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8.0%
DYCYANDIAMIDE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5.5%
AMMONIUM PICRATE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 45.0%

The tetryl additive in formula #3 is difficult to manufacture and unless the


manufacturer is very familiar with chemistry and lab procedure, its manufacture
is dangerous. This particular formula is given anyhow. The ammonium picrate
of formula four is simple to make. Picric acid is made or obtained (Kitchen
Improvised Plastic Explosives has a manufacture procedure for picric acid that
is very easy. Chapter 7). Ammonia water (plain) is placed in a glass jar. The picric
acid crystals are dropped into the ammonia water. This addition is completed.
The P.H. is checked with P.H. paper. It should be 7.0 or above. The ammonium
picrate crystals will form in the solution and should be filtered out and dried. The
other chemicals are very common. They would be very easy to obtain
surreptitiously.
AN-METHYLAMINE NITRATE
(Cast explosive) - "FORMIT"
DETONATION VELOCITY - 5400 M/sec.
DETONATION PRESSURE - Slightly less than T.N.T.
SENSITIVITY - Requires a booster for complete detonation.

USE-
BLASTING - A good choice, but cost effectiveness goes to ANFO. The need
for a booster limits blasting application. High gas yield upon detonation with
good shattering properties.
DEMOLITION - Could be used in the demolition field in some applications
that a cast explosive would find use. Perhaps could be used for mudcap type
blasting practices. Detonation velocity is the one of the two limiting factors for
this explosive.
MUNITIONS - Originally developed as a substitute explosive by the
Germans in WWII. The undesireable trait of this explosive, from a munitions
use standpoint, is the fact that, at slightly elevated temperatures (60-70 degrees
C.) this explosive extrudes from the device or shell it has been loaded in. Caution
should be taken to make sure that no copper or alloy of copper should come in
contact with the explosive composition.
Originally developed by Dr. Hans Walter as one of the substitute explosives
and designated "Formit". It is a faintly yellow explosive formulation. Developed
in the late part of WWII, as the Axis powers chemical industries were being
bombed to dust. The actual composition of this explosive is Methylamine
Nitrate ("MAN") 25-30%, Ammonium nitrate 67-74% and trimetnylammonium
nitrate 1-3%. MAN is the major sensitizer in E.I. DuPont's "Tovex" series
explosives. This is the only dynamite DuPont makes now. This is a cast
explosive with a setting point of 90 degrees C. The only drawbacks of this
explosive are the tendancies to extrude from the loaded munitions and the lower
detonation velocity as opposed to T.N.T.. This would be a simple explosive to
make. The 37% formaldehyde solution is added to the ammonium nitrate.
CAUTION: Avoid Breathing Formaldehyde! Use with GOOD ventilation!
The resulting solution is heated to boiling in a pyrex or stainless steel pan with
a lid for 1 hour ("Reflux"). This liquid is then placed in a "filtering"flask hooked
to a vacuum source. A vacuum pump will work and so will a vacuum aspirator,
but the latter will do so at a much cheaper cost. The vacuum will cause the
solution to boil at a much lower temperature. The flask should be placed in an
electric frying pan that has been filled with cooking oil. The oil should be kept at
90 degrees C.. The solution will boil away. End point of this is at 470 ml. liquid
remaining in the flask at a temperature of 90-100 degrees. A vacuum gage in line
will give a drastic change when the end point is reached as the vacuum is
increased. The water will have completely boiled out of the solution. This liquid
remaining in the flask is poured directly into the mold and allowed to cool, as the
remaining liquid in the flask is the melted explosive munition desired. When
casting explosive, care should be taken to leave a "well" or hole for the booster
and/or detonator.
37% Formaldehyde solution . . . . . . . . . . . . . . . . . . . . . . 450 ml.
AN Prills . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ..... . . . . . . 480 G.
The 37% formaldehyde can have paraformaldehyde substituted for it as in the
following:

Paraformaldehyde . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 180 G.
AN Prills . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 480 G.
Water . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 90 ml.

The AN is mixed with the water first and heated to effect solution. With
solution the Paraformaldehyde is added and the solution heated as in the first
composition and boiled for one hour as above and vacuum dehydrated as above.
The addition of 15% total explosive weight of R.D.X. or P.E.T.N. (from det.
cord) will give this explosive the same amount of power as T.N.T., but the
bristance or fragmentation effectiveness will be greater than T.N.T.. I also
believe that the addition of 20% bullseye smokeless powder will do nearly the
same thing. The undehydrated liquid could also be used as a sensitizer for
slurries.
AN-HYDRAZINE (Hydrazine nitrate)
DETONATION VELOCITY - 8500 M/sec.
DETONATION PRESSURE - 5,000,000 P.S.I.
SENSITIVITY - One #6 blasting cap will detonate.

USE-
BLASTING - Too expensive to be used.
DEMOLITION - Equivalent to C-4 in detonation velocity and bristance. The
only drawback of this explosive is its liquid form. This can be overcome with a
little planning.
This explosive is more powerful than C-4 plastique explosive. With its high
detonation rate and great bristance, it should find some use. It is more sensitive
than most explosives obtained from AN, since it is not AN but hydrazine nitrate.
This explosive liquid is very corrosive and this should be taken into affect when
suitable containers are rounded up in which to place the explosive. Hydrazine is
a hard chemical to find. Used as a rocket fuel, obtaining this chemical could
arouse suspicion. It is used as a boiler deoxygenator and perhaps could be
procured for this purpose. The manufacture is simple with the AN prills being
dissolved in the hydrazine by small additions with good ventilation, as ammonia
gas is produced by the reaction.
To manufacture this hydrazine compound, the hydrazine is placed in a
container that would hold five times the amount of hydrazine being used.
CAUTION: Hydrazine is a dangerous chemical and ALL and any contact what
so ever should be avoided.
The ammonium nitrate prills are added a little at a time in an area with good
ventilation, to avoid the ammonia gas produced. When the small additions of
AN are made, the solution will boil up in the glass container. This reaction
should be allowed to subside before the next addition. These additions should be
made until they no longer cause the effervescent reaction. More AN is added
while stirring until no more will dissolve in the solution. The liquid remaining is a
liquid explosive more powerful than any military explosive with the exception of
perhaps straight "MEDINA". This liquid can be used to boost a powdered
ammonium nitrate charge by powdering the AN and pouring the clear liquid
over the powder. The following percentage of this composition should give
explosives with a detonation velocity of 6800 M / sec., whereas the straight liquid
is much more powerful, this will effectively stretch the hydrazine nitrates power:

HYDRAZINE NITRATE L I Q U I D . . . . . . . . . . . . . . . . . . . . . . . . . 25%


AMMONIUM NITRATE (Powdered Fert.) . . . . . . . . . . . . . . . . . . 75%

Care should be taken so that this composition does not contact other things or
metals, except inert materials to ensure the explosive is not contaminated, as this
could result in a premature detonation.

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