Additives For Wood Plastic Composites 2009-090420
Additives For Wood Plastic Composites 2009-090420
Additives For Wood Plastic Composites 2009-090420
BU Base Products
Technical Marketing Waxes
20.04.2009
Additives for
Wood Plastic Composites
Wood Plastic Composites - Advantages
Decking
Fencing
Railing
Pigments PV Fast®
Flame retardants Exolit®
Lubricants Licocene®, Licolub®
Coupling Agents Licocene®
Light Stabilizers Hostavin®*
Blowing agents Hydrocerol®
(Div. Masterbatch)
Between filler and matrix usually there are poor bonding forces
⇒ bad mechanical properties prevent polymer-like
applications
Li Lic
Li coc oce Po
co e n ly
ce ne e P m
ne PP E er Polymer chain is compatible with the polyolefin
PP M MA
M A 6 43 matrix Î interactions via entanglements
A 4 51
74 52
52 TP
TP Reaction between two multifunctional polymers
Î crosslinked structures
40 4
Tensile Strength [N/mm²]
30 3
25 2,5
20 2
4,4
4,3
4,2
4,1 without
7500
HDPE 30 -x %
Soft-wood 70 %
7000 Compatibilizer 3%
6500
6000
E-Modulus [MPa]
5500
5000
4500
4000
3500
3000
Without Licocene high molecular high molecular
compatibilizer PE MA 4351 weight weight
compatibilizer compatibilizer Bending test
HV K 2 HV 1112 Tensile test
Leistritz ZSE 27 HP 44 D
170-170-180-180-190-190-190-190-190-195-200°C, die: 210 °C; 2 x 4 mm, 6 kg/h
Public: Additives for WPC
BU Base Products, Technical Marketing Waxes (Copyright Clariant. All rights reserved.) 20.04.2009 Slide 13
Coupling Agent for Soft-Wood-Filled PE
Improvement of Mechanical Properties
Best mechanical properties compared to high molecular weight compatibilizer
50 HDPE 30 -x %
Soft-wood 70 %
45 Compatibilizer 3%
40
Tensile strength [N/mm²]
35
30
25
20
15
10
5
0
Without Licocene high molecular high molecular
compatibilizer PE MA 4351 weight weight
compatibilizer compatibilizer
HV K 2 HV 1112
Leistritz ZSE 27 HP 44 D
170-170-180-180-190-190-190-190-190-195-200°C, die: 210 °C; 2 x 4 mm, 6 kg/h
Public: Additives for WPC
BU Base Products, Technical Marketing Waxes (Copyright Clariant. All rights reserved.) 20.04.2009 Slide 14
Coupling Agent for Polypropylene
70 12
60 10
Tensile strength [N/mm²]
0 0
compatibilizer
0,5 phr 1,5 phr 3 phr 5 phr 0,5 phr 1,5 phr 3 phr 5 phr
Without
Tensile strength
Licocene PP MA 7452 TP Licomont AR 504
Impact strength
PP resin 30 %
10 Soft-wood 67 %
80 Coupling agent 3%
9
70 8
60 7
6
50
5
40
4
30 3
Without Licocene Licocene
Coupling Agent PP MA 7452 TP PP MA 6452 TP
Maximum force (bending test)
Impact strength (impact test)
Compounding: Leistritz ZSE 27 HP 44 D (170-170-180-180-190-190-190-190-190-195-200°C; 2 x 4 mm die: 210 °C; throughput: 20 kg/h)
Injection Molding: Arburg Allrounder 320 C (170-190-200-210-210 °C, molding tool: 80 °C)
Public: Additives for WPC
BU Base Products, Technical Marketing Waxes (Copyright Clariant. All rights reserved.) 20.04.2009 Slide 19
Better Performance of Licocene PP MA
7452 compared to PP MA 6452
Formulation:
PP resin 30 %
8500
Soft-wood 67 %
1,3 Coupling agent 3%
8000
1,2
7500
E-Modulus [MPa]
Elongation [%]
1,1
7000
1
6500
6000 0,9
5500 0,8
5000 0,7
Without Licocene Licocene E-Modulus
Coupling Agent PP MA 7452 TP PP MA 6452 TP Elongation
Compounding: Leistritz ZSE 27 HP 44 D (170-170-180-180-190-190-190-190-190-195-200°C; 2 x 4 mm die: 210 °C; throughput: 20 kg/h)
Injection Molding: Arburg Allrounder 320 C (170-190-200-210-210 °C, molding tool: 80 °C)
Public: Additives for WPC
BU Base Products, Technical Marketing Waxes (Copyright Clariant. All rights reserved.) 20.04.2009 Slide 20
Better Performance of Licocene PP MA
7452 compared to PP MA 6452
PP 27 %
15000 Soft-wood 70 %
24 Test product 3%
14000
22
Flexural strength [N/mm²]
18
12000
16
11000
14
12 10000
Without Coupling Licocene Licocene
Agent PP MA 7452 TP PP MA 6452 TP Flexural strength
Breaking energy
Cincinatti Fiberex K 38
210-200-135-195-190-190-190-190°C, 34 rpm, 25 kg/h, Tool decking
Public: Additives for WPC
BU Base Products, Technical Marketing Waxes (Copyright Clariant. All rights reserved.) 20.04.2009 Slide 21
Licocene PP MA 7452 TP in WPC/PP
Water Absorption
Lowest water absorption compared to competitive coupling agents
112 PP 30 -x %
Soft-wood 70 %
Compatibilizer 3%
110
Thickness increase [%]
108
106
104
102
100 without
0 10 20 30 40 50 60 Licocene PP MA 7452 TP
Time [days] Gl 950
HV K 1
HV 8112
Leistritz ZSE 27 HP 44 D
60-150-180-180-190-190-190-190-190-195-200°C, die: 210 °C; 2 x 4 mm, 6 kg/h
Public: Additives for WPC
BU Base Products, Technical Marketing Waxes (Copyright Clariant. All rights reserved.) 20.04.2009 Slide 22
Licocene PP MA 7452 TP in WPC/PP
Processing Properties
Lower extrusion pressure, lower mass temperature compared to high molecular weight coupling agents
210 136 PP 30 -x %
Soft-wood 70 %
Compatibilizer 3 %
200
134
190
180
170 130
160 128
150
126
140
124
130
120 122
Without compatibilizer Licocene HV 1020 Mass temperature
PP MA 7452 TP
Extrusion pressure
Cincinatti Fiberex K 38
210-200-135-195-190-190-190-190°C, 34 rpm, 25 kg/h, Tool decking
Public: Additives for WPC
BU Base Products, Technical Marketing Waxes (Copyright Clariant. All rights reserved.) 20.04.2009 Slide 23
Licocene PP MA 7452 TP in WPC/PP
Improvement of Mechanical Properties
Highest E-Modulus in tensile- and bending test compared to competitive coupling agents
9000 PP 30 -x %
Soft-wood 70 %
Compatibilizer 3%
8000
E-Modulus [MPa]
7000
6000
5000
4000
3000
HV 1
0
HV 0
HV 0
HV 3
HV 0
15
00
12
HV 0
3
TP
74 r
MA lize
10
61
95
4
K
10
10
31
32
30
30
81
52
HV
Gl
HV
HV
PP t ibi
HV
pa
ce om
c
Li out
ne
Bending test
ith
co
W
Tensile test
Leistritz ZSE 27 HP 44 D
60-150-180-180-190-190-190-190-190-195-200°C, die: 210 °C; 6 kg/h
Public: Additives for WPC
BU Base Products, Technical Marketing Waxes (Copyright Clariant. All rights reserved.) 20.04.2009 Slide 24
Licocene PP MA 7452 TP in WPC/PP
Improvement of Mechanical Properties
Highest Tensile Strength compared to competitive coupling agents
PP 30 -x %
70 Soft-wood 70 %
Compatibilizer 3%
60
Tensile strength [N/mm²]
50
40
30
20
10
0
1
0
40
3
P
er
10
61
95
2T
K
iliz
10
HV
Gl
HV
HV
5
t ib
HV
74
pa
MA
m
co
PP
t
ou
ne
ith
ce
co
W
Li
Leistritz ZSE 27 HP 44 D
60-150-180-180-190-190-190-190-190-195-200°C, die: 210 °C, 6 kg/h
Public: Additives for WPC
BU Base Products, Technical Marketing Waxes (Copyright Clariant. All rights reserved.) 20.04.2009 Slide 25
Compatibilizer for Soft Wood-Filled PP
Pressure Along the Extruder (Decking Tool)
Lower extrusion pressure, compared to high molecular weight coupling agents, provides smoother
processing conditions
136 PP 30 -x %
Soft-wood 70 %
134 Test product 3%
Extrusion pressure [bar]
132
130
128
126
124
122
without Licocene PP MA 7452 TP HV 1020
Cincinatti Fiberex K 38
210-200-135-195-190-190-190-190°C, 34 rpm, 25 kg/h, Tool decking
Public: Additives for WPC
BU Base Products, Technical Marketing Waxes (Copyright Clariant. All rights reserved.) 20.04.2009 Slide 26
Compatibilizer for Rubber Wood-Filled PP
Machine Load and E-Modulus (Bending Test)
Lower machine load provides smoother processing, without loosing mechanical properties
PP 30 -x %
43 3000 Rubber wood 70 %
Test product 3%
2500
42 2000
Machine load [%]
E-Modulus [MPa]
1500
41 1000
500
40 0
without Licocene PP MA 7452 TP HV 1020 Machine load
E-Modulus
Cincinatti Fiberex K 38
220-215-135-195-190-190-190-190°C, 34 rpm, 25 kg/h, Tool decking
Public: Additives for WPC
BU Base Products, Technical Marketing Waxes (Copyright Clariant. All rights reserved.) 20.04.2009 Slide 27
Flame Retardants for WPC
After 10 s 15 s 30 s 60 s 90 s
After 10 s 15 s 30 s
60 % wood
x % flame retardant
0,5 3 % coupling agent
add 100 % polypropylene
(MFR 30 g/10 min at 230 °C/2.16 kg)
0,4
0,3
LOI
0,2
0,1
0
Without 5% 10% 15%
Exolit AP 422
60 % wood
10000 x % flame retardant
add 100 % polypropylene
9000
8000
[MPa]
7000
6000
5000
4000
Without 5% 10% 15%
Exolit AP 422
60 % wood
50 x % flame retardant
add 100 % polypropylene
48
[N/mm²]
46
44
42
Without 5% 10% 15%
Exolit AP 422
+ 2 % Licocene PE MA 4351
40 2
Tensile strength at break [N/mm²]
35
51
4
4
t
02
02
ou
10
10
43
13
13
th
HV
HV
MA
wi
PP
PP
ne
ne
PE
ce
ce
%
co
co
2
HDPE 50 -x %
Li
Li
ly
on
TP
TP
Maple-wood 50 %
Test products 3%
Leistritz ZSE 27 HP 44 D
160-160-170-170-180-180-180-180-185-185-190°C, die: 200 °C, 20 kg/h
Public: Additives for WPC
BU Base Products, Technical Marketing Waxes (Copyright Clariant. All rights reserved.) 20.04.2009 Slide 37
Lubricants for Maple Wood-Filled PE
Bending Test
+ 2 % Licocene PE MA 4351
3500
3000
2500
E-Modulus [MPa]
2000
1500
1000
500
0
51
4
4
t
02
02
ou
10
10
43
13
13
th
HV
HV
MA
wi
PP
PP
ne
ne
PE
HDPE 50 -x %
ce
ce
%
co
co
Maple-wood 50 %
2
Li
Li
ly
Test products 3%
on
TP
TP
Leistritz ZSE 27 HP 44 D
160-160-170-170-180-180-180-180-185-185-190°C, die: 200 °C, 20 kg/h
Public: Additives for WPC
BU Base Products, Technical Marketing Waxes (Copyright Clariant. All rights reserved.) 20.04.2009 Slide 38
Lubricants for Maple Wood-Filled PE
Processing Properties
Highest output and lowest energy consumption with Licocene PE MA 4351 and Licocene PP 1302
+ 2 % Licocene PE MA 4351
9 0,1
0,06
5
4
0,04
3
2 0,02
1
0 0
51
4
4
t
02
02
ou
10
10
43
13
13
th
HV
HV
MA
wi
PP
PP
ne
ne
PE
ce
ce
co
co
HDPE 50 -x %
Li
Li
ly
on
TP
TP
Maple-wood 50 %
Test products 3%
Compounding: Leistritz ZSE 27 HP 44 D
160-160-170-170-180-180-180-180-185-185-190°C, die: 200 °C, 20 kg/h
Public: Additives for WPC
BU Base Products, Technical Marketing Waxes (Copyright Clariant. All rights reserved.) 20.04.2009 Slide 39
Lubricants for Maple Wood-Filled PE
Pressure Along the Extruder and E-Modulus
Lowest extrusion pressure, highest E-Modulus with Licocene PE MA 4351 and Licocene PP 1302
HDPE 40 -x %
130 3000 Maple Wood 60 %
Test product 1 2%
Test product 2 2%
2500
Extrusion pressure [bar]
125
E-Modulus [MPa]
2000
120
1500
115
1000
110 500
105 0
2
3
t
51
ou
0
11
13
43
th
P
+H
wi
MA
+P
PE
1
5
5
43
t
Extrusion pressure
43
on
MA
m
MA
co
E-Modulus
PE
PE
Li
172
Mass temperature [°C]
171
170
169
168
167
without 2 % Licocene PE MA 2 % PE MA 4351
4351 + 1,5 % PP 1302
Cincinatti Fiberex K 38
210-200-150-160-175-175-175-175°C, 28 rpm, 25 kg/h, Tool decking
Public: Additives for WPC
BU Base Products, Technical Marketing Waxes (Copyright Clariant. All rights reserved.) 20.04.2009 Slide 41
Lubricants for Wood-Filled Polypropylene
Profile Extrusion
Better surface
Lower cavity pressure
Higher throughput
Formulation: 70 % Wood
3% Coupling Agent
4% Lubricant
23 % Polypropylene (MFR 30 g/10 min at 230 °C/2.16 kg)
Public: Additives for WPC
BU Base Products, Technical Marketing Waxes (Copyright Clariant. All rights reserved.) 20.04.2009 Slide 42
Lubricants for Soft Wood-Filled PP
Pressure Along the Extruder (Decking Tool)
Lowest extrusion pressure with Licocene PP MA 7452 and Licocene PP 1302
136 PP 30 -x %
Soft-wood 70 %
Test product 3%
134
132
Extrusion pressure [bar]
130
128
126
124
122
120
without Licocene PP MA HV 1020 PP MA 7452
7452 TP + PP 1302 (1,5 %)
Cincinatti Fiberex K 38
210-200-135-195-190-190-190-190°C, 34 rpm, 25 kg/h, Tool decking
Public: Additives for WPC
BU Base Products, Technical Marketing Waxes (Copyright Clariant. All rights reserved.) 20.04.2009 Slide 43
Lubricants for Rubber Wood-Filled PP
Machine Load and E-Modulus (Bending Test)
Lowest machine load, highest E-Modulus with Licocene PP MA 7452 and Licocene PP 1302
PP 30 -x %
43 3500 Rubber wood 70 %
Test product 3%
42 3000
2500
41
Machine load [%]
E-Modulus [MPa]
2000
40
1500
39
1000
38 500
37 0
without Licocene PP MA HV 1020 PP MA 7452 Machine load
7452 TP + PP 1302 (1,5 %) E-Modulus
Cincinatti Fiberex K 38
220-215-135-195-190-190-190-190°C, 34 rpm, 25 kg/h, Tool decking
Public: Additives for WPC
BU Base Products, Technical Marketing Waxes (Copyright Clariant. All rights reserved.) 20.04.2009 Slide 44
Industrial Recommendation I
Reifenhäuser Extrusion GmbH & Co.KG
Without ‒ ‒‒
3 % Coupling Agent + ‒
3 % Coupling Agent
++ +
+ 1,5 % Licolub H 12
General remarks:
– Lower wood filling level
(40 – 60 %)
– Efficient compatibilizer
hardly available
– Strong demand for lubricants
– „Standard“ lubricants like
EBS waxes, Ca-stearate,
PE waxes in use
130
PE PE 5301
4201
PP 4202
PE
[°C]
110
3401
PP 2602
PE 2401
90 PP 1302 PP PP
1502 1602
70
50
1 10 100 1000 10000 100000
[mPa.s]
(Measuring temp. PE: 140°C, PP: 170°C)
250
Oxidized PE wax 0,2 phr
200 Test product 1,0 – 1,25 phr
150
100
50
4 0,08
e - Value [kWh/kg]
3,5
Output [kg/h]
0,06
3
0,04
2,5
2 0,02
0
0
G
52
52
F
01
02
E
PE
42
xP
61
E
x
wa
wa
P P
ne
co
ico
ne
ce
Li
ce
ico
hr
hr
ico
5p
1p
Output
L
L
hr
1,2
hr
1p
e - Value
1p
16
Impact strength [kJ/m²]
12
0
0
0
G
52
52
2F
01
E
PE
42
10
xP
E
x
6
wa
wa
ne
ne
co
ico
ce
ce
Li
ico
L
ico
hr
hr
L
5p
1p
hr
hr
1p
1,2
1p
150 186
130 185
110 184
90 183
70 182
1 phr Licolub 1 phr Licocene 1 phr Licocene 0,5 phr Licocene
H4 PP 6102 PP 1502 PP 6102 + 0,5 phr Torque [Nm]
Licolub WE 4 Melt temperature [°C]
Extrusiometer E 30 M: D= 30 mm, 25 L/D, n= 30 rpm,
Temperature: 170-180-190-195-195°C, round-section die: 200°C
Public: Additives for WPC
BU Base Products, Technical Marketing Waxes (Copyright Clariant. All rights reserved.) 20.04.2009 Slide 52
Tin-Stabilized PVC Wood-Compounds
Output and Energy Consumption
29 0,07
28
26
Output [kg/h]
0,05
25
24
0,04
23
22 0,03
21
20 0,02
1 phr Licolub 1 phr Licocene 1 phr Licocene 0,5 phr Licocene
H4 PP 6102 PP 1502 PP 6102/ 0,5 phr Output
Licolub WE 4 Energy consumption
CE3Z twin screw: D= 52-24 mm, 25 L/D, n= 30 rpm,
Temperature: 180-190-190-190-190°C, flat-die: 190°C
Public: Additives for WPC
BU Base Products, Technical Marketing Waxes (Copyright Clariant. All rights reserved.) 20.04.2009 Slide 53
Water Bath Storage /
Extrusion Specimen
No significant differences (Standard bars / Charpy)
Weight increase about 1,4 – 1,7 % within 10 days and about 2,0 – 2,5 % within
20 days
Licowax PE 520
Licocene PP 6102*
TP Licocene PP 1502
Licocene PP 6102 /
Licolub WE 4