Basic concepts and Zeroth Law of Thermodynamics System, Surrounding ‘© Properties + Intensive + Extensive * Process Quasistatic and Non quasistatic + Reversible and Irerversibility * Zeroth law and Application (Types of thermometes) Energy (Work, Heat and First law of ‘Thermodynamics or Closed System) * Closed system work ‘+ Types of process * Ideal gas equations * First law (Closed system) + Heat interaction in various process + Internal energy and Enthalpy + Freeexpansion First law of Thermodynamics for Open System + Steady flow energy * Unsteady state ‘Second law of Thermodynamics ‘Thermal energy reservoir Kelvin plank and Clausius statement * Carnot principle * Temperature scale * Clausius inequality Entropy, Available energy and Irreversibility * Basic discussion * Entropy generation and Entropy change of universe * Closed system analysis * Open system analysis * Available energy calculation for different systems * Irreversibility and Gouy-stodola theorem Properties of Pure Substances * Basic discussions © Enthalpy and entropy calculation in various ‘Thermodynamic Relations (Only for GATE) * Gibbs function and Helmholtz function + Maxwell equations ‘+ Ts partial differential equations * To prove C, > C, and develop generalised Meyer's equation Energy equation ‘+ Joule Thomson coefficient ‘+ Clausius clapeyron equation7-¢ ea tae 8 4-4 10 -€ SHO t—b ss [Mf muttipte choice Questions {DA Aclosed systemis one whose boundaries allows (a) Only energy transfer (b) Only mass transfer (c) Both energy and mass transfer (d) None of the above The Zeroth law of thermodynamics deals with (@) Mechanical equilibrium (©) Chemical equilibrium (6). Thermal equiliorium (8) Thermodynamic equilibrium 3. thermodynamic property (@) Depends on the past history of the system (b) Does not depend on the past history of the system (©) Cannhave different values when the system ‘ is ina particular state, depending upon how the system is brought to that state (@) None of the above Which of the following are pure substances? 1. Gaseous air 2. Amixture of gaseous air and liquid water 3. Amixture of liquid water and water vapour 4. Amixture of gaseous air and oll (@) tand2 (o) 2and 3 (©) 3and4 (@) tand3 Which of the following statements regarding the concept of continuum are correct? 1. Large number of molecules enable meaningful statistical averaging and assignment of property values as aed aiton roa wD Fu DOB 0 PaanbOE ea Neu wood Hap UEGCH, La8O MONT UDI NSVE SOW Basic Concepts and Zeroth Law of Thermodynamics de 2. Mean free path of the molecules is order of magnitude higher than system dimensions 3, Behaviour of individual molecules is disregarded 4, Mean free path of the molecules approaches the order of magnitude of the system dimensions (@) 1and3 (o) 2and3 (©) 3and4 (©) tand4 For NH;-H,O mixture system existing in two phases in equllbrium, the number ofindependent properties requiredito fxthe state ofthe system are (a) 1 (o) 2 (©) 3 4 Which of the following are intensive properties? 1. Energy 2. Volume 3. Pressure « 4, Specific enthalpy, (@) 1and2 (b) 2and3. (©) 3and4 (@) 1and4 A single fixed point temperature scale is based on (a) Ice point (b) Steam point (©) Triple point of water (d) Critical point of water Experimental data obtained from a constant volume-gas thermometer is shown is the figur below. The value of lin °Cis Pp er re 4Publications Workbook 5 (@) 273.15 (&) 10 Coles (@) -100 (d) -273.15 ° P Qe,_s ° 0 Inthe tigure showing a schematic ofa thermal | 8 7 1 2 3 4 power plant, the closed system(s) and open |S 2 1 3 4 system(s) are correctly identified as z @2 14 3 2 @i 2 4 3 2 (a) boiler and condenser are open system and turbine, pump and overalll plant are closed systems turbine and pump are open systems and boiler, condenser and overall plant are closed system boiler, turbine, condenser and pump are open systems and overall plantis a closed system overall plant is an open system and boiler, turbine, condenser and pump are closed systems (b) (©) (@) Asystemis partitioned into two equal parts. An intensive property of each part will (@) Become halt (b) Remain unchanged (c) Double (@) Depend on the nature of the intensive property Match List-I with List-II and select the correct, answer using the codes given below the lists: List-1 A Jet engine is flight Water being heated in a sealed container Internal eneray Specific entropy List-I1 1. Closed system 2. Open system 3. Intensive property 4. Extensive property ypon Te peanporder aq Keui yooq Su jo ed ON WIRG MON BuOREOIRNG ASV SGWN OV eur inouiIn wr9) AUR UI ‘wojseved vai In anew temperature scale °P, the boiling and freezing points of water at one atmosphere are 100°P and 300°P respectively. Correlate this scale with the centigrade scale. The reading of O°P on the centigrade scale is (@) oc (b) -80°C (©) 100°C (6) +150°C Q.14 Which one of the following correctly defines 1 K, as per the internationally accepted definition of temperature scale? 2" 1 709th of the difference between normal boiling point and normal freezing point (a) 1 L rats #1 of the normal freezing point of water 100 times the difference between triple point of water and the normal freezing point of water 1 273.16 (b) (©) () thf the triple point of water |, 215 Which thermometer is independent of the substance or material used in its construction? (@) Mercury thermometer (b) Alcohol thermometer (©) Ideal gas thermometer (d) Resistance thermometer Q16 Triple point of water is (a) 273K (b) 273.14K (©) 273.15K (d) 273.16K | 2:17 The following are examples of some intensive and extensive properties 1. Pressure 2. Temperature 3. Volume 4, Velocity