International Journal of Engineering Trends and Technology (IJETT) – Volume 19 Number 2 – Jan 2015

Effect of Glass Powder and GGBS on Strength of Fly Ash Based

Geopolymer Concrete
Dr. I.R. Mithanthaya Dr. N. Bhavanishankar Rao
Professor, Dept. of civil Engineering, NMAMIT, Professor, Dept. of civil Engineering, NMAMIT,
Nitte, Karkala-574110, India Nitte, Karkala-574110, India

Abstract I. INTRODUCTION
In this study, the effect of glass powder (GP) and ground A. Scope for study
granulated blast furnace slag (GGBS) on the compressive Industrialization and uncontrolled exploitation of natural
strength of Fly ash based geopolymer concrete has been resources has lead to the formation of large quantity of
investigated. The mass ratio of fine aggregate (fA) to coarse industrial waste materials which pose problem of disposing
aggregate (CA) was maintained constant. NaOH flakes dissolved such materials and environmental pollution. Fly ash from
in water was used as activating liquid and mixed with fly ash thermal projects, GGBS from steel industries, broken glass
(FA) to produce geopolymer paste or cementing material. This from building industries and quarry dust from granite quarries
paste was added to mixture of CA and fA to obtain geopolymer are examples of industrial waste materials posing problems.
concrete. Cube samples were prepared from this concrete. The These are to be recycled / reused properly instead of disposing
ranges of investigation parameters include GP/FA from 0% to them as waste materials. Considerable research is taking place
20%, and GGBS/ FA from 0% to 20% with constant amount of throughout the world in developing suitable technologies for
GP. All the samples were air cured inside laboratory under room proper utilisation of these industrial waste materials. An
temperature. Compressive strength of cube samples after 7 days attempt made in this regard is presented in this paper.
and 28 days curing were determined. The test results are Davidovits 1994), (2005) suggested that an alkaline liquid
presented and discussed. Based on the results of limited tests, a could be used to react with Silicon (Si) and Aluminium (Al) in
suitable composition of FA, GP and GGBS for constant quantity a source material of geological origin or in by-product
of CA and fA has been obtained to produce geopolymer concrete materials such as fly ash to produce a good binder or
of M32. It is found that geopolymer concrete is 14% cheaper than cementing material. He named this binder as “Geopolymer”
concrete of the same strength using OPC. The strength gain in because the chemical reaction that takes place is a
the case of geo-polymer concrete is rather slow compared to that polymerisation process. Geopolymer is belonging to the
of Portland cement concrete. Tensile strength of this concrete family of inorganic polymers and the process involves a
was also determined by conducting flexure test on beams substantially fast chemical reaction under alkaline condition
prepared using this concrete. During curing, up to 7days, greyish- on Si-Al minerals.
white powder used to come out from all the surfaces of sample
and it was found to be a mixture of Carbonates and Sulphides of The main constituents of geopolymer are an alkaline liquid
Na, Mg and Fe. Detailed investigation is necessary to arrive at an and source materials. The source materials should be rich in
optimum mixture composition for producing Geo-polymer Silicon and Aluminium. They could be natural minerals such
concrete of required strength. Effect of greyish-white powder on as clays, metakaolin a product of kaolin clay or by-product
the strength and durability of the concrete is to be studied. materials such as fly ash (FA), silica fume (SF), Sodium
silicate, ground granulated blast furnace slag (GGBS), rice-
Keywords: Geopolymer, industrial waste, green material, cost husk ash (RHA) etc. Alkaline liquid is Sodium hydroxide
effective material, eco-friendly material. solution.

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 International Journal of Engineering Trends and Technology (IJETT) – Volume 19 Number 2 – Jan 2015
Geopolymer concrete can be produced using low-calcium fly indicated the possibility of attaining compressive strength up
ash obtained from thermal power plants where it is formed as to M30 without using plasticizer. Further improvement is
a by-product of burning anthracite or bituminous coal. Coarse possible using better mixture design and reducing water
and fine aggregates used for making Portland cement concrete content using plasticizer or super plasticizer. Such studies are
can also be used to make geopolymer concrete. Sodium in progress
hydroxide with 97%-98% purity in the form of flakes is
commercially available which can be dissolved in water to II. EXPERIMENTAL INVESTIGATION
have concentration in the range of 8 molar to 16 molar. Mass A. Selection of constituent materials
of NaOH required depends on the concentration required. It is well established that the constituents for
NaOH solution with concentration of 8molar requires geopolymerization should consist sufficiently large amount of
8x40=320 grams of NaOH flakes per litre of water. In order to Silicon and Aluminium oxides which should be soluble in an
improve the workability of the geopolymer concrete, a water alkaline solution to form reactive Si and Al. FA consists of
reducer super plasticizer or extra water may be added to the aluminosilicate and is selected as an important source material
mixture. The constituent materials can be mixed thoroughly for Si and Al. However, it is necessary to have additional
using appropriate method or approach to obtain geopolymer material which can provide more reactive silica Si and Al at a
concrete of required consistency or slump. reasonable cost. Caijun Shi et al, (2005) and Bajad et al,
B. Objective of the Study (2012) reported that Glass powder finer than 600micron
The objective of the study was to quantify the effects of becomes reactive silica. Hence, it can be used as an additional
adding glass powder and GGBS which are industrial waste source for Si. The chemical analysis of available FA indicated
materials, on the compressive strength of fly ash based low percentage (less than 9%) of Aluminium oxide. In order to
geopolymer concrete. Generally, geopolymer concrete is cured increase the amount of Al in geopolymer, GGBS can be added
under high temperature to get increased strength in a short as an additional source for Al. The above facts were
period which involves additional cost and input of additional considered in selecting materials for the experimental study
energy. Hence, the gain in the strength due to air curing of this reported in this presentation.
concrete under room temperature only was considered in this B. Materials used
study. The materials used in the study are: 1) Fly ash (FA), (2) Glass
C. Research Significance powder (GP), (3) GGBS, (4) NaOH flakes, (5) Fine aggregate
Geopolymer concrete has shown great potential in use for fA, (6) Coarse aggregate CA and (7) Water (W). Details of
construction purposes. In the literature, use of several costly these materials are given below.
constituents has been suggested to increase the strength of this Fly-ash
concrete. In many of the studies, it is shown that the curing Fly-ash from a thermal plant (Udupi Power Corporation Ltd)
0 0
under high temperature (60 C to 100 C) is required to attain close to our Institute was collected, sieved using 600 micron
2 2
the strength in the range of 60N/mm to 80N/mm . For IS sieve and used for the experiment. Major components of
practical applications, it is necessary to identify cheaper and Fly ash was found to be Silica (SiO2) = 80.2%, Alumina
effective constituent materials and obtain strength in the range (Al2O3) = 8.7% and Iron Oxide (Fe2O3) = 2.8%. Its specific
M30 to M50 without going for heating which is a laborious and gravity was found to be 2.38.
costly process. Thus the geopolymer concrete can be made Glass Powder
economical, popular, attractive and convincing the people in Glass powder was obtained by crushing available waste glass
the construction field. Use of a few cheaper constituents pieces using a crusher and the powder passing through

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 International Journal of Engineering Trends and Technology (IJETT) – Volume 19 Number 2 – Jan 2015
600micron IS sieve was used in the investigation. required number of cubes of 15cm size were calculated for
GGBS Powder different mixes and recorded. Sodium hydroxide flakes of
This powder available in market was collected, sieved using 0.75kg were dissolved in 2.978 litre of water to form an
600 micron IS sieve and used for the experiment. Its specific alkaline solution. Selected amount of FA or (FA + GP) or
gravity was found to be 2.88. (FA+GP+GGBS) as the case may be added to NaOH solution
Aggregate and mixed properly for about 10minutes to form a
Coarse aggregate with 20mm down, having FM=6.67 and homogeneous geo-polymer paste. This paste was added to pre-
specific gravity = 2.72 was used. Fine aggregate having FM= mixed aggregate (CA+fA) quantity placed on a GI sheet of
2.48 and specific gravity = 2.63 was used. 1mx2m size. All the materials were mixed properly to obtain a
Alkaline Liquid homogeneous and cohesive geopolymer concrete. In order to
Commercially available NaOH flakes dissolved in drinking or increase the workability, an additional quantity of 0.9 litre
potable water was used as alkaline liquid. water was added and mixed properly. The concrete so
prepared was placed in to steel cubes of 15cm size, compacted
C. Mix Proportion using standard tamping rod, levelled and kept in an isolated
Since there is no standard procedure for designing the mix place for air curing at room temperature in the laboratory.
proportion, considering the information available in Demolding of samples after 24 hours was not possible as they
literature, the following steps were used for designing required were not hard enough. Hence, after 3 days, the concrete cubes
mix for experimental investigation. Using the results of sieve were removed from the mould and cured in air till they were
analysis of course and fine aggregates four trial mixes of tested.
aggregates were selected and these mixes were used for In the first stage polymer paste was prepared by mixing FA
determining maximum bulk density. From the trials it was and NaOH solution and in the second stage mixture of FA and
found that mix with mass ratio of CA/fA = 0.522 gives different % of GP was used to mix with NaOH solution to
maximum density. Mass ratios for other materials were prepare the paste. In the third stage, mixture of FA, 10% GP
selected based on the information available in literature. and different % of GGBS was used to mix with NaOH
Hence, solution to prepare the paste.
. The mass ratio CA/fA is 0.522 When the cubes were tested after 7 days of curing, the
NaOH/FA or NaOH/(FA+GP) or NaOH/(FA+GP+GGBS) was strength obtained for concrete having FA and 10% GP was
taken as 7.50% found to be the highest. Hence, it was decided to prepare
W/FA or W/(FA+GP) or W/(FA+GP+GGBS) was taken as 0.3 concrete having FA, 10% GP and different percentages of
The mass ratio for different batches of concrete, (CA+fA)/FA, GGBS to study the effect of GGBS on the strength of geo-
(CA+fA)/ (FA+GP),(CA+fA)/ (FA+GP+GGBS) was polymer concrete.
maintained as 3.5 In order to study the tensile strength of concrete having
Variables considered were: (FA+GP+GGBS), the mix which gave the maximum
. GP/ FA 0%, 5%, 10% 15% and 20% compressive strength for 28 days of curing was used to cast
. GGBS/FA 0%, 5%, 10%, 15%, 20%, with GP/FA as 10% beams of 15cm, 15cm and 50cm size and cured for 28 days
Nine different mixes were considered and totally 54 before testing,
cubes were cast. During curing period greyish white powder was coming out
III. PRODUCTION OF TEST SAMPLES from all surfaces. When it was wiped out after 7 days using
Quantities of different constituents required for making wet cotton waste, it was stopped. This powder was subjected

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 International Journal of Engineering Trends and Technology (IJETT) – Volume 19 Number 2 – Jan 2015
to chemical analysis. Replace 0% 5% 10% 15% 20%
ment of
IV. TESTS CONDUCTED FA by
Cube samples were weighed after air curing for 7 and 28 days GP
Unit 8.15 8.13 8.11 8.05 7.97
and tested for compressive strength using compression testing weight in
machine of 2000KN capacity in accordance with the kg
Water 6.0 6.0 6.7 6.0 7.0
procedure mentioned in IS 516- 1959. absorptio
Beam samples were tested after 28 days of curing using “Two n in %
Table 4 :Variation in Unit Weight of Cubes and Water absorption –FA+ 10%
point loading” in universal testing machine of 40 tonnes
GP+ GGBS
capacity.
Replacement 5% 10% 15% 20%
Small pieces of failed concrete cubes were used for finding of FA by
their water absorption as per IS 2386 (Part III) 1963. GGBS
Unit weight in 7.95 8.005 8.055 8.074
V. EXPERIMENTAL RESULTS AND DISCUSSION kg
A. Presentation of Results Water 6.6 6.2 6.3 5.5
absorption in
Results of compression tests are shown in Table 1 and Table 2 %
and they are also depicted in Fig.1 to Fig.3. Variation in unit
weight of cubes and water absorption in % are shown in Table B. Discussion of Results
3 and Table 4. Average flexural strength of beam was found to Fig.1 clearly shows that the 7days cube strength increases as
be 2.1N/mm2. the replacement of FA by GP increases up to 10% and then
White powder coming out from the surfaces of samples was slightly decreases. However, the 28days cube strength is
found to be Carbonates and Sulphides of Sodium ( NA), increasing as the replacement of FA by GP increases up to
Magnesium (Mg) and Fe from the chemical analysis. 15% and then becomes almost constant. Since the 7days
strength decreased after 10%, it was decided to use 10%
Table 1 : Variation in Compressive Strength of Cubes in MPa For (FA+GP) replacement by GP and further replacement by GGBS.
Replacement 0% 5% 10% 15% 20%
of FA by GP
7 Days 4.22 5.45 6.67 4.89 5.34 Fig.2 shows the influence of replacement of FA by GGBS with
Compressive
10% replacement of FA by GP. It is observed that both 7days
Strength
28 Days 13.1 14.32 15.56 16.67 20.89 and 28 days strength increase continuously up to 15%
Compressive 1
replacement and afterwards the increase is small ie 1.4% to
Strength
4% respectively. Hence, the replacement up to 15% appears to
Table 2 : Variation in Compressive Strength of Cubes in MPa For (FA+ 10% be optimum and further increase is not much useful from the
GP+ GGBS) strength point of view. It is also observed from this figure that
Replaceme 0% 5% 10% 15% 20% 7days strength is 30% to 50% of 28 days strength where as it
nt of FA by will be about 70% for Portland cement concrete. Thus, the
GP
7 Days 6.67 8.33 12.45 16.67 17.33 strength gain in the case of geo-polymer concrete is rather
Compressiv slow compared to that of Portland cement concrete.
e Strength
28 Days 15.56 20.00 25.22 32.44 32.89
Compressiv
e Strength
Table 3: Variation in Unit Weight of Cubes and Water absorption –FA+GP

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 International Journal of Engineering Trends and Technology (IJETT) – Volume 19 Number 2 – Jan 2015
Fig.3 depicts a comparison of 28days strength for mixes
Variation in Compressive Strenth of without GGBS and with GGBS. Use of GGBS is certainly
25 Cubees for (FA+GP) useful in increasing the strength of Geo-polymer concrete with
Compressive strngth in MPa

20 10% replacement of FA by GP. However, it is necessary to

investigate the effect of 15% replacement of FA by GP and
15
7 Days replacement of FA by GGBS which may help in arriving at an
10 Strength optimum mixture of industrial waste materials for Geo-
5 polymer concrete.

0
0 5 10 15 20 Table 3 shows that the unit weight of cubes decrease
Replacement of FA by GP in % gradually as the replacement of FA by GP increases. But, from
Figure 1: Compressive Strength of Cubes: FA +GP the Table 4, it is seen that unit weight of cubes increases with
increase in replacement of FA by GGBS with constant value of
GP. This is due to the difference in specific gravity of GP and
Variation in Compressive Strenth of GGBS compared to FA. Water absorption of Geo-polymer
Cubes for
40 concrete is observed to be almost constant for both the mixes
(FA + 10 %GP +GGBS )
Compressive strngth in MPa

as depicted in the Table 3 and Table 4.

30
These results clearly show that Geopolymer concrete with
20 7 Days
Strength compressive strength of 30Mpa and water absorption less than
10 7% can be easily obtained using industrial waste materials
without using Sodium Silicate, Silica fume (costly materials)
0 or heating to higher temperature (costly process).
0 5 10 15 20
Replacement of FA by GGBS in % VI. COST ANALYSIS
Figure 2: Compressive Strength of Cubes: FA + 10% GP + GGBS Comparison of cost of producing 1M3 of concrete using
Portland cement and geo-polymer concrete used is shown
Variation in 28 days Compressive in the following Tables
40 Strenth of Cubes Table 5: Cost of 1M3 Portland cement concrete of M30 as per IS 10262
Compressive strngth in

30 Material Quantity Rs / unit Cost in Rs

/1M3
20 (FA+GP) Cement 465kg 6.8/kg 3162.00
MPa

Fine 0.395 m3 1000 / m3 395.00

10 aggregate
Coarse 0.762 m3 1220 / m3 937.26
0
aggregate
0 5 10 15 20
Replacement of FA by GP/ GGBS in % Water 192.69 0.5/Litre 96.35
Litre
Figure 3 : Comparison of 28 days Strength for two mixes

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 International Journal of Engineering Trends and Technology (IJETT) – Volume 19 Number 2 – Jan 2015
Table 6 Cost of 1M3 geo-polymer concrete of M32 coming out from all the Surfaces of cube sample /beam
Material Quantity Rs / unit Cost in sample, during initial periods of curing is found to be a
/1M3 Rs mixture of bicarbonates of Sodium, Magnesium and sulphides
Fly ash 367.33kg 2 / kg 734.66
Glass 48.98 kg 1 / kg 48.98 of Iron.
powder 7.Geo-polymer concrete is about 14 % cheaper compared to
GGBS 73.47 kg 4 / kg 293.88 concrete using PC.
NaOH 36.74kg 40 / kg 1469.60
Flakes
Fine 0.391 m3 1000 / m3 391.00 ACKNOWLEDGMENT
aggregate Experimental work was carried out using the facilities in Civil
Coarse 0.751 m3 1220 / m3 916.22 Engineering Department Laboratory of N.M.A.M Institute of
aggregate
Technology, Niite. The authors wish to thank the authorities of
Water 191.5 0.5/Litre 95.75
Litre N.M.A.M Institute of Technology for their kind support and
From the above tables, it is observed that geo-polymer encouragement.
concrete is 14 % cheaper than conventional concrete.
REFERENCES
VII. CONCLUSIONS [1] Davidovits J, Properties of Geopolymer cements, First International

Geopolymer concrete was produced using available industrial Conference on Alkaline Cements and Concretes (pp 131 -149), Kiev,

waste materials (FA, GP, GGBS), Sodium Hydroxide as Ukraine: Kiev State Technical University 1994.

activating solution, fine aggregate and coarse aggregate. [2] Davidovits J, Green Chemistry, Sustainable Development and False ideas

Different proportions of waste materials were considered to About Geopolymer Concrete, International Workshop on Geopolymers and

prepare the mixes. Cubes of 150 mm size were prepared from Geopolymer Concrete, Perth, Australia, 2005.

each mix, cured in air at laboratory temperature and tested for [3] Caijun Shi, Yanzhhong Wu,Chris Riefler andHugh Wang,

compressive strength. Based on the results the following “Characteristics and Pozzolanic reactivity of Glass powders”, Cement and

conclusions are drawn: Conc. Res., Vol. 35, 2005, pp 987-993

[4] Bajad M.N, Modhera C.D and A.K.Desai, Higher Strength Concrete

1. Use of FA and Sodium Hydroxide in making Geopolymer Using Glass Powder. Journal of Structural Engineering Vol.39, Number 3

concrete is not sufficient to obtain required strength. Aug.2012

2. Replacement of FA by GP up to 15% is useful in increasing [5] Ramlan. A.G, Albert Oomman Roy, Sujan Kumar, Sherin Rajan and

compressive strength up to 20Mpa. Supreetha. “Geo-Polymer Concrete Using Industrial Waste” Project Report

3. 10% replacement of FA by GP and further replacement of Submitted to V T U in Partial Fulfillment for the Award of B E Degree in Civil

FA by GGBS up to 15% increases the strength of concrete up Engineering. (April,2013)

to 32Mpa.
4. Water absorption of concrete made with different % of FA,
GP, and GGBS is found to be almost constant.
5. Geopolymer concrete with compressive strength of 30Mpa
and water absorption less than 7% can be obtained using only
industrial waste materials without using Sodium Silicate or
heating to higher temperature.
6.In all the mixes used, a greyish white powder which was

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