Defects in Galvanised Coatings INGALSM3
Defects in Galvanised Coatings INGALSM3
Defects in Galvanised Coatings INGALSM3
INTRODUCTION
Unlike many manufacturing processes, the hot dip galvanizing of
fabricated steelwork involves many variables that can impact on
the appearance and characteristics of the finished product.
The variables inherent in the process can each affect the Distortion of thin checker plate welded to
heavier supporting members can be reduced
appearance of the galvanized product. Many of these variables by fixing the checker plate after galvanizing
are classified as ‘coating defects’. Most are easthetic and do not
affect the performance of the galvanizing as an anti-corrosion
coating.
The hot dip galvanizing process involves immersing steel items in molten zinc at 450oC after pre-
treatment to remove organic materials, rust and mill scale. This hot dipping process, where the
steel is immersed in the molten zinc for several minutes, gives the galvanized coating its unique
characteristics.
The angle with which the work can be withdrawn from the bath will influence the drainage
characteristics. One-dimensional items that are short enough to dip vertically will produce smoother
and more uniform coatings than 2- or 3-dimensional items where some surfaces will be at shallow
withdrawal angles from the molten zinc.
Structural grades of steel always contains alloying elements, the most common of which are carbon,
manganese and silicon. Sulfur and phosphorous are residual elements arising from the raw material
used to make the steel, although some special steels have these elements added deliberately.
Of these elements, silicon and phosphorous have the most significant effect on the galvanized
coating’s characteristics, with silicon being the most common steel alloying additive affecting coating
appearance.
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18. GALVANIZED COATING DEFECTS
Conversely, if the molten zinc cannot completely drain from the work, zinc puddles will freeze in
pockets and cause problems.
The techniques of designing for galvanizing are well understood by galvanizers and consultation in the
design stage of fabrication will always result in a better quality outcome.
The main issues to be addressed in designing for galvanizing to minimise defects are as follows:
1. The item needs to be suspended during galvanizing. The provision of lifting lugs to eliminate touch
marks from wire or chains is an example of design improving quality.
2. The item needs to be have adequate venting and draining provisions to ensure the smooth flow of
zinc into and out of the item.
3. The dimensions of the item need to comfortably fit within the bath dimensions to allow adequate
withdrawal angles. Double dipping of the item will frequently produce a better quality than single
dipping an item that can be barely submerged in the bath.
2. When the steel reaches galvanizing bath temperature, the zinc reacts with the steel to form a series
of zinc-iron alloys. Some of these zinc-iron alloy crystals float off the surface of the steel and enter
the zinc bath.
3. The zinc bath becomes saturated with iron in solution, either from work entering the bath or from
the steel galvanizing kettle. This saturation level is typically about 250 parts of iron per million at
galvanizing temperature.
4. Over time, these zinc-iron crystals coalesce and sink to the bottom of the zinc bath. This forms
a mushy layer called ‘dross’. The dross is periodically removed by scooping it from the bath with
special equipment. Zinc dross is crystalline and has a much higher melting point than zinc (650oC
versus 420oC).
5. The molten zinc surface is constantly oxidising, and this oxide film is always present on the zinc
surface to a greater or lesser degree.
In the process of galvanizing a steel fabrication, the presence of ash and dross may have the following
effects on the appearance of the hot dip galvanized coating:
• If the item comes in contact with the dross layer in the bottom of the bath, the dross can get
caught in or on the work and form a rough, lumpy deposit.
• If areas of the item are inaccessible for skimming, ash may stick to the surface of the galvanizing as
it is withdrawn from the bath.
• If the rate of withdrawal varies or stops during the extraction of the galvanized item from the bath,
tide marks (oxide lines) may appear on the surface of the galvanizing causing variations in the shiny
appearance of the coating.
• With smooth-surfaced work such as tanks or large diameter pipes, dross crystals floating in the
bath may be caught up on the galvanized coating. These ‘dross pimples’ give the coating a gritty
appearance.
alloys that form on the steel to make the galvanized steel item a
composite material.
Hot rolled surfaces with mill scale may have 30 to 50% more surface area per unit than smooth, cold
rolled surfaces. Abrasive blasting will artificially increase surface roughness and is a way to deliberately
increase coating thickness for heavy duty applications.
Galvanized coatings are totally unlike paint films in the way in which they conform to sharp edges or
corners. The surface tension effects with paint films tend to thin the paint film out over corners and
edges.
Hot dip galvanized coatings,, on the other hand, tend to be thicker on edges and corners because the
crystals in the alloy layer can flare out and have more room to grow around the corner radius.
For this reason, hot dip galvanized coatings may exaggerate the appearance of defects where rolling
defects cause sharp ridges on the steel surface.
Small particles or slivers of steel can be rolled into the steel’s surface, and these may be almost
invisible to the naked eye. However, when the steel is pickled and the surrounding oxide is removed
from these shells and scales, as they are called, the galvanized coating can take on a pimply
appearance as the zinc reacts more quickly with these small, loosely attached steel slivers.
The manufacturing operations performed on some steel sections can also show up in the form of visual
defects, the most common of these being striations. These are narrow (typically about 1-2 mm wide)
longitudinal raised lines in the coating usually running the full length of the section.
The most common cause of striations is stress lines on the surface of the steel caused by cold working
of the section. Heavy gauge rod will sometimes show a spiral striation pattern arising from the rod or
wire being passed through a roller/straightener prior to final manufacture.
Welded sections will frequently have much thicker coatings in the weld areas. While this is rarely a
problem on structural steel sections, it can cause aesthetic problems on high quality fabrications such
as wrought iron and security doors, where the welds have been ground flush and the item is to be
painted after galvanizing.
This phenomenon is caused by the differing chemistry of the weld metal compared to the parent metal.
Most weld metals contain high levels of silicon, and the higher silicon in the weld metal will result in
thicker (sometimes 3-4X as thick) galvanized coatings.
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18. GALVANIZED COATING DEFECTS
EMBRITTLEMENT
Embrittlement of steel as a result of the hot dip galvanizing process is rarely encountered with
structural grades of steel. However, the use of higher-strength steel grades or inappropriate fabrication
techniques can lead to embrittlement problems with galvanized steel.
There are three types of embrittlement encountered in the hot dip galvanizing process. These are:
1. Hydrogen embrittlement
2. Strain-age embrittlement
3. Liquid metal embrittlement
Hydrogen embrittlement is most commonly encountered and affects susceptible steel whole yield
strength is above 800 MPa.
Hydrogen atoms from the acid pickling process penetrate the grain boundaries of these high strength
steels and can cause brittle fractures under certain conditions.
Many high strength steels can be galvanized and standard pre-
or post-galvanizing treatments are available to eliminate the risk
of hydrogen embrittlement.
Bending steel through too tight a radius, re-bending already cold worked steel, or hole punching
through thick sections are all manufacturing processes that can give rise to strain-age embrittlement
problems.
Many manufacturing standards for products such as re-bar address this issue within the standard,
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18. GALVANIZED COATING DEFECTS
DISTORTION
Distortion in galvanizing is one of the most common causes for
concern, In practice, a small proportion of fabricated items are
prone to distortion during the galvanizing process.
It is the heat of the galvanizing process and the manner it is transferred and withdrawn from the steel
during processing that determines the dimensional stability of an
item being galvanized.
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18. GALVANIZED COATING DEFECTS
Thin steel that has been processed into hollow sections or cold-
formed structural shapes is much more stable and is routinely
galvanized without problems. Corrugating thin sheet will also
largely eliminate the tendency to distort.
Fabrications containing elements of significantly different section thickness are another potential
problem area, and high stresses can be generated during the heating and cooling cycle that may cause
distortion due to differential heating and colloing..
Platforms with checker plate welded to structural framing are a common problem area that can be
avoided by galvanizing the thin and thick sections as separate elements.
The galvanizer has the responsibility to handle the work in a way that will reduce the risk of distortion.
Locating lifting points located at the optimum points to support the fabrication so that its own
unsupported weight does not contribute to it bending or sagging during galvanizing is a galvanizers’
responsibility.
The way the item is immersed in the molten zinc and the post galvanizing quenching process may also
have an influence on the dimensional stability of the finished product. Competent galvanizers should
be aware of these issues and be prepared to advise the client on design details that can minimise
distortion problems.
Where distortion is unavoidable, particularly with products such as waste bins and trailers, clients
are now prepared to accept the appearance of the thin metal
plate sections because of the dramatic increase in service life
provided by the coating.
PICKLING CORROSION
Hydrochloric acid is used for pickling steel prior to galvanizing.
Some galvanizers add inhibitor to the acid but most operate at
Zinc run caused by zinc freezing while draining
acid concentration levels of around 10%. from flat RHS surface. Durability is enhanced
but thick runs may interfere with connecting
At this level, the acid will efficiently attack and dissolve rust and surfaces
mill scale but will not react with the base steel at a very high
rate.
The exception is with high sulfur steel. The main application for
these types of steel is for small part manufacture of machined
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18. GALVANIZED COATING DEFECTS
components.
From time to time, threaded fitting such as sockets, spigots, Flux staining has occurred on unsealed vent
nipples and bushes are welded into fabricated assemblies. holes in overlaps on this fabrication. The stains
are caused by iron salts, that have penetrated
the overlap during pre-treatment, re-hydrating
Attack by the acid on these threaded components can quickly with atmospheric moisture.
dissolve the threads and render the item unserviceable.
Many fabricated items have overlapping surfaces, and during The gray coating on these pipes is a result
of high silicon content of the steel, making it
the pre-treatment process, pretreatment chemicals will more reactive and converting all the coating to
penetrate these overlaps and may not drain out because of zinc-iron alloy. These gray coatings are typi-
surface tension holding the liquor in place. cally thicker than shiny galvanized coatings on
similar sections.
When the item enters the galvanizing bath, any moisture
trapped in these crevices will rapidly boil and eject steam and
pretreatment resides onto the adjacent surface of the work.
The brown liquor bleeding from overlaps is not particularly aggressive to zinc but causes unsightly
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18. GALVANIZED COATING DEFECTS
FLAKING
Flaking of galvanized coatings can occur on reactive steels
which produce thick alloy layers in the galvanizing process.
If the zinc surface remains wet and cannot get access to good
air circulation (the main source of carbon dioxide to form the
stable oxide films), the water will continue to react with the zinc Thin, flat sheet will always buckle in the galva-
nizing process. Corrugating or ribbing of these
and can severely damage the coating at worst and result in
type of sections will significantly reduce the
unsightly staining at best. likelihood of distortion during galvanizing.
The main white rusting problems arise where galvanized work is stacked or packed in tightly nested
bundles, where water can be trapped and air circulation is poor.
Additional post-treatments that provide more durable protection from white rust over time can be
arranged in consultation with the galvanizer , usually at an additional small cost.
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18. GALVANIZED COATING DEFECTS
Exposure to sea water will also rapidly promote white rust, and for
this reason, it is recommended that galvanized products such as
boat trailers be washed down with fresh water after each salt water
immersion.
PINHOLING
On some fabrications, particularly welded beams and heavier
sections that have been assembled using submerged arc welding
techniques, the weld areas may show evidence of a series of small Where jigs are used to support large items
in the galvanizing processes, touch marks
pinholes along the weld bead. These pinholes are generally less will occur where the galvanized coating
than 1mm in diameter. adheres to the jig at the point of cobntact.
CONCLUSION
With the exception of blowouts and bleeding, and where the
galvanized coating is missing, most galvanizing defects have no
effect on the coatings’ durability. In fact, many `defects’, because
they result in thickening of the coating or deposition of much
more zinc or zinc-rich residues, coating life may be increased
significantly.
This small RHS section has severe galvanized
For example, a dull or mottled galvanized coating may be 2X or coating delamination arising from very high
phosphorous levels in the steel, creating a
3X as thick as a standard shiny coating that complies with the
thick, fragile coating almost 1000 microns in
relevant standard. The thicker gray coatings will thus have a thickness.
coating life 2X or 3X as long as the standard coating.
Where aesthetic issues are involved, hot dip galvanized coatings can only deliver a level of quality
within the limitations of the process.
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18. GALVANIZED COATING DEFECTS
However, an understanding of the issues of design, steel composition and the hot dip galvanizing
process will go a long way to ensure that hot dip galvanized coatings on structural fabrications can be
produced to a standard that will satisfy architectural applications.
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01 SPECIFIERS MANUAL
02 INDUSTRIAL GALVANIZERS COMPANY PROFILE
03 ADHESION OF PROTECTIVE COATINGS
04 BOLTING GALVANIZED STEEL
05 BURIED GALVANIZED STEEL
06 CONCRETE DURABILITY & GALVANIZED REBAR
07 CORROSION MAPPING
08 COST FACTORS FOR HOT DIP GALVANIZED COATINGS
09 CUSTOM COATING PACKAGES
10 CUT EDGE PROTECTION
11 DESIGNING FOR GALVANIZING
12 ILLUSTRATED GUIDE TO DESIGN FOR GALVANIZING
13 DEW POINT TABLES
14 DIFFICULT STEELS FOR GALVANIZING
15 DOCUMENTATION - CORRECT PAPERWORK ENSUES EFFICIENT PROCESSING
16 ENVIRONMENTAL ISSUES FOR INDUSTRIAL COATINGS
17 ZINC, HUMAN HEALTH AND THE ENVIRONMENT
18 DEFECTS IN GALVANIZED COATINGS
19 GALVANIC SERIES
20 GLOSSARY OF GALVANIZING TERMS
21 GUARANTEES FOR HOT DIP GALVANIZED COATINGS
22 LIFE CYCLE COSTS OF INDUSTRIAL PROTECTIVE COATING SYSTEMS
23 PAINTING OVER GALVANIZED COATINGS
24 POWDER COATING OVER GALVANIZED COATINGS
25 QUALITY AND SERVICE FACTORS AFFECTING GALVANIZED COATINGS
26 RESTORATION OF PREVIOUSLY GALVANIZED ITEMS
27 REPAIR OF GALVANIZED COATINGS
28 STEEL STRENGTH AND HOT DIP GALVANIZING
29 STANDARDS - AS/NZS 4680:2006
30 STANDARDS - AUSTRALIAN AND INTERNATIONAL STANDARDS
31 STEEL SURFACE PREPERATION
32 SURFACE PREPERATION FOR PAINTING HOT DIP GALVANIZED COATINGS
33 THICKNESS MEASUREMENT OF PROTECTIVE COATINGS
34 WELDING GALVANIZED STEEL
35 AN INTRODUCTION TO THE HOT DIP GALVANIZING PROCESS
36 ZINC COATING PROCESSES - OTHER METHODS
37 GALVANIZED COATINGS AND BUSHFIRE
38 LIQUID METAL ASSISTED CRACKING OF
GALVANIZED STRUCTURAL STEEL SECTIONS
39 GALVANIZING 500N GRADE REINFORCING BAR
40 PREDICTING THE LIFE OF GALVANIZED COATINGS
41 CHEMICALS IN CONTACT WITH GALVANIZED COATINGS.
42 ATMOSPHERIC CORROSIVITY ASSESSMENT
43 GLOBAL WARMING - CLIMATE CHANGE AND GALVANIZING
44 STEEL - ITS CORROSION CHARACTERISTICS
45 GALVANIZED STEEL AND TIMBER
46 WHITE RUST PREVENTION AND TREATMENT
2
01 - SPECIFIERS MANUAL – THIRD EDITION
Industrial Galvanizers Australian Galvanizing Division (IGAG) operates nine galvanizing plants around
Australia, ranging in size from large structural galvanizing facilities to specialised small plants designed
to process small parts.
The Australian Galvanizing Division has galvanized in excess of 2 million tonnes of steel products
in Australia since its first plant was commissioned in 1965 and is recognized for its ability to handle
complex and difficult projects, as well as routine contracts.
This experience has been collated in the Specifiers Design Manual, to assist those involved in the
design of steel products and projects to better understanding the galvanizing process and allow the
most durable and cost-effective solutions to be delivered to these products and projects. All sections of
this Third Edition have been completely updated and additional sections have been included to provide
additional technical information related to the use of hot dip galvanized steel.
In addition to its Australian Galvanizing operations, Industrial Galvanizers Corporation has a network of
manufacturing operations in Australia, as well as galvanizing and manufacturing businesses throughout
Asia and in the USA.
The company’s staff in all these locations will be pleased to assist with advice on design and
performance of hot dip galvanized coatings and products. Contact details for each of these locations
are located elsewhere in this manual.
This edition of the Industrial Galvanizers Specifiers Manual has been produced in both html and .pdf
formats for ease of access and distribution and all documents in the Manual are in .pdf format and can
be printed if paper documents are required.
The Specifiers Manual is also accessible in its entirety on the company’s web site at
www.ingal.com.au.
PUBLISHER:
Industrial Galvanizers Australian Galvanizing Division,
PO Box 503, MOOROOKA
QLD 4105
Ph: 07 38597418
EDITOR:
John Robinson,
Mount Townsend Solutions Pty Ltd
PO Box 355, JESMOND NSW 2299
Ph: 0411 886 884
Email: [email protected]