Hydrogen Peroxide, 3% w/w

Safety Data Sheet

according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date of issue: 02/17/2014 Revision date: 10/31/2017 Supersedes: 01/06/2016 Version: 1.3

SECTION 1: Identification
1.1. Identification
Product form : Mixtures
Product name : Hydrogen Peroxide, 3% w/w
Product code : LC15450
1.2. Recommended use and restrictions on use
Use of the substance/mixture : For laboratory and manufacturing use only.
Recommended use : Laboratory chemicals
Restrictions on use : Not for food, drug or household use
1.3. Supplier
LabChem Inc
Jackson's Pointe Commerce Park Building 1000, 1010 Jackson's Pointe Court
Zelienople, PA 16063 - USA
T 412-826-5230 - F 724-473-0647
[email protected] - www.labchem.com

1.4. Emergency telephone number

Emergency number : CHEMTREC: 1-800-424-9300 or 011-703-527-3887

SECTION 2: Hazard(s) identification

2.1. Classification of the substance or mixture
GHS-US classification
Skin corrosion/irritation H315 Causes skin irritation
Category 2
Serious eye damage/eye H318 Causes serious eye damage
irritation Category 1
Full text of H statements : see section 16

2.2. GHS Label elements, including precautionary statements

GHS-US labeling
Hazard pictograms (GHS-US) :

GHS05
Signal word (GHS-US) : Danger
Hazard statements (GHS-US) : H315 - Causes skin irritation
H318 - Causes serious eye damage
Precautionary statements (GHS-US) : P264 - Wash exposed skin thoroughly after handling
P280 - Wear protective gloves, eye protection
P302+P352 - IF ON SKIN: Wash with plenty of soap and water
P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
P310 - Immediately call a poison center or doctor/physician
P321 - Specific treatment (see ... on this label)
P332+P313 - If skin irritation occurs: Get medical advice/attention
P362+P364 - Take off contaminated clothing and wash it before reuse
2.3. Other hazards which do not result in classification
Other hazards not contributing to the : None under normal conditions.
classification
2.4. Unknown acute toxicity (GHS US)
Not applicable

SECTION 3: Composition/Information on ingredients

3.1. Substances
Not applicable
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Hydrogen Peroxide, 3% w/w
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

3.2. Mixtures
Name Product identifier % GHS-US classification
Water (CAS-No.) 7732-18-5 97 Not classified
Hydrogen Peroxide, 30% w/w (CAS-No.) 7722-84-1 3 Ox. Liq. 1, H271
Acute Tox. 4 (Oral), H302
Acute Tox. 4 (Inhalation), H332
Skin Corr. 1A, H314

Full text of hazard classes and H-statements : see section 16

SECTION 4: First-aid measures

4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical
advice (show the label where possible).
First-aid measures after inhalation : Allow victim to breathe fresh air. Allow the victim to rest.
First-aid measures after skin contact : Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation
occurs: Get medical advice/attention.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. Immediately call a poison center or doctor/physician.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
4.2. Most important symptoms and effects (acute and delayed)
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye damage.
4.3. Immediate medical attention and special treatment, if necessary
No additional information available

SECTION 5: Fire-fighting measures

5.1. Suitable (and unsuitable) extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Specific hazards arising from the chemical
No additional information available
5.3. Special protective equipment and precautions for fire-fighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire-fighting water from entering environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Protective equipment : Safety glasses. Gloves.
Emergency procedures : Evacuate unnecessary personnel.

6.1.2. For emergency responders

Protective equipment : Equip cleanup crew with proper protection.
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect
spillage. Store away from other materials.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection.

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Hydrogen Peroxide, 3% w/w
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work. Provide good ventilation in process area to prevent formation
of vapor.
Hygiene measures : Wash exposed skin thoroughly after handling.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions : Keep only in the original container in a cool, well ventilated place away from : incompatible
materials, combustible materials. Keep container closed when not in use.
Incompatible products : Strong bases. Strong reducing agents. metals. combustible materials.
Incompatible materials : Sources of ignition. Direct sunlight.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters
Hydrogen Peroxide, 30% w/w (7722-84-1)
ACGIH ACGIH TWA (mg/m³) 1.4 mg/m³
ACGIH ACGIH TWA (ppm) 1 ppm
OSHA OSHA PEL (TWA) (mg/m³) 1.4 mg/m³
OSHA OSHA PEL (TWA) (ppm) 1 ppm
IDLH US IDLH (ppm) 75 ppm
NIOSH NIOSH REL (TWA) (mg/m³) 1.4 mg/m³
NIOSH NIOSH REL (TWA) (ppm) 1 ppm

Water (7732-18-5)
Not applicable

8.2. Appropriate engineering controls

Appropriate engineering controls : Emergency eye wash fountains should be available in the immediate vicinity of any potential
exposure.

8.3. Individual protection measures/Personal protective equipment

Personal protective equipment:
Face shield. Gloves. Safety glasses.

Hand protection:
Wear protective gloves

Eye protection:
Chemical goggles or safety glasses

Skin and body protection:

Wear suitable protective clothing

Respiratory protection:
Respiratory protection not required in normal
conditions

Other information:
Do not eat, drink or smoke during use.

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Hydrogen Peroxide, 3% w/w
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state : Liquid
Color : Colorless
Odor : None.
Odor threshold : No data available
pH : No data available
Melting point : No data available
Freezing point : No data available
Boiling point : No data available
Flash point : No data available
Relative evaporation rate (butyl acetate=1) : No data available
Flammability (solid, gas) : Non flammable.
Vapor pressure : No data available
Relative vapor density at 20 °C : No data available
Relative density : No data available
Specific gravity / density : 1
Solubility : Soluble in water.
Log Pow : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosion limits : No data available
Explosive properties : No data available
Oxidizing properties : No data available
9.2. Other information
No additional information available

SECTION 10: Stability and reactivity

10.1. Reactivity
No additional information available
10.2. Chemical stability
Unstable on exposure to light.
10.3. Possibility of hazardous reactions
Not established.
10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures.
10.5. Incompatible materials
Strong reducing agents. Strong bases. metals. combustible materials.
10.6. Hazardous decomposition products
oxygen.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Likely routes of exposure : Inhalation; Skin and eye contact

Acute toxicity : Not classified

Hydrogen Peroxide, 30% w/w (7722-84-1)

ATE US (oral) 500 mg/kg body weight
ATE US (gases) 4500 ppmV/4h

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Hydrogen Peroxide, 3% w/w
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Hydrogen Peroxide, 30% w/w (7722-84-1)

ATE US (vapors) 11 mg/l/4h
ATE US (dust, mist) 1.5 mg/l/4h
Water (7732-18-5)
LD50 oral rat ≥ 90000 mg/kg
ATE US (oral) 90000 mg/kg body weight
Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Causes serious eye damage.
Respiratory or skin sensitization : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified

Hydrogen Peroxide, 30% w/w (7722-84-1)

IARC group 3 - Not classifiable
Reproductive toxicity : Not classified
Specific target organ toxicity – single exposure : Not classified

Specific target organ toxicity – repeated : Not classified

exposure

Aspiration hazard : Not classified

Potential Adverse human health effects and : Based on available data, the classification criteria are not met.
symptoms
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye damage.

SECTION 12: Ecological information

12.1. Toxicity
No additional information available

12.2. Persistence and degradability

Hydrogen Peroxide, 3% w/w
Persistence and degradability Not established.
Hydrogen Peroxide, 30% w/w (7722-84-1)
Persistence and degradability Not established.
Water (7732-18-5)
Persistence and degradability Not established.

12.3. Bioaccumulative potential

Hydrogen Peroxide, 3% w/w
Bioaccumulative potential Not established.
Hydrogen Peroxide, 30% w/w (7722-84-1)
Bioaccumulative potential Not established.
Water (7732-18-5)
Bioaccumulative potential Not established.

12.4. Mobility in soil

No additional information available

12.5. Other adverse effects

Effect on the global warming : No known effects from this product.

GWPmix comment : No known effects from this product.

Other information : Avoid release to the environment.

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Hydrogen Peroxide, 3% w/w
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

SECTION 13: Disposal considerations

13.1. Disposal methods
Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations.
Ecology - waste materials : Avoid release to the environment.

SECTION 14: Transport information

Department of Transportation (DOT)
In accordance with DOT
Not regulated

SECTION 15: Regulatory information

15.1. US Federal regulations
Hydrogen Peroxide, 3% w/w
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic
Substances Control Act (TSCA) inventory

Hydrogen Peroxide, 30% w/w (7722-84-1)

SARA Section 311/312 Hazard Classes Reactive hazard
Immediate (acute) health hazard

15.2. International regulations

CANADA
No additional information available

EU-Regulations
No additional information available

National regulations
No additional information available

15.3. US State regulations

California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer,
developmental and/or reproductive harm

SECTION 16: Other information

Revision date : 10/31/2017
Other information : None.
Full text of H-phrases: see section 16:
--- H271 May cause fire or explosion; strong oxidizer
---
--- H302 Harmful if swallowed
---
--- H314 Causes severe skin burns and eye damage
---
--- H315 Causes skin irritation
---
--- H318 Causes serious eye damage
---
--- H332 Harmful if inhaled
---

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Hydrogen Peroxide, 3% w/w
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

NFPA health hazard : 2 - Materials that, under emergency conditions, can cause
temporary incapacitation or residual injury.
NFPA fire hazard : 0 - Materials that will not burn under typical dire conditions,
including intrinsically noncombustible materials such as
concrete, stone, and sand.
NFPA reactivity : 1 - Materials that in themselves are normally stable but can
become unstable at elevated temperatures and pressures.
NFPA specific hazard : OX - Materials that posses oxidizing properties.
Hazard Rating
Health : 2 Moderate Hazard - Temporary or minor injury may occur
Flammability : 0 Minimal Hazard - Materials that will not burn
Physical : 1 Slight Hazard - Materials that are normally stable but can become unstable (self-react) at high
temperatures and pressures. Materials may react non-violently with water or undergo
hazardous polymerization in the absence of inhibitors.
Personal protection : B
B - Safety glasses, Gloves

SDS US LabChem

Information in this SDS is from available published sources and is believed to be accurate. No warranty, express or implied, is made and LabChem Inc assumes no liability resulting from the use of this
SDS. The user must determine suitability of this information for his application.

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