R=20170001809 2019-03-08T00:44:10+00:00Z
Chapter 7
Grant Henson
Chief Scientist
Invariant Laboratories LLC
Westlake, Ohio
7.1 Introduction
This chapter concerns materials for expendable and reusable launch
vehicle (LV) structures. An emphasis is placed on applications and design
requirements, and how these requirements are met by the optimum choice
of materials. Structural analysis and qualification strategies, which cannot
be separated from the materials selection process, are described.
A launch vehicle is an airborne system that delivers a payload from
the ground to suborbital, orbital or interplanetary space. The payload is
usually housed in a space vehicle or satellite that is not considered part
of the LV. When it is not important to distinguish the payload from the
space vehicle, both may be referred to as the payload.
Modern LVs are designed with a particular type of payload in mind
(astronauts, earth-orbiting instruments, interplanetary probes, etc.) but
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7. Materials for Launch Vehicle Structures
at the dawn of the Space Age, vehicles performed multiple duty. For
example, the Atlas, Titan, and Thor/Delta vehicles all began as long-range
weapons and were later adapted for orbital delivery. Sounding rockets
such as Aerobee (historical) and Black Brant can leave the atmosphere
but do not enter orbit. For the purpose of this chapter, shorter-range
missiles that never leave the atmosphere are not considered LVs.
Most LVs, including Atlas, Delta, Ariane and Proton are expendable.
Expendable vehicles are flown only once; the upper stages may be disposed
of through a controlled re-entry, or may be left in orbit as “space junk,”
whereas the first stage or booster falls to earth in a cleared area. The
term booster usually means the first stage of a multi-stage LV and will
be used in that sense here.
Reusable systems may incorporate a single vehicle that both launches
the payload and houses it while in space, the prime example being
the Space Shuttle Orbiter. The Orbiter, and the similar Soviet Buran
vehicle, are here considered LVs rather than space vehicles, because
they must sustain atmospheric flight loads and environments similar
to those sustained by expendable boosters. Therefore, the materials
selection aspects are much the same as for expendable LVs. Proponents
of reusable vehicles assert that they can be cheaper and more reliable
than expendables. On the other hand, recovery and refurbishment are
costly, and a failure of a vehicle intended for re-use is more damaging
to schedules and budgets than a failure of an expendable vehicle. The
envisioned benefits of reusability have led to recent investment, both
public and private, in reusable vehicle development.
One source [1] claims that a reusable variant of the Aerobee sounding
rocket was flown; if so, it was the first reusable vehicle. Notable reusable
orbital LV programs that never demonstrated powered flight were the Sea
Dragon, X-33, X-34 and the K-1. The first stage of the Soviet/Russian
Energia vehicle, developed to lift the Buran orbiter as well as other heavy
orbital payloads, was designed to be reusable for at least ten flights [2].
However, it has never actually been recovered and reused. The DC-
X/-XA was an early demonstration of reusable rocket flight within the
atmosphere. SpaceShipOne reached suborbital space in 2004, landed, and
repeated the feat. However, neither of these systems led to a sustained
record of operations. In 2015, a New Shepard vehicle, including both the
booster stage and the space vehicle, was recovered from suborbital flight
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7.1. Introduction
and then successfully reflown 61 days later. Also in 2015, the booster
stage of a Falcon 9 was recovered by powered descent onto a land-based
pad after having launched a payload to orbit; s i n c e t h e n several
attempts to descend onto a seagoing platform have been successful.
Today, space launch vehicles are considered, along with aircraft, part
of a single endeavor we call “aerospace.” But various dictionaries date this
term only back to the late 1950s, at least a decade after the guided missile,
for better or worse the archetype of the modern LV, was developed. In
most nations, the initial authority for developing guided missiles rested
with the artillery or ordnance corps, not the air corps. The relevance
of this observation is that while launch vehicle materials and structures
technologies have much in common with those of aircraft, the degree of
commonality is perhaps less than one might think.
Investment in LV development and operation is now a small part of
the overall aerospace economy.1 However, for several decades, political
and military imperatives drove high expenditures on LV development,
leading to significant advances. New materials and structures had to be
developed in parallel with other vehicle systems in “crash” programs,
under high risk of technological failure, in order to satisfy aggressive
performance requirements within the desired time frame. While the pace
of innovation was slow for decades, increased emphasis on cost reduction
and improved reliability continue to drive incremental advances in ma-
terials and structures technology. Also, large, qualitative improvements
in computing capabilities and newly available precursor materials have
provided a technology push to encourage further advances in LV materials
and structures.
Because materials selection for LVs is affected by laws and regulations
that vary from country to country, it is important to note where LVs are
built and used. Until the 1970s, the United States and the Soviet Union
(Russia and Ukraine) dominated LV production. More recently, France
1
For example, the U.S. Census Bureau reported about $23 billion in deliveries of “guided
missile and space vehicle manufacturing,” “guided missile and space vehicle propulsion unit
and propulsion unit parts manufacturing,” and “other guided missile and space vehicle parts
and auxiliary equipment manufacturing” in 2005, which surely includes many billions spent
on non-launch-vehicle hardware such as anti-aircraft missiles. Compare this to $114 billion
in deliveries of aircraft and related items [3]. Considering that many countries manufacture
aircraft but not launch vehicles, LVs probably constitute under 10% of the global aerospace
economy.
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7. Materials for Launch Vehicle Structures
Table 7.1: Orbital vehicles launched over two recent periods, grouped by
country of production [4, 5].
Period Country of Production Share
1990 to 1998 US 39%
Russia 32%
France 13%
Ukraine 9%
China 5%
Japan 2%
Israel, India < 1%
2007 to mid-2009 Russia 30%
US 26%
China 14%
Ukraine 13%
France 8%
India 4%
Japan 2%
Iran, Israel,
North Korea, South Korea < 1%
Chapters 11 and 12 of this book are dedicated to materials for the solid
rocket motors and liquid rocket engines, respectively, that propel LVs.
Propulsion materials and structures are mainly affected by the loads and
environments generated within the engine or motor itself, such as thrust
chamber pressure. However, a section is provided in this chapter on
large solid rocket motor cases, because they can form a significant part
of the load-bearing capability of the vehicle as a whole. The structural
failure of a large strap-on solid rocket motor on an Ariane 5 or the
Space Shuttle, or the solid rocket boost stage of the Ares I, would
doom the vehicle structure rather than just the propulsion system.
Inclusion of solid rocket motor cases with the structural system
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7.2. Launch Vehicle Structures
rather than the propulsion system follows the precedent set in [6]. Also,
propulsion support systems such as propellant feedlines are included in
this chapter, because they are usually the responsibility of the launch
vehicle contractor.
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7. Materials for Launch Vehicle Structures
cylindrical interstage can be seen joining the booster to the second stage,
and a conical one can be seen joining the second and third stages. Some
internal structures and stiffeners in the tanks are visible. The booster
fuel and oxidizer tanks are joined by a cylindrical intertank, while the
second and third stage tanks have common bulkheads to save weight and
volume.
The outer mold line is the outermost surface of the cylindrical struc-
ture, visible from the outside, while the inner mold line is the inner
surface. These terms, common in composite molding processes, are used
even if there was actually no molding involved in building the structure.
LV shell structures may completely lack internal bracing or stiffen-
ing, may have stiffeners integrally machined into the wall, or may have
mechanically attached stiffeners or braces. Extensive internal framing is
rarely used in launch vehicles except in thrust structures.
The term membrane is used to refer to the part of a shell structure
far from attachments or other discontinuities, in which only in-plane
loading is significant. This same area may be called acreage, especially
when discussing thermal protection systems. In contrast, flanges, door
seals, bolt lines, and the like may be called details or closeouts; closeouts
especially refer to small items or fasteners that are the last to be installed
when building the vehicle.
Reusable designs with winged launch and re-entry vehicles do not
conform to the description just given. The Space Shuttle is functionally
split into the reusable Orbiter, the partially reusable Solid Rocket Boosters,
and the expendable External Tank (ET). Many different concepts, from
single-stage-to-orbit to staged systems comprising a winged vehicle piggy-
backed on a more conventional missile-like booster, have been proposed.
Wilhite [7], in the context of a particular trade study, discusses some of
the materials selection aspects of advanced fully reusable designs. It is
telling that only rather exotic materials (a metal matrix composite with
silicon carbide fibers, and monolithic titanium aluminide) were considered
feasible for the two-stage-to-orbit systems he explored.
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7.3. Basic Material Characteristics
Figure 7.1: Cutaway view of the Saturn V launch vehicle with the Apollo
payload , showing major substructures . NASA graphic.
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7. Materials for Launch Vehicle Structures
pendable LVs as in reusable ones, and much less important than in
aircraft.
In many LV applications, the foregoing must remain favorable at very
high or low temperatures and in the presence of humid, corrosive or other
degrading environments. Because most launch vehicles use cryogenic propellants,
properties at very low temperatures are important; high- temperature properties
can also be important because of the aerodynamic heating encountered in the high-
speed atmospheric part of the trajectory.
Knowledge of material characteristics must be quantitative in order to play
a direct role in structural system trade studies. The stiffness and density of most
materials are consistent enough to be treated as deterministic values for a
particular material at a given temperature. However, material strength displays
sample-to-sample variation that must be taken into account in both design and
analysis; design values based on tenth- or first-percentile strength are more
important than average strength. Further, if the factors tending to cause variations in
strength are poorly understood, high safety factors must be used to preserve reliability,
leading to heavier structures.
Equally important is manufacturability. Without the ability to shape or
assemble a material into an efficient structure, the material’s intrinsic advantages
become meaningless. For instance, a single carbon nanotube is extremely strong, but
until a carbon nanotube structure of useful size can be manufactured while
preserving this extreme strength, that material will not play a significant
economic role. Aspects of manufacturability that are especially relevant to LV
applications include
• weldability,
• machinability,
• ease of making a composite laminate, and formability or “drape” of
plies,
• ease of assembly using fasteners, co-curing, adhesives, locking fea-
tures and so on.
Thermal properties may also be important; in particular, it is desirable to have
thermal expansion characteristics that are predictable and compatible with adjacent
materials, including tooling.
These general characteristics must be associated with relevant, measureable material
properties, or at least be translated into standardized tests. A good summary of the
properties and tests most relevant to structural design can be found by reviewing
the data tables in the universally referenced Metallic Materials Properties
Development and Standardization (MMPDS) published by the Federal
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7.3. Basic Material Characteristics
Aviation Administraion (FAA) [8]. This reference was formerly known as MIL-
HDBK-5. In this work we find data on
• material strength, including typical values and statistically derived
lower-bound design allowables for
– tensile yield and rupture (“ultimate”)
– compressive yield
– shear rupture
– bearing yield and rupture
• elongation to break
• tensile and compressive Young’s modulus
• shear modulus
• Poisson’s ratio
• density
• thermal conductivity, heat capacity, and thermal expansion coeffi-
cient
These properties are reported for a wide range of tempers of commonly
used metals. They are usually given for various thicknesses, because
heat or age treatment affects metals differently depending on the thick-
ness. Also, they may be given at elevated or cryogenic temperatures for
various exposure times, or plots of temperature adjustment factors may
be provided. In some cases, full-range stress-strain curves are provided.
These are required in order to perform stress analysis in the plastic range.
Finally, S-N (fatigue) diagrams and Paris-region crack growth curves are
provided for many alloys.
Metal properties at cryogenic temperatures depend strongly on the
crystal structure. Face-centered cubic metals such as aluminum and the
austenitic stainless steels experience a rise in ultimate strength but a
lesser increase in yield strength, which preserves their ductility. Body-
centered cubic metals such as the ferritic steels tend to experience a
greater increase in yield strength than in ultimate strength, which results
in more brittle behavior.
For composite materials, which are generally not isotropic, more exten-
sive (and expensive) testing may be required for full characterization. To
take full advantage of the directional stiffness and strength properties of
composites, directional material properties must be available. Composite
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7. Materials for Launch Vehicle Structures
10
7.3. Basic Material Characteristics
and less reliable than a well-planned test to determine, for example, the
fatigue life of a bonded joint. Some examples of strength testing from
the literature are biaxial strength [11], cryogenic fracture toughness and
fracture toughness ratio [12], hardness, tangent modulus, impact, notched
fatigue, weld coupons, and creep-rupture [13].
In addition to numerical property data, MMPDS and the Composite
Materials Handbook also include information on applications, material
processing, corrosion resistance, maximum service temperatures, and
other information relevant to the designer.
A comprehensive handbook on materials selection for launch vehi-
cles (and space systems in general) that is more oriented toward physi-
cal/chemical properties and compatibility is MSFC-HDBK-527, Materials
Selection List for Space Hardware Systems, published by NASA Marshall
Space Flight Center [14]. This handbook provides a very extensive sum-
mary of knowledge concerning the corrosion, stress corrosion cracking,
propellant and working fluid compatibility, flammability, toxicity and
thermal vacuum stability properties of aerospace materials, both metallic
and nonmetallic.
Another excellent reference is the Aerospace Structural Metals Hand-
book [15]. This work, which was originally sponsored by the Air Force
Materials Laboratory, contains not only extensive tables of data, but also
a cross-reference so that the same alloy may be located under names that
may vary from producer to producer or country to country. Data are
usually typical properties rather than statistical minimum design values.
The book is now available as an online database.
Per-piece raw material cost is usually small compared to tooling
and labor costs at the low production rates typical of LVs. Therefore,
the cost of the material in its unprocessed form is rarely an important
consideration in materials selection. If a material is commercially available
in the required sizes, quantities, and on the needed schedule, it is a
candidate for use in a launch vehicle structure, practically regardless of
cost. Historically, space programs would even specify custom materials
having no existing commercial applications and therefore being subject
to unknown cost and production fluctuations; for example, Rocketdyne
developed NARloy-Z specifically for use in the linear aerospike engine and
Space Shuttle Main Engine [16]. But lately this high-risk, high-reward
approach has been discouraged.
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7. Materials for Launch Vehicle Structures
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7.3. Basic Material Characteristics
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7. Materials for Launch Vehicle Structures
attempts should be needed per actual launch, so the assumed service life
may decrease. For life-limited structures, the shorter assumed service
life can lead to higher life margins, greater tolerance for manufacturing
discrepancies or found flaws, and lighter-weight structure in case there is
an opportunity for design changes.
Figure 7.2 shows an idealized crack growth curve for a metal under
fluctuating stresses. This is commonly referred to as a da/dN curve,
where a is the crack length and N is the number of cycles. The many
factors influencing this curve, such as stress ratio and frequency, are
discussed in detail in previous chapters. Due to the short life of an
expendable LV, crack-growth concerns are frequently in Region 3 of the
da/dN curve.
Being unstable in nature, Region 3 predictions can be unreliable.
When the metal is ductile, much of this Region 3 crack growth is of a
tearing nature. In situations where production discrepancies or damage
during pre-launch operations occur, it is sometimes necessary to remove
conservatism to adequately assess the risk associated with the damage.
In these cases, elastic-plastic fracture mechanics or other less conservative
theories may be used.
When sustained loading is part of the load spectrum, stress corrosion
of the potential flaw needs to be considered. Keac (or KIssc ) is a truncated
value which toughness can be degraded to, under sustained loads. The
stress corrosion resistance may need to be taken into account for pressure
vessels storing fluids used to pressurize pneumatic, hydraulic or ullage
pressure systems. The time at load can be as short as a few hours.
For vehicles considered to be at risk of failure due to crack propagation,
a formal fracture control program may be implemented. Information
describing how to write a fracture control plan may be found in [18]. A
fracture control program classifies parts as fracture-critical if they exceed a
certain mass, are uncontained, non-fail-safe, part of a pressurized system,
or meet other criteria that suggest serious consequences in case of failure.
For fracture-critical components, the fracture control program applies
special analysis, testing and inspection requirements to reduce the chance
of a harmful fracture. These vary from program to program but generally
amount to an analytical determination of the smallest crack that could
grow to critical size before the next regular inspection, and an inspection
plan that will detect a large percentage of cracks larger than that critical
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7.3. Basic Material Characteristics
Figure 7.2: Idealized plot of crack growth as a function of stress cycles for a
metal. By J. Hilgendorf, United Launch Alliance.
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7. Materials for Launch Vehicle Structures
ered, and then they will not be flown again anyway. However, expendable
vehicles must undergo ground tests that consume some of the safe life of
the parts, and inspection is possible after ground tests. So fracture control
may be applied in expendable vehicle programs to a limited extent.
Specialized Materials
Most of the foregoing discussion applies to metals and composites, which
are by far the most important materials used in launch vehicle structures.
Their useful regime is linear elastic, and the effects of temperature and
other environments on their behavior is small enough that it may usually
be accounted for with adjustment factors. If a metal structure does yield,
the amount of yielding is small enough that deformation plasticity in the
form of an isotropic Mises yield function followed by a Ramberg-Osgood
description of plastic flow, is usually sufficient.
For more complex materials such as elastomers, foam and adhesives,
materials testing becomes even more expensive and time-consuming,
and good property data accordingly harder to come by. Fortunately,
these materials are often used in applications where very accurate me-
chanical property data are not vital. Many of these materials display
time-dependent behaviors such as relaxation and creep, and have strong
temperature dependence. They may also have nonlinear stress-strain
curves, or may have such a large strain during operation that they must
be treated with one of the many nonlinear theories of mechanics.
For materials that are not linear elastic, the distinction between phe-
nomena and properties becomes important. Phenomena are behaviors
such as elasticity, creep, and relaxation that can be observed and mea-
sured without assuming a particular material model. Observing material
phenomena can be useful for screening or lot acceptance, and can suggest
an appropriate material model, but are usually insufficient inputs for
accurate simulation of structural response.
To conduct accurate analyses and simulations, a material model
(constitutive equation) must be assumed, and only then can the properties
defined in the model be measured. For instance, some type of stiffness
may be measured for all elastic materials, but once one is forced to
consider large strains of a compressible material, a large-strain model
containing three properties may be necessary. A conventional uniaxial
tension test will not suffice to determine the three properties; multiple
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7.4. Structural Design and Requirements
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7. Materials for Launch Vehicle Structures
Contractual Requirements
By far the most significant requirements are those imposed by the procur-
ing agency or, in the case of commercial operations, by the payload
client. In some cases these requirements are actually drawn up by the LV
contractor itself, subject to revision and approval by the procuring agency.
Requirements exist in a hierarchy that is managed by systems engineers
primarily to ensure that the LV delivers a functioning space vehicle to the
desired orbit, and secondarily to minimize the cost, development time,
danger to the public and other factors. The structural system, propulsion
system, guidance and navigation system, and other systems are considered
subsystems of the LV system as a whole. Blair and Ryan [21] provide a
good overview of requirements and standards, and how detailed design
criteria are derived from them.
A set of top-level functional requirements for the structural system
that could well apply to many different LVs is
• to support and protect the other vehicle systems and the space
vehicle such that they can function properly
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7.4. Structural Design and Requirements
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7. Materials for Launch Vehicle Structures
launches (and re-entries) from FAA scrutiny. Also, Title 14 of the Code
of Federal Regulations does not impose the same very detailed structural
requirements on LVs as it does on aircraft. It is mostly concerned with
hazards from expended stages, re-entering payloads, and mishaps. The
FAA’s relationship with the private space launch industry is still evolving
but it appears that private launches will not be regulated as closely as
passenger aircraft. Therefore, vehicle safety laws and regulations do not
significantly constrain materials selection for LV structures.
However, environmental regulations have had a significant and ongoing
impact on materials selection for LVs, particularly in the area of coatings
and insulation. Heavy metals such as cadmium, mercury and lead were
once commonly used in metals processing and plating, but as it has become
widely known that these substances are poisonous, regulations have
greatly reduced their use. Beryllium has important aerospace structures
applications due to its thermal stability, but beryllium dust is toxic
and must be handled carefully. Also, the use of asbestos insulation and
chlorofluorocarbon blowing agents for foam insulation has been greatly
reduced by environmental regulations.
Range Safety
The other major class of requirements is that imposed by operators of
launch ranges to minimize the risk of injury to personnel and damage to
ground equipment. Military, government non-military and commercial
organizations alike must adhere to range safety rules. The vast majority
of LVs are operated out of the ranges listed in Table 7.2.
For many years, the governing range safety document for the Eastern
and Western Ranges of the United States was EWR 127-1, Eastern and
Western Range Safety Policies and Procedures [24]. Although EWR 127-1
states that it is “applicable to all organizations, agencies, companies and
programs conducting or supporting operations on the ER and WR,” it now
only governs programs introduced at the Ranges prior to 2004. Since 2004,
Air Force Space Command has issued the manuals AFSPCMAN 91-710,
Range Safety User Requirements Manual [25] and AFSPCMAN 91-711,
Launch Safety Requirements for Air Force Space Command Organizations
[26] as replacements for EWR 127-1. The former is binding on all range
users, but the latter is binding only on Air Force space programs.
EWR 127-1 sets as a general goal that the risk of injury or damage
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Table 7.2: Major space launch ranges
Name Launch Location(s) Notes
Eastern Range Cape Canaveral Air Force Station, Florida Mainly low-inclination orbital
vehicles on a southeastward
ground track
Western Range Vandenberg Air Force Base, California High-inclination orbital vehi-
cles on a southward ground
track, and suborbital vehicles
westward toward Kwajalein
Atoll
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7.4. Structural Design and Requirements
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7. Materials for Launch Vehicle Structures
Structural Qualification
In this section, the most commonly used concepts in structural qualifi-
cation are introduced. While terminology varies, these concepts appear
in most government standards concerning structures, and knowing their
meaning is a prerequisite to understanding the various qualification strate-
gies.
Design limit load is the maximum expected in-service load. Programs
may be very precise; a common definition is that limit load is the 99.7
percentile of a distribution of loads that may be generated by analysis,
flight measurements, or both. Such loads are usually generated from a
finite number of samples, so it is often stated additionally that the 99.7
percentile load must be determined to a confidence level of 90%.
Design factors are factors by which limit load is multiplied to determine
the no-yield condition (the load at which the structure must not suffer
detrimental deformation), the proof condition (a load used for acceptance
testing), the no-break condition (the load at which a structure must not
lose its load-carrying capacity, through breakage or instability), and other
hypothetical load levels used in analysis. Design factors are chosen by, or
subject to the approval of, the procuring agency.
Test factors are analogous to design factors but are used to factor up
the limit load for testing purposes, as opposed to design purposes. They
are usually equal to the corresponding design factors, but they do not
have to be. For example, if limit load is 10 tons, and the design ultimate
factor is 1.25, analysis must show that the structure will withstand a load
of 12.5 tons. Most likely an ultimate load test would also specify a load
of 12.5 tons, but it could specify 14 tons or some other factored-up value.
Since limit load already takes quantifiable uncertainties into account,
design and test factors can be viewed as insurance against “unknown
unknowns.”
Capability is a lower bound on the ability of a structure to resist
detrimental deformation and to maintain its load-carrying capacity. It is
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7.4. Structural Design and Requirements
25
7. Materials for Launch Vehicle Structures
alone might miss, even when higher safety factors are used to compensate
for the lack of testing.
The relationship between the various design conditions, the test and
analysis results, and the design factors and margins is illustrated in
Figure 7.3. This figure shows the predicted flight loads and predicted
failure loads in the form of histograms, which could be generated by
Monte Carlo simulations or from an assumed distribution. For instance,
an individual failure load might be calculated Monte Carlo-style from
random draws of material strength and dimensions from distributions
consistent with sampled test and dimensional data. Or, more commonly,
it may simply be a Gaussian distribution fit to a mean and variance.
Flight loads are more likely than failure loads to be built up from random
underlying contributors, but in principle both can be done that way.
The figure shows the capability as a lower limit on predicted failure
loads, and the design limit load as an upper bound on predicted flight
loads. The illustration shows the typical circumstance in which flight load
predictions are more scattered than failure load predictions. This arises
from greater underlying uncertainty in wind statistics, trajectories, and
other inputs to the loads analysis, as well as uncertainty in the analytical
model itself. It also shows that the capability and limit load do not
enclose every single predicted load, and in that sense they are not truly
bounding values although we call them that for convenience.
The demonstrated limit load is a single value, shown in gray on the
figure. It is typically close to the design limit load. The intent is usually
to test the structure to exactly the limit load, but limit load can change
as new knowledge is gained. Finally, the figure shows that the design
factor provides separation between limit load and the no-fail condition,
and the separation between limit load and the capability is a function of
both the design factor and the margin of safety.
One may hear a statement like the following: “The test article was
loaded to 140% of the no-yield condition, so a tested margin of 40% has
been established.” This is not a correct use of the term margin, because
the test was of a single article that could have been stronger than average.
Margins are based on lower-bound strength, not averages. It would,
however, be correct to say, “The test load was 90% of capability, so there
was a 10% margin of safety during the test.” The capability represents
the lower-bound strength, and the test load is known, so there is no need
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7.4. Structural Design and Requirements
Figure 7.3: Distributions of predicted loads, failure loads, and the separation
of the two provided by lower-bound capability, upper-bound limit load (LIM ),
chosen design factor (DF), and realized margin of safety (MS). By the author.
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7. Materials for Launch Vehicle Structures
properties that are truly applicable at the scale of a full structure can be
challenging to measure. Specially laid up and cured coupons may have
different microstructure than the full-scale component. Coupons cut out
of a full structure may have damaged edges.
However, analysis for stiffness is less exact, and therefore more conser-
vative, than analysis for strength. The buckling failure mode is the one
most influenced by stiffness. Because the buckling load of a thin-walled
shell is strongly affected by slight geometric imperfections and edge con-
straint, adjustment or “knockdown” factors derived from experiments on
subscale specimens are applied. These factors may lead to a reduction
in the predicted buckling strength of 50% or more, as compared to the
theoretical value for a geometrically perfect shell. Factors documented in
a NASA monograph [34] were originally developed from experiments on
small plastic cylinders. Bushnell comprehensively reviewed the state of
the art in shell buckling analysis through 1980 [35]. Recently, recognizing
the major role played by buckling knockdown factors in vehicle design,
NASA conducted a Shell Buckling Knockdown Factors research program
that was the most significant work in the field in decades and which
experimentally supported a significant refinement and reduction in the
factors [36].
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7.4. Structural Design and Requirements
29
7. Materials for Launch Vehicle Structures
Outlook
The level of conservatism that ultimately proves more cost-effective is
different in every case and is what makes structures engineering more
than just a calculation process. It is not surprising that the organization
that bears the cost of testing tends to take a less conservative approach,
whereas the organization that bears the cost of a failed mission tends to
be more conservative. When the same organization bears the costs of
both testing and flight failures, a rational ordering of priorities is forced.
But often, the responsibilities are separated, and the negotiated level
of conservatism is determined by a political process, not an objective
technical one.
Current flight rates are too low to conclusively prove which approaches
are superior. The structural subsystem itself, and especially any single
structure, must have a very remote chance of failure in order for the vehicle
as a whole to have a reasonably small (say, one in a hundred) chance of
failure. It is not uncommon for the required probability of failure for a
particular structure to be on the order of one in a million. Even if a less
conservative approach leads to double the chance of failure (say, 2 × 10−6 )
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7.5. Pressurized Structure
31
7. Materials for Launch Vehicle Structures
integral load-bearing tanks. Also, the need to reduce mass has required
that propellant tanks be much more lightly constructed, with far smaller
design factors than stationary pressure vessels. Finally, propellant tanks
in expendable vehicles are operated for only a short time, so long-term,
time-dependent processes such as creep and corrosion are less relevant.
Flynn, in a book covering all aspects of cryogenic engineering, devotes
some discussion of propellant tanks as compared to other applications
of cryogenic technology [38]. He also provides a useful discussion of
cryogenic insulation, which will be discussed later in this chapter.
Government standards such as range safety requirements consider
the main propellant tanks to be “pressurized structures” rather than
pressure vessels (refer to [24] for one formal definition), reserving the
designation of pressure vessel for smaller tanks such as propulsion system
pressurization tanks that do not bear significant external loads. Factors of
safety and other requirements are much different for pressurized structures,
as opposed to pressure vessels.
Propellant tanks are of three basic designs. The commonest is the
stiffened metal shell, structurally stable under the load of its own weight
when empty and unpressurized. Stiffening is generally by integrally
machined stiffeners in an isogrid or orthogrid pattern, rather than by
mechanically fastened stringers. Such designs are constructed of aluminum
alloys. The next most common is the “steel balloon” design, which is very
thin-walled and not structurally stable under the load of its own weight
unless pressurized or stretched. Its stability before fill and pressurization
is maintained by pressurization with an inert gas or by mechanical tension
applied by a holding cradle. This design was most famously applied in
the Atlas missile.
Both the stiffened and balloon-style metal designs may be of a single
tank space, containing either fuel or oxidizer, or combined fuel and
oxidizer tanks separated by a common, dome-shaped internal bulkhead.
The common-bulkhead tank offers mass and size savings over separated
fuel and oxidizer tanks, and has been used in such high-performance upper
stages as the Saturn S-II and S-IVB [39] and the Centaur. A drawback
of this design is the need for the common bulkhead to control heat flow
between two propellants that may be at vastly different temperatures.
The third type of design is the composite tank. Whereas non-
cylindrical shapes would be very difficult to achieve in a mass-efficient
32
7.5. Pressurized Structure
manner with metallic shell designs, such shapes are less troublesome
with composites. Also, composite tanks offer potentially significant mass
savings through higher material specific strength and the ability to orient
the primary load-carrying direction of a composite laminate along the
expected loading direction. Composites also offer better resistance to fa-
tigue and flaw propagation, because microscopic flaws tend to be blunted
and stopped by the fibrous microstructure, although accumulated fatigue
damage can result in increased permeation of propellant. With all these
advantages, much effort has been expended on realizing an operational
composite propellant tank, but to date, successes have been small in
number.
All tank designs must perform the basic function of containing the
liquid propellants during testing, fueling and flight. Propellants vary from
RP-1, a highly refined kerosene, to cryogenic liquid oxygen (LOX) and
liquid hydrogen (LH2 ), to storable but often toxic combinations such as
hydrazine and nitrogen tetroxide. All have properties that constrain the
designer’s choice of propellant tank materials, and cryogenic propellants
require that the tank be insulated to minimize boil-off.
In almost all cases, tanks must sustain aerodynamic and inertial flight
loads, which for the typical long, cylindrical tank means a combination of
axial compression and bending. The Space Shuttle external LOX tank is
a special case in that it receives axial aerodynamic loading directly due
to its position at the forward end of the tank assembly. Inside the tank,
various baffles and propellant management devices must be supported.
Finally, depending on the tank’s location in the vehicle, main propellant
feedlines and electrical tunnels must be supported, either as an external
appendage or through centerline tunnels as in the Saturn S-IC stage [39].
The tank contents must be fed to the engines under pressure. For a
pressure-fed propulsion system, propellants are forced directly into the
combustion chamber by ullage pressure. The ullage is the unfilled space
at the forward end of the tank. For pump-fed engines, moderate pressure
is still necessary in order to prevent cavitation in feedlines. Just prior to
launch, large tanks are pressurized using a ground supply of gas; once
the booster engines have been started, the gas supply may be provided
by the engines through a re-pressurization system. For smaller stages, an
onboard supply of inert pressurant is often used.
It is worth recalling the basic relationship between load and internal
33
7. Materials for Launch Vehicle Structures
are called equivalent axial loads [40], and in terms of them the
longitudinal stresses are
In the preceding σ represents the average stress over the wall thickness.
Often, a local analysis that considers the variation of stress between the
skin and the stringers or the core and face sheets of a built up wall
needed. In such cases it is useful to work in terms of q, the integral of
stress over the wall thickness:
The quantity q is called the line load or tensile flux. Note that in all of
the above development, axial force is taken as positive in compression.
These equations apply to large tanks and cylindrical adapters except
where local irregularities or constraints render the underlying assumptions
invalid. For a structure such as an adapter or interstage that contains no
liquid, the terms containing density may be deleted. However, internal
pressure in such structures may be important. Consider that an adapter
35
7. Materials for Launch Vehicle Structures
with a radius of 100 inches and a wall thickness of 0.2 inches will experience
a longitudinal wall stress of 0.25 ksi for every psi of internal pressure.
From Equations (7.8), (7.10) and (7.11), we see that in the absence
of external load and static head, the state of stress in the membrane is
biaxial with a hoop-to-longitudinal ratio of two. External loads will cause
this ratio to vary significantly from two. Conventionally, material strength
is determined from uniaxial tensile tests, and then a combined-stress yield
theory such as the Mises theory is used to calculated a scalar effective
stress from the actual biaxial state of stress in the application. Although
a large amount of experimental effort has been directed toward gaining a
more sophisticated understanding of metal yielding and rupture under
biaxial stresses (see [41] for example), the results seem to be little used
today.
The use of the maximum principal stress failure criterion for metals is
near-universal, but consider that a ductile material has a higher ultimate
stress than its strength at rupture. In fact, for some high-strength steels,
the stress is higher at the offset yield point than at any subsequent
time [41]. Though maximum principal stress correlates very well to
rupture strength, it is possible that ultimate stress, which is the material
property customarily used to indicate failure, might be predicted better
by alternative criteria.
The foregoing discussion only addresses strength. Tanks may also
fail by global or local buckling, or by the fracture of a flaw at far-field
stresses below yield. In practice, the margin of safety tends to be about
the same for strength and buckling failures. The fracture failure mode,
which is managed by controlling the initial flaw size, may not be close to
the others in criticality.
Proof pressure testing is usually required, if not by the procuring
agency, then by the range safety organization. Pressure testing at cryo-
genic temperatures is very expensive, so proof testing is usually done with
room-temperature nitrogen gas or water. The ratio of yield to ultimate
strength, and the fracture toughness, of many materials is different at
room temperature than at the service temperature. Thus, it is not a
trivial problem to devise a room-temperature proof test that exercises all
failure modes of a cryogenic propellant tank adequately.
Designing for light weight requires that the structure be quite thin-
walled. Thicknesses (or effective thicknesses, in the case of stiffened
36
7.5. Pressurized Structure
structure) can be on the order of one tenth of an inch for a section 200
inches in diameter (R/t = 2000). For comparison, a soda-pop can has
R/t ≈ 1000.
Methods of flaw screening over large areas are usually sensitive enough
to allow very small initial flaws to be assumed in the safe-life analysis
and thus to provide ample safe life.5 Automation of flaw screening can
be developed during production planning. Years ago, flaw screening was
provided via proof test; a flaw that could survive the proof test without
catastrophic propagation was considered very likely to survive flight as
well. This was usually performed on pressure vessels, and pressurized
structures. A more rigorous screen may (depending on the material) be
provided by a proof test at cryogenic temperatures. For many materials,
at colder temperatures the yield strength increases, permitting testing
to a higher pressure, and the fracture toughness decreases, reducing the
margin against catastrophic flaw growth.
Methods of flaw detection include dye penetrants, ultrasound, x-
ray, magnetic particles, and eddy current inspection. The inspection
method is chosen based on cost, the required sensitivity, the accessibility
of the area to be inspected, surface finish and coating/plating, and
the material. MSFC-STD-1249 [42] is an oft-cited standard covering
inspection methods.
Some materials have high fracture toughness relative to yield strength,
so a larger flaw can be tolerated. The ratio of toughness to yield strength
is significant due to the need to restrict stress levels below yield strength.
Conversely, a high-yield-strength material with low fracture toughness
will need to be screened for very small flaws, which is the case with some
high strength steels with low ductility.
In some cases, when hardware is received, it is found to have been
inadequately inspected, or the results of the inspection may show that
the design intent was not met. It may prove faster and cheaper to con-
duct additional analysis, inspection and testing to accept the discrepant
hardware than to scrap the structure and manufacture a new one.
5
This discussion provided by John Hilgendorf, Structural Analysis Lead for Delta II,
United Launch Alliance.
37
7. Materials for Launch Vehicle Structures
38
7.5. Pressurized Structure
of a different temper from the barrel. The barrel and domes are joined
by welding. Squat tanks such as the S-II stage LOX tank have been laid
out completely as domes welded from gores, with no cylindrical section.
Large domes may be produced by explosive forming, as in the S-II stage
[39]. Mynors and Zhang [43] discussed the widespread use of explosive
forming in the 1970s, detailed the advantages and disadvantages, and
described a research program exploring potential modern applications.
Small end closures may be present at the apex of the domes, and these
are usually bolted on so that they may be removed if necessary.
Barrel panels are stiffened either with extruded stringers or with
integrally machined stiffeners. The integrally machined designs demand
that plate be available in fairly thick gauges (one inch or more). Stiffeners
may be created by machining or chemically milling pockets into a thick
plate. The machining process leaves thickened weld lands, which are
necessary because welds are not as strong as the as-machined metal.
Machining of stiffeners is conducted when the panel is still flat, as a
rule. Once machined, the panels are bump-formed or brake-formed into
cylindrical arcs and then welded into a barrel of circular cross section. To
avoid local buckling of ribs during forming, the machined pockets may
be filled with a thermoplastic compound, then round the panel after the
compound has cooled and hardened. The hardened compound provides
stability to the thin ribs. After forming, the compound is melted out [44].
Because of the large amount of material that is removed, integrally
machining the stiffeners may result in a scrap ratio of as much as 80%.
This can be a significant cost for the more expensive alloys, and has been
a motivation to attempt to produce Al-Li panels with extruded rather
than machined stiffeners [45].
The isogrid pattern [46], in which the integral stiffeners are a network of
equilateral triangles, is by far the most popular of the integrally stiffened
tank wall designs. It offers the stiffness and mass efficiency of other
stiffener patterns but preserves the large-scale isotropic behavior of the
panels, so that they may be modeled as shells with “equivalent isotropic”
properties. While the simplifications made possible by isotropic behavior
may not appear to be very advantageous in detailed stress analysis, when
rapid iterations must be done in design trade studies, isotropic behavior
is a significant benefit. Meyer et al. [46] provided the definitive work on
isogrid design and stress analysis.
39
7. Materials for Launch Vehicle Structures
40
7.5. Pressurized Structure
41
7. Materials for Launch Vehicle Structures
surface corrosion, especially in the clad grades. It was found that foam
insulation on a 2219 substrate resulted in collection of a chloride-rich
liquid in the salt air environment of the southern United States which
caused extensive corrosion after exposure of many months [51].
The other workhorse aluminum alloy for stable tank designs is 2014.
Alloy 2014 has copper as a principal alloying element (4.4%) but at a
lower level than 2219 (6.3%) [52]. It was developed in 1928 primarily for
use in aircraft structures as forgings and extrusions; for LV tanks, the
sheet or plate forms are used. Alloy 2014 generally has higher strength
than 2219: in the T6 temper, its A-basis tensile strength is 64-67 ksi, a
few percent stronger than 2219 [8].
Alloy 2014 is a precipitation-hardening alloy. Unlike the widely used
2219-T87 grade, commercial tempers of 2014 are not cold-worked. As
with 2219, considerable springback may occur after cold forming, and
this is typically corrected by “overforming” [52]. Both 2219 and 2014 are
easily machinable, which is important in designs with integrally machined
stiffeners.
Alloy 2014 has been used in the Titan II booster, the Saturn S-II
stage, and the Saturn S-IVB stage [49]. The Saturn I, designed in the
late 1950s, used the Al-Mg alloys 5456 and 5083, but these are rarely
considered any more due to their lower cold notch toughness, and greater
susceptibility to corrosion. However, they are more weldable than the
2000-series alloys. That is, they lose proportionately less strength and
ductility in the welded condition [49]. Both 5456 and 2014 appear to have
been early candidates for the S-IC stage [53], but 2219 was ultimately
selected. Another aluminum alloy, 6061, was used on the Agena tanks [54];
while this alloy still has some applications in other vehicle structures, it
is no longer used for tanks.
Welding processes for tanks have an influence on materials selection.
Historically, most tanks have been fusion-welded. The S-IC stage used
gas tungsten-arc welding (GTAW) to join 2219 panels [51], a practice
that continues to be popular. More recently, plasma arc welding has been
implemented. Variable-polarity plasma arc (VPPA) welding, in which the
arc polarity is periodically changed to reduce the accumulation of dross,
was successfully implemented on the Shuttle ET and Delta IV programs
and has also been used to join Al-Li alloys [55]. The large Soviet/Russian
Energia booster used electron-beam welding in its tanks [2].
42
7.5. Pressurized Structure
Within the last ten years the development of friction stir welding
(FSW) has been a major advance in tank manufacturing. FSW was devel-
oped in the 1990s and is now used in production on several LVs. In this
process, a rapidly rotating pin moves along the weld lands, mixing clean
base metal, which welds spontaneously. It produces a higher-strength
and higher-ductility joint than fusion welding because the material is
never melted [56]. FSW is particularly attractive for aluminum alloys
because of their low hardness. FSW was introduced into production on
the Delta II program in 1997 [55]. But FSW is more sensitive to weld
land alignment deviations than fusion welding.
Aside from 2000-series aluminum alloys, the material with the widest
current application to propellant tanks is the aluminum-lithium (Al-Li)
series of alloys. These alloys contain only a small amount of Li by weight
(about 1%), less than their Cu content of 2-4%, but they are known as
Al-Li alloys to contrast them with non Li-containing alloys. An Al-Li
alloy was developed specifically for aerospace applications as early as
the 1950s, but problems with fatigue, fracture and weldability precluded
its widespread use in the United States until the 1990s [51]. While all
wrought alloys are anisotropic in strength and stiffness to some degree,
Al-Li is anisotropic enough that it must be structurally analyzed as such.
One study found that 2195 Al-Li extrusions [57] had direct and off-axis
strengths differing by as much as 20% depending on the depth through
the section.
In the early 1990s, funding became available for a major redesign of the
Shuttle ET with the primary goal of reducing weight. Weight reduction
became necessary when it was decided that the ISS would be put into a
high-inclination orbit accessible to Russian launchers; the Shuttle then
had to reduce its empty weight to be able to reach the ISS. A series of
weldable Al-Li alloys under the Weldalite trade name was available to
Lockheed Martin, prime contractor for the ET. The redesigned tank was
given the abbreviation SLWT, for super-lightweight tank.
The Al-Li alloy 2195 ultimately selected for parts of the SLWT is
lighter than the formerly used Alloy 2219, but has yield strength about
20% higher at both ambient and cryogenic temperatures [12]. It is
also about 8% stiffer than 2219. However, 2195 is less formable in the
T3 condition than 2219, so an early attempt to simply drop it in as
a replacement for 2219 resulted in damaged forming equipment. The
43
7. Materials for Launch Vehicle Structures
remedy was to solution treat and quench the 2195 into the T0 condition,
then stretch form and shape to the T3 condition, and finally age to the
T8 condition [51]. Alloy 2195 is also less ductile than the 2000-series
aluminum alloys. Ultimately, all of the ET tank barrels as well as the
intertank thrust panels were changed to Al-Li.
It was also found that fusion welds on Al-Li were more susceptible to
hot cracking than on 2219, and that the subsequent repairs were more
difficult. Process changes involving a smaller heat load, a backside inert
gas purge, and weld bead planishing were necessary to enable the needed
repairs [51]. However, weld quality concerns led Marshall Space Flight
Center to investigation FSW for the Al-Li tank components. FSW was
implemented on the ET starting in 2002.
Other applications of Al-Li have been the DC-XA and X-33 research
vehicles. In both cases, composites were used for the LH2 tanks, but Al-Li
was used for the LOX tanks. Composite LOX tanks require a protective
liner, typically a halogenated polymer, to reduce the chance of ignition
[58]. The DC-XA LOX Tank was built in Russia from Al-Li alloy 1460
[59].
The Ares I upper stage was a structurally stable, common-bulkhead
propellant tank design with friction stir-welded Al-Li 2195 tank barrels
and domes. The common bulkhead was a sandwich construction consisting
of 2014 facesheets enclosing a phenolic honeycomb core. The bulkhead
was to be joined to the barrels by a 2219 Y-ring [60].
In a pump-fed stage, the propellant is held under low pressure in
the tanks, then pumped to the injection pressure after it has left the
tank. The tanks therefore may be constructed lightly, and stresses due to
external flight loading are comparable to those due to internal pressure.
In contrast, pressure-fed stages do not have pumps; the propellants are
forced into the engine by holding them under high pressure in the tanks.
This type of design is used when simplicity and reliability are paramount.
Injection pressures for pump-fed engines may be several thousand psi,
which would require inordinately heavy tankage. But pressure-fed systems
are designed to require only moderate injection pressures. While this is
higher than the tank pressure in a pump-fed stage, it is low enough that
the tank can be flight-worthy at an acceptable weight. Stresses in tanks
for pressure-fed stages are dominated by internal pressure loads.
Some pressure-fed designs have used internal bladders to expel pro-
44
7.5. Pressurized Structure
pellant from the tank rather than externally supplied gas. Many basic
design and materials selection aspects are discussed in [54]. Pope and
Penner [61] described testing of multilayered bladder materials consist-
ing of various arrangements of polyethylene terephthalate (PET) film,
composite balloon film, aramid film and polyimide film. They found
through subscale testing that a PET-balloon film fabric provided good
performance under cryogenic conditions, with the lowest permeability.
Gleich and L’Hommedieu [62] performed similar studies on wire-reinforced
metallic bladders of annealed austenitic stainless steel.
Calabro et al. [63], in the course of system studies for an advanced
pressure-fed cryogenic upper stage, proposed combining a 2219 aluminum
LOx tank with a filament-wound graphite-epoxy LH2 tank in a common-
bulkhead design. The LH2 tank used an internal aluminum foil liner.
The working pressure was 270 psi. Thermal insulation was provided by
externally applied polyurethane foam.
Many LVs use hydrogen as a propellant in the booster, the upper
stages, or both, so the compatibility of materials with hydrogen must
be thoroughly understood. Cataldo [64] summarized the findings of
several research programs investigating hydrogen embrittlement in high-
pressure storage tanks, fasteners, and weldments. Although the focus
was on titanium alloys and Inconel 718, useful information is provided
on a wide variety of aerospace metals. High pressure was not always a
necessary condition for problems with hydrogen compatibility. Hydrogen
embrittlement of metallic materials is discussed in Chapter 2.
Balloon Tanks
The Atlas vehicle designed by K.E. Bossart at Convair Division of General
Dynamics in the early 1950s is exemplary of this type of design. The
other notable application is the Centaur upper stage, also developed
by General Dynamics. The Atlas maintained the balloon tank design
through several ICBM variants, the early Atlas E and F space launch
vehicles, and the Atlas I, II and III commercial space launchers. The
Centaur stage still uses the balloon tank design. Balloon tanks require
either mechanical tension (“stretch”) or internal pressure to keep them
from collapsing under their own weight prior to operation. In operation,
the pressure required for propellant feed is sufficient to keep the tank
stable under flight loads. The following information is taken primarily
45
7. Materials for Launch Vehicle Structures
Figure 7.4: The Atlas launch vehicle carrying John Glenn to orbit. The balloon
propellant tanks can be seen; the LOX tank is forward and covered with frost,
while the fuel tank is aft and its shiny stainless steel skin is clearly visible.
Public-domain photo by NASA.
Balloon tanks have very thin walls (as thin as 0.01 inch, thinner
than three sheets of copier paper) and are built from corrosion-resistant
steel. In the Atlas and Centaur, most of the tank skins are made from
stainless steel Alloy 301 in the extra full-hard (EFH) grade. Skins that
must be formed into a shape other than a circular cylinder, such as
conical transitions or domes, are made from 1/2 and 3/4 hard grades,
for improved formability. Because the tank walls are so thin, machined
reinforcing rings must be placed at locations where external hardware
such as feedlines, electrical tunnels, or strap-on booster rockets must be
attached. These rings are made from 321 stainless steel, because it is
46
7.5. Pressurized Structure
more machinable than 301. Both 301 and 321 are austenitic stainless
steels, whose primary alloying elements are chromium and nickel.
In the very early phase of ICBM development, a vehicle was designed
using the balloon tank concept but with aluminum instead of steel as the
material. However, comparing the specific strength of 2219 aluminum
and 301 EFH stainless steel at LOX temperature,
Composite Tanks
While light weight is always a major goal in the design of aerospace struc-
tures, it is especially important in launch vehicle stages that ultimately
will be propelled to orbit. In staged vehicles, the inert weight of boosters
is jettisoned once the booster’s fuel supply is exhausted. However, the
orbital stage is not jettisoned, so there is a very high motivation to keep
47
7. Materials for Launch Vehicle Structures
its inert mass to the absolute minimum. Every pound of inert mass on
an orbited stage is one less pound of payload that can be carried.
The vision of a reusable, single-stage-to-orbit (SSTO) vehicle with
airliner-like operations has existed since the earliest speculations about
space travel. Such a vehicle would have no jettisonable boosters, with
all of its inert mass propelled into orbit, re-entering the atmosphere,
and returning to Earth to land. Therefore, structural mass efficiency is
paramount. Barring unforeseen developments in propulsion technology,
any SSTO vehicle must have a structure that is at the absolute maximum
efficiency possible with known materials.
The imperative to minimize inert mass has been one of the major
reasons so much research effort has been directed toward composites, the
other major reason being the ability to fabricate complex cross-sectional
shapes with inexpensive tooling and processes. The tensile strength-to-
weight ratio of graphite fibers is many times that of the aluminum alloys
and steels typically used in propellant tanks.
But the raw tensile strength-to-weight value that is so favorable for
graphite fibers can be misleading. To produce a useful structure, the fibers
must be incorporated into a matrix; this decreases the tensile strength by
about 50% and adds the weight of the matrix, which carries little load.
Also, unlike a true pressure vessel, the skin of a pressurized structure will
not always be in tension. Compression loading raises the possibility of
buckling. While composites with elastic moduli several times that of an
equivalent-weight metal design may be produced, it is difficult to control
the geometric imperfections that are so damaging to buckling resistance.
The polymeric matrix of conventional composites places an upper limit
on the service temperature. Conventional graphite-epoxy composites lose
strength and stiffness rapidly when temperatures reach 200 ◦ F to 300 ◦F,
due to softening of the matrix. Thus, composite tanks must be insulated
or protected from skin heating by trajectory limitations. This is especially
constraining to the design when the trajectory includes re-entry, as it does
for a reusable vehicle. Improvements in both thermoplastic and thermoset
matrix materials are potentially a means of raising the temperature limit.
Also, especially for tanks of complex shape, reinforced joints are
necessary. The need to reinforce these joints and to insulate a composite
tank against aerodynamic heating tends to erode the weight advantage
over a metal tank. It has been stated that a composite tank can represent
48
7.5. Pressurized Structure
49
7. Materials for Launch Vehicle Structures
50
7.5. Pressurized Structure
Figure 7.5: The X-33 liquid hydrogen tank on a test stand at NASA Plum
Brook Station, Sandusky, Ohio. Note the complex, lobed shape of the tank.
Public-domain photo by NASA.
draining, the tank began to warm to room temperature, and the pressure
in the core rose as the liquefied hydrogen and nitrogen warmed up and
began to evaporate. The pressure resulted in a sudden debond of the
entire area of the inner facesheet. A pre-existing bondline flaw, in the
form of a piece of slippery tape found between the core and facesheet,
probably contributed to the failure.
This failure mode is called cryopumping. Generally, in the context
of aerospace structures, cryopumping refers to the condensation of gas
in a void and the drawing in and condensation of additional gas due to
the lowered pressure in the void, followed by the possibly destructive
rapid venting of the gas upon reheating. In cellular insulations such as
polymeric foam, cryopumping occurs when the insulation is cooled by
contact with a tank filled with cryogenic propellant, then heated as the
51
7. Materials for Launch Vehicle Structures
vehicle ascends, the tank empties, and aerodynamic friction heats the
insulation. Liquid air condensed in voids in the foam is vaporized and
will blow a hole in the foam if it cannot gradually vent.
Cryopumping was a known condition that the X-33 design was sup-
posed to accommodate, and the failed core in fact had a measured
cryopumping pressure that was lower than the design value, but local,
unobservable peaks in the pressure may have exceeded the bondline capa-
bility. Despite ultrasonic NDI, the PTFE tape, as well as other debonded
areas, were not detected prior to testing. They were only observed after
the test article had failed. The possibility of manufacturing flaws difficult
to screen by inspection or proof testing has always been a disadvantage
of composites, especially in sandwich constructions.
It is a mistake to conclude that the X-33 failure proves composite
tanks can never work, because that particular application was much more
demanding than conventional applications. It is known that thermome-
chanical cycling, which is much more severe on a reusable vehicle like the
X-33 than on an expendable, is the primary driver of permeation and
leaking. After all, composite filament-wound, monocoque solid rocket
motor cases have been successfully used for years, and mechanically they
are similar to liquid propellant tanks. However, composites are not as
clean a solution as they might appear to be from a naive conception of
their raw material properties. In particular, the need to characterize and
control permeability without the use of a liner has been the thrust of
much recent research in composite tanks.
During and after the X-33 program, several research projects have
sought to improve the performance of composites in cryotank applications.
Heydenreich [72] described system studies carried on in Europe to establish
which tankage applications could most benefit from the use of composites.
He pointed out the need for a mechanically strong, yet thermally insulating
design, suggesting that a liner would be necessary to prevent permeation.
He also recognized the fact that composites do not exhibit plastic behavior,
which requires a different design philosophy than for metal tanks.
Sankar et al. [66] conducted a multiyear research program aimed at
developing improved analytical models of gas permeation through com-
posite panels at cryogenic temperatures and under complex, fluctuating
stress states. In particular, they examined the effect of interacting distri-
butions of oriented cracks in the different layers of a laminate. Transverse
52
7.5. Pressurized Structure
53
7. Materials for Launch Vehicle Structures
54
7.5. Pressurized Structure
a single, monolithic unit. Very large motors, including the Titan III
and IV strap-ons and the Space Shuttle SRBs, must be manufactured in
segments in order to be transportable over the road. Motor cases and
segments are permanently loaded with propellant by the manufacturer,
and therefore must be handled carefully as they are transported to the
launch site, where they are assembled or “stacked.”
A “case-bonded” (as opposed to cartridge-loaded) motor typical of
those used for LVs consists of an outer shell, closed forward and aft by
domes, and the assembled pressure vessel is lined with an insulating
material that both protects the case from the heat of combustion and
facilitates the bonding of the propellant to the case. The propellant is
then cast directly into the lined case and cures to a rubbery consistency.
Neither the propellant nor the insulation provides significant strength or
stiffness to the motor as a whole, so they are not discussed further here.
Additional details are given in Chapter 11.
The pressurized envelope of a motor case is capped by a forward
closure, which usually houses the igniter, and an aft closure that must
provide an attachment for the nozzle. Also, forward and aft skirts are
usually provided for attachment to other vehicle structures. These are
integral with the motor case.
Except for the very largest first-stage boosters, solid rocket motor
cases are designed based on the pressure stress plus flight loads amounting
to some fraction of the pressure stress. As with main liquid propellant
tanks, cyclic loading during proof testing may cause flaws to propagate.
But solid rocket motor cases are also subject to pressure oscillations
at frequencies up to 1000 Hz during the motor burn [77]. Therefore,
nondestructive inspection methods of similar type and significance as
those previously discussed for liquid propellant tanks also apply to solid
rocket motor cases.
Motor cases are generally constructed of high-strength steels, titanium,
or filament-wound graphite-epoxy. Pressure stresses usually preclude the
use of aluminum except for very small motors. Metal cases may be built
from rolled and welded sheet or by seamless methods such as drawing or
spinning. The presence of a welded seam lowers the strength of the nearby
material and requires heat treatment and careful inspection. Steels that
are commonly used are D6AC, the 18% nickel maraging steels, and 4130
alloy [77]. Steels requiring post-fabrication heat treatment may pose a
55
7. Materials for Launch Vehicle Structures
problem because of the very large diameter of the finished product. There
is a limit to how large the structure can be before exceeding the capacity
of commonly available heat treatment facilities.
Solid rocket motor cases were one of the earliest applications of
filament-wound composites technology. Peters [78] states that motor
cases “were primarily responsible for accelerating filament winding from a
laboratory curiosity to the major industry it is today.” As with propellant
tanks, a major reason composites are attractive as a material for motor
cases is the ability to orient the strong direction of the material along the
direction of highest loading. This leads to greater structural efficiency
than is possible with an isotropic material. In motor cases, more so than
other structures, it can be stated with high confidence that the state
of stress is close to biaxial, with the axial stress about half of the hoop
stress. Flight loading is small compared to internal pressure and will alter
this ratio but little.
The titanium alloys and high-strength steels commonly used for motor
cases have specific strengths of about 850 ksi/(lb/in3 ), whereas composites
can achieve 3-5 times this value. Other reasons to use composites include
lower-cost and more adaptable tooling, relatively low-cost raw materials,
and imperviousness to corrosion. The thermal environment for motor
cases is not significantly different from that of non-cryogenic primary
structure. Although combustion temperatures are as much as 4000 K,
this extreme temperature does not have time to penetrate through the
very poorly conducting solid propellant and insulation to the case.
Several programs, including Titan and Space Shuttle, have developed
composite filament-wound replacements for motor cases that were initially
metal. Not all of these new designs were put into production. In the case
of the Space Shuttle, the filament-wound motor offered a definite mass
fraction advantage over the existing design, but the extra capability was
only needed for polar orbit launches from the Western Range, which were
canceled after the Challenger failure [79].
The Delta II uses up to nine large strap-on GEM-40 solid rocket
motors. The GEM-40, -46 and -60 have graphite-epoxy filament-wound
cases. Filament-wound cases have even been able to meet the very
stringent mass efficiency requirements of upper stages. The Inertial
Upper Stage (IUS) developed as an upper stage for both Titan and
Shuttle, incorporated two aramid-epoxy filament wound motors.
56
7.6. Feedlines, Small Lines and Pressure Vessels
Feedlines
Feedlines are different from other pipes and tubes due to their large size,
higher criticality and high flow rates. Operating pressures are similar
to those in the tanks. Some lines are downstream of pumps and the
pressure can be several thousand psi, but pipes downstream of feed pumps
are usually considered part of the propulsion system and therefore fall
outside the scope of this chapter. Either the fuel or the oxidizer tank
may be in the forward position. The feedline from the forward tank has a
downcomer that may run along the side of the aft tank, or may penetrate
the tank. The downcomer can be more than 50 feet long.
Feedlines are usually constructed of 321 corrosion-resistant steel
(CRES), although 347 CRES, Inconel 718, Hastelloy and A-286 have
also been used [84]. Inconel 718 and Hastelloy are especially suited to ar-
eas experiencing fluctuating loads and corrosive environments. Feedlines
can experience a high fluctuating load component relative to the mean
57
7. Materials for Launch Vehicle Structures
Pressure Vessels
Launch vehicles need to store small quantities of hydraulic fluid, sec-
ondary propulsion or reaction control propellants, helium for system
58
7.7. Unpressurized Structure
59
7. Materials for Launch Vehicle Structures
launch, as the vehicle ascends through the atmosphere, the internal gases
escape the structure through vents or natural leak paths.
Unpressurized structures may need to maintain a controlled interior
temperature and humidity environment, as with a payload fairing, or
there may be no control at all of the interior environment, as is usually
the case with intertanks and thrust sections.
As with all airborne structure, the strength-to-weight ratio is the most
important design characteristic, and when liquid propellants need not be
contained, there is more freedom to optimize the materials and structure
for light weight. Therefore, unpressurized structures have seen greater
use of composites, and the stronger grades of aluminum, whose lower
fracture toughness is less of a disadvantage than it would be in structure
that sees pressure cycling, may be considered. Lighter designs can result.
The 7000-series aluminum alloys are often used in unpressurized
structure. These alloys have zinc as their major alloying element, and
have a much higher static strength than the 2000-series alloys used in
propellant tanks. However, the 7000-series alloys are not as resistant to
damage from repeated loading as the 2000-series alloys, and have less
favorable cryogenic properties.
60
7.7. Unpressurized Structure
61
7. Materials for Launch Vehicle Structures
62
7.7. Unpressurized Structure
63
7. Materials for Launch Vehicle Structures
the sandwich was heated until the gas-generating material was activated,
causing bubbles to expand in the core and increase the thickness of the
sheet without an increase in mass. The large foam cells produced by
this process were about as big a honeycomb cell. A prototype conical
adapter was built using this process and successfully tested to about half
of the limit loads applicable to the conventional structure it was meant to
replace. Homogeneous core/facesheet sandwich structures such as these
overcome the problems of material incompatibility, but cannot be tailored
as precisely as sandwiches with differing core and facesheet materials.
Lane et al. [97] investigated a fairing design composed of tubes joined
into a sheet, subsequently formed into a cylindrical barrel. The tubes
were then punctured on the inside of the barrel to reduce the acoustic
levels inside the barrel. This design, known as the chamber core fair-
ing, is intended to provide acceptably low sound levels inside the fairing
without the need for the usual nonstructural acoustic blankets. They
built a laboratory-scale specimen and measured noise reduction equal to
that provided by blankets for low-frequency noise. The specimen was
constructed of inner and outer filament-wound facesheets with composite
tubes between them. There may be difficulties in integrating the cylindri-
cal chamber-core barrel with the required conical shape at the forward
end of the nose.
Ochinero et al. [98] described the design optimization and subscale
wind tunnel testing of an unconventional Large Asymmetric Payload
Fairing intended to accommodate very bulky payloads.6 They discussed
an optimization procedure that resulted in the selection of carbon fiber
reinforced facesheets and a Rohacell foam core. This design was governed
strongly by buckling rather than strength, which is typical for payload
fairings. Consideration was given to buckling behavior beyond the elastic
stability limit (postbuckling), which has been applied in practice to
balloon propellant tanks but is not usual for other structures.
The use of a Rohacell foam core highlights important considerations,
discussed in more detail in the following section, related to core materials.
A primary reason for using Rohacell for this application was the relatively
low knock-down factor imposed by the program. Program requirements
6
Material on the Large Asymmetric Payload Fairing and the subsequent section on core
materials and inserts were contributed by Tomoya Ochinero and Eric Ruolo, Structural
Mechanics Corporation.
64
7.7. Unpressurized Structure
Core Materials
Core material is used to separate thin composite facesheets and increase
the structural efficiency in bending. The purpose of this core material
is to tie the facesheets together in shear, thus allowing them to work
together in bending. For this reason, when modeling, the properties of
the core must be properly taken into consideration. One often overlooked
core property is the in-plane modulus of aluminum honeycomb cores.
Facesheet-stabilized aluminum honeycomb has a significant in-plane mod-
ulus that must be accounted for when conducting thermal analysis or
thermal distortion analysis of sandwich parts with thin facesheets. A
65
7. Materials for Launch Vehicle Structures
good reference to estimate the modulus in the absence of test data is [99].
Incomplete bonding between core edges and facesheets is often the
source of many manufacturing induced flaws which cause disbonds and
panel failures. These can be mitigated by using reticulation to premelt
one layer of film adhesive on the bare core. This increases the bond
fillet between the honeycomb and facesheet and has been shown to
dramatically increase sandwich panel integrity. The downside is the
increase in processing time and the use of twice the number of film
adhesive layers, which increases the mass of the panel and adds more
high-CTE adhesive into the panel.
For large panels and complex sections, core splices are required. The
need to use separate core sections and then bond them together with
foaming adhesive adds another design detail with challenging analysis
requirements. For most aerospace applications, the foaming adhesive has
stronger shear strength than the core, so if the dimensions of the splices
are controlled to ensure proper adhesion, the core splice is stronger than
the base materials. Splices should be designed to be away from any load
introduction points and as far away from highly loaded regions of the
panel as practically possible.
With sandwich structures that ascend to outer space or have rapid
depressurization requirements, vented core is required to prevent the
facesheets from blowing off. An approach to compute this failure mode
is presented in [100]. The vapor needs to have a pathway to ambient,
requiring edge closeouts to also be vented. Mylar closeout tapes come
perforated for such applications.
The core out-of-plane shear strength is utilized to introduce out-of-
plane loads via potted inserts. Potted inserts are placed in sandwich
panels to connect ancillary components such as equipment boxes to
the panel and provide load paths for panel to panel connections. Most
companies have proprietary insert designs, but off-the-shelf designs are
sold commercially. The analysis of these joints is complicated and is
described in great detail in [101]. Test data for these joints is required
to validate the design before production. Attention should be paid to
the potting compound for this style of insert. With extreme thermal
environments, the out-of-plane CTE difference can cause the potting
compound to either shear the core or force the failure of the core-to-
facesheet bond. Potting compound weight can also become a major driver
66
7.8. Thermal Protection and Insulation
67
7. Materials for Launch Vehicle Structures
68
7.8. Thermal Protection and Insulation
69
7. Materials for Launch Vehicle Structures
to achieve a low-drag outer profile for both poured and sprayed foams.
The various failure modes of foam insulation received intense study
following the Columbia accident. Stresses sufficient to fail foam may be
caused by cryopumping, thermal expansion, flexing and stretching of
the structural substrate, thermal cycling, pre-existing flaws, voids and
unbonds, and probably several other failure modes that have yet to be
conceived. Bednarcyk et al. [104] provided a discussion of the failure
modes from the micromechanics viewpoint along with an analytical
framework for predicting failure under complex combinations of stress,
temperature and pressure histories.
The Space Shuttle contains both major types of TPS: a low-strength,
lightweight layer of foam on the expendable External Tank, and more
capable, reusable insulation on the Orbiter. The Orbiter is not only
reused, it also must withstand the rigors of atmospheric re-entry, which
are a far more challenging thermal environment than launch. Figure 7.6
illustrates the location of the different types of TPS on the Space Shuttle
Orbiter.
Re-entry TPS technology for reusable launch vehicles has its roots in
the (primarily ablative) TPS designs for the early expendable capsules.
A summary of the state of the art in ablative heat shield materials for
re-entry vehicles was given by Bauer and Kummer [105]. They described
the design of a low-density, filled silicone ablative material cast into
a nonmetallic honeycomb reinforcement, bonded to a plastic sandwich
structure, as applied to the Gemini spacecraft. This was an advance
over the Mercury heat shield, which was a glass-phenolic, and a step in
the direction of the Apollo Command Module heat shield, which was
silica fiber-epoxy resin again cast into a non-metallic honeycomb support
structure. These early ablative systems were extremely heavy. The
Apollo shield made up almost a third of the total weight of the Command
Module.
A reusable TPS with a great deal of operational experience is the
ceramic tiles covering most of the Space Shuttle orbiter. The development
of these tiles was a major pacing item in the Shuttle program as a whole.
There are actually four different types of tiles, with differing capabilities,
used in different areas. All of the tiles are composed of amorphous
silica fibers with a 0.015-in-thick reaction-cured borosilicate glass coating
on the side facing the atmosphere. The system is tiled, rather than a
70
7.8. Thermal Protection and Insulation
Figure 7.6: Thermal protection system of the Space Shuttle Orbiter. Public-
domain graphic by NASA.
71
7. Materials for Launch Vehicle Structures
72
7.9. Manufacturing Considerations
Introduction
Manufacturing of launch vehicles is a process that transforms raw materi-
als into a space launch vehicle.8 This includes tanks, engines, structure and
necessary sub-systems for full operations. This process has three phases;
8
This section was contributed by Clyde S. Jones III, NASA Marshall Space Flight Center
73
7. Materials for Launch Vehicle Structures
74
7.9. Manufacturing Considerations
75
7. Materials for Launch Vehicle Structures
76
7.9. Manufacturing Considerations
with complex curvature. The programmable path of the robot can reduce
the cost of motion control compared to a specially designed system for a
specific geometry. Robots using the gas tungsten arc welding (GTAW)
process were able to join a wide variety of components previously welded
manually on the Space Shuttle Main Engine in 1989, and are still in
use today. A robot using the plasma arc process was used for a saddle
joint on the docking nodes of the International Space Station in the
mid-1990s. The robot used eight axes of motion to position both the
component and the weld torch in the ideal orientation for a successful
weld. Because the robot could be programmed for multiple paths, it was
also used for other welds on the Space Station structure, avoiding the
need for additional welding systems. Currently the Orion crew vehicle
uses one robot to perform friction stir welding for every weld joint on the
vehicle, including circumferential and linear geometries. Using a robot to
bring the welding process to multiple fixtures and weld stations reduces
the overall floor space that would have been required for conventional
welding. The universal programmability feature inherent in the robot is
ideal for low production rate of launch vehicles, providing a cost-effective
approach to design changes and different model configurations.
Many different welding processes have been used successfully in a
production system on operational launch vehicles, including gas metal
arc, resistance, GTAW, plasma arc, electron beam (EB), and friction
stir welding processes. Gas metal arc has been phasing out since the
1960s because it is prone to porosity and oxide inclusions when welding
aluminum. When used on the Saturn vehicles, the process required
significant rework compared to the welding processes used today [39].
Resistance welding processes have been used extensively on launch
vehicles. It worked well with the 301 and 321 stainless steels used in the
Atlas family, and is still used for the Centaur upper stage. This process
has not found similar success in aluminum structures, primarily due to
inconsistent quality. This is likely due to the high resistance of aluminum
oxide that quickly forms on the surface of aluminum, affecting the current
flowing between the electrodes. The overlap design of a resistance-welded
joint also leads to difficulties in applying non-destructive inspection
techniques. Other applications for this welding process include structural
covers for insulation systems.
GTAW is still commonly used on aluminum welds for launch vehicles.
77
7. Materials for Launch Vehicle Structures
These processes have higher energy density than the gas metal arc process,
resulting in a smaller heat affected zone and thus higher mechanical prop-
erties. GTA and plasma welding processes can be operated in alternating
polarity, which provides a cathodic cleaning action to aluminum during
welding. This reduces the presence of oxides, minimizing the chance for
oxide inclusions in the weld zone, and improves flow of the molten pool.
Oxides are further discouraged in the weld zone by abrading the joining
surfaces, through draw filing, wire brushing, or other mechanical means.
Since aluminum will develop a surface oxide quickly, there is usually a
time limit established between completion of surface cleaning and when
welding starts. If this limit is exceeded, additional cleaning is required
before welding.
Electron beam welding uses a high voltage to accelerate electrons,
which are focused using magnetic fields to melt metals for welding. This
welding process has the advantage of very high energy density, which
can penetrate and join thick parts with minimal distortion, and minimal
effect on the temper of adjacent material. It is used extensively on launch
vehicles to assemble engine components, hermetically seal batteries and
join thick materials used in heavily loaded structural parts. The process
takes place in a vacuum, so metals that oxidize at elevated temperatures,
such as titanium, can be welded with minimal risk of included oxides.
Since the process must take place in a vacuum chamber, there is a practical
limit to the size of components that can be EB welded. It is also limited
to metals that are non-magnetic, that wont deflect the beam during
welding.
Friction stir welding has been adopted by launch vehicle manufacturers
rapidly since its invention in the early 1990s. FSW is ideally suited for
aluminum, because it is relatively soft at elevated temperatures. This
allows commonly available tool steels to be used for the pin that applies
friction to the part. It also reduces the forces that must be reacted by the
weld tooling. While titanium and ferrous alloys have been welded with
the FSW process, aluminum alloys are the most common application.
The first application of this process in a production environment was in
Europe, fabricating aluminum structures for shipbuilding in the mid-1990s,
applied to a 6000-series alloy.
The first launch vehicle application was by Boeing on a Delta II
variant that first flew in 2001, which applied the process to the 2024 alloy
78
7.9. Manufacturing Considerations
Weld Distortion
A common problem in all welding processes is distortion. A distorted
component is more difficult to join to adjacent structure, and has higher
residual stress, both of which reduce structural efficiency.
Distortion resulting from the weld process comes primarily from shrink-
age in the weld zone, but can also result from the interaction of residual
stresses in each component, and how they change after welding heats the
parts. Because high-strength materials are often used in launch vehicles,
distortion is exacerbated since localized shrinkage in the weld area is
not distributed across a larger area by yielding. There are a variety of
mitigation techniques for weld distortion and fit-up issues. Well-designed
fixtures position the parts precisely, and pneumatic actuators restrain
the parts during application of heat. (Hydraulic actuation is rarely used
for welding fixtures to avoid contamination by leaking fluid.) Alignment
is measured before welding, and extra pressure is applied, or trimming
operations are used, to bring the fit-up within specifications. Tack welds
can be used to restrain the parts and maintain alignment as heat is
applied. Spacing, depth of penetration and the sequence of application
are all important parameters in tack welding.
Weld processes with low energy density and a less concentrated heat
source, such as gas metal arc, are usually more prone to distortion. Areas
79
7. Materials for Launch Vehicle Structures
with thinner material, or areas that require more heat passes, exhibit
more distortion. Weld repair areas are more prone to excessive distortion,
because the part is subjected to multiple weld passes and solidification
shrinkage in repair areas. The additional heat reduces the strength of the
base metal by changing any previous tempering processes. Multiple welds
in the same area will also act on any residual stresses in the components
being joined, producing additional distortion and residual stress.
High-energy-density weld processes such as EB and laser welding
result in less distortion. Resistance welding, plasma arc, and GTAW fit
between these two extremes. This is primarily due to a smaller molten
pool along the weld seam, which reduces metal solidification shrinkage.
FSW produces less shrinkage because it does not melt the material.
After welding is completed, procedures typically require measurement
of the joint geometry to verify that reinforcement, peaking, and offset (or
mismatch) are within specification. If corrective measures are warranted,
planishing can be used to compress the weld reinforcement and correct
geometry problems. In rare cases, additional welding passes can be used
to shrink certain areas to bring the geometry into compliance. This
approach is less often used because of the risk of distortion.
80
7.10. Summary, Trends and Outlook
81
7. Materials for Launch Vehicle Structures
82
7.10. Summary, Trends and Outlook
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