CHNG2803-9203-part 1-2 PDF
CHNG2803-9203-part 1-2 PDF
CHNG2803-9203-part 1-2 PDF
Presented by
Professor Yuan Chen
School of Chemical and Biomolecular Engineering
– Wanyu (Emerald) Li
wali2928@uni.sydney.edu.au
– Edward Qiu
eqiu7913@uni.sydney.edu.au
– Scott Nelson
snel5915@uni.sydney.edu.au
Reaction Engineering
q (J/s or W) q
Heat transfer rate: q =
''
dT T2 − T1 dT T1 − T2
= =
dx L dx L
T2 − T1 T1 − T2
q = −k
''
x
q = −k
''
x
Pay attention to the direction. L L
Two mechanisms:
Superposition of energy
transport by the random
motion and bulk motion.
Forced or Natural
Depends whether flow is
caused by external means
Boiling or Condensation
Phase changes, liquid to
vapor or vapor to liquid
q = h(T − Ts )
''
(
q = h Ts -T¥
''
)
From fluid to solid surface From solid surface to fluid
The University of Sydney Page 25
Thermal radiation
Physicist
Nuclear Engineer Electrical Engineer
Stefan-Boltzmann constant
5.67×10-8 W/m2K4
Emissivity (0≤ε≤1 ) Describe the
radiative ability of a surface
Energy been absorbed by the surface
Gabs = G = T 4
sur
Surrounding Temperature (K)
Irradiation
(energy released from surrounding)
Absorptivity (0≤ ≤1 )
Describe the absorptive ability of a surface
The University of Sydney Page 29
Radiation (simplified version)
Irradiation
Radiation
q" (W / m ) = E − Gabs = (T − T )
2
s
4 4
sur
Fourier’s law
dT
q" = -k
dx
All require Temperature distribution
T (x, y, z, t)
q" = h (Ts -T¥ ) How to find an unknown T?
E(q ) = es T"
1 1
4
E tot
= KE ( mV ) + PE (mgz) + U
1 2
2
Thermal energy
Mechanical energy
Most often in heat transfer, changes are small
The University of Sydney Page 36
Thermal energy in heat transfer
E tot = KE ( 1 mV 2 ) + PE (mgz) + U
2
Sensible component mc p T
Latent component
Chemical component mh fg
Nuclear component
For example: water has the specific heat (cp) of 4.217 kJ/kgK at 0 oC
Heat of vaporization (hfg) 2257 kJ/kg at 100 oC
q = m c p (Tout − Tin )
dEin dEout
− =0
dt dt
q "
cond −q "
conv −q
"
rad =0
× ×
E in - E out = 0
q"cond - q"conv - q"rad = 0
Ti - Ts
k = h(Ts - T¥ ) + es (Ts4 - Tsur
4
)
L
Ts = 307.2K (in air), 34oC; Ts = 300.7K(in water), 27.5oC
q = −kT
''
Plate wall
Cylinder
k Sphere
Heat equation With thermal energy generation
Fin (extended surface)
2-D steady state conduction
Transient conduction
dT
q x = −k
''
dx
q '' = −kT
ez ey
T T T
T = ex + ey + ez
ex x y z
T 1 T T
e T = er + e + ez
r r z
e T
er 1 T 1 T
T = er + e + e
r r r sin
''
kx −
qx
kx = k y = kz k
T x
k
Thermal diffusivity (m2/s)
= Specific heat (J/kg∙K)
c p
Density (kg/m3)
– Appendix of textbook
– Handbooks at library
– http://webbook.nist.gov/chemistry/fluid/
– http://properties.nist.gov/fluidsci/semiprop/gases/
http://www.youtube.com/watch?v=vqDbMEdLiCs&list=
EC16649CCE7EFA8B2F&index=4&feature=plcp
q z q y
q z + dz = qz + dz q y + dy = q y + dy
z y
q x
q x + dx = q x + dx
x
T
q x = −k (dydz)
x T
Est = c p dxdydz
t
T
q y = −k (dxdz) T
y q z = −k (dxdy)
z
E in = q x + q y + q z E out = q x + dx + q y + dy + q z + dz
T qx
q x = −k (dydz) qx + dx = qx + dx
x x
qx qx
qx − qx + dx = qx − ( qx + dx) = − dx
x x
T
( −k ( dydz ))
x T
=− dx = k dxdydz
x x x
E in − E out + E g = E st
T
qx + q y + qz − qx + dx − q y + dy − qz + dz + q dxdydz = c p dxdydz
t
Substitute: T T T T
k + k + k + q = c p
Simplify: x x y y z z t
2T 2T 2T q 1 T k
If k is a constant: + 2 + 2 + = Here: =
x 2
y z k t c p
T T T T
Steady state =0 k + k + k + q = 0
t x x y y z z
T 1 T T
T = er + e + ez
r r z
T k T T
qr = − k
"
q = −
"
qz = − k
"
r r z
volume : dr rd dz
1 T 1 T T T
kr + k + k +
q = c
r r r r 2 z z t
p
T 1 T 1 T
T = er + e + e
r r r sin
T k T k T
qr" = −k q" = − q" = −
r r r sin
volume : dr r sin d rd
1 2 T 1 T 1 T T
kr + 2 2 k + 2 k sin + q = c p
r r
2
r r sin r sin t
T (0, t ) = Ts
Constant surface heat flux
(2) Finite heat flux
T
−k = qs"
x x =0
T
−k = h[T − T (0, t )]
x x =0
Ts , 2 − Ts ,1
qx = −kA
L
Ts ,1 − Ts , 2 L
Rt ,cond =
qx kA
Should always be positive
Ts − T 1
Rt ,conv =
q hA qt ,conv = hA(Ts − T )
Ts − Tsur 1
Rt ,rad =
qrad hr A
T ,1 − T , 4
Rt = q
x
Unit: K/W
The University of Sydney Page 66
Example: thermal resistance for composite wall
x L2 5cm
For concrete: R2 = =
k2 A 1W / m KA
L1 0.5cm
For aluminum: R1 = =
k1 A 200W / m KA
T1 − T4
Heat flux: q " = q / A = = 9595.2 W/m2
( R1 + R2 ) A
T ,1 − T , 4
Rt = q Unit: K/W
x
T¥,1 - T¥,4
qx =
"
= UDT
å Rt A
1
U= Unit: W / K m 2
Rt A
q x = UADT
qx " should be a constant, why?
Consider: if heat flux is not 1
U=
constant, can we still apply the 1 / h1 + LA / k A + LB / k B + LC / kC + 1 / h4
concept of heat resistance?
The University of Sydney Page 68
Contact resistance
1 T 1 T T T
kr + 2 k + k + q = c p
r r r r z z t
1 T
kr =0
r r r
T
kr =C
r
T (r ) = C1 ln r + C2
T (r1 ) = Ts ,1 & T (r2 ) = Ts , 2
T
Heat transfer rate: qr = q A = −k
"
( 2rL)
r
r
Ts ,1 − Ts , 2 ln(r2 / r1 )
Thermal resistance: Rt ,cond = =
qr 2Lk
The University of Sydney Page 72
Critical insulation radius
dRtotal
=0
dr
1 1
− =0
2kr 2r h 2
k
rcritical
h
dT
q x = q x A = −kA
"
dx
x dx T
qx = − k (T )dT
x0 A( x) T0
A = 4r 2
qr r2 dr Ts , 2
4 r1 r 2
= − k (T )dT
Ts ,1
Steady-state, no heat
generation, 1-D
1 1 1 4k (Ts ,1 − Ts , 2 )
Rt ,cond = − qr =
4k r1 r2 (1 / r1 ) − (1 / r2 )
The University of Sydney Page 78
1D heat condition solutions
Target: find q
From Fourier's law: q = −kT
''
E in − E out + E g = E st
E in − E out = 0
Steady-state E in − E out + E g = 0
2T 2T 2T q 1 T
+ 2 + 2 + =
x 2
y z k t
d 2T q
2
+ =0
dx k
q 2
T =− x + C1 x + C2
2k
T (− L) = Ts ,1 & T ( L) = Ts , 2
Ts ,2 − Ts ,1 q 2 Ts ,1 + Ts ,2
C1 = , C2 = L +
2L 2k 2
The University of Sydney Page 82
Plane wall with energy generation
q 2 Ts , 2 − Ts ,1 q 2 Ts ,1 + Ts , 2
T =− x + x+ L +
2k 2L 2k 2
Ts ,1 − Ts ,2
Rt ,cond q is a variable.
qx
Fourier's law still can be applied.
T (− L) = Ts ,1 = T ( L) = Ts , 2 Ts
qL2 x 2
T ( x) = 1 − 2 + Ts
2k L
qL2
Tmax = T (0) T0 = + Ts
2k
dT
−k = h(Ts − T )
Why this equation dx x= L
does not include
qL
energy generation Ts = T +
term? h
The University of Sydney Page 84
Adiabatic surface (perfectly insulated surface)
– Apply Fourier's law, we can find a surface (usually in the
middle of a control volume) where the temperature gradient is
zero. No energy is transferred crossing this surface. We can
consider this surface is perfectly insulated.
– Can be applied to simplify calculation, especially in numerical
simulation
q L2 x2
T ( x) = 1 − 2 + Ts
2k L
dT dT
=0 q" = −k =0
dx x =0 dx
dT ( x ) − q x q
=
dx k
-L
L x
q”
-L
q" = q x L x
q = q xA
q L = h (Ts − T )
Can you draw the distribution of T, q and
A: cross section area q” for conditions without energy
generation?
The University of Sydney Page 86
Radial system with energy generation
Steady-state, constant k and 1-D
1 T q
r + = 0
r r r k
q 2
T (r ) = − r + C1 ln r + C2
4k
dT
= 0 & T (r0 ) = Ts
dr r =0
qr02 r 2
T (r ) = 1 − 2 + Ts
4k r0
Ts
r
qr0 0
Ts = T +
2h q
q = q r 2 L, q" = q r / 2
r
q (r02 L) = h(2r0 L)(Ts − T ) 0 r0
Apples 80 mm in diameter,
ventilated with air at 5oC and a
velocity of 0.5m/s. The
corresponding heat transfer
coefficient 7.5W/m2·K. Within each
apple thermal energy is uniformly
generated at 4000J/kg·day .
Density,840kg/m3 and thermal
conductivity 0.5W/m·K.
Determine apple center and surface
temperature.
The University of Sydney Page 89
Example: fruit handling temperature
– Temperature distribution in sphere
1 2 T q
r + = 0
r r r k
2
stegosaurus
The University of Sydney Page 92
Example: air conditioners
dqconv = hdAs (T − T )
qx = qx + dx + dqconv
dqx
qx + dx = qx + dx
dx
dT d dT
= −kAc − k ( Ac )dx (ab)’=a’b+ab’
dx dx dx
dT dAc dT d 2T
= −kAc − k( + Ac 2 )dx
dx dx dx dx
dAc dT d 2T
qx = qx + dx + dqconv k( + Ac 2 )dx − hdAs (T − T ) = 0
dx dx dx
d 2T 1 dAc dT 1 h dAs
2
+ − (T − T ) = 0
dx Ac dx dx Ac k dx
dAc
Ac = wt =0
dx d 2T ( x) hP
2
− (T ( x) − T ) = 0
dAs dx kAc
As = Px =P
dx
d 2T ( x) hP
2
− (T ( x) − T ) = 0 ( x) T ( x) − T
dx kAc
d 2 hP
2
− m 2
=0 m2
dx kAc
( x ) = C1emx + C2e− mx
We need two boundary conditions:
(1) at x=0, base temperature Tb
The formula is the
same for Pin fin. (0) = Tb − T b
The University of Sydney Page 98
Boundary conditions of fin
(2) the second condition for the fin tip may have four different
situations:
Case 1: convection: − kAc dT = hAc [T ( L) − T ]
dx x=L
d
−k = h ( L)
dx x=L
d
Case 2: Adiabatic =0
dx x =L
e x + e− x
cosh( x ) = , cosh( − x ) = cosh( x )
2
e x − e− x
sinh( x ) = , sinh( − x ) = − sinh( x )
2
e x − e− x
tanh( x ) = x −x
, tanh(− x ) = − tanh( x )
e +e
Table of hyperbolic functions is in Appendix B.1.
T T
d The behavior of 1-D fin
Tb 0 with an insulated tip
dx x =L
hP
q f = M tanh mL, M = hPkAc b , m 2 =
kAc
qf M tanh mL
= = tanh mL Dimensionless heat
M M
TL ( tip temperature), x = L flow into the fin
TL − T L cosh m( L − L)
=
Tb − T b cosh mL
L 1 Dimensionless
= temperature at the tip
b cosh mL
The University of Sydney Page 103
Variation of heat transfer rate and tip temperature
The temperature
excess at the tip is less
than 1.4% beyond
L=5/m
The University of Sydney Page 104
Temperature distribution in fin vs. mL
T − T cosh m( L − x )
=
Tb − T b cosh mL
b
x
cosh mL(1 − )
= L
cosh mL
x hP
L m2 =
kAc
hP L / kAc
m2 = , ( mL) 2 =
kAc 1 / h( PL )
internal resistance in x - direction
( mL) 2 =
gross external resistance
1
→0
cosh mL
When it is big, we may neglect tip convection, because tip
temperature will be very close to the surrounding temperature.
mL>3, is sufficient for the infinite fin approximation.
When it is small, the temperature drop along the axis of the fin
becomes small. Not an efficient fin.
The University of Sydney Page 107
Fin effectiveness
1/ 2
kP
f =
hAc
Ac,b 1 Rt ,b
Rt ,b = f =
hAc ,b Rt , f
T gradient along fin
The maximum driving potential for convection
is the temperature difference at the base.
Tb>T(x); x(0,L)
qmax = hAf (Tb − T )
This is an ideal situation, but cannot be achieved in reality.
The University of Sydney Page 110
Fin efficiency
q f = h[T ( x) − T ]dAs
Af
qf qf
f = =
qmax
M tanh mL tanh mL
f = =
h( PL )(Tb − T ) mL
N number of fins in
qt qt
an array 0 = =
Each fin has a qmax hAt (Tb − T )
surface area of Afa
Perspiration:
In humans, sweating is primarily a
means of thermoregulation which
is achieved by the water-rich
secretion of the eccrine glands.
Maximum sweat rates of an adult
can be up to 2-4 liters per hour
or 10-14 liters per day (10-15
g/min•m²).
T T
2 2
+ 2 =0
x 2
y
2T = 0
Depending on your mathematical background and the specific
problem (boundary conditions), the analytical solution can be
anything fro straightforward calculation to a considerable
challenge.
(0, y ) = 0 ( x,0) = 0
( L, y ) = 0 ( x, W ) = 1
( x, y ) = X ( x ) • Y ( y )
(−1) n +1 + 1
2
nx sinh( ny / L)
( x, y ) = sin
n =1 n L sinh( nW / L)
[T ] = [ A]−1[C ]
Object:
1) determine the time dependence of the temperature
distribution within a sold during a transient process
2) determine heat transfer between the solid and its surroundings
The University of Sydney Page 127
Lumped capacitance method
Assume the temperature of the solid is spatially uniform at any
instance during the transient process, temperature gradients within
the solid are negligible
− E out = E st
dT
− hAs (T − T ) = Vc p
dt
T − T i Ti − T
d Vc p d t
− hAs = Vc p
dt hAs i
= − dt
0
Vc p i
ln = t
hAs
T − T hA
= = exp − s
t
i Ti − T Vc p
Vc p
t =
hAs
t t t
Q = qdt = hAs dt = Vc p i 1 − exp −
0 0
t
The University of Sydney Page 129
Validity of lumped capacitance method
kA
(Ts ,1 − Ts , 2 ) = hA(Ts , 2 − T )
L
Ts ,1 − Ts , 2 ( L / kA) Rcond hL
= = = Bi
Ts , 2 − T (1 / hA) Rconv k
characteristic length
hLc V volume
Bi = 0.1 Lc
k As surface area
Use the above formula if you can, or alternatively
consider the following:
Plane wall: half-thickness
Long cylinder: r/2 or r Note: if the method to calculate Lc
Sphere: r/3 or r have been specified, you may just
follow the specific instruction.
The University of Sydney Page 132
Fourier number
T − T hA V
= = exp − s
t Lc =
i Ti − T
Vc p As
hAs t ht hLc k t hLc t
= = = = Bi • Fo
Vc p c p Lc k c p Lc
2
k Lc2
t
Fo 2 dimensionless time
Lc
= exp( − Bi • Fo )
i
The University of Sydney Page 133
More about Fourier number
Heat conduction through a solid is concurrent with thermal
energy storage by the solid
T
Characteristic length L Temperature gradient L
Cross-sectional area A ~ L2 Volume V ~ L3
2 T T
Energy storage Est ~ L c p
3
Heat transfer by conduction q ~ kL
L t
For a sphere: As = D 2
V = D 3 / 6
1 D 3 6h t
Time constant of 1 s: t = c D = = 7.06 10 −4
m
hD 2
6 c
(D 3 / 6)c Ti − T
t= ln = 5.2s
h(D )
2
T − T
The University of Sydney Page 136
General lumped capacitance analysis
dT
q As ,h + E g − (qconv + qrad ) As ( c ,r ) = Vc p
"
s
" "
dt
dT
q As ,h + E g − [(h(T − T ) + (T − Tsur )] As ( c ,r ) = Vc p
"
s
4 4
dt
heat flux transfer region convection radiation
The University of Sydney Page 137
Two simplified cases
dT
q As ,h + E g − [(h(T − T ) + (T − Tsur )] As ( c ,r ) = Vc p
"
s
4 4
dt
– Nonlinear, first-order, nonhomogeneous, ordinary differential
equation that can not be integrated to obtain an exact solution.
dT
− As ,r (T − T ) = Vc p
4 4
sur
dt
As ,r t T dT
Vc p 0
dt = 4
Ti T − T 4
sur
The University of Sydney Page 138
Simplified case 1
As ,r t dT
T Vc 1 1
Vc p 0 dt =Ti T 4 t=
3As ,r
3 − 3
T Ti
d (T − T ) hAs ,c qs" As ,h + E g
+ (T − T ) − =0
dt Vc Vc
hAs ,c qs" As ,h + E g
a= ,b =
Vc Vc
T − T b/a
= exp( −at ) + [1 − exp( −at )]
Ti − T Ti − T
dT
As (T 4
sur − T ) = Vc p
4
dt
The University of Sydney Page 141
Example: heating of coal pellets
Length required:
If Bi<0.1 If Bi>0.1
Analytical solutions
E in − E out + E g = E st can be obtained for
a few simple cases.
2T 2T 2T q 1 T
If Bi>0.1 + 2 + 2 + =
x 2
y z k t
1 T 1 T T T
kr + 2 k + k + q = c p
r r r r z z t
1 2 T 1 T 1 T T
kr + 2 2 k + 2 k sin + q = c p
r r
2
r r sin r sin t
2T 1 T
=
x 2
t
Need an initial condition and two
boundary conditions:
T
T ( x,0) = Ti =0
x x =0
T
−k = h[T ( L, t ) − T ]
x x=L
Solution : T ( x, t , Ti , T , L, k , , h )
difference L
t * = f ( x* , Fo, Bi)
t
*
2
Fo
L
The University of Sydney Page 146
Non-dimensionalizing equation
2T 1 T 2 * *
= =
x 2
t x *2 Fo
T ( x,0) = Ti * ( x* ,0) = 1
T *
=0 =0
x x =0 x* x* =0
T *
−k = h[T ( L, t ) − T ] = − Bi * (1, t * )
x x=L x* x* =1
* = f ( x* , Fo, Bi)
= Cn exp(− n2 Fo ) cos( n x* )
*
n =1
4 sin n
Cn =
2 n + sin( 2 n )
n tan n = Bi
Appendix B.3
* = C1 exp( − 12 Fo ) cos( 1 x* )
4 sin 1
C1 =
2 1 + sin( 2 1 )
when x* = 0, 0 = C1 exp( − 12 Fo )
*
* = 0* cos( 1 x* )
T0 − T
where, 0 =
*
Ti − T
See Table 5.1 in the textbook for numerical solutions
The University of Sydney Page 150
Total energy transferred
Q − [T ( x, t ) − Ti ] dV 1
= = (1 − * )dV
Qo Ti − T V V
Q sin 1 *
= 1− 0
Qo 1
The University of Sydney Page 151
Transient temperature distribution in plate
Heisler charts, 1947 * = f ( x* , Fo, Bi)
x/L=0
center
x/L=1
boundary
– Lc=L
hLc t
Bi = = 0.313, Fo = 2 = 5.64
k Lc
– Bi=0.313, and Fo>0.2. C1=1.047 and ζ1=0.531
T0 − T
0* = = C1 exp( − 12 Fo ) = 0.214
Ti − T
T (0,8 min) = T + 0* (Ti − T ) = 42.9o C
– x=L q "x ( L,480s ) = qL" = h[T ( L,480s ) − T ]
with x* = 1, * = 0* cos( 1 )
T ( L, t ) = T + (Ti − T ) 0* cos( 1 )
T ( L,8 min) = 45.2o C , so qL" = −7400W / m 2
Q sin 1 * '
= 1− 0 , Q = −2.73 107 J / m
The University of Sydney
Qo 1 Page 154
Solutions for infinite cylinder
t
= Cn exp( − Fo ) J 0 ( n r ), Fo =
* 2
n
*
n =1 ro2
J 1 ( n )
2
Cn =
n J 02 ( n ) + J 12 ( n ) Simplified form:
J 1 ( n ) hr0
n = Bi, Bi = * = C1 exp( − 12 Fo ) J 0 ( 1r* )
J 0 ( n ) k
C1 and 1 are listed in Table 5.1
for a range of Biot numbers.
J1, J0 are Bessel functions of the first kind and their values
are tabulated in Appendix B.4.
The University of Sydney Page 155
Solutions for sphere
1 t
= Cn exp( − Fo ) * sin( n r ), Fo = 2
* 2 *
n =1 nr n
ro
4[sin( n ) − n cos( n )]
Cn =
2 n − sin( 2 n )
Simplified form:
hr0
1 − n cot n = Bi, Bi = 1
= C1 exp( − Fo ) * sin( 1r * )
* 2
k 1r
1
J1, J0 are Bessel functions of the first kind and their values
are tabulated in Appendix B.4.
The University of Sydney Page 156
Semi-infinite solid
– The semi-infinite solid: extends to infinity in all but one
direction with a single identifiable surface. If a sudden
changes of conditions is imposed at this surface, transient, 1-D
conduction will occur within the solid.
T ( x → , t ) = Ti
2 w
−v 2
T ( x → , t ) = Ti erf ( w) = e dv erfc( w) = 1 − erf ( w)
0
T ( x, t ) − Ti x hx h 2t x h t
= erfc − exp + 2 erfc +
T − Ti 2 t k k 2 t k
The University of Sydney Page 159
Solutions for semi-infinite solid
k (Ts − Ti )
q (t ) =
"
t
s
– http://skepdic.com/firewalk.html
Steady Unsteady