FUELPOWER SOOT REMOVER

Wilhelmsen Ships Service AS*

Catalogue number: 571240 Issue Date: 21/01/2019
Version No: 8.11 Print Date: 15/04/2019
Safety Data Sheet (Conforms to Regulation (EU) No 2015/830) L.REACH.RUS.EN

SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING

1.1. Product Identifier

Product name FUELPOWER SOOT REMOVER

Synonyms Product Part Number: 571240 (25 kg). Pr.No: 18008

Proper shipping name TOXIC SOLID, INORGANIC, N.O.S. (copper hydroxidecarbonate, mixture)

Other means of
571240, 571240
identification

1.2. Relevant identified uses of the substance or mixture and uses advised against

Procedural Category PROC16 Using material as fuel sources, limited exposure to unburned product to be expected

Product Category
PC13 Fuels
Chemical

Sectors of Use SU3 Industrial uses: Uses of substances as such or in preparations* at industrial sites

Relevant identified uses Soot Deposit Remover

Uses advised against Not Applicable

1.3. Details of the supplier of the safety data sheet

Registered company Outback (M)SDS portal: http://jr.chemwatch.net
Wilhelmsen Ships Service AS*
name /outb/account/autologin?login=wilhelmsen
--------Use our Outback portal to obtain our (M)SDSs in
other languages and/or format.--------- For questions
Address Willem Barentszstraat 50 Rotterdam Netherlands
relating to our SDSs please use Email:
[email protected] --------- Norway

Telephone +31 10 4877 777 Not Available

Fax +31 10 4877888 Not Available

Website http://www.wilhelmsen.com Not Available

Email [email protected] Not Available

1.4. Emergency telephone number

Association /
Dutch nat. poison centre American Chemistry Council 24hrs - Chemtrec
Organisation
Emergency telephone
+ 31 30 274 88 88 +1 703 527 3887
numbers
Other emergency
Not Available (800) 424 9300
telephone numbers

SECTION 2 HAZARDS IDENTIFICATION

2.1.
Classification of the substance or mixture
 H302 - Acute Toxicity (Oral) Category 4, H332 - Acute Toxicity (Inhalation) Category 4, H319 - Eye Irritation Category 2,
Classification
H411 - Chronic Aquatic Hazard Category 2

2.2. Label elements

Hazard pictogram(s)

SIGNAL WORD WARNING

Hazard statement(s)
H302 Harmful if swallowed.

H332 Harmful if inhaled.

H319 Causes serious eye irritation.

H411 Toxic to aquatic life with long lasting effects.

Supplementary statement(s)
Not Applicable

Precautionary statement(s) General

P101 If medical advice is needed, have product container or label at hand.

P102 Keep out of reach of children.

P103 Read label before use.

Precautionary statement(s) Prevention

P271 Use only outdoors or in a well-ventilated area.

P261 Avoid breathing dust/fumes.

P270 Do not eat, drink or smoke when using this product.

P273 Avoid release to the environment.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

Precautionary statement(s) Response

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
P305+P351+P338
Continue rinsing.

P337+P313 If eye irritation persists: Get medical advice/attention.

P391 Collect spillage.

P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor/physician/first aider/if you feel unwell.

P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P330 Rinse mouth.

Precautionary statement(s) Storage

Not Applicable

Precautionary statement(s) Disposal

P501 Dispose of contents/container in accordance with local regulations.

2.3. Other hazards

REACh - Art.57-59: The mixture does not contain Substances of Very High Concern (SVHC) at the SDS print date.

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

3.1.Substances
See 'Composition on ingredients' in Section 3.2

3.2.Mixtures
1.CAS No
2.EC No
%[weight] Name Classification
3.Index No
4.REACH No
 1.12069-69-1*
2.235-113-6
copper Acute Toxicity (Oral) Category 4, Acute Toxicity (Inhalation) Category 4, Eye Irritation
3.029-020-00-8 10-30
carbonate basic Category 2, Chronic Aquatic Hazard Category 1; H302, H332, H319, H410
4.01-2119513711-50-
XXXX|01-2119949567-21-XXXX

SECTION 4 FIRST AID MEASURES

4.1. Description of first aid measures

If this product comes in contact with the eyes:
Wash out immediately with fresh running water.
Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by
Eye Contact
occasionally lifting the upper and lower lids.
Seek medical attention without delay; if pain persists or recurs seek medical attention.
Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

If skin or hair contact occurs:

Skin Contact Flush skin and hair with running water (and soap if available).
Seek medical attention in event of irritation.
If fumes or combustion products are inhaled remove from contaminated area.
Lay patient down. Keep warm and rested.
Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid
Inhalation procedures.
Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or
pocket mask as trained. Perform CPR if necessary.
Transport to hospital, or doctor.
Immediately give a glass of water.
Ingestion
First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.

4.2 Most important symptoms and effects, both acute and delayed
See Section 11

4.3. Indication of any immediate medical attention and special treatment needed
As in all cases of suspected poisoning, follow the ABCDEs of emergency medicine (airway, breathing, circulation, disability, exposure), then the ABCDEs
of toxicology (antidotes, basics, change absorption, change distribution, change elimination).
For poisons (where specific treatment regime is absent):
--------------------------------------------------------------
BASIC TREATMENT
--------------------------------------------------------------
Establish a patent airway with suction where necessary.
Watch for signs of respiratory insufficiency and assist ventilation as necessary.
Administer oxygen by non-rebreather mask at 10 to 15 L/min.
Monitor and treat, where necessary, for pulmonary oedema.
Monitor and treat, where necessary, for shock.
Anticipate seizures.
DO NOT use emetics. Where ingestion is suspected rinse mouth and give up to 200 ml water (5 ml/kg recommended) for dilution where patient is able to
swallow, has a strong gag reflex and does not drool.
--------------------------------------------------------------
ADVANCED TREATMENT
--------------------------------------------------------------
Consider orotracheal or nasotracheal intubation for airway control in unconscious patient or where respiratory arrest has occurred.
Positive-pressure ventilation using a bag-valve mask might be of use.
Monitor and treat, where necessary, for arrhythmias.
Start an IV D5W TKO. If signs of hypovolaemia are present use lactated Ringers solution. Fluid overload might create complications.
Drug therapy should be considered for pulmonary oedema.
Hypotension with signs of hypovolaemia requires the cautious administration of fluids. Fluid overload might create complications.
Treat seizures with diazepam.
Proparacaine hydrochloride should be used to assist eye irrigation.
BRONSTEIN, A.C. and CURRANCE, P.L.
EMERGENCY CARE FOR HAZARDOUS MATERIALS EXPOSURE: 2nd Ed. 1994

SECTION 5 FIREFIGHTING MEASURES

5.1. Extinguishing media

Water spray or fog.
Foam.
Dry chemical powder.
BCF (where regulations permit).
Carbon dioxide.

5.2. Special hazards arising from the substrate or mixture

Fire Incompatibility None known.
5.3. Advice for firefighters
Alert Fire Brigade and tell them location and nature of hazard.
Wear full body protective clothing with breathing apparatus.
Prevent, by any means available, spillage from entering drains or water course.
Fire Fighting Use fire fighting procedures suitable for surrounding area.
Do not approach containers suspected to be hot.
Cool fire exposed containers with water spray from a protected location.
If safe to do so, remove containers from path of fire.

Non combustible.
Fire/Explosion Hazard Not considered a significant fire risk, however containers may burn.
May emit poisonous fumes.

SECTION 6 ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

See section 8

6.2. Environmental precautions

See section 12

6.3. Methods and material for containment and cleaning up

Remove all ignition sources.
Clean up all spills immediately.
Avoid contact with skin and eyes.
Minor Spills
Control personal contact with the substance, by using protective equipment.
Use dry clean up procedures and avoid generating dust.
Place in a suitable, labelled container for waste disposal.
Clear area of personnel and move upwind.
Alert Fire Brigade and tell them location and nature of hazard.
Wear full body protective clothing with breathing apparatus.
Major Spills Prevent, by any means available, spillage from entering drains or water course.
Stop leak if safe to do so.
Contain spill with sand, earth or vermiculite.
Collect recoverable product into labelled containers for recycling.

6.4. Reference to other sections

Personal Protective Equipment advice is contained in Section 8 of the SDS.

SECTION 7 HANDLING AND STORAGE

7.1. Precautions for safe handling

Avoid all personal contact, including inhalation.
Wear protective clothing when risk of exposure occurs.
Use in a well-ventilated area.
Safe handling Prevent concentration in hollows and sumps.
DO NOT enter confined spaces until atmosphere has been checked.
DO NOT allow material to contact humans, exposed food or food utensils.
Avoid contact with incompatible materials.

Fire and explosion

See section 5
protection
Store in original containers.
Keep containers securely sealed.
Store in a cool, dry, well-ventilated area.
Other information
Store away from incompatible materials and foodstuff containers.
Protect containers against physical damage and check regularly for leaks.
Observe manufacturer's storage and handling recommendations contained within this SDS.

7.2. Conditions for safe storage, including any incompatibilities

Lined metal can, lined metal pail/ can.
Plastic pail.
Polyliner drum.
Packing as recommended by manufacturer.
Check all containers are clearly labelled and free from leaks.
For low viscosity materials
Suitable container Drums and jerricans must be of the non-removable head type.
Where a can is to be used as an inner package, the can must have a screwed enclosure.
For materials with a viscosity of at least 2680 cSt. (23 deg. C) and solids (between 15 C deg. and 40 deg C.):
Removable head packaging;
Cans with friction closures and
low pressure tubes and cartridges
 may be used.
-
Where combination packages are used, and the inner packages are of glass, there must be sufficient inert cushioning
material in contact with inner and outer packages *.
-
In addition, where inner packagings are glass and contain liquids of packing group I and II there must be sufficient inert
absorbent to absorb any spillage *.
-
* unless the outer packaging is a close fitting moulded plastic box and the substances are not incompatible with the
plastic.
Storage incompatibility None known

+ X + O + + +

X — Must not be stored together

0 — May be stored together with specific preventions
+ — May be stored together

7.3. Specific end use(s)

See section 1.2

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION

8.1. Control parameters

DERIVED NO EFFECT LEVEL (DNEL)

Not Available

PREDICTED NO EFFECT LEVEL (PNEC)

Not Available

OCCUPATIONAL EXPOSURE LIMITS (OEL)

INGREDIENT DATA

Source Ingredient Material name TWA STEL Peak Notes

Russia Maximum Allowed
Concentrations (PDK) of
copper carbonate Not Not Not
Harmful Substances in the 1,4-Дигидроксибензола и меди аддукт 1 mg/m3
basic Available Available Available
Air of Workplace Zone
(Russian)
Russia Maximum Allowed
Concentrations (PDK) of
copper carbonate Абразивный порошок из -/10 Not Not Not
Harmful Substances in the
basic медеплавильного шлака mg/m3 Available Available Available
Air of Workplace Zone
(Russian)

EMERGENCY LIMITS

Ingredient Material name TEEL-1 TEEL-2 TEEL-3

copper carbonate basic Copper(II) carbonate hydroxide (2:1:2) 5.2 mg/m3 45 mg/m3 270 mg/m3

Ingredient Original IDLH Revised IDLH

copper carbonate basic Not Available Not Available

MATERIAL DATA
It is the goal of the ACGIH (and other Agencies) to recommend TLVs (or their equivalent) for all substances for which there is evidence of health effects
at airborne concentrations encountered in the workplace.
At this time no TLV has been established, even though this material may produce adverse health effects (as evidenced in animal experiments or clinical
experience). Airborne concentrations must be maintained as low as is practically possible and occupational exposure must be kept to a minimum.
NOTE: The ACGIH occupational exposure standard for Particles Not Otherwise Specified (P.N.O.S) does NOT apply.
Sensory irritants are chemicals that produce temporary and undesirable side-effects on the eyes, nose or throat. Historically occupational exposure
standards for these irritants have been based on observation of workers' responses to various airborne concentrations. Present day expectations require
that nearly every individual should be protected against even minor sensory irritation and exposure standards are established using uncertainty factors or
safety factors of 5 to 10 or more. On occasion animal no-observable-effect-levels (NOEL) are used to determine these limits where human results are
unavailable. An additional approach, typically used by the TLV committee (USA) in determining respiratory standards for this group of chemicals, has
been to assign ceiling values (TLV C) to rapidly acting irritants and to assign short-term exposure limits (TLV STELs) when the weight of evidence from
irritation, bioaccumulation and other endpoints combine to warrant such a limit. In contrast the MAK Commission (Germany) uses a five-category system
based on intensive odour, local irritation, and elimination half-life. However this system is being replaced to be consistent with the European Union (EU)
Scientific Committee for Occupational Exposure Limits (SCOEL); this is more closely allied to that of the USA.
8.2. Exposure controls
Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed
engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions
to provide this high level of protection.
The basic types of engineering controls are:
8.2.1. Appropriate Process controls which involve changing the way a job activity or process is done to reduce the risk.
engineering controls Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and
ventilation that strategically "adds" and "removes" air in the work environment. Ventilation can remove or dilute an air
contaminant if designed properly. The design of a ventilation system must match the particular process and chemical or
contaminant in use.
Employers may need to use multiple types of controls to prevent employee overexposure.

8.2.2. Personal
protection

Safety glasses with side shields.

Chemical goggles.
Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy
document, describing the wearing of lenses or restrictions on use, should be created for each workplace or task. This
Eye and face protection
should include a review of lens absorption and adsorption for the class of chemicals in use and an account of injury
experience. Medical and first-aid personnel should be trained in their removal and suitable equipment should be readily
available. In the event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon as
practicable.

Skin protection See Hand protection below

Wear chemical protective gloves, e.g. PVC.
Hands/feet protection
Wear safety footwear or safety gumboots, e.g. Rubber

Body protection See Other protection below

Overalls.
Eyewash unit.
Other protection
Barrier cream.
Skin cleansing cream.

Respiratory protection
Particulate. (AS/NZS 1716 & 1715, EN 143:2000 & 149:001, ANSI Z88 or national equivalent)

Required Minimum Protection Factor Half-Face Respirator Full-Face Respirator Powered Air Respirator
P1 - PAPR-P1
up to 10 x ES
Air-line* - -
up to 50 x ES Air-line** P2 PAPR-P2
up to 100 x ES - P3 -
Air-line* -
100+ x ES - Air-line** PAPR-P3

* - Negative pressure demand ** - Continuous flow

A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acid gas or hydrogen cyanide(HCN), B3 = Acid gas or hydrogen cyanide(HCN), E =
Sulfur dioxide(SO2), G = Agricultural chemicals, K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB = Methyl bromide, AX = Low boiling point
organic compounds(below 65 degC)

8.2.3. Environmental exposure controls

See section 12

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

Appearance Blue, green powder with no odour; soluble in water.

Relative density (Water =

Physical state Divided Solid|Crystalline 1.00
1)
Partition coefficient
Odour Not Available Not Available
n-octanol / water
Auto-ignition temperature
Odour threshold Not Available Not Available
(°C)
Decomposition
pH (as supplied) Not Available Not Available
temperature
Melting point / freezing
Not Available Viscosity (cSt) Not Available
point (°C)
 Initial boiling point and
Not Applicable Molecular weight (g/mol) Not Available
boiling range (°C)

Flash point (°C) Not Available Taste Not Available

Evaporation rate Not Available Explosive properties Not Available

Flammability Not Available Oxidising properties Not Available

Upper Explosive Limit Surface Tension (dyn/cm

Not Available Not Applicable
(%) or mN/m)

Lower Explosive Limit Volatile Component

Not Available Not Available
(%) (%vol)
Vapour pressure (kPa) Not Applicable Gas group Not Available

Solubility in water Miscible pH as a solution (1%) Not Available

Vapour density (Air = 1) Not Applicable VOC g/L Not Available

9.2. Other information

Not Available

SECTION 10 STABILITY AND REACTIVITY

10.1.Reactivity See section 7.2

Unstable in the presence of incompatible materials.
10.2. Chemical stability Product is considered stable.
Hazardous polymerisation will not occur.

10.3. Possibility of
See section 7.2
hazardous reactions
10.4. Conditions to avoid See section 7.2

10.5. Incompatible
See section 7.2
materials
10.6. Hazardous
See section 5.3
decomposition products

SECTION 11 TOXICOLOGICAL INFORMATION

11.1. Information on toxicological effects

Inhalation of dusts, generated by the material, during the course of normal handling, may be harmful.
The material is not thought to produce respiratory irritation (as classified by EC Directives using animal models).
Inhaled
Nevertheless inhalation of dusts, or fumes, especially for prolonged periods, may produce respiratory discomfort and
occasionally, distress.
The material is not thought to produce adverse health effects following ingestion (as classified by EC Directives using
Ingestion animal models). Nevertheless, adverse systemic effects have been produced following exposure of animals by at least
one other route and good hygiene practice requires that exposure be kept to a minimum.

Skin contact is not thought to produce harmful health effects (as classified under EC Directives using animal models).
Systemic harm, however, has been identified following exposure of animals by at least one other route and the material
may still produce health damage following entry through wounds, lesions or abrasions. Good hygiene practice requires that
Skin Contact exposure be kept to a minimum and that suitable gloves be used in an occupational setting.
Open cuts, abraded or irritated skin should not be exposed to this material
Entry into the blood-stream through, for example, cuts, abrasions, puncture wounds or lesions, may produce systemic
injury with harmful effects. Examine the skin prior to the use of the material and ensure that any external damage is
suitably protected.
Evidence exists, or practical experience predicts, that the material may cause eye irritation in a substantial number of
individuals and/or may produce significant ocular lesions which are present twenty-four hours or more after instillation into
Eye the eye(s) of experimental animals.
Repeated or prolonged eye contact may cause inflammation characterised by temporary redness (similar to windburn) of
the conjunctiva (conjunctivitis); temporary impairment of vision and/or other transient eye damage/ulceration may occur.
Long-term exposure to the product is not thought to produce chronic effects adverse to health (as classified by EC
Chronic
Directives using animal models); nevertheless exposure by all routes should be minimised as a matter of course.

FUELPOWER SOOT TOXICITY IRRITATION

REMOVER Not Available Not Available

TOXICITY IRRITATION
[2] Not Available
Oral (Pig) LDLo: 1000 mg/kg
copper carbonate basic Oral (Rabbit) LD50: 159 mg/kg [2]

Oral (rat) LD50: 1350 mg/kg[2]

 Oral (rat) LD50: 159 mg/kg[2]

Oral (rat, male) LD50: 1889 mg/kg* [2]

Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS.
Unless otherwise specified data extracted from RTECS - Register of Toxic Effect of chemical Substances

Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This may be due
to a non-allergenic condition known as reactive airways dysfunction syndrome (RADS) which can occur following exposure
to high levels of highly irritating compound. Key criteria for the diagnosis of RADS include the absence of preceding
respiratory disease, in a non-atopic individual, with abrupt onset of persistent asthma-like symptoms within minutes to
hours of a documented exposure to the irritant. A reversible airflow pattern, on spirometry, with the presence of moderate
to severe bronchial hyperreactivity on methacholine challenge testing and the lack of minimal lymphocytic inflammation,
without eosinophilia, have also been included in the criteria for diagnosis of RADS. RADS (or asthma) following an irritating
inhalation is an infrequent disorder with rates related to the concentration of and duration of exposure to the irritating
substance. Industrial bronchitis, on the other hand, is a disorder that occurs as result of exposure due to high
copper carbonate basic
concentrations of irritating substance (often particulate in nature) and is completely reversible after exposure ceases. The
disorder is characterised by dyspnea, cough and mucus production.
for copper and its compounds (typically copper chloride):
Acute toxicity: There are no reliable acute oral toxicity results available. In an acute dermal toxicity study (OECD TG
402), one group of 5 male rats and 5 groups of 5 female rats received doses of 1000, 1500 and 2000 mg/kg bw via
dermal application for 24 hours. The LD50 values of copper monochloride were 2,000 mg/kg bw or greater for male (no
deaths observed) and 1,224 mg/kg bw for female. Four females died at both 1500 and 2000 mg/kg bw, and one at 1,000
mg/kg bw. Symptom of the hardness of skin, an exudation of hardness site, the formation of scar and reddish changes
were observed on application sites in all treated animals. Skin inflammation and injury were also noted. In addition, a
reddish or black urine was observed in females at 2,000, 1,500 and 1,000 mg/kg bw.

Acute Toxicity Carcinogenicity

Skin Irritation/Corrosion Reproductivity

Serious Eye
STOT - Single Exposure
Damage/Irritation
Respiratory or Skin STOT - Repeated
sensitisation Exposure
Mutagenicity Aspiration Hazard

Legend: – Data either not available or does not fill the criteria for classification
– Data available to make classification

SECTION 12 ECOLOGICAL INFORMATION

12.1. Toxicity

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE

FUELPOWER SOOT
Not Not Not
REMOVER Not Available Not Available
Available Available Available

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE

LC50 96 Fish 0.001-0.4mg/L 2

copper carbonate basic EC50 48 Crustacea 0.001-0.213mg/L 2

EC50 72 Algae or other aquatic plants 0.0165mg/L 2
NOEC 768 Fish 0.0048mg/L 2

Legend: Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic
Toxicity 3. EPIWIN Suite V3.12 (QSAR) - Aquatic Toxicity Data (Estimated) 4. US EPA, Ecotox database - Aquatic Toxicity
Data 5. ECETOC Aquatic Hazard Assessment Data 6. NITE (Japan) - Bioconcentration Data 7. METI (Japan) -
Bioconcentration Data 8. Vendor Data

Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Do NOT allow product to come in contact with surface waters or to intertidal areas below the mean high water mark. Do not contaminate water when
cleaning equipment or disposing of equipment wash-waters.
Wastes resulting from use of the product must be disposed of on site or at approved waste sites.
DO NOT discharge into sewer or waterways.

12.2. Persistence and degradability

Ingredient Persistence: Water/Soil Persistence: Air
No Data available for all ingredients No Data available for all ingredients

12.3. Bioaccumulative potential

 Ingredient Bioaccumulation
No Data available for all ingredients

12.4. Mobility in soil

Ingredient Mobility
No Data available for all ingredients

12.5.Results of PBT and vPvB assessment

P B T
Relevant available data Not Applicable Not Applicable Not Applicable
PBT Criteria fulfilled? Not Applicable Not Applicable Not Applicable

12.6. Other adverse effects

No data available

SECTION 13 DISPOSAL CONSIDERATIONS

13.1. Waste treatment methods

Product / Packaging
disposal
Waste treatment options Not Available

Sewage disposal options Not Available

SECTION 14 TRANSPORT INFORMATION

Labels Required

Marine Pollutant

Land transport (ADR)

14.1. UN number 3288

14.2. UN proper
TOXIC SOLID, INORGANIC, N.O.S. (copper hydroxidecarbonate, mixture)
shipping name

14.3. Transport hazard Class 6.1

class(es) Subrisk Not Applicable

14.4. Packing group III

14.5. Environmental
Environmentally hazardous
hazard

Hazard identification (Kemler) 60

Classification code T5
14.6. Special precautions
Hazard Label 6.1
for user
Special provisions 274
Limited quantity 5 kg

Air transport (ICAO-IATA / DGR)

14.1. UN number 3288

14.2. UN proper
Toxic solid, inorganic, n.o.s. * (copper hydroxidecarbonate, mixture)
shipping name
 ICAO/IATA Class 6.1
14.3. Transport hazard
ICAO / IATA Subrisk Not Applicable
class(es)
ERG Code 6L

14.4. Packing group III

14.5. Environmental
Environmentally hazardous
hazard

Special provisions A3 A5

Cargo Only Packing Instructions 677

Cargo Only Maximum Qty / Pack 200 kg
14.6. Special precautions
Passenger and Cargo Packing Instructions 670
for user
Passenger and Cargo Maximum Qty / Pack 100 kg
Passenger and Cargo Limited Quantity Packing Instructions Y645
Passenger and Cargo Limited Maximum Qty / Pack 10 kg

Sea transport (IMDG-Code / GGVSee)

14.1. UN number 3288

14.2. UN proper
TOXIC SOLID, INORGANIC, N.O.S. (copper hydroxidecarbonate, mixture)
shipping name

14.3. Transport hazard IMDG Class 6.1

class(es) IMDG Subrisk Not Applicable

14.4. Packing group III

14.5. Environmental
Marine Pollutant
hazard

EMS Number F-A , S-A

14.6. Special precautions
Special provisions 223 274
for user
Limited Quantities 5 kg

Inland waterways transport (ADN)

14.1. UN number 3288

14.2. UN proper
TOXIC SOLID, INORGANIC, N.O.S. (copper hydroxidecarbonate, mixture)
shipping name
14.3. Transport hazard
6.1 Not Applicable
class(es)
14.4. Packing group III

14.5. Environmental
Environmentally hazardous
hazard

Classification code T5
Special provisions 274; 802
14.6. Special precautions
Limited quantity 5 kg
for user
Equipment required PP, EP
Fire cones number 0

14.7. Transport in bulk according to Annex II of MARPOL and the IBC code
Not Applicable

SECTION 15 REGULATORY INFORMATION

15.1. Safety, health and environmental regulations / legislation specific for the substance or mixture

COPPER CARBONATE BASIC(12069-69-1*) IS FOUND ON THE FOLLOWING REGULATORY LISTS

 Europe EC Inventory European Union (EU) Regulation (EC) No 1272/2008 on Classification,
Europe ECHA Registered Substances - Classification and Labelling - Labelling and Packaging of Substances and Mixtures - Annex VI
DSD-DPD European Union (EU) Regulation (EC) No 1272/2008 on Classification,
European Chemical Agency (ECHA) Classification & Labelling Inventory - Labelling and Packaging of Substances and Mixtures - Annex VI -
Chemwatch Harmonised classification Chemwatch Standard Format
European Customs Inventory of Chemical Substances ECICS (English) Russia Maximum Allowed Concentrations (PDK) of Harmful Substances in
European Union - European Inventory of Existing Commercial Chemical the Air of Workplace Zone (Russian)
Substances (EINECS) (English) Russia National Chemical Inventory (Russian)

This safety data sheet is in compliance with the following EU legislation and its adaptations - as far as applicable - : Directives 98/24/EC, - 92/85/EEC, -
94/33/EC, - 2008/98/EC, - 2010/75/EU; Commission Regulation (EU) 2015/830; Regulation (EC) No 1272/2008 as updated through ATPs.

15.2. Chemical safety assessment

No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.

ECHA SUMMARY
Ingredient CAS number Index No ECHA Dossier
copper carbonate basic 12069-69-1* 029-020-00-8 01-2119513711-50-XXXX|01-2119949567-21-XXXX

Harmonisation (C&L
Hazard Class and Category Code(s) Pictograms Signal Word Code(s) Hazard Statement Code(s)
Inventory)
1 Acute Tox. 4; Skin Irrit. 2; Eye Irrit. 2; STOT SE 3 GHS07; Wng H302; H315; H319; H335
Harmonisation Code 1 = The most prevalent classification. Harmonisation Code 2 = The most severe classification.

National Inventory Status

National Inventory Status
Australia - AICS Yes

Canada - DSL Yes

Canada - NDSL No (copper carbonate basic)
China - IECSC Yes
Europe - EINEC / ELINCS /
Yes
NLP
Japan - ENCS Yes
Korea - KECI Yes
New Zealand - NZIoC Yes
Philippines - PICCS Yes
USA - TSCA Yes
Taiwan - TCSI Yes
Mexico - INSQ No (copper carbonate basic)
Vietnam - NCI Yes

Russia - ARIPS Yes

Thailand - TECI Yes
Yes = All declared ingredients are on the inventory
Legend: No = Not determined or one or more ingredients are not on the inventory and are not exempt from listing(see specific
ingredients in brackets)

SECTION 16 OTHER INFORMATION

Revision Date 21/01/2019

Initial Date 16/07/2018

CONTACT POINT
- For quotations contact your local Customer Services - http://wssdirectory.wilhelmsen.com/#/customerservices - - Responsible for safety data sheet
Wilhelmsen Ships Service AS - Prepared by: Product HSE Manager, - Email: Email: [email protected] - Telephone: Tel.: +31 10
4877775

Full text Risk and Hazard codes

H315 Causes skin irritation.

H335 May cause respiratory irritation.

H410 Very toxic to aquatic life with long lasting effects.

Other information
 Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the
Chemwatch Classification committee using available literature references.

The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are
Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or
available engineering controls must be considered.

For detailed advice on Personal Protective Equipment, refer to the following EU CEN Standards:
EN 166 Personal eye-protection
EN 340 Protective clothing
EN 374 Protective gloves against chemicals and micro-organisms
EN 13832 Footwear protecting against chemicals
EN 133 Respiratory protective devices

Definitions and abbreviations

PC－TWA: Permissible Concentration-Time Weighted Average
PC－STEL: Permissible Concentration-Short Term Exposure Limit
IARC: International Agency for Research on Cancer
ACGIH: American Conference of Governmental Industrial Hygienists
STEL: Short Term Exposure Limit
TEEL: Temporary Emergency Exposure Limit。
IDLH: Immediately Dangerous to Life or Health Concentrations
OSF: Odour Safety Factor
NOAEL :No Observed Adverse Effect Level
LOAEL: Lowest Observed Adverse Effect Level
TLV: Threshold Limit Value
LOD: Limit Of Detection
OTV: Odour Threshold Value
BCF: BioConcentration Factors
BEI: Biological Exposure Index

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