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5.2 Comparison The Experimental Diffusivity and Literature Diffusivity Value of Cobalt (II) Chloride

The document compares the experimental diffusivity value of cobalt (II) chloride to literature values calculated using the Wilke-Chang and Stokes-Einstein equations. The experimental diffusivity was 0.877 m2/s. The Wilke-Chang equation calculated a value of 1.6178 × 10-3 m2/s, with a 99.99% error compared to the experimental value. The Stokes-Einstein equation calculated a value of 9.023 × 10-10 m2/s, also with a 99.99% error compared to the experimental value.

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45 views2 pages

5.2 Comparison The Experimental Diffusivity and Literature Diffusivity Value of Cobalt (II) Chloride

The document compares the experimental diffusivity value of cobalt (II) chloride to literature values calculated using the Wilke-Chang and Stokes-Einstein equations. The experimental diffusivity was 0.877 m2/s. The Wilke-Chang equation calculated a value of 1.6178 × 10-3 m2/s, with a 99.99% error compared to the experimental value. The Stokes-Einstein equation calculated a value of 9.023 × 10-10 m2/s, also with a 99.99% error compared to the experimental value.

Uploaded by

miza adlin
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as DOCX, PDF, TXT or read online on Scribd
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5.

2 Comparison the experimental diffusivity and literature diffusivity value of Cobalt


(II) Chloride.

Literature value of diffusivity of cobalt (II) chloride.

𝐖𝐢𝐥𝐤𝐞 𝐂𝐡𝐚𝐧𝐠 𝐄𝐪𝐮𝐚𝐭𝐢𝐨𝐧

T
DAB = 1.173 × 10−16 (∅MB )0.5
μB VA0.6

T = 298 K

kg
MB = molecular weight of water (18.016 )
kgmol

kg
μB = viscosity of water (0.8937 × 10−3 )
m. s

∅ = 2.6

m3
vA = atomic volume of CoCl2 ( kg )

m3
Atomic volume of Co (6.67 × 10−3 )
kg

m3 m3
Atomic volume of Cl2 (21.6 × 10−3 ) × 2 = 43.2 × 10−3
kg kg

m3
Total atomic volume of is 49.87 × 10−3 kg

𝟐𝟗𝟖
𝐃𝐀𝐁 = 𝟏. 𝟏𝟕𝟑 × 𝟏𝟎−𝟏𝟔 (𝟐. 𝟔 × 𝟏𝟖. 𝟎𝟏𝟔)𝟎.𝟓
(𝟎. 𝟖𝟗𝟑𝟕 × 𝟏𝟎−𝟑 ) (𝟒𝟗. 𝟖𝟕 × 𝟏𝟎−𝟑 )𝟎.𝟔

−𝟑
𝐦𝟐
𝐃𝐀𝐁 = 𝟏. 𝟔𝟏𝟕𝟖 × 𝟏𝟎
𝐬
Stokes Einstein Equation

9.96 × 10−16 T
DAB = 1/3
μVA

𝟗. 𝟗𝟔 × 𝟏𝟎−𝟏𝟔 (𝟐𝟗𝟖)
𝐃𝐀𝐁 = 𝟏/𝟑
(𝟎. 𝟖𝟗𝟑𝟕 × 𝟏𝟎−𝟑 ) (𝟒𝟗. 𝟖𝟕 × 𝟏𝟎−𝟑 )

−𝟏𝟎
𝐦𝟐
= 𝟗. 𝟎𝟐𝟑 × 𝟏𝟎
𝐬

Compare the experimental value of diffusivity with the theoretical value


𝑚2
Experimental value = 0.877 𝑠

𝑚2
Literature value of Wilke Chang Equation = 1.6178 × 10−3 𝑠

𝑚2
Literature value of Stokes Einstein Equation = 9.023 × 10−10 𝑠

Calculation the percentage error between experimental diffusivity value with literature
value

Percentage error of Wilke Chang Equation

𝐷𝐴𝐵 𝑒𝑥𝑝𝑒𝑟𝑖𝑚𝑒𝑛𝑡𝑎𝑙 − 𝐷𝐴𝐵 𝑙𝑖𝑡𝑒𝑟𝑎𝑡𝑢𝑟𝑒


= × 100%
𝐷𝐴𝐵 𝑒𝑥𝑝𝑒𝑟𝑖𝑚𝑒𝑛𝑡𝑎𝑙
0.877 − 1.6178 × 10−3
= × 100%
0.877
= 99.99%

Percentage error of Stokes Einstein Equation

𝐷𝐴𝐵 𝑒𝑥𝑝𝑒𝑟𝑖𝑚𝑒𝑛𝑡𝑎𝑙 − 𝐷𝐴𝐵 𝑙𝑖𝑡𝑒𝑟𝑎𝑡𝑢𝑟𝑒


= × 100%
𝐷𝐴𝐵 𝑒𝑥𝑝𝑒𝑟𝑖𝑚𝑒𝑛𝑡𝑎𝑙
0.877 − 9.023 × 10−10
= × 100%
0.877
= 99.99%

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