Assignment 3 (Due date 05 March 2019) Grand Canonical Ensemble Problem 1. For a system in grand canonical ensemble: i, Find the expression for the grand probability distribution function, p(E, NV), and the grand partition function, Qy(T,V, 1). ii. Find the following relations: a. Average number of particles: (z = eM is the fugacity term) a a W) = ke? 5 In Qu = 251m Qy b. Average energy: a (8) = spin Qn + ul) cc. Pressure: Pak, ren = kel 3510 Oy 4. Grand potential energy: Dy (TV, we) = ‘aT In Qu (TVs) Problem 2. For a system in grand canonical ensemble show the following relations: i, Fluctuation in the number of particles of the system: ‘GN) 2 (2 = B((AN)’) MH lye root-mean square fluctuation in the number of particles of the system: VGN -o(4) ) oy iii, Relate mean-square fluctuation in the particle density (n = N/V) of the system to isothermal compressibility (ir): (Gan?) _ mm ~V ii, Rek Kr Problem 3: Consider a system in grand canonical ensemble i. Evaluate the mean-square fluctuation in energy: ae) ate) ((QE)*) = kT? Gr), + wkyT @),, ii, Relative root-mean square fluctuation in the energy of the system: GE) (4) 8) ia) Problem 4: Consider a classical ideal gas of N particles in grand canonical ensemble. Evaluate the following thermodynamic quantities: Qu, Qy,{N), {E), P,S, F, Cy. Show that the relative root- mean square fluctuations in the energy (Prob. 2(ii)) and the number of particles (Prob. 3(ii)) of the system hold true. Biasoe : inear classical harmonic Parasol open system of N non-interacting, independsns, dineat fe the frequency of oscillators, each of mass m, in thermal equilibrium at nl oscillation. The Hamiltonian of any one of them is then gi’ HG) = 3 Evaluate the following thermodynamic quantities Qu matq? + peri = ts N)- é Oy, (N) {EY SF, and Cy in one dimension f an (b) Consider the Quantum mechanical situation of the above problem where the enerBy © oscillator is expressed as o). 1 ey = (n +5) ho (n= 0112, i. Evaluate the following thermodynamic quantities Qy, %y,(N), (E),S, F,and Cy. ; ii, Discuss the limiting cases: Pha > 1 (low temperature limit) and Bhw «1 (high temperature limit) for S, £ and Cy.Aasynment 's ne peeve te energy (Eset ao eect GP ports, wedlunrn (WV), deweponaborel) egy ee eek ® System re Yonge yt a Be pee) eth te e compote a Yer We atguered Ae oe : Tsolobed! fy > Ee @ wre tern ee eke ae age eucauansen gescnecinten he © een) + ameganens eT ine qe = D ay qrneres ees ew rien) 2 vers ect we = Ee foreah, PEM) a geben ie | ise! A, eH) RU ER€, raw) 2 Sine, ss = Glee, y ers e Paces a Tegflevin semen, exemesen —— 0 Fea) F Fld + FO + aesie wear ger) =E aia e cle - ve - y Ligh ote GR) a ~ £ oh 2 Ong a a 5 oe waa * = ae be). welt el? Ged Ce tg) Use 7 ef sn] Ba : Sn QUE) © On G+ Sn [1- eet) eae er tally = PEP) 5 tnlen) = ead > [ey = Treverlors, ta prokall rn disteibubion AT for @ grand Comoniesl) emeemble is given (6) <= co te Pl sem) = >® ee On = nermalligkin dacker = harlhien 27 Que Sheedy -©® 77 Summation 18 ever oll Ha Sraba aceneile be tha Saki,