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Problem#1: TBP vs. Vol%

1) This document contains the name, ID, and assignment details of Siraj Ibrahim Ahmed Al sharif. It includes a problem involving plotting TBP (temperature of boiling point) versus volume percent of a petroleum product and deriving an equation to relate the two variables. 2) Tables are presented showing the TBP, normal boiling point (NBP), volume percent and other properties for fractions of the petroleum product. Calculations are shown to determine mass flow rates, molar flow rates, mass fractions and mole fractions for each fraction. 3) The document determines the molar mass of the petroleum product to be 356.8580514419 kg/kgmol based on the presented

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seraj ibramem
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0% found this document useful (0 votes)
49 views3 pages

Problem#1: TBP vs. Vol%

1) This document contains the name, ID, and assignment details of Siraj Ibrahim Ahmed Al sharif. It includes a problem involving plotting TBP (temperature of boiling point) versus volume percent of a petroleum product and deriving an equation to relate the two variables. 2) Tables are presented showing the TBP, normal boiling point (NBP), volume percent and other properties for fractions of the petroleum product. Calculations are shown to determine mass flow rates, molar flow rates, mass fractions and mole fractions for each fraction. 3) The document determines the molar mass of the petroleum product to be 356.8580514419 kg/kgmol based on the presented

Uploaded by

seraj ibramem
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as XLSX, PDF, TXT or read online on Scribd
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Name:siraj Ibrahim Ahmed Al sharif ID:3115204

Assignment#2

Problem#1

solution:
Vol TBP
% °C TBP vs. Vol%
0 -9.44
4.5 32.22 600
9 73.89 f(x) = 0.0005190796x^3 - 0.0696333111x^2 + 9.0586107719x - 5.6070070997
500 R² = 0.9984801479
14.5 115.56
20 154.44 400
30 223.89
40 273.33 300
TBP,°C

50 326.67 200
60 393.33
70 473.89 100
76 520.56
0
80 546.11 0 10 20 30 40 50 60 70 80 90
85 565.56 -100
100 723.00056
Vol,%

a:
TBP= 0.0005190796(Vol%)3 -0.0696333111(Vol%)2 + 9.0586107719(Vol%) - 5.6070070997

IBP(Vol%=0)= -5.607007 °C Kw=11.12


EP(Vol%=100)= 723.00056 °C

Petroleum Refinig 1 Chemical and Petroleum Eng. Dep.


Name:siraj Ibrahim Ahmed Al sharif ID:3115204
Assignment#2

Interval= 72.860757 °C

Vol% vs. TBP

90
80
f(x) = - 2.65070506589183E-07x^3 + 0.0002356018x^2 + 0.0967252918x + 0.7974928437
70
R² = 0.9986545849
60
50
Vol,%

40
30
20
10
0
-100 0 100 200 300 400 500 600
TBP,°C

TBP NBP Vol NBP NBP Sp.Gr Mw


°C °C % °F R - g/gmol
-5.607007 - - - - - -
67.25375 30.823371 87.482068 547.08207 0.7354944 69.111294
140.11451 103.68413 18.246321 218.63143 678.23143 0.7901105 100.28376
212.97526 176.54488 29.523479 349.78079 809.38079 0.8380685 138.54259
285.83602 249.40564 41.503946 480.93015 940.53015 0.8810883 185.72746
358.69678 322.2664 53.572555 612.07952 1071.6795 0.9202734 244.25198
431.55753 395.12715 65.114138 743.22888 1202.8289 0.9563786 317.23461
504.41829 467.98791 75.513527 874.37824 1333.9782 0.9899459 408.69084
577.27905 540.84867 84.155555 1005.5276 1465.1276 1.0213792 523.79462
650.1398 613.70942 90.425052 1136.677 1596.277 1.0509885 669.22627
723.00056 686.57018 93.706852 1267.8263 1727.4263 1.0790173 853.63276

b:

Volumetric flow rate= 1000bbl/day*(42USgal/bbl)*(3.785L/Usgal)*(1m3/1000L)=158.97m3/day

Vol. flow for each fraction= Vi * Volumetric flow rate


mass flow for each fraction= Sp.Gr * 1000 * Vol. flow for each fraction
molar flow for each fraction= mass flow for each fraction/Mw
mass fraction= mass flow for each fraction/ total mass flow
mole fraction= mole flow for each fraction/ total mole flow

Petroleum Refinig 2 Chemical and Petroleum Eng. Dep.


Name:siraj Ibrahim Ahmed Al sharif ID:3115204
Assignment#2

TBP Vol Vol. flow mass flow molar flow mass fr. mole fr. xi *Mwi
°C % m3/day kg/day kmol/day - - g/gmol
-5.607007 - - - - - - -
67.25375 0 0 0 0 0 0 0
140.11451 18.246321 2900.6177 2291809 22853.238 0.0264934 0.0942762 9.4543727
212.97526 29.523479 4693.3474 3933347 28390.883 0.0454696 0.1171206 16.226191
285.83602 41.503946 6597.8823 5813317 31300.256 0.0672021 0.1291226 23.981614
358.69678 53.572555 8516.4291 7837443 32087.53 0.0906011 0.1323703 32.331718
431.55753 65.114138 10351.195 9899660 31206.117 0.1144404 0.1287343 40.838961
504.41829 75.513527 12004.385 11883692 29077.462 0.1373758 0.1199529 49.023665
577.27905 84.155555 13378.209 13664225 26086.989 0.1579588 0.1076164 56.368876
650.1398 90.425052 14374.871 15107824 22575.06 0.1746469 0.0931286 62.324139
723.00056 93.706852 14896.578 16073665 18829.719 0.185812 0.077678 66.308514
total 86504981 242407.26

c:

356.8580514419 kg/kgmol

Petroleum Refinig 3 Chemical and Petroleum Eng. Dep.

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