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    Exercise CHM420 3

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    syaza
    This document contains an exercise with multiple chemistry problems related to equilibrium constants and calculations. 1) It asks to calculate equilibrium constants for several reactions, including the reverse reaction of N2(g) + 2O(g) ⇌ 2NO2(g). 2) It involves calculating the equilibrium constant Kc for the reaction H2(g) + I2(g) ⇌ 2HI(g) based on initial and equilibrium concentrations. 3) It asks to predict the effects of heating the reaction mixture or adding an inert gas on the equilibrium of the reaction 2SO2(g) + O2(g) ⇌ 2SO3(g).

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    Exercise CHM420 3

    Uploaded by

    syaza
    191 views2 pages
    This document contains an exercise with multiple chemistry problems related to equilibrium constants and calculations. 1) It asks to calculate equilibrium constants for several reactions, including the reverse reaction of N2(g) + 2O(g) ⇌ 2NO2(g). 2) It involves calculating the equilibrium constant Kc for the reaction H2(g) + I2(g) ⇌ 2HI(g) based on initial and equilibrium concentrations. 3) It asks to predict the effects of heating the reaction mixture or adding an inert gas on the equilibrium of the reaction 2SO2(g) + O2(g) ⇌ 2SO3(g).

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    EXERCISE_CHM420_3 (1)

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    This document contains an exercise with multiple chemistry problems related to equilibrium constants and calculations. 1) It asks to calculate equilibrium constants for several reactions, including the reverse reaction of N2(g) + 2O(g) ⇌ 2NO2(g). 2) It involves calculating the equilibrium constant Kc for the reaction H2(g) + I2(g) ⇌ 2HI(g) based on initial and equilibrium concentrations. 3) It asks to predict the effects of heating the reaction mixture or adding an inert gas on the equilibrium of the reaction 2SO2(g) + O2(g) ⇌ 2SO3(g).

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    191 views2 pages

    Exercise CHM420 3

    Uploaded by

    syaza
    This document contains an exercise with multiple chemistry problems related to equilibrium constants and calculations. 1) It asks to calculate equilibrium constants for several reactions, including the reverse reaction of N2(g) + 2O(g) ⇌ 2NO2(g). 2) It involves calculating the equilibrium constant Kc for the reaction H2(g) + I2(g) ⇌ 2HI(g) based on initial and equilibrium concentrations. 3) It asks to predict the effects of heating the reaction mixture or adding an inert gas on the equilibrium of the reaction 2SO2(g) + O2(g) ⇌ 2SO3(g).

    Copyright:

    © All Rights Reserved
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    Download as docx, pdf, or txt
    of 2

    AS/CHM420/MAR-JUL_2019

    EXERCISE: CHAPTER 6

    1. At a certain temperature, the value of the equilibrium constant corresponding to the


    following equation is 100.

    N2(g) + 2O(g) 2NO2(g)

    Write the equilibrium constant expression for each of the following reactions and calculate the
    value of the equilibrium constant for each of them.
    2NO2(g) N2(g) + 2O2(g)

    Kreverse=1/Kforward

    1/100= 0.01

    NO2(g) 1/2 N2(g) + O2(g)

    = 1/50= 0.02

    2. Hydrogen iodide is a colourless gas that is exceptionally soluble in water. It can be prepared
    by combining hydrogen and iodine according to the following equation.
    H2(g) + I2(g) 2HI(g)

    Initially, 0.80 mol H2 gas and 0.50 mol of I2 gas were mixed in a 5.25 L vessel at 25℃. After
    the system had reached the equilibrium, 0.91 mol HI gas was found in the vessel. Calculate the
    Kc.
    Kc= 0.1733^2/(0.152x0.0952)
    = 2.0703

    3. Consider the reaction system:


    2SO2(g) + O2(g) 2SO3(g)
    ΔH° = -198.2 kJ

    Predict the effect that each of the following changes will have on the concentration of SO2 and
    SO3. Justify your answers.
    i) The reacting mixture is heated.
    Increasing temperature shifts the equilibrium to the left. Thus, high temperatures
    favour SO2, while SO3 predominates at low temperatures. Temperature rise will
    increase K for system with positive deltaH reaction
    AS/CHM420/MAR-JUL_2019

    ii) Helium gas is added at constant volume.


    When an inert gas is added to the system in equilibrium at constant volume, the total pressure
    will increase. But the concentrations of the products and reactants (i.e. ratio of their moles to
    the volume of the container) will not change.
    Hence, when an inert gas is added to the system in equilibrium at constant volume there will
    be no effect on the equilibrium
    4. Dinitrogen tetroxide (N2O4) is an important component for rocket fuel. At 25℃, dinitrogen
    tetroxide is a colourless gas that partially dissociates into red-brown nitrogen dioxide (NO2)
    gas. The ΔH for the reaction is +58 kJmol-1.
    i) Write a balanced equation of this dissociation at equilibrium state.
    N2O4 <= >2NO2
    ii) Initially, 138 g of N2O4 gas was introduced into a 5 L vessel at 25℃. At equilibrium, it was
    observed that 45% of N2O4 had dissociated. Calculate the Kc.
    45/100X138= 62g
    62/92= 0.674 mol
    1N2O4 2NO2
    0.674 mol N2O4=1.348 mol NO2
    Kc = (1.348/5)^2/(0.674/5)
    = 0.54
    iii) Determine the Kp for the dissociation of dinitrogen tetroxide at 25℃.
    Kp=Kc(RT)
    = 0.54X (0.08206X298)
    = 13.2
    iv) The temperature of this equilibrium mixture is lowered. Give the effect of this on the value
    of the equilibrium constant and the yield of NO2. Justify your answer.
    When the temperature of this equilibrium is lowered, the effect on the value of equilibrium ,K
    is the value of K decrease and the yield of NO2 decrease. This is because the temperature drop
    will decrease the K value for a system with positive ΔHrxn thus the decrease in temperature
    will move position in endothermic reaction to the left.

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