Plastisol Coatings and Application Techniques: I. Plastisol Material Description
Plastisol Coatings and Application Techniques: I. Plastisol Material Description
by D A V I D H. HARDEN
Research Associate in Physical Medicine and Rehabilitation,
University of Michigan Medical Center, Assistant Professor
of Mechanical Engineering, Wayne State University
and
RICHARD D . KOCH
Research Orthotist in Physical Medicine and Rehabilitation,
University of Michigan Medical Center
Braces and splints that apply supporting and corrective forces to the
human body have traditionally been covered with various types of leather.
At present, however, good leather hides are becoming very expensive and
difficult to obtain. The problems involved in using leather have motivated
research in the use of plastic materials and new covering processes to replace
leather coverings. Ten years ago a polyvinylchloride-based material called
plastisol was introduced as a covering material for hand splints. Since then
this process has been used both experimentally and clinically at the Univer
sity of Michigan Medical Center.
The effectiveness of a plastisol covering on hand splints led us to in
vestigate the use of this material on other items such as back braces and
leg-brace bands. Our first coating formulation was limited in application
because of its high coefficient of friction and uncontrollable density, and
the fact that no well-defined criteria for the coating process had been estab
lished. However, there remained the desirability of a smooth, encapsulating
covering that could be applied simply by dipping the heated brace in the
liquid material. Therefore a study was undertaken to characterize plastisol
in detail and to perfect the dipping process. The resulting procedure is being
effectively used on back braces, leg bands, pelvic bands, mouth sticks, hand
splints, and brace straps. Clinical applications over the past five years tend to
confirm the usefulness, acceptability, and advantages of this plastic covering.
C. Toxicity*
Certain materials when placed in contact with the skin may produce a
reaction, either through the mechanical action of the two surfaces rubbing
together, or by chemical reaction between the substance and the skin. A
"patch test" was used to check for reactions souch as redness, irritation,
inflamation, or eruption. Samples of plastisol and horsehide were placed
on 53 subjects, 28 in the lumbar area of the back over the erector spinae
muscle, 3 in the upper back between the scapulae, and 22 in the shoulder
region over the deltoid muscle.
After 47 to 50 hours the patches were removed and the skin examined
for evidence of irritation. Of the 53 subjects, three showed a reaction. One
subject developed erythema under the leather patch, the plastisol patch, and
the tape which held the patches in place. The erythema in each of these
areas lasted 4 to 6 hours. Another subject developed mild erythema local
ized to the area under the plastisol patch. In this case the redness disap
peared in a few hours. Erythema developed under the leather patch in the
third subject. Twenty-four hours later this reaction cleared up.
None of the plastisol patches discolored from the test, but in many
instances the skin under plastisol was found to be moist. This is attributed
to the nonporous and nonabsorbent nature of the plastisol. The leather,
however, absorbed perspiration and became moist or saturated and dis
colored.
Forty-eight hours after the patches were removed the subjects were
again examined and did not show any new signs of positive reaction or any
residual signs of reactions. The major significance of this test is that it
shows plastisol to be less affected by body contact and that plastisol patches
produce no more skin reaction than did leather patches.
coating from forces applied over the sharp edge; also the coating is thinner
at sharp edges. Plastisol coating should not be used to cover poor metal-
work. Well-rounded edges on the metal parts are easily produced by a fine
belt sander, Figure 5, or filing or grinding. Contours and curves should be
smooth and flowing to avoid abrupt changes in cross-section or configuration.
2. Preheating
Since gelling of the liquid plastisol on the metal part is caused by heat
transfer, it is necessary to preheat the part to be covered, Figure 6. The
thickness of the coating depends on the amount of heat transferred. The
heat transfer rate in turn depends on the temperature of the metal part, its
specific heat and conductivity, and the mass of the part compared to its
surface area. Thus, the coating thickness is governed by the thickness of
the part as well as the temperature to which it is preheated, Chart 1. Pre
heating is usually done in an oven at 190° to 220°C for five to fifteen
minutes depending on the coating thickness and thickness variation desired.
Considerable time is required to heat a cold metal part to the desired
dipping temperature even in a hot oven, and the thicker the part, the more
time required. Chart 1 shows results of a thermocouple test in which
various thicknesses of aluminum were placed in an oven at 195°C. It is
desirable to use the same oven temperature for the preheat step as for the
curing step so that the oven does not have to be adjusted between steps.
A single setting is advantageous too, in that it allows preheating and curing
of several pieces simultaneously.
3. Dipping
The preheated metal part is removed from the oven with appropriate
tools such a pliers or hooks and immediately dipped into the liquid plastisol.
Figure 7. Gelling of the plastisol on the part continues as long as sufficient
heat transfer takes place between the object and the surrounding liquid, thus
the amount of heat transfer determines the thickness of the coating, Chart 1.
The gelling process usually terminates in about two minutes if the parts are
of moderate thickness. If the part is removed before gelling is complete,
the coating will sag and gel further as the part is drained, creating an
irregular surface. When the gelling process is terminated, in one to three
minutes, the part should be slowly lifted from the plastisol bath and sus
pended for draining, Figure 8. Several minutes should be allowed for the
liquid material to drain off.
4. Surface Sealing
Next the surface must be sealed (surface molecules gelled to prevent
further sagging) by rotating the dipped part above a soft Bunsen burner
Figure 7—Dipping. Figure 8—Dripping.
5. Curing
In order to produce a tough, durable coating on a brace part, it is
necessary to fuse the resin particles in what is called the curing step of
the process. Since we are dealing with coating thicknesses of 1/16 to 1/4
inch, considerable time is required for heat transfer from the curing oven
to the inner part of the plastisol coating. This process depends on time
and temperature, just as in roasting meat, which must reach a certain
temperature at the center in order to be " d o n e " to the desired degree.
Chart 2a indicates the relationship between coating thickness, curing oven
temperature, and curing time required to give the desired coating strength.
Curing is best accomplished in oven temperatures ranging from 190° to 200°C
for ten to twenty minutes, depending on the part and coating thickness. It
should be noted that insufficient cure due to inadequate curing time or oven
temperature results in a very weak coating. Since increased oven temperature
reduces the time required for a complete cure, there is a tendency to increase
the oven temperature beyond the recommended limit; however, while this may
quickly cure the outer surface of the plastisol coating, the interior will be
under-cured. Excessive oven temperatures may also cause discoloration of
the surface before the inner part of the coating is completely cured.
C O A T I N G PROCESS REVIEW
1. Metal Preparation—Clean the surface and round all edges (polishing
not necessary).
2. Preheating of Metal—The metal parts must be given sufficient heat
content to pick up the desired coating thickness. Preheating is
usually done in an oven at 190° to 220°C for five to fifteen minutes
depending on the coating thickness and thickness variation desired.
3. Dipping—The preheated metal part is dipped into the liquid plasti
sol for several minutes until the heat has been dissipated and the
desired coating thickness attained. The part is then slowly removed
and the excess material allowed to drain off.
4. Surface Sealing—Next the part is rotated above a soft Bunsen
burner flame or between two infrared lights to seal the coating sur
face quickly. Sagging during the curing step is thus prevented.
5. Curing—The dipped and sealed part is placed in the curing oven at
temperature of 190° to 200° C for ten to twenty minutes depending
on the part size and coating thickness. During this step the polyvinylc
tough plastisol coating.
6. Cooling and Finishing—After removing the part from the curing oven
the handling hooks are removed and the coating is trimmed and sand
ed to obtain a neat appearance. The part is then ready for use.
panel in the oven door is essential for observing progress of the curing;
the onset of discoloration that warns of overcure can be quickly detected. The
oven should have rods or a rack near the top of the interior chamber for
hanging the parts to be heated or cured.
Since the liquid plastisol does not evaporate or age appreciably under
normal room conditions, it is not necessary to have an air-tight dipping con
tainer; however, the container should be covered when it is not in use, to
prevent accumulation of dust or dirt particles on the plastisol surface. The
can in which the material is purchased can be used as the dipping container,
but a specially prepared tank or glass container may be more suitable in
size and shape for the particular parts to be coated.
A Bunsen burner, Figure 9, or two infrared lamps, Figure 10, are
required for the sealing process after the part has been dipped. Two goose
neck desk lamps can be set so that the two infrared bulbs face each other
several inches apart; the part to be sealed can be slowly rotated between these
lamps. If a gas supply is available and the open flame of a Bunsen burner
is permissible, sealing can be accomplished by slowly rotating the part to be
sealed over the lop of the soft Bunsen burner flame. This method requires
caution because the flame temperature is high enough to scorch the surface
very quickly if the part is held in the flame.
Small tool and equipment requirements consist of simply fabricated wire
hooks for hanging the parts in the oven or cooling rack, and tools such as
pliers or vice-grip pliers for handling the hot parts, a sharp knife or a
scalpel, sandpaper for trimming and finishing the final plastisol coating, and
several hanging racks located both over the dip tank and in some appropriate
cooling area, Figure 12.
D. Plastisol Straps
Leather straps have normally been attached to braces by riveting or
sewing, causing discontinuity in the brace appearance. When using plastisol
as a brace covering material, it is possible to make the straps a continuous
part of the plastisol coating, Figure 16. This is accomplished by attaching a
temporary piece of metal to the brace for the dipping process in such a way
that a continuous coating is obtained on both the brace and the attached
metal. When the piece of metal is removed, an integral strap of plastisol
will remain attached to the brace and brace covering. A little careful trim
ming and sanding give the strap and coating a neat appearance, and little
or no trace of the special process is evident. Strap thickness can be con
trolled by selection of the thickness of the preliminary metal strap.
Another method of forming plastisol straps is to cut them from plastisol
sheets which can be formed on metal plates. The sheets can be easily stripped
Figure 16—Continuous Plastisol Straps.
from the metal plates if no primer is used. The straps are then attached to
the brace by normal procedures such as riveting and sewing.
V. SUMMARY A N D C O N C L U S I O N S
Basic and clinical studies of plastisol, carried out at The University
of Michigan Medical Center during the past five years, indicate that this
polyvinlchloride-based material is a satisfactory replacement for leather as
a covering for braces and splints, Figure 17. Clinical applications have shown
that patients enthusiastically approve this change in most instances.
Plastisol-covered braces have the advantage of being nonabsorbent and
nonreactive to body oils, waste, or detergent, Figure 18, 19. Although oc
casional erythema may develop from plastisol, as with leather, it will usually
disappear shortly after the material is removed. Material tests show that the