Technical Information and Data of Conversion Factor - Important PDF
Technical Information and Data of Conversion Factor - Important PDF
Technical Information and Data of Conversion Factor - Important PDF
SPECIAL PUBLICATION
by
L. Hunter
SOUTH AFRICAN
WOOL AND TEXTILE RESEARCH
INSTITUTE OF THE CSIR
P.O. B O X 1 1 2 4
PORT ELIZABETH
REPUBLIC OF SOUTH AFRICA
WOL 47
loo0
tex (mglm) = (Metric count = Nm)
metric count
- 886
tex worsted count (Worsted couni = Ne worsted)
- 590,6
tex (Cotton count = Ne)
English cotton count
886
From the above we have: tex =-= 26,1
34
Tenacity
For cotton this should lead to: cN/tex = 0,454 (Pressley in 1 000 psi) but in
general the following conversion is used:
Therefore:
= 9.81 x (gf.mm3
Flexural Rigidity
It is recommended to use mN.mm
S d a c e Tension
It is recommended to use mN/m
The tex twist factor (iurns/cm m h a s been recommended although the twist
-
factor (= dtex) based on decitex has also been suggested' since it is numerically
.
equal to the metric twist factor=,,- - turnslm widely used in Europe.
JNm
We have;
where
tpi
English Cotton twist factor == = tpi/ J E Cotton
~ ~Count
. = Nc
Worsted Twist factor = = w = tpi/ d ~ o n t e dCount
e.g. Convert a metric twist factor (lm) of 110 to a tex twist factor (.
tex )
From the above we bave:
= = 0,316 X = ~ = O , x~ 110
I ~
tex
= 34,76
i.e. tex twist factor = 34,76.
Similarly an English cotton twist factor of 4 equals a tex twist factor of 38,3.
typical weft
typical warp
typical hard twist
+
Fabr~cmasslunit area (g/m2) = 0.1 [(pickslcm) x (tex2) (ends,'cm) x (tex,)]
where tex, is thelineardens~tvofthewelt yarnand tex, isthe l~neardcnslty01 the
warp This cakulation, however, d k s not allow for warp and w;ft yarn
crimp; more corredy it should read:
cN = 0.98 x (gf)
= 0,l x (mN)
= 444.8 x (Ibs-force)
= 100 x newtons
= 981 x (kgf)
= 27.8 x (02)
Fluidity
To convert g/cm3 to kg/m' multiply by 1000. The term specific gravity is being
replaced by relative density.
Work of Rupture
Initial Modulus
Cover Factor
where Wp and Wf are the number of warp ends and picks per centimetre,
respectively, and the yam linear density (tex) is the same in both warp and weft
(filling) directions.
It has been suggested* that a nominal cover factor for a woven structure be
defined as:
threads t x r centimetre x
Tex cover factor =
J spec& gravity of the fibre substance
COVERFACTOR
Open scrim
Fairly close
plain weave
Maximum cover
Fibre
Di8mdCr
(LJ@
-
14
15
16
17
18
19
20
21
22
23
24
25
20
27
28
29
I
If fibre obliquity (i.e. the effects of twist) is ignored then the average
number of fibres (u) in the y a m crosssection can be calculated as follows:
yam tex
n=
0,0007854 x d2 x p x (1 f 0,0001 Vd2)
For cotton n = -
590600
CH
10 SA WTRl Special Mlication - July. 1978
where C is the English cotton count (Ne) and H is the fibre linear density in
mtex (i.e. mg/ km).
Ideal Irregularity
where the symbols have the same meaning as in the previous section. For wool
with a CV of fibre diameter of 24% this reduces to:
often 112 is used instead for wool7 while for cotton we have?
-
Fibre
Cotton
Hemp/Jute 114
Viscose 102
Consider now a modcl strand similar to Martindale's simplest model but one in
which the fibres all have the same linear density and the same extent, k, defined
as tbe ratio' of the axial length occupied by the fibre in the strand to the
straightened fibre length. This means that the effective fibre linear density in the
-c
strand is l / k times the actual linear density, and hence: CV - 100 becomes
1
GENERAL CONVERSIONS
590.6 - 590.6
tex (in mglm) =
English Cotton Count
- - Ne
Metric Count = Nm
English Cotton Count = Ne
SHOE-SIZE/HOSIERYSIZE CHART
S=
- -
91.5 (L) 18,3 C 70,3
C
where S is the predicted skein strength in lbs, Lis thestaple length in 32nds of an
inch, C is the yam count (English cotton).
The value of 18,3 appearing in the formula represents the count-strength
correction. It has been suggested that the CSP results of carded yams be
corrected as follows:
where
where symbols are as before and K is a constant, usually 8 for load expressed in
kgf and 18 for Load expressed in lbsJ4.
Skein strength is generally expressed in pounds and from this the Count-
Strength-Product (CSP) or break factor can be calculated.
The followingequations can be used as a general guide for relatingsingle
thread strength to skeln strength".
To convert CSP to gf/tex divide by 208,3 and for CSP to cN/tex divide
by 212.6.
1 English Conaa
Medium
Superfine
Most cotton knitting yarns have tex twist factors which lie within the
range 26.8 to 30,6 (2,8 to 3.2 English cotton count)although slightlyhighertwist
factors may be required for warp knits and certaindouble knits1b.The following
tables give some average values for the twist factors employed for various types
of yarnsl7.
Lonu
E
zs wt = Tex Twist factor = (turnslcm)
6' turnslm
a = Metric twist factor =
m
I /Metric Count
.2
T
" YARN TWIST
9 = helix angle19 where T is the number of turns per unit length and D is the
yam diameter.
Some typical twist facton given inanotherarticlearealso given below for
several spun yams"?
Cotton:
low twist warp 35.9 3.75
ordinary warp 38.3 4.00
low twist weft 31.1 3.25
ordinary weft 33.5 3.50
hard twist yarn 43.1 4.50
ultra hard twist yarn 45.6 4.75
high grade knitting less than 19.1 less than 2
yam
ordinary knitting yarn
Woollcn:
ordinary wovcn yam
hard twist woven
yam
knitting yarn
The American Cotton Handbook21 gives the following twist factors for
cotton:
Short cottons would, however, require higher twist factors than the
above".
For Indian hosiery yams the twist factors normally fall within the
following ranges:
=e = = =1
dtex m
dter 33 33 56 56 56
Nrnr/m IODO 3W IMW) 800 300
Temperature ("0 110-120 70-80 100-110 W100 70-80
Time (min) 30 30 30 30 M
Tumslm MO 3W 3W IWO MO
Temperature ("0 70 70 100 90
E m c (mm) 30 40 40 40
Steaming method:
TWlSTED
wet ( m 0 hrirt)
Integrated campsite
Aerodynamic bnkc Pavena P u t
Self-twist 99-183 TNO 152-365
Spinning
wool 80 end breaks/ 1 000 spindle hours
(*50%)
wool/ polyester 60 end breaks/ l 000 spindle hours
(*W o )
Heap12 states that, for cotton rotor (OE) yams the spinning limit lies
between about 80 and 120 fibres in the cross-sation whereas for ring yarns it is
about 50 fibres. Generally yams finer than about 12,5 tex arc spun on the
combed cotton system.
For cotton an end breakage rate of 40 per 1 000 spindle hours is often
taken as an average for ring spinning and 60per 1000 rotorhoursforrotor(0E)
Thick I to 10 60 to @XI
Coarse I1 to 22 27 to 54
Medium 23 to 46 13 to 26
Mediumifine 47 to 80 710 13
Fine 81 and over 7 and below
The highest count at which a yarn would be expected to give a lea (skein)
count strength product (CSP) of 2 000 (carded) or 2258 (combed) has been
defined as the highest standard count.
The following table gives some ranges of highest standard count for
various cottons25.
Highest Standard Counts
(fnrtirh cotton) I Equivalent tcr
Approximate
TW sf.@ L-@ Yarn Comtr Tcr
(a) (mm) (N+)
Pima > 1.38 > 34.9 greater tha2l 70's C 8.4
A a l a 1517 1.13 to 1.16 28.6-29.4 50-7J's 8.4-1 1.8
SJ wries 1.W to 1.13 27-28,6 &Ws 11.8-14.8
Modal type I to 1.09 25.4-27.8 Z&UJ's 14.8-29.5
Shon m p l c <I < 25.4 I c u than M's > 19.7
Up to 10s
42 to 59 10s to 20s
30 to 42 20s to 30s
20 to 30 30s to 36s
16,4 to 20 36s to 45s
11.8 ta 16.4 4% to Mh
8.4 to 11.8 60s to 80s
COMBED YARN
The following Limits have been given for the ring-spinning of cotton".
--
I . TYPE OF FIBRE
Acrylic
Fibre Viwov Nylon Spin.iog Polytn
Det~ik dter/Nrn dtcrl Nm Imk dtex/Nm
dtexlrnm dtex/Nm
A v w g e Fibre Diameter ( p m) 21 23 25
N = 37 14.6 17.8 21.3 25.2
Note: for wool the average number of fibres in the yam crosssection (N) can be
972T
calculated as follows: N = d2
0,0001V2)
+
For wool the following spinning limits have also been given's:
AAA
AA
A
B
C
D
E
Messrs Zellweger Uster Lid give the following experience values for the
frequency of short stops in cotton weaving3':
Single Shuttle
(plain) 2W 150 20
Muhishuttle
(Coloumd) MO 225 30
The following table compares warp breaks for rotor and ring yams on
various looms:
~ o l ~ ~ r o ~ ~ l e ~ e
Polyethylene
Rubber fibres
Polyamide (Rilsan)
Nylon 6 and 66
Nylon 66
Nylon 6 1;18
Acrylic 1.18-1.19 and 1,14-1,42
Silk (boiled-off) 1.25
Wool 1:jl and 1.32
TriaEetate 1.32
Acetate 1.29-1.33
Silk (raw) 1.34
Modacrylic 1.34
Polpster 1.38
Polyvinyl chloride 1.4
Hemp and jute 1.48
Carbon fibre type 1 1,s
34 SA WTRI Special hblicofion - July. 1978
Relation Density
Fibre (Specific Gravity)
Linen 1.5
Rayon 1.50-1.53
Ramie 1.52
Cupprammonium filament 1.52
Cotton 1.53-1.54
Carbon fibre type 2 1,6
Vinylidene chloride co-polymer 1.7
Alginate 1,78
Glass fibre composite 1.9
Asbestos (chrysolite) 2.4-2.6
Glass filament 2.45-2.60
Triton ceramic 2.56
Aluminium L65 23
Titanium 4.5
Steel S97 7.8
Metal fibre (tinsel) 7.90
WOOL CLASSIFICATION
W m l Tap Cnd"
Army
Polymer Fibre
Polyester Mype
W-type
Converter tow
B-me
W-type
T-type
Polyacrylonitrile w-type
Polypropylene T-type
Cellulose w-type
r
I
Cotton
Normal virose
High tenacity viscose
Triaatate
Nylon 6.6
Polpter
Acrylic
Polyurethane elaston
Polypropylcnc
Drycleaning
pcrtormance I 1 3 5 4 3 3
UV Stability 1-2 2-3 5 I 2-3 7 ?
Comfort
Warmth I 3 5 4 4 4 3
Moisture
Absorption I 2-3 5 4 4 5 3
Elasticity 1-2 4 3 5 3 4 3
Porosity 1-2 2 2 2 2 2 2
Permeability 1-2 2 2 2 2 2 2
Appcannce
Drape I 4 4 5 3 4 2
Texture 1-2 2 3 4 2 4 2
Colour 1-2 2 4 5 3 5 2
Crease resist 4 4 2 5 2 2 2
Wrinkle recovery
- 2
--4 4 5
-4 4 3
Press (Wet)
Retention
I Bulk and Laft
Pilling Resistance
Heat Resistance
Absorbency
Wrinkle Recove! Stability Absorbency Absorbency
Press (Wet) Static Rcsistance
Retention
I Pillinn Resistance
COMPARISON OF FIBRE QUALITIES RELATING TO APPEARANCE RETENTION FOR
CARPETS"
Rellllenco
Nylon
Polyeater
Polypropylene
Rayon
Wool
Nylon
Polyester
Wool
Cotton
Acrylic
Viscose rayon
Acetate rayon
1.28-1.33 I5 t o 25 1 3 7 to 12 25 to 40 M to 60 4M
Cotton 1.52 23 to 45 4 5 to 27 26 to 29 7 to 10 9 to 12 50
- 60 to 95 - - 2 to 3 20 to 25 -
(Viscose) rayo 1.52 161078 131022 7 1 0 1 1 1 5 t o M 251035 79
(CcUuloa)
acetate
trLzcnatc
Polyamide
(nylon 6)
Polycrtcr
nitrile
Polrinyl
Wool
tight Wether
rut- R&
nes h"CC
'olycster
4ylon 6.6
iylon 6
\crylie
V. good
Good
I
Good
Satisfactory
Good Satisfactory
Exmllcnt
Uool
:otton
Fair
hir 1E
NsMI IC
- - -
a x C.rbw
conw 114 Carbon Cnphitr lbrw
- -
26.5-53 4.5-13.2 62 26.5-247 26.5-26
II Moisture absorption
2(PC 65% R H (76)
Heat endurance (DC)
6-10
Chars
a t 300
none
MO
2-14
4 m
none
4M0
none
4M0
psi
tenacity (&denier =
12 800 x density'
p = density (glm')
The strength of Kcvlar is-191 cN/tex which is mom than twicc that of the strongest nylon*.
Wool 1.26-1.33 9-25 8,3-13 7-12 610 3 W 7694 Excellent S W - - S W SW 430 Excellent 16
1.52
Cotton 1.54-1.55 2245 22,5-27 2629 25-55 9-12 102-110 Passable S FS - - W S SW M Good 7
Nylon 6 1.14 35-84 3 145 2639 1660 25-90 83-92 Excellent S S 7 21s-220 FS S SW 640 Excellent 3.5-5.0
Polyvlnrlidenc cyamde 1.70 8-23 - - 18-33 - 100 Excellent S S 145-165 165-185 V. strong S S - Passable 0
- - - -
Acctatc (Cellulose) 1.32 10,560 10-13,2 7-9 17-35 28-35 60-67 Goad W W 2W230 260 SW SW SW 50 Good 6.0-7.0
Rayon 1.50-1.52 1678 13-22 7-11 7-30 25-35 4540 Passable W W -I - W SW SW 79 Excellent 12-14
Key: S - Stmng
FS - Fairly Strong
W - Weak
SW - Somewhat w a k
The following tables have been given for the regain of different
fibre34.JS.Jb.
I I !
The following table compares the regain and water retention levels for
various fibres57:
The following table has been presented for the regainand water retention
of different fibres58:
The following table has been given for the smelling of fibres in water?
Cotton
Linen
Mcnxriscd cotton
Menxrised linen
Vsow rayon
Lilieafcld
viscose rayon
Cuprarnrnonium
rayon
Wool
silk
Nylon
NO. Fibm
-
2
Msnmdr
Nylaa
Dacron
Anill
Casein
V~scoxRayon
Acrylic
Odon
Dyncl
Natonl
T dSi
Wool
Ramie
Cotton: Auburn 3
(65%maturity)
Cotton: NC 14
(2.5% maturity)
d4 (1 + 6 V2 + 3 V4).
56 SA WTRI Special Pkblication - July, 1978
FIBRE FLEXURAL, TORSIONAL, SHEAR AND TENSILE PROPERTIES*
(MORTON AND HEARLEY'
A t a w 6 R H a n d 2 O D C ~ abcrrl.
s ~ To wn*cn cN/tex d c N . m m ' / ~ dto m f v / t n and mN.mrn'/uxl mspxivcly, multiply by 10.
Type of strain
F i i
Bcnding Tcrailc
Nylon
Courtelle
Polypropylene'
Britch Wool
Evkan
15% strain
meet of exposure, h a t and ndiatiw
The following rating has been given for various fibres in order of increasing rate
of loss of strength on exposure to sunlight:
Fibreglass
Acrylics
Polyesters
Linen
Cotton
Wool
Silk
One must remember that these fibres have verydiffercnt initialstreogtbs,
which
~ ~must
- - - be
- - - - ~into account as wdlas the rate of strength loss, when Crying
~ taken ~
to decide on the best buy from the point of view of light stability.
-
florid.
21 WO
I-g-
I Fibre
V i o s c rayon
At 1 W C
90
Cotton 92
Linen 70
Glass 100
Silk 73
I Nylon
Polyester. Tcrylcne
Acrylic. Orlon
Some details of the effect of radiation on textiles are givenin the table and
figures below":
Cotton
Rayon
Acctafe
Wool
Nylon 6 or 66 (polyamidcs)
Dyncl (modacrylic)
Orlon (acrylk)
Dacron (polprtcr)
LL
1.1. POLYESTER
-
0
Y.
a
m RAYON
0,s
F
o,, COITON
I ,O r-- RAYON
POLYESTER
0.6
50 -
40 -
MOSI,YT"
MODAClll,.,<
*cm,.** 'I
-
...-.----- - --.---.--POI "LITER
Is0 IW 200 210
TEMPERATCRE " C
I
SOME POLYESTER FIBRE PROPERTIES
The following physical properties have been given for some Japanese
synthetic fibres and yarns7?
TIC, TlW
TlW
-p-
T / R T!W. T/Ram
Bright TIW. TIRam
El01
(Normal
shrinkage
type)
Anti-pilling
El04
s right
I 32
:
(High
shrinkage
tYF)
Bright 1 4.4
5.5
TI W
TIW
K26 1
(Cationic
dyeable)
K2M
(Cationic TIW
dyeable) TKO. TIW
KEY. T - Tetoron
W - Wool
R - Rayon
C -- Catton
TYPE I TMI+ I
~ 3 0 1 4 TM2' 1 1
~ 3 0 3TWAJ
~ T981 1 1981 1 T981 1 E101'-
Shrinkagr (%)
(Hot air a t 18000 1 6.0
* I or
below
-
*I or
below
-lor
below
.lor
below
Bending rtrcngh
+ Hard crepe cydcts are recommended when waving yarns spun from this fibre
SpeeificaUy uwd for cotton blending on rotor (OE) machines
Shrinkap in boiling water
** S u p Anti-Pilling Tetoron staple for knitted and woven goods, panicularly in blends
A Used for sewing thrnds
Count
T-303
I Elongation (96) 1 22
Twist plying (turns/m)
N-l PES
pure and blended with
natural or other
chemical fibres
Non-woveas.
I I€O~EO-O-(CHJ~*l n
home
texfilcr
I Bright (626)
Semi-dull (547)
Semi-dull (526)
Semi-dull (536)
Bright (636)
Hollow Bright (H635)
Modified (P634)
Modified (545)
Anti-pill (555)
Hollow (H38F)
Hollow fH38Y)
*,"ice Ropde.3
C x a s xnsitivity
Abrasion mistance
Pilling tendency
Pleat stability
Shape retentivity
Strength (cN/tex)
Efongation (%)
Knifesdgc abrasion (revs)
Shrinkage a t boil (%)
Density (glcm3)
Melting point (OC)
Glass transition ump. (OC)
Sonic modulus (cN1drcx)
Thnmal shrinkage M(PC (96)
Rcl. knot strength (%)
Rel. loop strength (9%)
Angle of distortion a t b m k (%)
.~..
CELLULOSICS
3045 1Y-40" 24
(depending on
stretch)
Fortisan 49 5- 143
'PRIMA' is ITT Rayonieh Trademark for its high Crimp. High ust Modulus Rayon.
I
Bnght r s c a r (1.67 dtcr)
Vmmw arrtatr 12.4 dlcr)
Vlr- acetate (2.4 dtcx)
Bright VirCMC.
VirMC acctatc
Bright + o a
V i o x acetate
V i r o w dull
Viscox acetau
CcUulov accptc (duW(3.3 dtex)
HSO is a modified viscose; the HS stands for "hot stretch" which implies
increased molecular orientation and, therefore, improved fibre tenacity,and the
"0" is a pictorial representation of the tubular form which this fibre takes.
The objective of Courtaulds was two fold: if possible to increase the
"cover" given by viscose fibres, and secondly, to incline the handle of fabrics in
which the new HSO is used more towards a cotton type handle?.
The HSO fibre has been named Viloft.
I
P b h l Ctuncter Fbx Hemp llunie Jute Yurm
Cellulow (%)
Wax (%)
Ash (96)
77.3
238
1.01
83.21
0.22
2.66
77.7
3.48
0.82
I I I 63.01
0.38
0.68
77.9
. 0.56
0.73
Mest,
Fibre
Single-fibre extension a t
1 (16?74)
Single-fibre externion a t
Ftbre-bundle tenacity
(cN/ tcx) 1 (21?:2.7)
T e density (g/cm3)
A p p a m t density (glcm') 1 0.62
Constituent Percentage
Ash 5,63
Water 10,15
Aq. extract 10.34
Fat and wax 0,59
Cellulose 61,22
Inter-cellular substances and pectins 12,07
-
100.00
Ramie 1 1 1
Flax 4 times less 1,5 times less 1,2 times less
Cotton 8 times less I (same as Ramie) 4 times more
Silk 7 times less 4 times more 6 times more
As a bast fibre, ifflaxis compared with ramie, from the spinning point of
view the following differences can be observed.
Ramie Flax
1. Tensile strength Superior to flax -
2. Cohesiveness - Superior to Ramie
3. Fineness -do- -
4. Uniformity - do-
5. Pliability - do-
The durability of the ramie fibre makes it a very prominent fibre among
cellulosic fibres. After washing 30 times in a fixed percentage of soda and soap,
ramie, flax and cotton yam of the same count show a decrease in tensile
strength to the extent of 6%. 64% and 15%, respective1y91.
(R 1412)
P.I. London
'DcgummedF lbre
Ultimate cells
LengIh (mm)
Breadth ( S m )
L/B ratio
Filaments
Cravimetric fineness (tex)
Tenacity (eNItex)
Extension at break (9%).
Modulus of tarsianal ngidity
(X 10" dyneicm?
Flexural rigidity (dyne/em2)
Tranrvcrw swelling in water (96)
Bundle
Tenacity (cN/tex)
True Density (g/cm3)
Apparent Density (g/cmJ)
Porosity (%)
M a i r t u ~regain at 65% RH
at 100% RH
Ropertin
Relative Lknrity
Tenacity dry
(cN/tex) wet
Elongation dry 25-33
(%) wet
Young's modulus
wmm2 8Nl-I Y
cNjtex 594-89 1
Elastic Recovery at 5%
Elongation (96) 1 95-97
m m Si
Dry tenacity (cN/tex) 31 t o 4 0 26 to 35
Dry elongation (9%) 15 to 25 I5 to 25
Wet tenacity (cN/tex) 28 to 37 19 t o 25
Moisture regain (96) 4,5 to 5.5 9
Relative Dendtv 12 1.33 t o 1.45
'high temperature
.~..
Shrinkaec in heated water (%)
*norditempcratm - -
-
8-9
20-22
-
-
Moist- content (96) 11.0 0.4 0.4
Density (relative) 1.33-1.45 1,385 1.34
Terncity Tenacity
Fibre (cN/tex) (cN/tcx) Mohtvrr =.in (%)
Air dry (65% RH) Wet/W.trr at 65% RH
Silk 36 33 10.0
Cotton 35 39 7.0
Wool 15.5 10.8 17.0
Nylon 6.6 51 44 4.3
POI~CST~~ 50 91 0.4
BmLiog l a r d
Nylon (monofilammt)
linear
m
We=)
42
y
-
SOME PHYSICAL PROPERTIES OF ROPES (DIAMETER 8 mm)
laul
(N)
13230
9410
T e *
(cN/ter)
31,4
T
btio
to
nunim
32
e
Polypropykne 30 31.4 32
Polpthykne
(monafiament) 31.5 6860 21.6 2.2
Manilla 54 5292 9.8 1.0
Sisal 54 4802 8.8 0.9
I - manilla, 2 - -
niaal. 3 polypropylene. 4 - polpthylana. 5 - nylon.
ACRYLIC A N D MODACRYLIC
The most significant advance in acrylic fibres of late has been the
introduction of second-generation bicomponent fibreslD4. Such fibres should
not be confused with biconstituent fibres. A bicomponent fibre is composed of
two derivatives of the same genetic polymer. Biconstituent fibres are composed
of two generically different polymers spun side by side into the same fibre.
First-generation acrylic fibres are crimped by mechanical deformation
followed by heat setting, generally in a stuffer-box type of operation. The crimp
so formed is usually of the planar, semi-permanent zig-zag type. Second-
generation bicoinponent acrylic fibres are composed of two polymers spun side
by side in the same fibres; in some varieties the distribution of the two polymers
is the same in all fibres, in others it is random. Tke two polymers are almost
identical in all respects except thermal properties'".
The crimp development mechanism ismuch thesameas that operatingin
a bi-metallic strip, where, on heating, the two sides expand a t different rates
causing the strip to bend. Whensubjected todry heat, boiling wateror steam, the
two segments comprising each fibre, shrink to different degrees introducing a
helical threedimensionaf permanent crimplM.
The fibre bulk associated with such a crimped acrylic fibreapproximates
to the volume of a cylinder enclosing a helical coil rather than the volume of the
fibre itself. When the distribution of the two polymers within the fibres is
random, there is the additional advantage that the relatively low-crimp fibres
composed of either of the two polymers prevent crimp register and intermeshing
between the fibres of higher crimp, thus promotingmaximum bulk andcoverl".
Owing to large recovery forces, helical, bicomponent crimp resists
deformation more, and recovers more easily from deformation, than
mechanicauy crimped fibresBM.
Bicomponent acrylic fibres were initially developed for piecedyeing end
uses. Historically, crimp wash-out is the principal reason preventing the
production of piecedyed carpet from acrylic fibres. With carpets made from
bicomponent acrylic fibre, virtually aU the crimp washed out duringdyeing b
recnvered in~-~ ~~- .
finishhe. One
- -
nrobfem facine fibre manufacturers is to restrict the
crimp development to a level that will aUow the fibre to be spun without
excessive breakage. With bicomponent fibres, appr'oximatefy75% of the bulk is
F i acrylic lo^
A 1.3 dtex Acrilan Type E l 6 introduced by Monsanto Textiles
obviously falls in the category of replacement-forsotton fibres: Its announced
usage is for topweight broadwovens and f i n e a t knits.
The spin limit of the new staple is rated at 10 tex. This may be contrasted
with a limit of 24texfor 3,3dtexacrylics. Asidefromcharacteristic acrylic hand,
lustre and easy-care performance, the 1,3 dtex Acrilan yams spun 100%and in
blends permit manufacture of fme-cut single knitsforshirts, blousesand dresses;
fine-xt interlock and double knit for sportswear, shirts and blouses; and
lightweight broadwovens for shirts, blouses and dresses. These are spring and
summer products.
A 12 tex yam spun from the 1,3 dtex fibre has a skein break factor of
2273, a 24% elongation, and exhibits boiling water shrinkage of 6,0%105.
T-%2F
Physbl Ropntr Unit (32dtex)
Tenacity '33.6
Elongation 33.0
Number of Crimps 4.3 (8.7)
Demee of C r i m ~ l5,O (26,O)
shhn~agcin Bdiling
Water 3.0
Relative Density 1.17 1.17 1.17
Moist- Regain 2.0 2.0 20
Lustre Bright Bright Bright
Linear density 3.3 5,6 5,6
Fibre Lenmh 102 102 102
NOTE: the figure in parenthesis denotes the value after treatment in boiling water
Differential calorimetry
Ran- 80.2-108 76.3-105 %I09
Mean 94.2 91 94.5
Dilatometry 90 87 93
NYLON
TE"= Constant
TEMPERATURE ("CJ
Hamopolymtt Copolymer
Strength loss (%) 20 80
Mass lass (%) II 70
RV l a 0 0
1 1
NYLON, NYLON 6.6 AND A POLYESTER"'
Relative density - M
.:: 33:14
Interlace 5 to 10 cm 6 to 19
Elongation (%) M to 35 25 to 45
Tenacity (cN/ tex) 26.5 to M 44 to 53
Modulus (cNItex)
Chemical Resistance
Acid (IWr93'0 Insoluble Solvbk ~blsolublc
Alkali (40-Wr93T) Insoluble lasolvblc Solubk
Cotour ('b" MI~c) +
1.0 + TO f 0.8
Dye Raponvs
TYW Dir- Acid Di- Acid %perr~
Carrier Ycs No Ycs
Softening Point
Melting Point
Modulus a t 65% RH-2OOC (cN/tex)
Modulus a t 93% RH-21°C (=Nitex)
Modulus a t 93% RH-149°C (cN/tex)
Relative Density
Moirturt Regain
Tenacitv (cN1te.x)
SETTING CONDITIONS"5
Nylon is generally set before dyeing and polyester after dyeing since the
carrier and high temperature dyeing generally override much of the effect of
presetting.
Some properties of different polyamides (nylons) are given in the table
below"7:
Nylon 6.6 4%
Nylon 6 4,5%
Nylon 4 7 to 8%
- Nylon and PETfibre properties and responses are surprisingly similar when
measured in the absence of moisture.
- Water is a potent carrier for nylon.
- Water, a t least by itself, is not an effective carrier for PET.
- Water provides "chemical energy" which is equivalent to about 1 W C of
thermal energy in its effects on a variety of nylon fitre properties.
- The dyeing of nylon in water is equivalent to dyeing polyester in 10%
camer i.e. solvent dyeing.
W Dry H a t SbrinL.g
Y8rn I dtcx lWC 17PC 1%-C
Nylon
Nylon
Nylon 4.6
Nylon 4.6 6.2
Nylon 1.9 3.1
Nylon 0.5 0.9 1.6
Polyester 1111 3.1 4.5 5.9
Polyester 1111 3.1 5,l
Polyester 1111 10.0 14.0 18.0
Polyester 1222 8,8 11.9 14.5
Polyester 933 12.7 14.0 15.8
*Boil-off Shrinkage
Water meets this criterion for nylon. The shrinkage of a range of nylon
fibres in water at 100°C is virtually identical to the dry heat shrinkage of the
same yams at 196°C. The data again shows that water has very little chemical
energy effect on PET, equivalent to only about 10-20°C of thermal energy (see
above table).
In air, nyldn 6.6 melts at about 250-2S0 C. In water, it "melts-at about
160-170°C. Thus water again provides chemical energy equivalent to about
100°C of thermal energy. Data for polyester were not available.
Humidity reduces WE (work to elongate) for nylon from 16.8 in air (8%
RH) to 3.5 cN cmltex cm x 100) in water a t 21°C. In dry air, atemperature of
about 13WC is required to reduce WE to 3 5 Thus water provides the chemical
energy equivalent of at least l W C of thermal energy. Water has little effect on
WE for PET :21.2 in air and 21.1 in water at 21°C. The WE for polyesterand
nylon in dry air are equivalent to IM°C, indicating again that nylon and PET
behaviour is similar when properties are measured in the absence of moisture.
Water reduces the stress value for nylon from 7.9 (cN/tex) in air at 8%
RH to 2.6 (cN1tex) at 21°C in water. There is no effect on polyester: 9.7 in air
and 9,7 in water. In dry air, about 1 W C is necessary to reduce stress to the 2.6
value obtained in water at 2I0C. Again, the value for PET in air is virtually
identical to that of nylon above about IW0C, where residual moisture would be
negligible.
The dependence of fibre properties on temperature is a general
characteristic of polymers. As temperature rises, interchain distances increase.
Strength (cN/tex)
Elongation at Break (%)
Yield point (eN/tex)
Initial modulus (cN/tex)
Crvstalline Orientation
G o strength Temp (OC) 233-235
I 230-U2
R . Y ~
ROP* bi-componnt
C-311
Tensile strength (cN!tex) 28.2
Tensile strrngth (wet) (cN/tex) 26,s
Uongation, dry (%) 11.0
Elongation, run (%) 14.0
The melting points do not vary much and usually have a value
intermediate between those of the components. For example melting point of
Orlon T-21 is 250°C while that of ordinary Orlon is 255°C. Information is now
available about the bi-component thermal-bonding fibre being introduced into
various international markets by Chisso Polypro F~berCo.135.
There are significant differences between the Japanese fibre and the
heterofd fibres produced by ICI Fibres. The latter have a sheath-core
configuration, whereas it is understood that the Chisso items have a basically
round crosssection formed by a core of polypropylene 'capped' for a large
proportion of the circumferenrx by a layer of polyethylene (see diagram right'35.:
WATEPSOLUBLE FIBRES
GENERAL PHYSICAL PROPERTIES OF SOLVRON
(WATER-SOLUBLE POLYVINYL ALCOHOL FIBRE)ln
- - --
Tspc
Row*
SH SM SL SX
SL 55-65
Staple SX 45-3
SS 10-15
-I
APPLICABILITY OF VARIOUS FIBRES TO TRANSFER PRINTING123
ckaiitiaa I Sdtcning
Point 'C
Dicel (Courtaulds)
Trice1 (Courtaulds)
Tricelon (Courtaulds)
Courtelle Standard (Courtaulds)
Courtelle RR (Courtaulds)
Acrilan (Monsanto)
Orlon 42 (Du Pont)
Nomex (Du Pont)
Polyester (I C I)
Polyester/cotton: 70130 and 80/20
Lirelle (Courtaulds-polyester)
Spectran (Monsanto-polyester)
Polyester/ Lycra (Du Pont)
Celon (Courtautds-nylon 6)
Ultron (Monsanto-nylon)
Qiana (Du Pont)
Nylon 6.6/Lycra (Du Pont)
Dacron/ wool (Du Pont)
Polyester/cotton: 'Koratron' sensitised
Self-extinguishing Fibre S.E.F. (Monsanto)
Basic dyeable Dacron Type 65 (Du Pont)
Teklao (Courtaulds)
Aluminium-anodised
The temperatures and times are approximate and depend upon the fabrication
of the material.
Printing times ranges bet- 60and 120 seconds and even up to 5 min
Lycra/nylon 170°C-185°C
Lycralpolyester 18WC-190°C
Lycral Qiana 195°C-2050C
C O N D I T I O N S O F APPLICATION: GENERAL G U I D E O F
RECOMMENDED TEMPERATURES AND TIMES FOR TRANSFER
PRINTING128
Secondary acetate
T-rate
Nylon 6
Nylon 6.6
Acrylic
Polyester
Polyntcr-wool
Polycster~Uulaic
Triacztate-nyhn hetero
Nylon hevrol nylon typc 472
& 473 (Qiana)
-- -
2 90
Fine Order
E-
1
Tnnnition
111
Y1
Y 9 -
t
is
$
09 -
1
M 108 150 201 250
TEMPERATURE ( C )
Listed below are the times and temperatures required for the various
machines together with the thermos01 temperatures for the BASF Palanil and
Cottestren dyestuffs. Dyestuffs selection: For polyester /cellulosic blends, as the
polyester is almost always dyed with dispersed dyestuffs it is predecided, whilst
the most important dyestuff groups for the ceUulosic component are:
1. Vat dyestuffs
2. Sulphur dyestuffs
3. Reactive dyestuffs
1
Temp. ' C Time (s) Temp. OC T i e (I)
Hot air (stenter)
(Hot-flue. hfM-unit ) ~ ~ 2 1 5 6&30 215-221, 6030
Hot air conact
(Reinner RT-range) 2 W 2 15 45-20 2 15-225 4sm
Conact (cylinder) 215 15-30 22&225 1 S30
HEAT SETTING
Some heat setting details are given below for various fibre types'Jt:
I Hydrwsetting
on beams
1 125-130°C
15-20 min
1 125-130°C
15-30 min
125-130°C
15-30 min I -
Saturated rteam-setting 125-130°C 125-130°C 125-130°C
2.5-3 bar 25-3 bar 2.5-3-bar
15-30 min
Heat-setting
Stenter
Flbre
Hot water
Temp.
' Saturated steam
Temp. Reasure
-
rime
I Hot alr
Temp.
Infn-red
selective
emitter
- - - -
- - - 2 10-230
- - - 180-200
Y ! W l iapun
8u!(oo~pus m e m u! t u ~ u t a n sIn11
""'r .;lpun
PBOI ou r w n 3 . o ~ SU!IOOJpus J ~ D Ii s i ~ Bu!u!srls
p (!!I
1 8 q s r q i l p m buy em^ pto, 8u!u!ws (1) uqg qln~.uo[AmA(nd IU~A(O~-J!I~~~U&
Y!UII
5.081 0 ) 8u!,aw i3PUn lU!looJ Pus 3.081 18 8"!"!WlS I!')
LAPBu!u!ws (!) 31~1a19pOrolnlllJ
Y!WS
p0
.1 OY lop"" a u ! ~ l r f i dopun 8u!Llp puw 8 n Bu!u!n~.lls (!!I
LP
I B"!U!SJlS I!) "0i.1 .SO,S!A p,mu,as:
"!.,IS.,pun au!L,p
P0.1 OU I3PY" SY!113M PYU 13m BY!U!BJVAq I U " O U @ II8U9 A'% 1815
u w m rrpun B u ! i ~ ppun m
n L!u!.ns (!I)
p-1 ou l r p u n a u ! n a ~ Arp .IY!O~ p y A omq. ~Y!Y!UIS (1) IODM lunlll
Softening
temp.
"C
Polyamide'6.6 235
Polyamide 6 170
Polyester 230-240
Polypropylene IM-155
Polyacrilonibile 235-350
Adheres at
2 q c
175-190
REFERENCES
WOL 47
P u b l M by
South *I&-W d lad Text& Raarth Imtitmle
P.O. Box 1124 Port UinM, h r h *Irk=.
lad pint& ia tbe Republic d Swtb Africa
by P.U.D. Rcpm (Ry) L I P P.O. Ear 44. Dnp.trL