Page # 16 STOICHIOMETRY - II

Class Room Problems

1. A volume of 12.53 ml of 0.051 M SeO2 reacts
Sol.
exactly with 25.5 ml of 0.1 M CrSO4 which is
oxidised to Cr3+. To what oxidation state was the
selenium converted by the reaction.
Sol.

2. In basic solution CrO42– ion oxidises S2O32– ion to

form Cr(OH)4 – and SO42– ions respectively. How
many ml of 0.154 Na2CrO4 solution are required
just to react with 40 ml of 0.246 M Na2S2 O3
5. 25 ml of 0.17 M HSO3– in strongly acidic solution
solution.
required the addition of 16.9 ml of 0.01 M MnO4–
Sol.
for its complete oxidation to SO42 –. In neutral
solution it requires 28.6 ml. Assign oxidation no.
of 'Mn' in each of the products.

Sol.

3. What mass of N2H4 can be oxidised to N2 by 24

gm of K2CrO4 which is reduced to [Cr(OH)4]–.
Sol.

6. A given amount of Fe2+ is oxidised by x mol of

MnO4– in acidic medium. Calculate mol of Cr2O72–
required same amount of Fe2+ in acidic medium
Sol.

4. The ion An+ is oxidised to AO3– by MnO4– changing

to Mn2+ in acid medium. Given that 2.68 ×10–3
mole of An+ required 1.61 ×10–3 mole of MnO4–.
What is the value of n.

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 STOICHIOMETRY - II Page # 17

9. 5.5 gm of a mixture of FeSO4. 7H2O and Fe2(SO4)3.

9H2O requires 5.4 ml of 0.1 N KMnO4 solution for
complete oxidation. Calculate the no. of gm moles
of hydrated ferric sulphate in the mixture?
Sol.

7. Calculate mol of (a) MnO4– and (b) Cr2O72– to

oxidase 1 mol of FeC2O4 (ferrous oxalate) in acidic 10. 19.6 g m of ferrous amm oni um sul p hate
medium. [FeSO4(NH4)2SO4.6H2O] were dissolved and made
Sol. up to 500 ml with acidified water. 25 ml of this
solution required 20 ml and 27.5 ml of the solution
A and B of KMnO4 respectively. How many ml of A
must be added to 1 litre of B to make N/10 KMnO4
solution.
Sol.

8. A mixture of Na2C2O4 and KHC2O4. H2C2O4 required 11. 0.5 gm of an oxalate was dissolved in water and
equal volume of 0.1 M KMnO4 and 0.1 M NaOH the solution raised to 100 ml. 10 ml of this solution
separately. What is the molar ratio of Na2C2O4 and when titrated with N/20 KMnO4 required 10 ml of
KHC2O4. H2C2O4 in the mixture? KMnO4. Calculate the % of oxalate ion in the
Sol. sample.
(K = 39, Mn = 55)
Sol.

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 Page # 18 STOICHIOMETRY - II

12. Hydroxylamine reduced iron (+3) according to eq. out the mole ratio of Cu++ and C2O42– in the compound.
2NH2OH + 4Fe+++ → N2O(g) + H2O + 4Fe++ + 4H+. Sol.
Iron (+2) thus produced is estimated by titration
with a standard solution of permagnate. The
reaction is MnO4– + 5Fe++ + 8H+ → Mn2+ + 5Fe+++
+ 4H2O. A 10 ml solution of hydroxylamine solution
was diluted to 1 litre 50 ml of this solution was
boiled with an excess of iron (+3) solution. The
resulting solution required 10 ml of 0.02 M KMnO4
solution for complete oxidation or iron (+2).
Calculate the weight of hydroxylamine in one litre
of the original solution.

Sol.

15. 2.180 gram of a sample contains a mixture of XO

and X2O3 which are completely oxidised to XO4– by
0.015 mole of K2Cr2O7. Calculate the atomic weight
of X, if 0.0187 mole XO4– is formed.
Sol.

13. A 10 gm mixture of Cu2S and CuS was treated

with 200 ml of 0.75 M MnO4– in acid solution,
producing SO2, Cu2+ and Mn2+. The SO2 was boiled
off and the excess of MnO4– was titrated with
175 ml of 01.0 M Fe2+ solution. Calculate the %
CuS in the original solution.
Sol.

16. 5 ml 8N HNO3, 4.8 ml of 5N HCl, 1.4 gm of NaOH

and a certain volume of 17 M H2SO4 are mixed
together and made upto 2 litres. 50 ml of this
solution exactly neutralized 32.9 ml of barium
hydroxide solution containing 2.21 gm of Ba(OH)2,
8H2O in 100 ml of solution. Calculate (a) the volume
H2SO4 used (b) The amount in grams of sulphate
ion in the solution.
Sol.

14. A solution of 0.2 gm of a compound containing

Cu2+ and C2O42– ions on titration with 0.02 M KMnO4
in presence of H2SO4 consume 22.6 ml of the
oxidant. The resultant solution is neutralized with
Na2CO3, acidified with dilute acetic acid and treated
with excess KI. The liberated I2 required 11.3 ml of
0.05 M Na2S2O3 solution for complete reduction. Find

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 STOICHIOMETRY - II Page # 19

17. A polyvalent metal weighing 0.1 gm and having Sol.

at. wt. 51 reacted with dil. H2SO4 to give 43.9 ml
of hydrogen at S.T.P. The solution containing the
metal in this lower oxidation state, was found to
require 58.8 ml of 0.1 N permagnate for complete
oxidation. What are the valencies of the metal.

Sol.

20. A 6.0 gm sample contained Fe3O4, Fe2O3 and inert

materials. It was treated with an excess of KI in
acid, which reduced all iron to Fe2+. The resulting
18. A sample of ferrous sulphate and ferrous oxalate solution was diluted to 50 ml, and a 10 ml sample
was dissolved in dil. H2SO4. The compete oxidation of it was taken. The liberated iodine in the small
of reaction mixture require 40 ml of N/15 KMnO4. sample was titrated with 5.5 ml of 1M Na2S2O3
After the oxidation the reaction mixture was solution yielding S4O62–. The iodine from another
reduced by zn and H2SO4. On again oxidation by 25 ml sample was extracted, after which the Fe2+
same KMnO4 25 ml of KMnO4 was required. was titrated with 3.2 ml of 1.0 M MnO4– in H2SO4
Calculate the ratio of Fe atoms in ferrous sulphate solution. Calculate the percentage of Fe3O4 and
and oxalate. Fe2O3, in the original mixture.
Sol. Sol.

21. 0.1 M KMnO4 solution completely reacts with 0.05

M FeSO4 solution under acidic conditions. The
volume of FeSO4 used is 25 ml. What volume of
KMnO4 was used?
Sol.

19. A sample of Fe2(SO4)3 and FeC2O4 was dissolved

in dil H2SO4. The complete oxidation of reaction
mixture req. 40 ml of N/16 KMnO4. After the
oxidation mixture was reduced by Zn and dil.
H2SO4. On again oxidation by same KMnO4, 60 ml
were require. Calculate the ratio of millimoles of
Fe2(SO4)3 and FeC2O4 in mixture.

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 Page # 20 STOICHIOMETRY - II

22. 20 g of a sample of Ba(OH)2 is dissolved in 50 ml. 25. A solution containing 2.68 ×10–3 moles of An+ ions
of 0.1 N HCl solution. The excess of HCl was titrated requires 1.61 ×10–3 moles of MNO4 – for the
with 0.1 N NaOH. The volume of NaOH used was complete oxidation of An+ to AO3– in acidic medium.
20cc. Calculate the % Ba(OH)2 in the sample. What is the value of n?
Sol. Sol.

23. 1 solution contains a mixture of Na2CO3 and NaOH. 26. (i) What is the mas of sodium bromate and the
Using phenolphthalein as indicator. 25ml. of mixture solution necessary to prepare 85.5 mL of 0.672 N
required 19.5 ml. of 0.995 N HCl for the end point. solution when the half cell reaction is BrO3– + 56H+
With methyl orange. 25ml. of solution required 25 + 6e– → Br– + 3H2O.
ml. of the same. HCl for the point. Calculate grams (ii) What would be the mass as well as molarity if
per litre of each substance in the mixture. the half cell reaction .
Sol. 2BrO3– + 12H+ + 10e– → Br2 + 6H2O
Sol.

24. 5.7 g of bleaching powder was suspended in 500

ml. of water. 25 ml. of this solution on treatment
with KI in the presence of HCl liberated iodine
which reacted with 24.35 ml. of N/10 Na2S2O3.
Calculate the % of 'available' chlorine in the
bleaching powder.
Sol. 27. A mixture of H2C2O4 (oxalic acid) and NaHC2O4
was dissolved in water and the solution made upto
one litre. Ten milliliters of the solution required
3.0 mL of 0.1 N sodium hydroxide solution for
complete neutralization. In another experiment
10.0 mL of the same solution, in hot dilute sulphuric
acid medium, required 4.0 mL of 0.1 N KMnO4
solution for complete reaction. Calculate the
masses of H2C2O4 and NaHC2O4 in the mixture.
Sol.

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 STOICHIOMETRY - II Page # 21

30. A solution contains Na2CO3 and NaHCO3 20 cm3 of

28. A solution of 0.2 g of a compound containing Cu +2
this solution requires 5.0 cm3 of 0.1 M H2SO4
and C2O4–2 ions an titration with 0.02 M KMnO4 in solution for neutralization using phenolphthalein
presence of H2 SO4 consumes 22.6 mL of the as the indicator. Methylorange is then added when
oxidant. The resultant solution is neutralized with a further 5.0 cm3 of 0.2 M H2SO4 was required.
Na2CO3, acidified with dilute acetic acid and treated Calculate the masses of Na2CO3 and NaHCO3 in 1
with excess KI. The liberated iodine requires 11.3 L of this solution.
mL of 0.05 N Na2 S2 O3 solution for complete Sol.
reduction. Find out the mole ratio of Cu+2 to C2O4–
2
in the compound. Write down the balanced redox
reactions involved in the above titration.
Sol.

31. A 50.0 cm3 portion of a mixture of H2SO4 and

H2C2O4 required 48.9 cm3 of 0.15 M NaOH solution
for titration. Another 50 cm3 required 38.9 cm3 of
0.10 N KMnO4 solution for titration. Calculate the
masses of H2SO4 and H2C2O4 present per dm3 of
the solution.
Sol.

29. A 2.0 g sample of a mixture containing sodium

carbonate, sodium bicarbonate and sodium
sulphate is heated till the evolution of CO2 ceases.
The volume of CO2 at 750 mm Hg pressure and at
298 K is measured to be 123.9 ml. A 1.5 g of the
sample requires 150 mL of M/10 HCl for complete
neutral i zati on. cal cul ate the percentage
composition of the components of the mixture.

Sol.

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 Page # 22 STOICHIOMETRY - II

Exercise - I (Only one option is correct)

1. The equivalent weight of MnSO4 is half its
molecular weight when it is converted to :
(A) Mn2O3 (B) MnO2
(C) MnO 4
–
(D) MnO42– 5. 20 ml of 0.1 M solution of metal ion reaCteD with
Sol. 20 ml of 0.1 M SO2 solution. SO2 reacted according
to the equation. SO2 + 2H2O → SO42– + 4H+_ + 2e–
. If the oxidation no. of metal ion was +3, the
new oxidation number of the metal would be:
(A) 0 (B) +1
(C) +2 (D) None of these
2. Given the equation S2O82– + 2e– → 2SO42– , Mn2+
+ 4H2O → MnO4– + 8H+ + 5e– . How many moles of Sol.
S2O82– ions are require to oxiDes 1 mole of Mn2+:
(A) 0.4 (B) 0.5
(C) 2.5 (D) 1.0
Sol.

6. How many ml of 0.150 M Na2CrO4 will be required

to oxidize 40 ml of 0.5 M Na2S2O3.
CrO42– + S2O32– → Cr(OH)4– + SO42–.
(A) 225 ml (B) 355 ml
3. A solution of 10 ml 0.1 M FeSO4 was titrated with
(C) 455 ml (D) 555 ml
KMnO4 solution in acidic medium. The amount of
KMnO4 used will be: Sol.
(A) 5 ml of 0.1 M (B) 10 ml of 0.1 M
(C) 10 ml of 0.5 M (D) 10 ml of 0.02 M
Sol.

7. Number of moles of electrons take up when 1

mole of NO3– ions is reduced to 1 mole of NH2OH
is:
(A) 2 (B) 4
4. NH2OH reacts with ferric sulphate as follows :
(C) 5 (D) 6
2NH2OH + 4 Fe3+ → N2O + H2O + 4 Fe2+ 4H+. The
eq. wt. of NH2OH in this reaction is : Sol.
(A) (mol. wt.)/1 (B) (mol.wt.)/2
(C) (mol.wt.)/3 (D) (mol.wt.)/4
Sol.

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 STOICHIOMETRY - II Page # 23

8. The number of moles of thiosulphate (S2O32–) that Sol.

will required to react completely with one mole I2 in
alkaline medium (where it gets oxidised to SO42–) is :
(A) 1/4 (B) 4
(C) 8 (D) 1/8
Sol.

12. In a reaction 4 moles of electron are transferred

to one mole of HNO3. When acted as an oxidant.
The possible reduction product is :
(A) 1/2 mole of N2 (B) 1/2 mole of N2O
(C) 1 mole of NO2 (D) 1 mole of NH3
9. The number of moles of oxal ate KHC 2 O 4 .
H2C2O4.2H2O oxidised by one mole of permanganate Sol.
ion is:
(A) 3/4 (B) 1
(C) 5/4 (D) 6/4
Sol.

13. One mole of N2H4 loses ten moles of electrons to

from a new Compound y. Assuming that all the
nitrogen appears in the new compound. What is
10. How many equivalents are there per mol of H2S in
the oxidation state of nitrogen in y. There is no
its oxidation to SO2 ?
change in the oxidation state of hydrogen:
(A) 2 (B) 4
(A) –1 (B) –3
(C) 6 (D) 8
(C) + 3 (D) +5
Sol.
Sol.

11. 3 mol of a mixture of FeSO4 and Fe2(SO4)3 required

100 mL of 2M KMnO4 solution is acidic medium .
14. 1 g equiv of a substance is the weight of that
Hence mol fraction of FeSO4 in the mixture is:
amount of a substance which is equivalent to :
(A) 1/3 (B) 2/3
(A) 0.25 mol of O2 (B) 0.50 mol of O2
(C) 2/5 (D) 3/5
(C) 1 mol of O2 (D) 8 mol of O2

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 Page # 24 STOICHIOMETRY - II

Sol. 18. In the following reaction (unbalanced), equivalent

wt. of As2S3 is related to molecular wt. M By:
As2S3 + H+ NO3– → NO + H2O + AsO43– + SO42–
(A) M/2 (B) M/4
(C) M/28 (D) M/24
Sol.

15. Which of the following changes requires reducing

agent?
(A) CrO42– → Cr2O72– (B) BrO3– → BrO–
(C) H2AO3 → HAsO42– (D) Al(OH)3 → Al(OH)4–
Sol.

19. Mass of KHC2O4 (potassium acid oxalate) required

to reduce 100 mL of 0.02 M KMnO4 in acidic medium
(to Mn2+) is x g, and to neutralise 100 mL of 0.05
M Ca(OH)2 is y g then :
(A) x = y (B) 2x = y
16. Which of the following is a disproportonation
reaction? (C) x = 2y (D) None is CorreCt
(A) CaCO3 + 2H+ → Ca2+ + H2O + CO2 Sol.
(B) 2CrO42– + 2H+ → Cr2O72+ + H2O
(C) Cr2O42– + 2OH– → 2CrO42– + H2O
(D) Cu2O + 2H+ → Cu + Cu2+ + H2O
Sol.

20. 100 mL of 1 M KMnO4 oxidised 100 mL of H2O2 in

17. If equal volumes of 1M KMnO4 and 1M K2Cr2O7 acidic medium (when MnO4– is reduced to Mn2+) ;
solutions are allowed to oxidise Fe2+ in acidic volume of same KMnO4 required to oxidise 100 mL
medium. of H2O2 in basic medium (when MnO4– is reduced
to MnO2) will be:
The amount of iron oxidised will Be :
(A) (100/3) mL (B) (500/3) mL
(A) more by KMnO4 solution
(C) (300/5 ) mL (D) 100 mL
(B) more by K2Cr2O7 solution
Sol.
(C) equal in both the cases
(D) cannot be determined
Sol.

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 STOICHIOMETRY - II Page # 25

21. 1 mol of ferric oxalate is oxidised by x mol of 25. 10.78 g of H3PO4 in 550 mL solution is 0.40 N.
MnO4– and also 1 mol of ferrous oxalate is oxidised Thus this acid:
By y mol of MnO4– in acidic medium. The ratio (x/
(A) has been neutralised to HPO42–
y) is:
(B) has been neutralised to PO43–
(A) 2 : 1 (B) 1 : 2
(C) 3 : 1 (D) 1 : 3 (C) has been reduced to HPO32–

Sol. (D) has been neutralised to H2PO4–

Sol.

22. 0.7 gm of Na2CO3.xH2O is dissolved in 100 ml, 20

ml of which required 19.8 ml of 0.1 N HCl. The 26. When 0.75 gm of a substance was kjeldalised, it
value of x is: produced NH3. Which neutralizes 30 ml of 0.25 N
sulphuric acid. The percentage of nitrogen in the
(A) 4 (B) 3
organic compound is :
(C) 2 (D) 1
(A) 14 (B) 11
Sol.
(C) 1 (D) None
Sol.

23. A metal is burnt in oxygen and all the products

of combustion are weighed. It is found that the
wt. of the metal seems to have increased by 24%.
The equivalent wt. of the above metal. 27. 15 mol of KMnO4 are treated with excess H2C2O4
in H2SO4 medium. How many moles of CO2 will be
(A) 25 (B) 24 formed and how many moles of H2C2O4 will be
(C) 33.34 (D) 76 consumed?
Sol. (A) 75, 37, 5. (B) 3, 15
(C) 3, 6 (D) 75, 150
Sol.

24. When one gm mole of KMnO4 reacts with HCl, the

volume of chlorine liberated at NTP will be:
(A) 11.2 litre (B) 22.4 litre 28. An equimolar mixture of NaHC2O4 and H2C2O4
consumes 20 ml 0.3 M NaOH solution for complete
(C) 44.8 litre (D) 56.0 litre
neutralization. The same mixture requires V ml.
Sol. 0.05 M KMnO4 solution in acidic medium for
oxidation.
The value of V is :
(A) 160 ml (B) 32 ml
(C) 24 ml (D) None of these

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 Page # 26 STOICHIOMETRY - II

Sol. Question No. 33 to 35 (3 questions)

A steel sample is to be analysed for Cr and Mn
simultaneously. By suitable treatment Cr is oxidized
as Cr2O72– and the Mn to MnO4–.
Cr → Cr2O72–
Mn → MnO4–
A 10 gm sample of steel is used to produce 250.0
mL of a solution containing Cr2O72– and MnO4–. A
10 mL portion of this solution is added to a BaCl2
solution and by proper adjustment of the acidity,
the chromium is completely precipitated as BaCrO4
Question No. 29 to 32 (4 questions)
; 0.0549 g is obtained.
30cc of a solution containing 9.15 gm of salt KxHY
2– H⊕
(C2O4)z. nH2O per litre required 27cc of 0.12 N Cr2 O7 → BaCrO 4

NaOH for neutralization. The same quantity of
A second 10 mL portion of this solution requires
solution was also found to require 36cc of 0.12 N
exactly 15.95 mL of 0.0750 M standard Fe2+
KMnO4 solution for complete oxidation.
solution for its titration (in acid solution)
29. What is the value of X
33. % of chromium in the steel sample
(A) 1 (B) 2
(A) 1.496 (B) 2.82
(C) 3 (D) 4
(C) 1.96 (D) 5
Sol.
Sol.

30. What is the value of Y

(A) 4 (B) 3
(C) 2 (D) 1 34. Equivalent of Fe2+ required for reduction of MnO4– is
Sol. (A) 5.44 × 10–4 (B) 0.544 × 10–2
(C) 1.196 × 10–3 (D) 11.96 × 10–4
Sol.

31. What is the value of Z

(A) 4 (B) 1
(C) 2 (D) 3
Sol. 35. Amount of BaCl2 required for conversion of Cr2O72–
to BaCrO4 in steel sample
(A) 0.045 (B) 0.0549
(C) 1.125 (D) 2.82
32. What is the value of n Sol.
(A) 4 (B) 3
(C) 1 (D) 2
Sol.

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 STOICHIOMETRY - II Page # 27

Question No. 36 to 38 (3 questions)

25 ml from a stock solution containing NaHCO3
and Na2CO3 was diluted to 250 ml with CO2 free
distilled water. 25 ml of the diluted solution when
titrated with 0.12 M HCl required 8 ml., when
phenolphthalein was used as an indicator.

HPh
Na2CO3 + HCl  → NaHCO3 Question No. 39 to 41 (3 questions)

When 20 ml of diluted solution was titrated with 1.16 g CH3(CH2)n COOH was burnt in excess air
same acid it required 18 ml when methlyorange and the resultant gases (CO2 and H2O) were passed
was used as an indicator. through excess NaOH solution. The resulting
solution was divided in two equal parts. One part
Na2CO3 + 2HCl MeOH
→ 2NaCl + H2O + CO2 requires 50 mL of 1 N HCl for neutralization using
phenolphthalein as indicator. Another part required
MeOH
NaHCO3 + HCl  
→ NaCl + H2O + CO2 80 mL of 1 N HCl for neutralization using methyl
orange as indicator.
36. Concentration of NaHCO3 in gm/lit.
39. Produced mole of the CO2
(A) 0.312 (B) 2.62
(A) 0.1 (B) 0.01
(C) 3.12 (D) 26.208
(C) 0.06 (D) None of these
Sol.
Sol.

40. What is the value of n

37. Amount of NaOH that should be added to convert (A) 4 (B) 3
all bicarbonate into carbonate in 100 ml stock (C) 2 (D) 1
solution
Sol.
(A) 1.248 gm (B) 0.312 gm
(C) 3.12 × 10–2 gm (D) 7.8 × 10–3 gm
Sol.

41. Amount of excess NaOH solution taken initially.

(A) 3.2 gm (B) 6.4 gm
(C) 1.2 gm (D) None of these
Sol.
38. Millimoles of NaHCO3 present in stock solution
(A) 0.624 (B) 2.16
(C) 1.536 (D) 7.8
Sol.

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 Page # 28 STOICHIOMETRY - II

Exercise - II (One or more than one option correct)

1. In the titration of K2Cr2O7 and ferrous sulphate, 5. 27 g of Al will react completely with
following data is obtained: V1 ml of 1.0 M1 K2Cr2O7
(A) 24 g of O2 (B) 0.75 mole of O2
requires V2 ml of 1.0 M2 FeSO4. Which of the
(C) 16.8 L of O2 at STP (D) 1 mole of O2
following relations is/are true for the above
titration ? Sol.
(A) 6 M1V1 = M2V2 (B) M1V1 = 6 M2V2
(C) N1V1 = N2V2 (D) M1V1 = M2V2
Sol.

6. 10.78 g of H3PO4 in 550 ml solution is 0.40 N.

Thus this acid
(A) has been neutralized to HPO42–
2. Cr2O72− is reduced to Cr3+ by Fe2+. Identify the
(B) has been neutralized to PO43–
incorrect statement from the following : (C) has been reduced to HPO32–
(A) 6 moles of Fe2+ are oxidised to Fe3+ ions. (D) has been neutralized to H2PO4–
(B) The solution becomes yellow Sol.
(C) The solution becomes green
(D) 3 moles of Fe2+ get oxidised to Fe3+
Sol.

7. Which of the following contains equal number of

3. 15 g of KMnO4 in acidic medium equal to atoms ?
(A) 0.095 moles (A) 11.2 ml of N2 and 0.015 g of nitric oxide
(B) 0.477 g equivalents (B) 22.4 L of nitrous oxide and 22.4 L of CO2
(C) 9.54 L of 0.05 N KMnO4 (C) 1 mole of HCl and 0.5 mole of H2S
(D) 10 ml of 0.05 M KMnO4 (D) 1 mole of H2O2 and 1 mole of H2SO4
Sol. Sol.

4. Which of the following statements are correct ?

(A) One mole of Cl2 means 8 equivalents of chlorine 8. When 100 ml of 0.1 M KNO3, 400 ml of 0.2 M HCl
and 500 ml of 0.3 M H2SO4 are mixed. Then in the
when Cl2 → Cl– + ClO−4 resulting solution
(B) One mole of Cl2 means 6 equivalents of chlorine (A) The molarity of K+ = 0.01 M
when Cl2 → Cl– + ClO−4 (B) The molarity of SO24− = 0.15 M
(C) When one mole of As2S3 is oxidised to As2O5 + (C) The molarity of H+ = 0.38 M
SO2 then it mean 22 equivalents of As2S3 are (D) The molarity of NO3– = 0.08 M and Cl– = 0.01 M
oxidised. Sol.
(D) The equivalent weight of As2S3 is always = mol.
wt./22.
Sol.

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 STOICHIOMETRY - II Page # 29

9. A 110 % sample of oleum contains 13. 10 g mixture of KI and NaClO3 treated with 200
(A) 44.4% of SO3
N
(B) 55.6% of sulphuric acid cc HCl gives a gas which absorbes in 40 ml of
10
(C) 55.6% of SO3
(D) 44.4% of sulphuric acid sodium thiosulphate solution. Then the correct
Sol. statement is/are
(A) equivalent weight of iodine in the reaction is M/2
(B) percentage of KI in the mixture is 66.4%
(C) sodium thiosulphate converted into Na2S4O6.
(D) percentage of NaClO3 is 66.4%
Sol.
10. A mixture of 1 mole each of FeSO4 and FeC2O4
are taken then :
(A) nmoles of KMnO4 required to oxidise Fe2+ to
Fe3+ in acidic medium is 0.4
(B) nmoles of KMnO4 required to oxidise SO 24− is 6/5
(C) nmoles of KMnO4 required to oxidise oxalate 14. H2C2O4 and NaHC2O4 behave as acids as well as
ion is 0.4 red uci ng ag ent s. Whi c h i s/are c orrec t
(D) The total number of moles of KMnO4 required statement(s) ?
to completely oxidise the mixture is 0.8 (A) Equivalent wt. of H2C2O4 and NaHC2O4 are
Sol. equal to their molecular weights when behaving
as reducing agent
(B) 100 ml of 1 N solution of each is neutralised
by equal volumes of 1 M Ca(OH)2
(C) 100 ml of 1 N solution of each is neutralised
by equal volumes of 1 N Ca(OH)2
11. 100 ml of 0.06 M Ca(NO3)2 is added to 50 ml of
(D) 100 ml of 1 M solution of each is oxidised by
0.06 M Na2C2O4. After the reaction is complete
equal volumes of 1 M KMnO4
(A) 0.003 moles of calcium oxalate will get
precipitated Sol.
(B) 0.003 M of excess of Ca2+ will remain in
excess
(C) Na2C2O4 is limiting reagent.
(D) Ca(NO3)2 is excess reagent.
Sol.

15. 100 ml of 0.15 N H2O2 is completely oxidized by

(A) 150 ml of 0.1 N KMnO4 solution
(B) 2.5 × 10–3 moles of K2Cr2O7 in acidic medium
(C) 15 × 10–3 moles of KMnO4 in basic medium
(D) 15 moles of O3 in acidic medium
12. To 25 ml of H2O2 solution, excess of acidified Sol.
solution of KI was added. The iodine liberated
required 20 ml of 0.1 N Na2S2O3 solution. Calculate
the % of H2O2 solution.
(A) 0.0136 % (B) 0.136 %
(C) 0.0068 % (D) 0.068 %
Sol.

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 Page # 30 STOICHIOMETRY - II

Exercise - III Subjective Level-I

Balancing of reactions Sol.
1. Complete and balance the following equations
(a) KMnO4 + H2SO4 + H2O2 →
K2SO4 + MnSO4 + H2O + .........
(b) Cu2+
+ I → Cu+ + I2
–

Sol.

4. Balance the following equations in acidic medium

(a) KClO3 + H2SO4 → KHSO4 + HClO4 + ClO2 + H2O
(b) Br– + BrO3– + H+ → Br2 + H2O
(c) H2S + Cr2O72– + H+ → Cr2O3 + S8 + H2O
2. Balance the following in basic medium (d) MnO4 + C2O42– + H+ → Mn2+ + CO2 + H2O
(i) CrI3 + H2O2 + OH– → CrO42– + IO4– + H2O (e) Cu2O + H+ + NO3– → Cu2+ + NO + H2O
(f) [Fe(CN)6]4– + MnO4– →
(ii) KOH + K4Fe(CN)6 + Ce(NO3)4 → Fe3+ + CO2 + NO3– + Mn2+
Fe(OH)3 + Ce(OH)3 + K2CO3 + KNO3 + H2O Sol.
Sol.

5. Balance following equations in proper medium

3. Balance the following equations using desired (a) C2H5OH + MnO4– → C2H3O– + MnO2(s) + H2O
medium: (b) Cr2O72– + C2H4O + H+ → C2H4O2 + Cr3+
(c) P + OH– + H2O → H2PO4– + PH3
(a) SbCl3 + KIO3 + HCl → SbCl5 + ICl + H2O + KCl
(d) S + OH– → S2– + S2O32–
(b) FeC2O4 + KMnO4 + H2SO4 → (e) Na2S2O3 + KMnO4 + H2O →
Fe2(SO4)3 + CO2 + MnSO4 + K2SO4 + H2O Na2S4O6 + MnO2 + KOH + NaOH
(c) FeCr2O4 + K2CO3 + KClO3 → (f) FeC2O4 + KMnO4 + H2SO4 →
Fe2O3 + K2CrO4 + KCl + CO2 Fe2(SO4)3 + CO2 + MnSO4 + K2SO4 + H2O
(d) Pb(N3)2 + Co(MnO4)3→ (g) C2H5OH + I2+ OH– → CHI3 + HCOO– + H2O + I–
CoO + MnO2 + Pb3O4 + NO

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 STOICHIOMETRY - II Page # 31

Sol. Sol.

Acid Base Titration

6. A solution containing 4.2 g of KOH and Ca(OH)2 is
neutralized by an acid. It consumes 0.1 equivalent
of acid, calculate the percentage composition of
the sample.
Sol.

9. H3PO4 is a tri basic acid and one of its salt is

NaH2PO4. What volume of 1 M NaOH solution should
be added to 12 g of NaH2PO4 to convert it into
Na3PO4 ?
Sol.

7. How many ml of 0.1 N HCl are required to react

completely with 1 g mixture of Na2CO3 and NaHCO3
containing equimolar amounts of two ?
Sol.

Double titration
10. A solution contains Na2CO3 and NaHCO3. 20 ml of
this solution required 4 ml of 1 N HCl for titration
8. 0.5 g of fuming H2SO4 (oleum) is diluted with water. with Ph indicator. The titration was repeated with
The solution requires 26.7 ml of 0.4 N NaOH for the same volume of the solution but with MeOH.
complete neutralization. Find the % of free SO3 in 10.5 ml of 1 N HCl was required this time. Calculate
the sample of oleum. the amount of Na2CO3 & NaHCO3.

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 Page # 32 STOICHIOMETRY - II

Sol.

Redox Titration
13. It requires 40.05 ml of 1 M Ce4+ to titrate 20 ml of
1 M Sn2+ to Sn4+. What is the oxidation state of
the cerium in the product.
Sol.

11. A solution contains a mixture of Na2CO3 and NaOH. 14. A volume of 12.53 ml of 0.05093 M SeO2 reacted
Using Ph as indicator 25 ml of mix required 19.5 ml with exactly 25.52 ml of 0.1 M CrSO4. In the
of 1 N HCl for the end point. With MeOH, 25 ml of reaction, Cr2+ was oxidized to Cr3+. To what
the solution required 25 ml of the same HCl for oxidation state was selenium converted by the
the end point. Calculate gms/L of each substance reaction.
in the mixture. Sol.
Sol.

15. Potassium acid oxalate K2C2O4. 3H2C2O4.4H2O can

be oxidized by MnO4– in acid medium. Calculate
the volume of 0.1 M KMnO4 reacting in acid solution
with one gram of the acid oxalate.
Sol.

12. 200 ml of a solution of mixture of NaOH and Na2CO3

N
was first titrated with HCl with indicator Ph.
10
17.5 ml of HCl was required for end point. After
this MeOH was added and 2.5 ml of same HCl was
again required for next end point. Find out amounts
of NaOH and Na2CO3 in the mixture.
Sol.

16. A 1 g sample of H2O2 solution containing x% H2O2

by mass requires x cm3 of a KMnO4 solution for
complete oxidation under acidic conditions.
Calculate the normality of KMnO4 solution.

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 STOICHIOMETRY - II Page # 33

Sol. 19. A 1.0 g sample of Fe2O3 solid of 55.2 % purity is

dissolved in acid and reduced by heating the
solution with zinc dust. The resultant solution is
cooled and made upto 100.0 mL. An aliquot of
25.0 mL of this solution requires 17.0 mL of 0.0167
M solution of an oxidant for titration. Calculate
the number of moles of electrons taken up by the
oxidant in the reaction of the above titration.
Sol.

17. Metallic tin in the presence of HCl is oxidized by

K2Cr2O7 to stannic chloride, SnCl4. What volume
of deci-normal dichromate solution would be
reduced by 1 g of tin.
Sol.

20. 0.84 g iron ore containing x percent of iron was

taken in a solution containing all the iron in ferrous
condition. The solution required x ml of a
dichromatic solution for oxidizing the iron content
to ferri c state. Cal cul ate the strength of
18. 5g sample of brass was dissolved in one litre dil. dichromatic solution.
H2SO4. 20 ml of this solution were mixed with KI, Sol.
liberating I2 and Cu+ and the I2 required 20 ml of
0.0327 N hypo solution for complete titration.
Calculate the percentage of Cu in the alloy.
Sol.

21. 5 g of pyrolusite (impure MnO2) were heated with

conc. HCl and Cl2 evolved was passed through
excess of KI solution. The iodine liberated required
N
40 mL of hypo solution. Find the % of MnO2 in
10
the pyrolusite.

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 Page # 34 STOICHIOMETRY - II

Sol.

24. What amount of substance containing 60% NaCl,

37% KCl should be weighed out for analysis so
that after the action of 25 ml of 0.1N AgNO3
solution, excess of Ag+ is back titrated with 5 ml
of NH4SCN solution? Given that 1 ml of NH4SCN =
1.1 ml of AgNO3.
[AgNO3 + NaSCN → AgSCN + NaNO3]
Sol.
Back Titration
22. 50 gm of a sample of Ca(OH)2 is dissolved in 50 ml
of 0.5 N HCl solution. The excess of HCl was titrated
with 0.3N NaOH. The volume of NaOH used was
20cc. Calculate % purity of Ca(OH)2
Sol.

25. 10 g CaCO3 were dissolved in 250 ml of 1 M HCl.

What volume of 2 M KOH would be required to
neutralise excess HCl ?
23. One gm of impure sodium carbonate is dissolved
Sol.
in water and the solution is made up to 250ml. To
50ml of this solution, 50ml of 0.1N – HCl is added
and the mixture after shaking well required 10ml
of 0.16N NaOH solution for complete titration.
Calculate the % purity of the sample.
Sol.

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 STOICHIOMETRY - II Page # 35

Exercise - IV Subjective Level-II

1. A mixture of FeO and Fe2 O3 is reacted with 9. A sample of steel weighing 0.6 gm and containing
acidified KMnO4 solution having a concentration of S as an impurity was burnt in a stream of O2, when S
0.2278 M, 100 ml of which was used. The solution was converted to its oxide SO2. SO2 was then oxidized
was then titrated with Zn dust which converted Fe3+ to SO4– – by using H2O2 solution containing 30ml of
of the solution to Fe2+. The Fe2+ required 1000 ml of 0.04 M NaOH. 22.48 ml of 0.024 M HCl was required to
0.13 M K2 Cr2 O7 solution. Find the % of FeO & Fe2O3. neutralize the base remaining after oxidation. Calculate
2. 50 ml of a solution, containing 0.01 mole each the % of S in the sample.
Na2CO3, NaHCO3 and NaOH was titrated with N-HCl. 10. 3.3 gm of a sample of Anhydrous CuSO4 was
What will be the titre readings if dissolved in water and made to 250 ml. 25 ml of this
(a) only Ph is used as indicator. solution after taking usual precautions was treated
(b) only MeOH is used as indicator from the beginning. with a little excess of KI solution. A white ppt. of
(c) MeOH is added after the first end point with Ph. Cu2I2 and iodine was evolved. The iodine so evolved
3. A 0.517 g sample containing Ba(SCN)2 was required 24.6 ml of hypo solution containing 20 gm of
dissolved in a bicarbonate solution. 50.0 mL of 0.107 (Na2S2O3. 5H2O) per litre. What is the purity of CuSO4
N iodine was added, and the mixture was allowed to solution ?
stand for five minutes. The solution was then acidified, 11. A certain sample of coal contained some iron pyrite
and the excess I2 was titrated with 16.3 mL of 0.0965 (FeS2) – a pollution causing impurity. When the coal
M sodium thiosulphate. Write a balanced equation for was burnt iron (II) was oxidised and SO2 was formed.
the oxidation of SCN– into SO42– and HCN. Calculate The SO2 was reacted with NaOH when sodium sulphite
the percent Ba(SCN)2 in the sample. and water was formed. On a particular day 103 kg of
4. A substance of crude copper is boiled in H2SO4 till coal was burnt and it required 4 litres of 5 M NaOH for
all the copper has reacted. The impurities are inert to the treatment of SO2. What was the percentage of
the acid. The SO2 liberated in the reaction is passed pyrite in the coal ? What was the percentage of sulphur
into 100 mL of 0.4 M acidified KMnO4. The solution of in the coal ?
KMnO4 after passage of SO2 is allowed to react with 12. In the presence of fluoride ion, Mn2+ can be titrated
oxalic acid and requires 23.6 mL of 1.2 M oxalic acid.
with MnO4–, both reactants being converted to a
If the purity of copper is 91%, what was the weight
complex of Mn(III). A 0.545 g sample containing Mn3O4
of the sample.
was dissolved and all manganese was converted to
5. A 1.87 gm sample of chromite ore (FeO.Cr2O3) Mn2+. Titration in the presence of fluoride ion consumed
was completely oxidized by the fusion of peroxide. 31.1 ml of KMnO4 that was 0.117 N against oxalate.
The fused mass was treated with water and boiled to (a) write a balanced chemical equation for the reaction,
destroy the excess of peroxide. After acidification the assuming that the complex is MnF4–.
sample was treated with 50 ml of 0.16 M Fe2+. In back (b) what was the % of Mn3O4 in the sample ?
titration 2.97 ml of 0.005 M barium dichromate was
required to oxidize the excess iron (II). What is the 13. Calculate the % of MnO2 in a sample of pyrolusite
percentage of chromite in the sample ? ore, 1.5 g which was made to react with 10 g. of
Mohr's salt (FeSO4. (NH4)2SO4. 6H2O) and dilute H2SO4.
6. 25 mL of a solution containing HCl was treated MnO2 was converted Mn2+. After the reaction the
with excess of M/5 KIO3 and KI solution of unknown solution was diluted to 250 ml and 50 ml of this solution,
concentration where I2 liberated is titrated against a when titrated with 0.1 N K2Cr2O7, required 10 ml of
standard solution of 0.021 M Na2S2O3 solution whose the dichromate solution.
24 mL were used up. Find the strength of HCl and
14. The neutralization of a solution of 1.2 g of a
volume of KIO3 solution consumed.
substance containing a mixture of H2 C2 O4 . 2H2 O,
7. A 10 g sample of only CuS and Cu2S was treated KHC2O4.H2O and different impurities of a neutral salt
with 100 mL of 1.25 M K2Cr2O7. The products obtained consumed 18.9 ml of 0.5 N NaOH solution. On titration
were Cr3+, Cu2+ and SO2. The excess oxidant was with KMnO4 solution, 0.4 g of the same substance
reacted with 50 mL of Fe2+ solution. 25 ml of the needed 21.55 ml of 0.25 N KMnO4. Calculate the %
same Fe2+ solution required 0.875 M acidic KMnO4 the composition of the substance.
volume of which used was 20 mL. Find the % of CuS 15. Chrome alum K2SO4. Cr2(SO4)3. 24H2O is prepared
and Cu2S in the sample. by passing SO2 gas through an aqueous solution of
8. H2O2 is reduced rapidly by Sn2+, the products being K2Cr2O7 acidified with dilute sulphuric acid till the
Sn4+ & water. H2O 2 decomposes slowly at room reduction is complete. The alum is crystallized followed
temperature to yield O2 & water. Calculate the volume by filtration/centrifugation. If only 90% of the alum
of O2 produced at 20°C & 1.00 atm when 200g of can be recovered from the above process, how much
10.0% by mass H2O2 in water is treated with 100.0 ml alum can be prepared from 10 kg of K2Cr2O7 ? Give the
of 2.00 M Sn2+ & then the mixture is allowed to stand number of moles of electrons supplied by SO2 for
until no further reaction occurs. reducing one mole of K2Cr2O7.

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 Page # 36 STOICHIOMETRY - II

Exercise - V JEE-Problems
1. A 5.0 cm3 solution of H2O2 liberates 0.508g of
Sol.
iodine from an acidified KI solution. Calculate the
strength of H2O2 solution in terms of volume
strength at STP. [JEE' 1995]
Sol.

4. The number of moles of KMnO4 that will be needed

to react with one mole of sulphite ions in acidic
solution is [JEE 1997]
(A) 2/5 (B) 3/5
(C) 4/5 (D) 1
Sol.

2. A 3.00 g sample containing Fe3O4, Fe2O3 and an

inert impure substance, is treated with excess of
KI solution in presence of dilute H2SO4. The entire
iron is converted into Fe2+ along with the liberation
of iodine. The resulting solution is diluted to 100
ml. A 20 ml of the diluted solution require. 11.0 ml
of 0.5 M Na2S2O3 solution to reduce the iodine
present. A 50 ml of the diluted solution, after
complete extraction of the iodine requires 12.80
ml of 0.25 M KMnO4 solution in dilute H2SO4 medium 5. One litre of a mixture of O2 and O3 at NTP was
for the ox i d at i on of F e 2 + . C al cul at e the allowed to react with an excess of acidified solution
percentages of Fe2O3 and Fe3O4 in the original M
of KI. The iodine liberated required 40 ml of
sample. [JEE'96, 5] 10
Sol. sodium thiosulphate solution for titration. What is
the percent of ozone in the mixture? Ultraviolet
radiation of wavelength 300 nm can decompose
ozone. Assuming that one photon can decompose
one ozone molecule, how many photons would
have been required for the complete decomposition
of ozone in the original mixutre ?
[JEE'97, 5]
Sol.

3. The number of moles of KMnO4 that will be needed

to react completely with one mole of ferrous
oxalate in acid solution is [JEE 1996]
(A) 3/5 (B) 2/5
(C) 4/5 (D) 1

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 STOICHIOMETRY - II Page # 37

6. An aqueous solution containing 0.10 g KIO3 9. One mole of calcium phosphide on reaction with
(formula wt. = 214.0) was treated with an excess excess of water gives [JEE 1999]
of KI solution. The solution was acidified with HCl. (A) one mole of phosphine
The liberated I2 consumed 45.0 ml of thiosulphate (B) Two moles of phsophoric acid
solution to decolourise the blue starch - iodine (C) Two moles of phosphine
complex. Calculate the molarity of the sodium (D) One mole of phosphorus pentoxide
thiosulphate solution. [JEE' 1998] Sol.
Sol.

10. An aqueous solution of 6.3 gm of oxalic acid

dihydrate is made upto 250 ml. The volume of 0.1
N NaOH required to completely neutralize 10 ml of
7. How many millilitre of 0.5 M H2SO4 are needed to this solution is [JEE 2001]
dissolve 0.5 gm of copper II carbonate ? (A) 40 ml (B) 20 ml
[JEE' 1999] (C) 10 ml (D) 4 ml
Sol. Sol.

8. The normality of 0.3 M phosphorus acid (H3PO3) is

11. In the standarization of Na2S2O3 using K2Cr2O7 by
(A) 0.1 (B) 0.9
iodometry the equivalent mass of K2Cr2O7 is
(C) 0.3 (D) 0.6 [JEE 1999]
Sol. M.Mass M.Mass M.Mass
(A) (B) (C)
2 6 3
(D) Same as M. Mass. [JEE 2001]
Sol.

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 Page # 38 STOICHIOMETRY - II

12. Hydrogen peroxide solution (20 mL) reacts 14. Match the reactions in Column I with nature of
quantitatively with a solution of KMnO4 (20 mL) the reactions / type of the products in Column II.
acidified with dilute H2SO4. The same volume of [JEE' 2007]
the KMnO4 solution is just decolorized by 10 mL of Column I Column II
MnSO4 in neutral medium simultaneously forming
(A) O 2– → O 2 + O 22 – (P) Redox reaction
a dark brown precipitate of hydrated MnO2. The
brown precipitate is dissolved in 10 mL of 0.2 M (B) CrO 2– +
(Q) One of the products
4 +H →
sodium oxalate under boiling condition in the
has trigonal
presence of dilute H2SO4. Write the balanced
planar structure
equations involved in the reactions and calculate
the molarity of H2O2. [JEE' 2001] (C) MnO 4– + NO 2– + H+ → (R) dimeric bridged
Sol. tetrahedral metal ion
(D) NO 3– + H2SO 4 + Fe 2+
→ (S) disproportionation
Sol.

13. Consider a titration of potassium dichromate

solution with acidified Mohr's salt solution using
diphenylamine as indicator. The number of moles 15. White phosphorus on reaction with NaOH gives
of Mohr's salt required per mole of dichromate is PH3 as one of the products. This is a
[JEE' 2007] [JEE 2008]
(A) 3 (B) 4 (A) dimerization reaction
(C) 5 (D) 6 (B) disproportionation reaction
Sol. (C) condensation reaction
(D) precipitation reaction
Sol.

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 STOICHIOMETRY - II Page # 39

ANSWER-KEY

Exercise-I

1. B 2. C 3. D 4. B 5. B 6. B 7. D 8. A

9. C 10. C 11. A 12. B 13. C 14. A 15. B 16. D

17. B 18. C 19. B 20. B 21. A 22. C 23. C 24. D

25. A 26. A 27. A 28. B 29. A 30. B 31. C 32. D

33. B 34. A 35. C 36. D 37. A 38. D 39. C 40. A

41. B 0

Exercise-II

1. A,C 2. A,C 3. A,B,C 4. C 5. A,B,C 6. A 7. A,B 8. A,B,C

9. A,B 10. A,C,D 11. A,C,D 12. B 13. A,C 14. B,C,D 15. A,B,C

Exercise-III

1. (a) 2KMnO4 + 3H2SO4 + 5 H2O2 →

K2SO4 + 2MnSO4 + 8 H2O + 5O2
(b) 2Cu 2+
+ 2I → 2Cu+ + I2
–

2. (i) 2CrI3 + 27H2O2 + 10 OH– → 2CrO42– + 6IO4– + 32H2O

(ii) 258KOH + K4Fe(CN)6 + 61Ce(NO3)4 → 61Ce(OH)3 + Fe(OH)3 + 36H2O + 6K2CO3 + 250KNO3

3. (a) 3SbCl3 + KIO3 + 6HCl → 2SbCl5 + ICl + 3H2O + KCl

(b) 10FeC2O4 + 6KMnO4 + 24H2SO4 → 5Fe2(SO4)3 + 20CO2 + 6MnSO4 + 3K2SO4 + 24H2O
(c) 6FeCr2O4 + 12K2CO3 + 7KClO3 → 3Fe2O3 + 12K2CrO4 + 7KCl + 12CO2
(d) 30Pb(N3)2 + 44Co(MnO4)3→ 132MnO2 + 44CoO + 180NO + 10Pb3O4

4. (a) 3KClO3 + 3H2SO4 → 3KHSO4 + HClO4 + 2ClO2 + H2O

(b) 5Br– + BrO3– + 6H+ → 3Br2 + 3H2O

394 - Rajeev Gandhi Nagar Kota, Ph. No. 0744-2209671, 93141-87482, 93527-21564
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 Page # 40 STOICHIOMETRY - II

(c) 24H2S + 8Cr2O72– + 16H+ → 8Cr2O3 + 3S8 + 32H2O

(d) 2MnO4– + 5C2O42– + 16H+ → 2Mn2+ + 10CO2 + 8H2O
(e) 3Cu2O + 14H+ + 2NO3– → 6Cu2+ + 2NO + 7H2O
(f) 5[Fe(CN)6]4– + 188H+ + 61MnO4– → 5Fe3+ + 30CO2 + 30NO3– + 61Mn2++ 94H2O

5. (a) 3C2H5OH + 2MnO4– + OH– → 3C2H3O– + 2MnO2(s) + 5H2O

(b) Cr2O72– + 3C2H4O + 8H+ → 3C2H4O2 + 2Cr3++ 4H2O
(c) 4P + 3OH– + 3H2O → 3H2PO4– + PH3
(d) 4S + 6OH– → 2S2– + S2O32–
(e) 6Na2S2O3 + 2KMnO4 + 4H2O → 3Na2S4O6 + 2MnO2 + 2KOH + 6NaOH
(f) 10FeC2O4 + 6KMnO4 + 24H2SO4 → 5Fe2(SO4)3 + 20CO2 + 6MnSO4 + 3K2SO4 + 24H2O
(g) C2H5OH + 4I2+ 6OH– → CHI3 + HCOO– + 5H2O + 5I–

6. KOH = 35%, Ca(OH)2 = 65% 7. V = 157.8 ml 8. 20.72 % 9. 200 mL 10. 0.424 gm; 0.21 gm

11. 23.32 gm, 22.4 gm 12. 0.06 gm; 0.0265 gm 13. +3 14. zero 15. V = 31.68 ml

16. 0.588 N 17. 337 mL 18. 41.53% 19. 6.07 ≈ 6 20. 0.15 N 21. 0.174g ; 3.48 %

22. 1.406% 23. 90.1 % 24. 0.1281 g 25. V = 25 mL

Exercise-IV

1. FeO = 13.34%; Fe2O3 = 86.66% 2. 20 ml ; 40 ml; 20 ml

3. SCN– + 3I2 + 4H2O SO42– + HCN + 7H+ +6I–, 15.68 % 4. 5g 5. 15.68 % Chromite

6. VKIO 3 = 0.42 mL , [HCl] = 0.0168 N 7. 57.4 % CuS, 42.6% Cu2S 8. 4.67 L 9. 1.76 %

10. 95.8 % 11. pyrite : 0.06 %; S = 0.032 % 12. 40.77% 13. 59.16%

14. H2C2O4.2H2O = 14.36%, KHC2O4 . H2O = 81.71 % 15. 30.55 kg, 6 eleCtrons

Exercise-V

1. 4.48 % 2. Fe2O3 = 49.33 %, Fe3O4 = 34.8% 3. A 4. A

5. 6.57 % O3 (By weight), 1.2 × 1021 photons 6. 0.0623 M 7. 8.097 ml 8. D 9. C 10. A

11. B 12. 0.1M 13. D 14. (A) P, S ; (B) R ; (C) P, Q ; (D) P 15. B

394 - Rajeev Gandhi Nagar Kota, Ph. No. 0744-2209671, 93141-87482, 93527-21564
www. motioniitjee.com , [email protected]