001 Shiv Puran Nepali

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Sunday, 9 June 2013
silica
silica
Silica is available abudantly in many forms. Some the forms of
silica forms are:
clay, marl, sand, flyash, slag, quartz, flint,felspar, mica, sandstone,
Illite, diatomite
chemical name: silicon di oxide (SiO2) 
Melting point : 2072 deg celcius
No need to add silica seperately as it was present in mixed
condition along with limestone and with iron & alumina. The basic
thumb rule is:
A high lime material will have less silica and low lime material will
have high silica.
Two types of silica is availabe:
1. Reactive silica : This silica will react, burn easily with rawmix
(limestone with iron and alumina ) and without causing burning,
operational or cement manufacturing problems.
2. Free silica : This silica will not react or burn easily with rawmix
(limestone with iron and alumina). It requires very high
temperature compared to reactive silica.It is also difficult to grind.
So ensure care while selecting raw material which contains silica in
the form of free silica.
CLAYS :
These are aluminim silicates which contain about 50 % to 70 % of
silicon di oxide. They are fine grained in appearance and size under
2 microns in diameter. The fusion temperature of clays varies
between 1150 deg celcius to 1750 deg celcius. The following table
provides you about general clay types:
 
KAOLIN  GROUP MONTMORILLONITE GROUP

Kaolinite Montmorillonite
Dickite Beidellite
Nacrite Nontronite
Halloysite Saponite

Saponite is magnesium silicate based and remaining clay types are


aluminium silicate types. Clay mica including illite are alkali with
magnesium based clays.
Clays with no impurities will be white in colour, but it contains iron
hydroxide which is the principle colouring matter in clay.
 

 
(clay image, courtesy : www.learnnc.org)
What to do if silica content is low in raw mix ?
Just add sand to raw mix as it contains more silica.
How to select a raw material containing silica for
cement manufacturing ?
1. Ensure care while selecting alkali and magnesium based clays (as
they create operational and cement quality problems like cement
expansion and cracking) by keeping them under permissible
limits. 
2. Again and always try to keep auxillary components under limits
as they also create cement expansion with cracking and
operational problems. (clays are major source of alkalies in
cement)
3.If high silica, then it means material having low lime. So add high
grade limestone or any material of high grade lime so that the lime
grade limestone or any material of high grade lime so that the lime
increases and silica decreases.
 
What to do if you have more free silica ?
Under such condition,grind the raw mix less than 45 microns. This
makes material with free silica reactive and easy burning type.
(silica image,courtesy:www.consingeologicalsurvey.org)

bhaskar ramamurthy at 02:00

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