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Thermal Cracking of Dichloroethane From Oxychlorination of Ethylene

The document describes the process of thermally cracking dichloroethane produced from the oxychlorination of ethylene. Ethylene and chlorine undergo direct chlorination or oxychlorination with oxygen to produce ethylene dichloride. The ethylene dichloride is then cracked through pyrolysis at high temperature and pressure to produce vinyl chloride monomer and hydrogen chloride, which can be recycled in the process.
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0% found this document useful (0 votes)
312 views2 pages

Thermal Cracking of Dichloroethane From Oxychlorination of Ethylene

The document describes the process of thermally cracking dichloroethane produced from the oxychlorination of ethylene. Ethylene and chlorine undergo direct chlorination or oxychlorination with oxygen to produce ethylene dichloride. The ethylene dichloride is then cracked through pyrolysis at high temperature and pressure to produce vinyl chloride monomer and hydrogen chloride, which can be recycled in the process.
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Thermal Cracking Of Dichloroethane From OxyChlorination of Ethylene

Ethylene
Chlorine
Direct Chlorination

Light Column Heavies Column

Ethylen
Oxygen
Oxy Chlorination Caustic
Wash
Cl
Hydrogen Chloride Waste Ethylene Dichloride Recycle

Hydrogen Chloride Recycle

Vinyl Chloride
monomer
HCl column pyrolisis
VCM Column
Balance Process For Chlorination of Ethylene

Gas and dirty Pumping Work


Water

O2
C2H4
HCl C2H4Cl2, H2O
Oxychlorination Decanter
260 C, 10 atm Pressure Temperature
Phase Change
Change Change

Temperature Change

500 c, 26 atm Pyrolisis


Temperatur change
500 c, 26 atm

Vapor at
Temperature change boilling
point

Vapor at dew Liqiud


point bubble
point

Phase change
6 c, 12 atm
C2H3Cl

C2H4Cl2

HCl

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