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Rumus Persamaan Freundlich Q K C Log Q Log K + 1/n Log C

The document contains a table with experimental data on the concentration of benzidine before and after filtration using various amounts of Filtrasorb. It then shows the calculations and graphs to determine the Langmuir and Freundlich isotherm equations that fit the data. The Freundlich equation was determined to be q = 5.966 C1/6.770 and the Langmuir equation was determined to be c/q = [(1/3.649 x 0.163)] + [(1/0.163) x C)].

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51 views5 pages

Rumus Persamaan Freundlich Q K C Log Q Log K + 1/n Log C

The document contains a table with experimental data on the concentration of benzidine before and after filtration using various amounts of Filtrasorb. It then shows the calculations and graphs to determine the Langmuir and Freundlich isotherm equations that fit the data. The Freundlich equation was determined to be q = 5.966 C1/6.770 and the Langmuir equation was determined to be c/q = [(1/3.649 x 0.163)] + [(1/0.163) x C)].

Uploaded by

mega chania
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© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Nama : Mega Chania

NPM : 1531010230
Paralel :E
Matkul : PLP

Soal persamaan Langmuir dan persamaan Freundlich isoterm.


Berat Filtrasorb, m Konsentrasi Benzidine Konsentrasi Benzidine
No
(mg/L) mula-mula (Ci) (mg/L) akhir (Ci) (mg/L)
1 3,72 9,81 8,63
2 8,42 9,81 7,52
3 24,5 9,81 3,55
4 39,8 9,81 1,41
5 1,08 1,17 0,98
6 2,12 1,17 0,84
7 4,05 1,17 0,66
8 10,85 1,17 0,17
9 11,9 1,17 0,11
Jawab :

Konsentrasi Benzidine
Berat Filtrasorb, m (mg/L) ΔC( mg/L)
No (mg/L) Awal Akhir
1 3,72 9,81 8,63 1,18
2 8,42 9,81 7,52 2,29
3 24,5 9,81 3,55 6,26
4 39,8 9,81 1,41 8,4
5 1,08 1,17 0,98 0,19
6 2,12 1,17 0,84 0,33
7 4,05 1,17 0,66 0,51
8 10,85 1,17 0,17 1
9 11,9 1,17 0,11 1,06

Rumus Persamaan Freundlich

q = Kf C1/n

log q = log Kf + 1/n log C

dimana :

q = X/m
X X/m Log X/m Log C
1,18 0,317204 -0,4987 0,0719
2,29 0,271971 -0,5655 0,3598
6,26 0,25551 -0,5926 0,7966
8,4 0,211055 -0,6756 0,9243
0,19 0,175926 -0,7547 -0,7212
0,33 0,15566 -0,8078 -0,4815
0,51 0,125926 -0,8999 -0,2924
1 0,092166 -1,0354 0,0000
1,06 0,089076 -1,0502 0,0253

Grafik Persamaan Freundlich


0.2000

0.0000
-1.0000 -0.5000 0.0000 0.5000 1.0000 1.5000
-0.2000
Log X/m

y = 0,1477x - 0,7757
-0.4000 R² = 0,1627
-0.6000

-0.8000

-1.0000

-1.2000
Log C

Persamaan :
Y = ax + b
Maka :
Y = 0,1477 x + 0,7757

b = log Kf
0,7757 = log Kf
Kf = 5,966

a = 1/n
0,1477 = 1/n
n = 1/0,1477
n = 6,770
Sehingga didapat Persamaan Freundlich :
q = Kf C1/n
q = 5,966 C1/6,770
Rumus Persamaan Langmuir
c/q = [(1/KA x qm)] + [(1/qm) x C)]
1/q = [(1/qm)] + [(1/KA x qm) x (1/C)]
Dimana :
q = X/m
X X/m 1/q 1/C
1,18 0,3172 3,153 0,847
2,29 0,2720 3,677 0,437
6,26 0,2555 3,914 0,160
8,4 0,2111 4,738 0,119
0,19 0,1759 5,684 5,263
0,33 0,1557 6,424 3,030
0,51 0,1259 7,941 1,961
1 0,0922 10,850 1,000
1,06 0,0891 11,226 0,943

Grafik Persamaan Langmuir


12.000
y = 0,168x + 6,144
10.000 R² = 0,0087

8.000
1/q

6.000

4.000

2.000

0.000
-1.000 0.000 1.000 2.000 3.000 4.000 5.000 6.000
1/C

Persamaan :
Y = ax + b
Maka :
Y = 0,168 x + 6,144
B = 1/qm
6,144 = 1/qm
qm = 1/6,144
qm = 0,163

a = 1/KA x qm
0,168 = 1/KA x 0,163
1/KA = 0,168 x 0,163
1/KA = 0,0274
KA = 1/0,274
KA = 3,649
Sehingga didapat Persamaan Langmuir :
c/q = [(1/KA x qm)] + [(1/qm) x C)]
c/q = [(1/3,649 x 0,163)] + [(1/0,163) x C)]

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