TOPIC 4 – CHEMICAL BONDING AND STRUCTURE
4.4 INTERMOLECULAR FORCES
1. What are the differences between intramolecular and intermolecular forces of attraction? Identify which one is
stronger.
2. Describe London/Dispersion forces of attraction by:
a. Defining it:
b. Providing a diagram:
c. Explaining what is meant by these forces form instantaneous dipoles
3. Describe Dipole-Dipole forces of attraction by:
a. Defining it:
b. Providing a diagram:
4. Describe Hydrogen bonding forces of attraction by:
a. Defining it:
b. Providing a diagram:
c. Explaining why hydrogen is considered as dipole-dipole interaction?
d. Using the figure below, answer the questions:
i. What is the trend of the boiling point of hydrides (groups 14 to 17) as you go down the group? Explain
why.
ii. Explain why do NH3, HF, and H2O have higher boiling points than expected from their molar mass?
5. Complete the following table for the properties of covalent compounds
Polar Covalent
Ionic Giant Molecular Nonpolar Covalent Molecules
Molecules
Melting/
Boiling Point
Solubility
Electrical
Conductivity
Volatility
6. Explain the following observations: tetrachloromethane, CCl4, is immiscible in water but methanol, CH3OH, is
miscible with water in all proportions. Methanoic acid, HCOOH, is soluble in water but octanoic acid
(C7H15COOH) is much less soluble.