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Answer Key

This document contains the answer key for exercises related to thermochemistry. It provides the answers to multiple choice and numerical questions testing understanding of concepts such as heat of reaction, enthalpy, bond energies, and thermochemical calculations. The exercises cover topics including thermochemistry laws, thermochemical equations, Hess's law, bond dissociation energies and their application in calculating enthalpy changes.

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0% found this document useful (0 votes)
129 views1 page

Answer Key

This document contains the answer key for exercises related to thermochemistry. It provides the answers to multiple choice and numerical questions testing understanding of concepts such as heat of reaction, enthalpy, bond energies, and thermochemical calculations. The exercises cover topics including thermochemistry laws, thermochemical equations, Hess's law, bond dissociation energies and their application in calculating enthalpy changes.

Uploaded by

Rishabh
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© © All Rights Reserved
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Page # 28 THERMOCHEMISTRY

Answer-Key

Exercise-I

1. D 2. D 3. D 4. A 5. C 6. C 7. B 8. A
9. A 10.C 11. A 12. D 13. D 14. C
15. (i) B (ii) A (iii) A (iv) C 16. A  (P,R), B  (Q,S), C  (Q,S), D  (Q,S)
17. A  (P,S), B  (Q), C  (R) 18. A 19. B 20. B 21. A 22. A
23. A 24. D 25. B 26. A 27. B 28. B 29. A

Exercise-II

1. C,D 2. A,B,C 3. C,D 4. A,B,C 5. B,C,D 6. A,Ca 7. C,D 8. B,C,D


9. A,B,C 10. A,C 11. A,C,D 12. A,B,C,D 13. A,C,D

Exercise-III

1. –324.8 kJ/mol 2. –34.5 kJ/mol 3. –26.8 kJ/mol 4. 35.973 MJ


5. 18.95% 6. 25.66 days 7. E = 27.91 KJ mol–1, t = 514 sec.
8. 27.43 g O2 9. –22.123 k cal 10. 2.95 kcal 11. –1410 cal 12. –18.7 kcal
13. 11.2 Kcal 14. –75.14 kJ/mol 15. (i) –885 kJ/mol (ii) –889.980 kJ/mol
16. 10.0 mol% CH4 17. –726.6 kJ/mol 18. 208 kJ/mol 19. –120.08 J/ml
20. B.E. (C – C) = 82 kcal/mole; fH [C2H6(g)] = – 20.1 kcal/mole 21. –72 kJmol–1
22. (i) 343.08 ; (ii) 891.2 23. EC  C = 160.86 k cal 24. –192.3 kJ mol–1 25. 277.5 kJ/mol
26. –23.68 KJ/mol 27. –669.7 kJ mol 28. –352 kJ mol–1 29. –618.7 kJ mol–1 30. –90.75 kcal mol–1

Exercise-IV

1. –85 kJ/mole 2. (a) 92.435 g (b) 93.72 g 3. 404 K


4. mole % O2(g) = 37.5, H2O (g) = 62.5
b
5. (a) (i) aT (ii) aT + (T 2 – T12) (b) 1000cal, 1012cal, 1.1858% error
2 2
6. 0.9346 k cal g–1, 3.94 kcal cm–3 7. 9.822 MJ/day evolved
8. 1 : 3 9. –666.81 k cal mol–1, 15.55 Mcal
10. C – C = 97.81 kJ, C – H = 454.64 kJ, C = O = 804.26 kJ, C = C = 434.3 kJ, C = C = 733.48 kJ
11. +20.6 kcal 12. –266 kJ mol–1 13. 292 kcal/mol
14. for Cl – 384 kJ mol , for I – 307 kJ mol–1
– –1 –
15. advantage = 5393 kJ mol–1
16. –718 kJ/mol 17. –30.06 kJ/mol 18. 22 kcal mol–1
19. 2.80 : 1

Exercise-V

1. B 2. B 3. A 4. C 5. B 6. –2035 kJ mol–1 7. 309.6 kJ/mol

8. 9 9. D

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