CUMULATIVE TEST -3 (CT-3)

JEE ADVANCED
TARGET : JEE (ADVANCED)-2013
DATE : 12-05-2013 COURSE : REVISION CLASSES
HINTS & SOLUTIONS
PAPER-1 6. Figure  given below shows................................
PART-I (Physics)
1. At shown instant a thin ............................
Sol. (A)
1 1
Sol. (C) Kinetic energy of rod = mV 2cm + Icm 2 = 74 J 
2 2 
P r
2. A particle of mass 2kg.................................. r

 Q
  dr 
Sol. (B) P  mv  m = 2[–4t] ĵ =  16 ĵ
dt
 For refraction at glass-air interface, ray passing through point Q,
r  5 î  2(2)2 ĵ = 5 î  8 ĵ
   sin r 1 1
L  r  p  80k̂ . =  sinr =
sin 90 1.5 1 .5
3. A block is suspended by a..................................... For refraction at water-glass interface, ray passing through
point P,
/////////////////////////
sin 1.5 3
0 =  sin =
Sol. (D) sin r 4/3 4
zero gravitational potential
energy level
x 7. An insect moves along a.......................................
Sol. (D) In t time, distance travelled by the insect = V0t

1 2 arc V0 t
Potential energy U = kx – mgx  = =
2 radius R
From graph between U versus elongation x, Distance of the shadow
U from point O is
x = R tan 

x=
mg  V0 t 
0  
K
x x = R tan
2mg
K
 R 

dx  V0  V t V t
4. A particle of mass m0 ..................................
Velocity V = = (R)   sec2  0  = V sec2  0 
Sol. (B) Befor collision dt  R   R  0
 R 
8. Amplitude of simple pendulum....................................
After collision An s . (C)
9. When two blocks connected......................................
Sol. (C,D) The spring pulls both the blocks with same force. Hence
force on both blocks is equal and opposite.
since no net external force acts on system and its initial mo-
mentum is zero, therefore net momentum of system is always
[By momentum conservation in both direction] zero. Hence momentum of blocks are equal and opposite.
10. A wedge is moved rightwards........................................
mv 0 Sol. (B,C) If moving with constant velocity then a = 0
mv0 = 2mv cos + ..........(i)
2 so friction available = µmgcos
= (0.8) (10) (10) (4/5) = 64 N.
mv 0 but mgsin = 60N
0= – 2mv sin ..........(ii)
2 so required friction is 60N.
By (i) & (ii), tan = 45º So net force is zero.
Now again momentum conservation in y–direction and a = 2 î
since due to acceleration N > 80, so favailable > 64N
mv 0 1 v0
= 2mv..  v= . and when a = 10 î then friction is 20N downwards.
2 2 2 2

5. AB is small object dipped ......................................

An s . ( A)

RESONANCE SOL120513 - 1
11. A particle which can move............................................ 15. The maximum shift of.............................
Sol. (B,C) The potential is not quardratic so the motion is not An s . ( A)
sinusoidal or simple harmonic. The motion is periodic since the
16. The tangential acceleration...............................
particle is bounded by the potential. The energy is constant and
An s . (D)
so the particle will move back and forth between a maximum
Sol.(15 to 16)
negative position and the position x = x0 .
From the figure, the centre of mass of two body system (G)
The potential energy is continuous and hence K.E. = TE – U is
continuous. Therefore, speed is continuous. 
The derivative of the potential energy is not continuous at x = 0. moves along a partial circular path with radius . Hence the
Since, force is equal to the negative derivative of the potential 2
energy, the force is not continuous at x = 0. Therefore, maximum shift of centre of mass from initial position is
F
acceleration   is not continuous at x = 0. 2

 2 = 4 m
m
2
m A
12. A rigid body undergoing pure....................................
Sol. (B,C) Angular momentum will be conserved as external torque
G
is zero. / 2
/2
13. A uniform disc (with block) is........................................... B C
m

d(KE )
Sol. (A,B,C,D)P = 0
dt
The centre of mass is at lowest position when AC is horizontal.
 
For block a  2 r , direction of Since gravitational potential energy of system is least at this
 position, its kinetic energy shall be maximum. Thus the speed of
a is continuously changing with time. both objects shall be maximum at this position and as a result the
Normal force is parallel to axis and for uniform circular motion of tangential acceleration of both object is zero
block friction force 'f' passes through axis of rotation, so torque
17. Actual distance of object.....................................
of these forces are zero about vertical axis.
14. Two persons A and B wear glasses...................................... x
Sol. (C) = 10  x = 20 cm
Sol. (A,B,D) we have f1 = 50 cm and f2 = 100 cm 3
let the real distance between A and B be x. Also let refractive
3/2
index of liquid be . Then
18. Actual distance of...................................
1 3   1 1   1 1  2 2 3 23
  1        =
f1 =  2  R
 1 R 2  R
 1 R 2  f1
Sol. (C)  
 20  y  20  y = 20

1  3   1 1  1 2  3  2  19. The system shown is in..................

  1       Ans. 03
f1 =  2   1R R 2  f1 =
f1  2 
Sol. F sin = (F cos)
1 2  3  2  tan = 
and =    = 0.75
f2' f2  2  4 = 3.
Now, for A we have
20. In figure shown minimum mass......................................
 1   1  2  3  2  Ans. 03
–   –   =   Sol. Minimum for required,
 200    x  50  2 
mg mg
1 1 2  3  2   =
 =    ...(1) 1 2 2
x 200 50  2 
Also for B we have 1 1
1
=  2 =  = 3.
1  1 2  3  2  3 3 2
–    =  
100  x  100  2  21. The blocks of mass m 1 = 1 kg....................................
An s . 10
1 1 2  3  2 
so,     ....(2) Sol. For the block of mass m 2 , not to move, the maximum
x 100 100  2  compression in the spring xo should be such that
from (1) and (2) we get kxo =  m 2 g .... (1)
Applying work energy theorem to block of mass m 1 we get
2(3  2 ) 1 1 2(3  2 )
 100 (2 ) + 100 = 200 + 50 (2 ) 1 1
m1 u 2  k x o2   m1 g x o .... (2)
2 2
2(3  2 )  1 1  1 1 1 From equation (1) and (2) we get
    =  =
(2 )  50 100  100 200 200 1 1  2 m 22 g2  2 m1 m 2 g2
m1 u2  
(3  2) 1 2 2 K K
   6 – 4 =  putting the appropriate value we get u=10m/s.
2 2

6 12
so = =
5 10

RESONANCE SOL120513 - 2
22. An object lies in front of...................... 34. An ideal gas is taken from the same .............
An s . 20 Sol. (CD)
Sol. The figure shows the image Since work done on the system, is maximum in single stage
formation compression hence all other adiabatic points will fall between 1
(2t + nx) + t – (t + nx) = 4 m and 2.
t = 2 cm Ans.
5. Select correct ............
Sol. (BC)

PART-II (Chemistry)
23. If series limit (in nm) of a series of hydrogen .............. ( A ) PCl3F2
Sol. (A)

hc 12400 e V Å  = zero (non-polar)

E= E=


12783 .5 Å = 0.97 eV Hybridisation of central atom = sp3d.
Shape of molecule about central atom / ion = trigonal
hence the photon will belong to the Paschen series bipyramidal.
(0.66  E  1.51)
Hence series limit

hc 12400
 n =  to n = 3  = = PCl2F3
E 1.51
24. The order of first electron ..............
Sol. (B)
 zero (polar)
O has exceptionally smaller value of electron affinity (–141 kJ–1 Hybridisation of central atom = sp3d.
mol) due to smaller atomic size than sulphur (weaker electron- Shape of molecule about central atom / ion = trigonal
electron repulsion in 3p-subshell). It is less than Se and Te also. bipyramidal.

25. The gaseous decomposition ...............

(B)
Sol. (B)
Cl2O7 (g)  Cl2 (g) + 7/2O2 (g)
t = 0 P0 0 0
(C) C6H6
t = 15 P0 – P P 7/2 P
t= 0 P0 7/2 P0
 = zero (non-polar)
Hybridisation of central atom = sp2.
t =  9/2 P0 = 900 mm of Hg Shape of molecule about central atom / ion = trigonal plannar.
P0 = 200 mm of Hg

t = 15 min P0 + 7/2 P = 375

P = 50 mm of Hg B3N3H6

PCl2 at t   P0 200
= = = 4. Ans. 4.  = zero (non-polar)
PCl2 at t  15 P 50 Hybridisation of central atom = sp2.
Shape of molecule about central atom / ion = trigonal
plannar.
26. Potassium dichromate ............
Sol. (C)

K2Cr2O7  K2Cr2O4 + O2 + Cr2O3
(D) ICl2–
27. The SRP for S2– ..............
Sol. (C)
0.0591  = zero (non-polar)
E0 2   E0  log Ksp E = – 0.694 V Hybridisation of central atom = sp3d.
S / CuS / Cu Cu2  / Cu 2 Shape of molecule about central atom / ion = linear.
28. Boron can be obtained ................
Sol. (D)
29. Amongst the following which ................ I3–
Sol. (B)
30. The preparation of SO3(g) ...............
Sol. (B)  = zero (non-polar)
31. Which of the following ................. Hybridisation of central atom = sp3d.
Sol. (ABD) Shape of molecule about central atom / ion = linear.

(C) SO42– + 3Hg2+ + 2H2O  HgSO4.2HgO  (yellow) + 4H+. 36. Which of the following .............
Sol. (ABCD)
32. Which is (are) the correct ................
Sol. (ACD) 37. The sum of pressure inside ...............
Greater is the extent of disorder, greater will be the molar entropy. Sol. (D)
33. Saturated hydrocarbon gas ............
Sol. (BD) 38. If the compartments initially ..............
Sol. (D)
(A) Pressure in compartment 1 = PºL = 500 torr, Pressure is
compartment 2 = PºS = 300 torr.
P total = 800 mm Hg.

RESONANCE SOL120513 - 3
 (B) The compartments contain air at 800 mm Hg initially. Let the Sol. (40)
piston move towards the right side, so as to cause a change in
volume by 'x'. Then since P1V1 = P2V2. MCaCl2 = 111 g
For compartment 1, for dry air only
800 V = P1ƒ.(V + x) 222 324
nCaCl2 = = 2 mole nH2O = = 18 mole
111 18
Relative lowering in vapour pressure
P0  PS n1i 100  80 i 2
R.L.V.P. = =
P0 n1i  n 2 = 100 = i  2  18
2i
= 0.2 = or 0.4i + 3.6 = 2i
2i  18
i = 2.25.
So i = 2.25
For CaCl2  i = 1 + (n –1) 
2.25 = 1 + (3 – 1) 
1.25
For compartment 2, for dry air only  = = 0.625.
800 V = P2ƒ.(V – x) 2
In this pressure of dry air, vapour pressure will also get added 64 × 0.625 = 40.
up. Also, pressure on the either side of piston must also be
44. The value of equilibrium ...............
same finally, since it is freely movable. Hence :
Sol. (20)
P1ƒ + PºL = P2ƒ + PºS
rGº = – RT ln Keq
(800 V ) (800 V )
Thus, + 500 = + 300 nFE º 2  0 .6
(V  x) ( V  x) or log Keq =   20
RT  2.303 0.06
or x = ( 17 – 4)V = 0.125 V
Thus, V1ƒ = 1.125 V, V2ƒ = 0.875 V  V1 = 2.25 Lit. K = 1020.
PART-III (Mathematics)
39. Which of the following statements ................
Sol. (B) 45. If a pair of variable ............................................
Sol. (D)
40. If x-axis is the molecular axis ..............
Let the point of intersection of tangents A and B be P (h, k), then
Sol. (C)
41. A sample of calamine ore (ZnCO3) ............. xh yk
equation of AB is   1 ...(1)
Sol. (16) 4 1
Let total mass of sample = 100 g
2 2 2
m ZnCO3 x y  xh yk 
 = 62.5g and mclay = 37.5 g Homogenizing the ellipse using (1)     
4 1  4 1 
ZnCO3  ZnO + CO2
125g 44g
62.5 g 22g A
mH2O + mCO2 = 28g  mH2O = 28 – 22 = 6g
O P
6 B
 % loss in weight of clay =  100 = 16
37.5
42. An element X (atomic weight = 24 gm/mol) ..............  2
2 h 4 2hk
 2 2
Sol. (96) x 
 16 
 y k 1 
4
xy  0   ..(2)
Z.M  
Theoretical density =
NA .a3
Given equation of OA and OB is x 2  4 y 2  áxy  0 ...(3)
4  24  10 –3  2 and 3  represent same line, Hence
= = 2.5 × 103 kg/m3
6  1023  ( 4  10 –10 )3
Observed density h2  4 k2  1 hk
 
% occupancy = ×100 16 4 2á
Ideal density

2.4  103 h2  4  4 k 2  1  h2  4k 2  0
 
= 3 × 100 = 96%
2.5  10 h  2k  h  2k   0  locus x  2y x  2y   0 .

a b c
46. If 2  , ....................................
bc c b
43. ................. Sol. (D)

a b c
2    a  b  c  2 bc
bc c b

RESONANCE SOL120513 - 4
 2 52. Let a curve ....................................
a  b  c   a b c  a  b c 0  dy
 a b c 0 a  b  c  0  a, b, c  0 
Sol. (B) Given y  x , ydy = x dx, y 2  x 2  c
dx
Comparing with ax  by  c  0
f 1  3  9  1  c  c  8  y 2  x 2  8,
Hence x = -1, y = 1 then –a is not real
47. If |z - 1| = 1 and ....................................
f x   x 2  8 , f 4   16  8  2 6

Sol. (B) z 1  1 represents a circle with centre at 1 and radius 53. If the sum to n ....................................

r2 2r  1  r 1 1
ð Sol. (BD) Tr  r
 r
 r 1
 r ,
equal to 1. We have OPA  2 r  1.r 2 r  1.r 2 .r 2 r  1
2
n n
y 1 1 1
Sn   Tr   r 1
 r
 1 n .
r 1 r 1 2 r 2 r  1 2 n  1
P(z)
 2 54. Let f(x) =....................................
x
O 1 A
 0 x0
 2
 x sin x  x  ( 1,1)  0
Sol. (AD) f(–x) =  = – f(x)
2z ð z  2 AP x x |x||
 arg     i , Now in 
0z 2 z OP
odd function

AP z2 55. The triangle formed by ....................................

OAP, tan è  . Thus  i tan è . Sol. (C) f ’(x)=2x-a At (2, 4), f ’(x) = 4 - a equation of normal at (2,
OP z
1
48. In ABC, if b2  c 2  2a 2 .................................. 4) is y  4   x  2 .
4  a 
Let point of intersection with x and y axis be A and B respectively
R b2  c 2  a2
  then
abc cot A 1
 
Sol. (A) R a 2  c 2 – b 2
 R a2  b2 – c 2
  cot B  cot C 2 .
  4a  18  9
abc

abc
A   4a  18, 0 , B   0,  , Hence a  as,
 a  4  2
49. The abscissa of point .................................... 1
Sol. (B) Slope of such normal is 1.  area of triangle  4a  18 4a  18  2
2 a  4
dy
 =1
dx 17
 4a  17  a  5   0  a  5 or .
ay2 = x3 4
dy 56. The solution of ....................................
2ay = 3x2
dx Sol. (ABC) a1 / 3  b1 / 3  a  b 
1/ 3
is true, when either a = 0
2
3x2  3x2  4a 3
 y=  
a
 = x3  x= or b = 0 or a + b = 0  x  0, , 1.
 2a 
 9 2
2a
1/ 3
a1 / 3  b1 / 3  a  b  lR; gSt c a = 0 ;k b = 0 ;k a + b =
50. Let f : X  Y, f  x   sinx  cos x  2 2 ...............
 ð  ð 3
Sol. (A) f x   2 sin  x    2 2 or f x   2 cos x    2 2  Y 
4 4
 2, 3 2  0  x  0, , 1.
  2
 3ð ð   ð 5ð  57. If f(x) be such that....................................
and X   ,  or  , .
 4 4 4 4  Sol. (AD) Clearly from the graph, f(x) is continuous  x R
but not differentiable at -1, 0, 1, 2 (4 points).
51. The number of values....................................
Sol. (B) x4 = 2x + 2y

dy y=x-2
or = 2x3 – 1 y=2-x
dx (0, 2)
3
if, 2x3 – 1 = – ( 3x + 4y = c touches the curve) (2, 0)
4
1 1 1 15
 x=  y= – =– -1 1 y = 2-x3
2 32 2 32
 only one value of c is possible

RESONANCE SOL120513 - 5
58. The point of inflection ....................................
Sol. (ACD) 63. Let A 2iˆ  3ˆj  5kˆ , B ˆi  3ˆj  2kˆ
    .................
Ans 17
dy  x 2  2x  1 d2 y 2x3  6x 2  6x  2 Sol. P.V.of
 2
and  ,
dx x2  1  dx2
 x2  1
3
  ë 1 ì2
D î  4 ĵ  k̂ ,
2 2
d2 y D.R. of AD 
 5
, 1,
8
2 is 0 at three points which are the roots of the equation 2 2
dx
A 2 î  3 ĵ  5k̂
x 3  3 x 2  3 x  1  0 , i.e.  2  3 ,  2  3 , 1 .

dy  x 2  2x  1 d2 y 2x3  6x 2  6x  2
 2
and  ,
dx x2  1  dx2
 x2  1
3
 
B D C
 î  3 ĵ  2k̂  î  5 ĵ  k̂
i.e.  2  3 ,  2  3, 1 .

d2 y 1
,
1
,
1
Checking the sign of 2 in the neighborhood of these points,
But direction ratios of AD should be ,
dx 3 3 3
all these are the point of inflection.
5 8
 1 ,   7,   10,     17
59. The area of the largest .................................... 2 2
Ans. (B)
60. Total distance travelled .................................... 64. If 6-digit number ....................................
Ans. (D) ans 27
Sol. 59-60:
Sol. 6 abcdef  defabc
 , 6 1000abc def  1000def  abc
   ,
x  y  21     0   x  2  y  2   0 , pass
5999abc = 994def  857abc  142def ,
through (–2, 2)
abc = 142, def = 857, the number is 142857.hence sum=27
x  y  21     0   x  2  y  2   0 , (-2, 2)
65. Suppose that the side ....................................
ìx  y  21  ì   0  ì x  2  y  2  0 pass ans- 15
through (2, 2). Sol. Let B= 2A and BD be bisector of the angle B,then
Clearly these represent the foci of ellipse, so 2ae = 4.
ab cb
2 CD  and AD  ,
The circle x 2  y 2  4 y  5  0  x 2  y  2  9 ac ac
represents auxiliary circle thus Now  ABC and  BDC are similar,so
2 2 2 BC CD ab
a  9  e  and b  5 .Area of the largest triangle 
2
a 
2
b  b  aa  c  ...(1)
3 AC BC ac
 abe  2 5 .
The total distance = sum of focal distances = constant. B

A A c
61. p1 + p2 is ....................................
a
Ans. (C)

62. AB . OB .................................... C D A
Ans. (C) Since b > a  either b = a + 1 or b = a + 2, if b = a + 1 then
Sol. 61-62
from (1)
r  x î  yĵ , x 2  y 2  8 x  10 y  40  0 , centre C(-

Let 1
a  12  a  c  a  c 2 ,
4, 5) radius (1), 
p1  max x  2  y  3 
2 2
 a
2 2  c is integer  a  1, b  2, c  3 , but then no triangle

p 2  min x  2  y  3  ,  CP  2 2, CA  1 , will form.
2 2 2 1
p1  AP 2  2 2  1 , p 2  BP  2 2  1 ,
    a  12  a  c  a  c 2 ,
a
p1  p 2  18 (tangent is drawn) If b = a + 2 then obviously c = a + 1 and then from (1)

 dy  a  22  a2a  1  a 2  3a  4  0 or a4

slope of AB     2 , equation of AB, 2x + y = 6
 dx  2, 2  a  4, b  6, c  5 is the only possible solution. Hence
perimeter is 15
OA  2i  2 j , OB  3i , AB  i  2 j , AB . OB  i  2 ĵ 3 î  3   
a  22  a2a  1  a 2  3a  4  0 or a4

RESONANCE SOL120513 - 6
66. If f(x + y + z) = f(x) + f(y) ..................................
6. A prism of angle BAC = 45° .......................................
Ans. 12
Sol. (D) For ray to be normally incident on side AC,  AQR is 45°.
Sol. f 3   3 f 1  3, f 4   f 2  1  1  2  1  1  4
Hence n sini = 6 sin45° so n > 3
and so one. In general, we get f(r) = r for r N. 7. An aeroplane flying at ....................................
n Sol. ( A) For 1/4 cycle it takes 15 sec.
Therefore T = 60s N
3  4r  f 3r 
r 1 36nn  12n  1 TV
 lim 3
 lim 3
 12 . 2 r
n n n 6n T=  2 E
V

V 2 2V 7
PAPER-2 and
r

T
=
2
m/s 2
S

PART-I (Physics)
1. A uniform ring and a uniform................................... 8. A horizontal plane supports.................................
An s . (D)
Sol. (A) A s 2 = 02 + 2
  9. A uniform bar of mass M.................................
Sol. (A) Angular momentum will conserve about A just before and
0= 2 – 2.(2n) just after collision.
2 L mL2 L
= mv0. cos = . – mv.. cos
4n 2 12 2
Now same torque is applied Ring disc
 1 = 2
1 1 = 22
1 2
Mr2= Mr 2
2
2 = 21 = 2
6( v 0  v ) cos 
 2 = 02 + 2 = .
0 = 2 – 2.2 2n' L
8 n' = 2  n' = n/2. 10. A train is running at a speed of....................................
2. A block is placed on a rough................................... 5
Sol. ( A) Till block starts moving x =0. Sol. (B) 108 km/h = 108 × = 30 m/s
Aft erwo rds 18
Kx = mg sin – mg cos 
30m/s 10m/s v1 v2
mg sin    mg cos  Train Cart Train Cart
x= M m M m
K
From momentum conservation
x is maximum at  = 90°.
M× 30 + m× 10 = Mv1 + mv2 ...(i)
3. An insect is moving on an.......................................... e × velocity of approach = velocity of separation
Sol. (D) To move downwards, the insect has to apply friction force
on the incline in upper direction, so its reaction will act on the 1
 × (30 – 10) = v2 – v1
insect in downward direction. 2
Fnet = fr + mg sin  = m (a)  10 = v2 – v1 ...(ii)
(m) amax = (fr)max – mg sin   On solving ,

(m) amax = (s mg cos ) – mg sin  10

40  m .
amax = s g cos  + g sin  M  40  m  10 M
v2 = m/s =  40 m/s
 Mm m
4. A force F = (3 t î  5 ĵ ) N acts on................................... 1
M
Sol. (B) W =  F . ds =  (3t î  5 ĵ) . (4t dt î ) 11. The extension in spring when......................................
Sol. ( A) From work energy theorem, the masses stop when-
total work done on them is zero.
2 2
2 12 t 3  1 2 2 mg 3 mg
= 12 t dt =
 0 = 32 J
W = mgx – kx – mgx = 0  (1 – ) =
0 3 2 k 2k
5. Figure shows a plot of potential............................................ 12. The minimum value of  ...................................
dU Sol. (B) When the masses are stopped at this value of x, the
Sol. (A) F = – forces on left mass for it to remain at rest is zero
dx

 U(x) = kx2 2 mg
 kx = mg + f  k (1 – ) < mg + mg
k
  > 1/3  least value of  is 1/3.
F = –2kx
RESONANCE SOL120513 - 7
13. The magnitude of normal...................................
Ans. (C) 100
s= 4m
14. The magnitude of normal................................. 24.8
Ans. (B) time to reach the hishest point
Sol.13 to 14. V = u + at
FBD of rod and cylinder is as shown. O = 10 + (12.4) t

10
t=  0.8 sec
12.4
and after that the block will remain stationery a becouse tan
 < s . So in 2 sec distance travelled is 4 m.
19. A light rigid rod of length............................................
Ans. 8
Net torque on rod about hinge 'O' = 0
20. A vertical narrow smooth tube......................................
L mg 5g Ans. x=7
 N1 × L = mg × or N1 = = = 25 N
2 2 2 Sol. By energy conservation v = 2gh = 2  9.8  2.5
Net torque on cylinder about its centre C is zero.
 f1R = f2 R or f1 = f2 v = 7 m/s  x = 7.
Net torque on cylinder about hinge O is zero. 21. A uniform rod of mass 200 grams.....................................
An s . 9
3mg 3  5g
 N2 × L = N1 × L + mgL or N2 = = = 75 N Sol. From conservation of angular momentum.
2 2
 2 2 2
15. The speed of the wedge......................................
L L 2m L  m  L    L   
mu + mu =
1 2 1 2 1 2 2  2v 
2
2 2  12 2  2  
Sol. ( A) mgh = mv + mv + . mv  
2 2 2 5  r 
 mL2 mL2 mL2  2 mL2
2 muL =     = 
1 2 8 1 2 18 9 mv  6 4 4  3
= mv [1 + 1 + ] = mv =
2 5 2 5 5
3u 36
or =  = 9 rad/s
5 2L 21
 v= gh
9 22. A system consists of two......................................
Ans. 9
16. The total kinetic energy................................
1
2 Sol. KEA/CM = .1.(vA/CM)2 = 2 Joules
1 1 2  2v  13 2
Sol. (D)KE of the ball= mv2 + mv2   = mgh
2 2 5  r  18  VA/CM = 2 m/s.
Let ; COM move towards +ve x-direction.
17. Match the column........................................... 
Then, v A / CM = 2 î
Ans. (A) – (p,q) ; (B) – (p, q, r, s); (C) – (q) ; (D) – (r, s)
Sol. Let acceleration of 1kg block be a1 and 4kg block be a2  
 m1v 1  m 2 v 2
1  vB/CM =  î ( Use ; v CM =
m1  m 2 )
(p) 1 = 0 , 2 = (f ) = 25 N
2 2 max
1  2 1  2
5  KESystem =
2
 
.1. 2 î  v CM + .2  î  v CM
2
 
a1 = 0 , a2 = = 1.25 m/s2
4
1 2  1 2 
1 =
2

4  v CM 
 2.2 î.v CM  .2. 1  v CM
2
 2.î.v CM 
(q) 1 = , 2 = 0
2  
a1 = a2 = 3 m/s2 No sliding occur between the blocks = (2  2  2 î.v CM )  (1  4  2 î.v CM )
= 9J Ans.
1
(r) 1 = , 2 = 0
2
PART-II (Chemistry)
30  5 5
a1 = = 25 m/s2 ; a2 = m/s2
1 4 23. Complexes formed .............
Sol. (B) (I) Mond's process for purification of Ni-[Ni(CO)4]
1 (II) Removal of unreacted AgBr from photographic plate–
(s) 1 = 0 , 2 = [Ag(S2O3)2]3–
2
(III) Removal of lead poisoning from body –[Pb(EDTA)] 2– .
a1 = 30 m/s2 , a2 = 0
18. A block of mass m is slided.............. 24. Which gas shows real ...........
Ans. 4 Sol. (C)
Sol. Displacement till it comes to rest
V2 = u2 + 2as 25. A gas is collected by downward ..............
O2 = (10)2 + 2 (–(g sin + k gcos)) (s) Sol. (A)

RESONANCE SOL120513 - 8
26. Three closed rigid vessels ................
Sol. (A) 5
time of electrolysis = = 500 minutes.
3 10  10 – 3
Total heat recieved by gass = heat provided 2 × R (Tf – 300)
2 1
+ 2 × 3 R(Tf – 400) Cu2+ (aq) + H2O  Cu (s) + O + 2H+ (aq).
2 2
5
+3× R (Tf – 500)= 15600 i t 0.04825  500  60
3  moles of H+ formed = =
F 96500
Tf = 900 K
= 0.015 M
900  0.0821 7
Pf = 35. What would be the ionisation ..............
7 Sol. (B)
Pf = 73.89 atm
CH3COOH + NaOH CH3COONa + H2O
27. The enthalpy of combustion .............. 150 × 0.1 50 × 0.1
Sol. (A)
C3H8(g) + 5O2(g)  3 CO2(g) + 4H2O(l) [salt ]
pH = pKa + log (Since acidic buffer)
[acid]
6  B.E.(C  O ) 
8  B. E.(C — H)    50  0.1
    8  B.E . ( O — H) 
CH =   2  B.E.(C — C) –  4.7 = pKa + log
 3 | R.E. | of CO 2  100  0.1
  5  B.E.(O  O )   
 4   vap H (H2O )  pKa = 5 ka = 10–5

36. What will be the pH .............

28. Which of the following reactions ................ Sol. (D)
Sol. (D)
CH3COOH + KOH CH3COOK + H2O
29. The gaseous decomposition ............... m mol 150 × 0.1 150 × 0.1
Sol. (B) m mol 0 0 15

A (g)  2B (g) + C (g) 15 1

[CH3COOK] = =
Let initial pressure P0 0 0 300 20
After 10 min. (P0 – x) 2x x 1 1 1
After long time (t) 0 2P0 P0 pH = 7 + ×5+ log ( Salt of WA + SB)
as per given (P0 – x) + 2x + x + vapour pressure of H2O = 188. 2 2 20
P0 + 2x = 160 and 3P0 + 28 = 388
1
so, P0 = 120 and x = 20 torr pH = 7 + 2.5 – × 1.3
2
1  P0  pH = 9.5 – 0.65 = 8.85
k= ln  
t  P – x  = 0.02 min–1 = 1.2 hr–1.
 0  37. Which of the following gases ..............
Sol. (C)
30. The distance between two ..........
Sol. (D) 38. What would happen if the gas E ..............
227
Sol. (A)
31. Ac has half-life of 22 years ............. ZnS + 2H+  Zn2+ + H2S 
Sol. (B) (white) (colourless) (colourless)
2 A C B
0.693 1
 Cr2O72– + 14H+ + 3S2–  2Cr3+ + 7H2O + 3S
 = 1 + 2 ;  = and
22  2 98 (H2S) (green) (yellowish white)
1 = 0.00063 year–1; 2 = 0.03087 year–1 B D
S + O2  SO2 
32. Select the correct statement............ D E
Sol. (B) SO2 + MnO4– + H+ SO42– + Mn2+
33. Calculate e.m.f. of the ............
Sol. (C) 39. Reactions are listed in ...............
Ans. (A-p,s; B-q; C-r,s; D-r)
1 Sol. (A) P4 + 8 SOCl2  4PCl3 + 4SO2 + S2Cl2 (dimeric halide)
Cell reaction is, H2(g) + O (g)  H2O() (B) 2KI + H2O + O3 2KOH + ºI 2  O º
2 2 2
V O / heat
0.06 1 (C) SO2 + O2 25  SO3 ; SO3(s) exists as (SO3)3–
Ecell = 1.246 – log P  P cyclic form, at room temperature.
2 H2 O2
heat in a sealed tube
(D) 3H3PO3 + 3Br2       (HPO3)3 + 6HBr..
0.06 1
= 1.246 – log
2 20 10 40. 63.5 kg sample of K2C2O4 . 3H2C2O4 . 4H2O ............
Sol. (5)
0.06 1
= 1.246 + (1.3 + ) = 1.246 + 0.054 = 1.3 V.. Eq. of salt = Eq of KMnO4
2 2
34. The above fuel cell is used completely .................
x
× 8 = 10 × 5
Sol. (A) 508
V 1. 3 5080 5.08
i= = = 0.04825 A. x = 5× g=5× kg
R 26.94 8 8

RESONANCE SOL120513 - 9
 5  5.08 49. If in a ABC, cos A.cosB ..................................
% purity = × 100 = 5
8  63.5 Sol. (D)
cosA.cosB + sinA.sinB.sinC = 1

41. The compound Na2IrCl6 reacts ............. 1 cos A cos B

 sin C = 1
Sol. (1) sin A sin B
Coordination number of Ir is four. Ir is in (+1) oxidation state ( max (sin Q) = 1, Q  R)
with 5d8 configuration. So its hybridiation should be dsp2 on
account of higher CFSE. 1 cos A cos B
 –10
[IrCl(CO)(PPh3)2] sin A sin B
 1 – cos A cos B – sin A sin B  0
 1 – cos A cos B – sin A sin B  0
 cos (A – B)  1
Hence only possible is cos (A – B) = 1  A = B
1  cos 2 A
 the given relation reduce to sin C = =1
sin 2 A
All electrons are paired, so number of unpaired electron is zero.  C = 90°.
Therefore, 0 + 1 = 1
42. In the spinal structure oxide ions .............
Sol. (1)
50. If arg z  = 21 arg....................................
1/ 3

43. The hybridization of central atoms ............. 1/ 3 2 1/ 3

Sol. (B) 2 arg z  = arg z  zz 
Sol. (6)
P=3 Q=2 R=1 S=0
Hence P + Q + R + S = 6.  z 2  zz1/ 3   4/3 z 
z
   1/ 3  = 0
arg  z2 / 3  =0  Img.
44. How many of the ............    z 
Sol. (4)
Ge, graphite, SiC, SiO2  4/3 z   z 
z  1/ 3    z 4 / 3  1/ 3 
 z   z 
 =0
PART-III (Mathematics) 2i
45. If the equation ....................................
Sol. (C)  1 
x 2  bx m  1
  (m  1)x 2  b (m  1) x  (m  1)(ax  c )
 z 4/3
 z 
4/3
 1  | z | 2/3 

=0
ax  c m 1
|z|2/3 = 1 or z = z (not possible)
 (m  1)x 2  ((a  b)  (a  b)m ) x  c (m  1)  0
|z| = 1. z not real number

46. Complete solution .................................... 51. Let P, Q, R be points with.................................

Sol. (C)  
2[x]2 – 11[x] + 12  0 Sol. (B) Equation of the plane OQR is r =  r2 + µ r3 ,
 2[x]2 – 8[x] – 3[x] + 12  0  (2[x] – 3) ([x] – 4)  0  
 [x] = 2, 3, 4  x  [2, 5) i.e. r . ( r2 × r3 ) = 0
  
 1– x2  r1.( r2  r3 )
  So the distance of P from the plane OQR is
47. If cos + ...........................
| r2  r3 | .
–1
 1 x2   
 
Sol. (C) Let x = tan    
Since r2 × r3 = – 10 î + 10 ĵ – 5 k̂ , so | r2 × r3 | = 15
  
Since x  [– 1, 0]    – , 0 – 30 – 20  5
 4  and the perpendicular distance = =3
cos–1 (cos 2) = – 2 15
Also , sin–1 (sin 2) = 2 52. Let f(a, b) ....................................
cos–1 (cos 2) + sin–1 (sin 2) = 0 Sol. (A) c2 c2 – ac1
 1– x2   2x 
cos –1
 
 1 x2  + sin–1   = 0 x  [– 1, 0] a 0 0
 1 x2 
  f(a, b) = 1 a  b (a  b ) 2
k = 0
48. The co-ordinates ....................................
0 1 a  2b
Sol. (C) = a(a + b) (a + 2b – a – b) = ab(a + b)
shortest distance will be part of the common normal of
parabola as well as circle any normal of parabola y2 = 8x 53. Minimum value of  ....................................
will be
y = mx – 4m –2m 3 at the point (2m 2, – 4m) 4
this normal will be normal of circle also. So it will pass through Sol. (D) Given equation  9ax + =+2
centre of circle i.e. ax
– 6 = 0 m – 4m – 2m 3 2m 3 + 4m – 6 = 0 By AM  GM, we have LHS  12
real value of m. m = 1 will be  for real solution  + 2  12    10
 point will be (2, –4)

RESONANCE SOL120513 - 10
54. The sum of the square .................................... 58. If  = 3, then ....................................
Sol. (A) For  = 3
n
Sol. (C) If AB is the chord x + y = n, then OM = 1 3 5  3 2 4 
2
   
A =  2 4 8  and B = 3 2 5 
3 5 10  2 1 4 
 tr(AB) + tr(BA) = 2tr(AB)
 tr(AB) = C11 + C22 + C33 = 119
1 1
 (tr(AB) + tr(BA)) = (238) = 34
 2 n2  7 7
2 2
Thus (AB) = (2AM) = 4 × (AM) 2
= 4 2   = 2(8 – n2)
 2  59. If a,b be positive and....................................
Ans. (C)
60. If a, b, c be distinct ......................................
Hence the required sum = 2 [8 – 12 + 8 – 22] = 2(16 – 5) = 22 Ans. (B)
1/ 3 1/ 3
55. Circumcentre of .................................... a1 / 3  b1/ 3  a  b   1
Sol. 59 <   =  
Sol. (A) PT2 = PT1 = (– 4)2  0 2 – 4 = 2 3 2  2  2
circum centre of triangle PT1T2 is mid point of PO as 2
 A< 1/ 3  A < 22/3
2
n
an  c n  a  c 
60. >  
2  2 
n
ac
or an + cn > 2   ..........(i)
 2 
but we know that AM > GM > HM
 AM > HM
PT1O = PT2O = 90º
ac
– 40 00 >b
, 2
so ,   = (–2, 0)
 2 2 
n
ac
  > bn
56. Ratio of the area ....................................  2 
Sol. (D) P be a point on the circle
n
  ac
3    2  > 2bn ..........(ii)
2 6  2 
Area of the rhombus from (i) and (ii) an + cn > 2bn

an  c n
or > 2 or  > 2
bn

 2 a
61. (A) If tan–1  x  x   
 4
Ans. (A)  r, (B)  q, (C)  p, (D)  q

= 
2 3 3  6 3  Sol. (A) x2 + x +
a
must be greater than 0
Ratio is 1 : 1 4
2
 1  a  1
57. If matrix 2A + 3B is ....................................  x   +   > 0,  x  R
 2  4 
11 12 2  16   a–1>0
Sol. (D)  2A + 3B = 13 14 31 
  a>1
so smallest [a] = 1
12 13 32 
x 2  3x  2
 |2A + 3B| = 0 (B) <0
x 2  7 x  10
17
we get  = ( x  1) ( x  2)
2
 2 = 17

( x  2) ( x  5) < 0 , x  2

RESONANCE SOL120513 - 11
  x  (1, 5) – {2} 65. Let a, b, c  R+ and ..................................
 x=3 Ans. 3
       
(C) [ ab a  b ] = a  b.a  b n
n
  Sol. lim 
= | a  b |2 = 4 n  k  k
k 1 n2  a    b  
(D)  |x – a| is not differentiable at x = a  n  n
 f(x) is not differentiable at x = 0.5, 1, –1, 2
n
But 2  (–2, 2) so only 3 points 1 1
= nlim
 n
 k  k
62. The number of zeros ...................................... k 1 a   b  
Ans. 2  n  n
Sol. Since, one pair of 2 and 5 makes 10 (i.e. 2 × 5 = 10)
which gives one zero at the end. 1 1
1 1 (a  x ) – (b  x )
Hence 56, 1011, 1516, 2021, 2526, 3031, 3536, 4041, 4546, 5051 = dx =  dx
Total number of fives

0
(a  x ) (b  x ) a–b 0
(a  x )(b  x )
= 6 + 11 + 16 + 21 + 2.26 + 31 + 36 + 41 + 46 + 2.51
1
10 1  1 1 
=
2
(6 + 51) + 51 + 26 = 362 =
a–b   b  x – a  x  dx
0
Clearly number of 2's is greater than that of 5's.
Thus number of zeros at the end = 362. 1
=
a–b
n b  x  – n a  x 10
63. A curve passes through ..........................
Ans. 2 1
1  (b  x )  1 (b  1) a
=  n  = n
dy
Sol. = x2 – 2x
a–b  (a  x )  0 a–b (a  1) b
dx
 A+B+C=3
3
x
y=  x2  C
3  y2 y 2 
66. If f  2x 2  , 2x 2  = xy, ......................
Passing through (2, 0) 
 8 8 
8 4 Ans. 4
 0= –4+C C 
3 3
 y2 y 2 
Sol. f  2x 2  , 2x 2 
x3 4  8 8 
 y=  x2  
3 3
y = x2 – 2x = x(x – 2)  y = 0 if x = 2. 2 2
and at x = 2, y takes the minimum value.  2 y2   2 y2 
= xy =
 2x     2x  
 8   8 
8 4 
 minimum value of y is =  4  = 0  a = 2, b = 0
3 3
a + 6b = 2
1
 {f(60, 48) + f(80, 48) + f(13, 5)}
28
64. Slope of tangent at a point of .......................... =
Ans. 1
Sol. Equation of tangent at (2a, 0) 1 
y – 0 = m (x – 2a)
602  482  802  482  132  52 
28  
y = mx – 2am ... (i)
1
x2 y2 = [36 + 64 + 12] = 4.
For tangent to the ellipse  1 28
a2 b2
2 = a2m2 + b2
3a2m2 = b2

b2
3m2 =
a2

b2  b2 
value of 3m2 + e2 =  1 – 2 
2 =1
a  a 


RESONANCE SOL120513 - 12