Corrosion Resistance of Self-Compacting Concrete Containing Calcium Stearate
Corrosion Resistance of Self-Compacting Concrete Containing Calcium Stearate
Corrosion Resistance of Self-Compacting Concrete Containing Calcium Stearate
Abstract
This study aims to determine the corrosion resistance of self-compacting concrete
(SCC) combined with calcium stearate (CS), Ca(C18H35O2)2. The concrete
qualities tested are 20, 30, and 40 MPa. The CS dose used ranges from 0 to 2.85%
of the cement weight. Two types of testing were performed in this study, namely
compressive strength and accelerated corrosion tests. The compressive test was
performed using cylinders 150 mm in diameter and 300 mm in height and
accelerated corrosion specimen was a prism 100 x 100 x 200 mm. The results
show the improvements of the compressive strength of SCC 20, 30 and 40 MPa
without and with CS are 28, 31, 28, and 37%; 16, 8, 10 and 3%; and 20, 14, 6
and -2% respectively, compared with conventional concrete. The corrosion attack
decreased by around 29, 46, 86 and 86% for SCC 20 MPa with CS content of 0,
0.28, 2.43, and 2.85% respectively; 23, 27, 34, and 65% for SCC 30 MPa with
CS content of 0, 0.24, 1.20 and 2.40% respectively; and around 7, 46, 62 and
63% for SCC 40 MPa with CS content of 0, 0.19, 0.93, and 1.86% respectively
compared with conventional concrete.
Keywords: Calcium stearate, Corrosion resistance, Self-compacting concrete,
Compressive strength, Accelerated corrosion.
3263
3264 A. Maryoto et al.
1. Introduction
SCC is a type of concrete that can consolidate itself without any external vibration.
This type of concrete is made up of cement, crushed stone, sand, water and
admixtures, which usually use a superplasticizer of a high-range water reducer type.
It was first developed in Japan in 1988 [1]. The admixture material is a
superplasticizer that serves to make fresh concrete more flow able, more viscous
[2] and easy to cast [3]. Then the concrete is recognized as SCC. SCC is very
suitable for use in concrete structures that have tight reinforcement. This is due to
its ability to solidify itself. Finally, more solid hardened concrete is obtained
without honeycomb. The porosity present in the hardened concrete is also
extremely reduced [4]. Another advantage is that the need to use skilled labour for
concrete compaction can be significantly reduced. Recent studies have found that
SCC is more resistant to acid attack [5], more difficult for segregation [6], and
suitable for casting on site and in precast concrete [7].
Increasing the superplasticizer dose, as one of the added ingredients in SCC,
increases the compressive strength of the concrete [8]. Although SCC has many
advantages over conventional concrete, the treatment methods affect its mechanical
properties [9, 10]. Practically, SCC can not only be made from Ordinary Portland
Cement (OPC) but can also be combined with the use of fly ash [11] and rice husk
ash [12]. The use of fly ash in the SCC endows the concrete with higher
compressive strength and bending capacity. More specific research has found that
the compressive strength of SCC is lower than that of conventional concrete at 28
days, but higher at 90 days [13].
In terms of its macrostructure, SCC is a very dense material. However, the
microstructure, although the SCC is very solid, still has capillaries. These capillaries
are formed during the cement hydration reaction process. Some of the unused water
in the hydration reaction of the cement evaporates and leaves the capillary pathways.
Corrosive ions, i.e., chloride and sulphate, can then enter through the capillaries [14]
to reach the concrete reinforcement surface in the concrete. Some researchers have
conducted studies on the corrosion progression and prediction of the corrosion rate
[15, 16] in reinforced concrete and prestressed concrete. Corrosion causes a decrease
in the compressive strength of the concrete [17, 18], reduces the volume of the
original reinforcement [19], and causes the loss of reinforcement capacity and
concrete bonds [20, 21], resulting in a decrease in the structural capacity, ductility
and service life of the reinforced concrete. These corrosion defect have resulted in a
rise in the cost of maintaining reinforced concrete structures [22]. When the concrete
cover begins to peel off due to pressure from corrosion products, degradation of
reinforced concrete structures occurs faster [23].
The penetration of liquids that carry corrosive ions into the concrete greatly
threatens the concrete structure with corrosion attack in the long term. The danger
of a corrosion attack on the concrete structure can be reduced by protecting the
reinforcement and increasing the properties of the concrete microstructure [24, 25].
Concrete reinforcement can be protected from corrosion using a coating system or
by increasing the anodic level of the reinforcement bar. Improved properties of
concrete microstructures can be obtained by increasing the hydrophobicity of the
hardened concrete [26, 27, 28]. Some researchers have used butyl stearate [29, 30,
31] and other compounds [32] to improve the properties of conventional concrete
and to protect concrete from corrosion attack. This study aims to determine the
2. Methods
2.1. Material and equipment
The materials used in this study consist of cement (Portland Composite Cement
type, PCC), crushed stone, sand, water, superplasticizer (Viscocrete 1003), calcium
stearate, 3% sodium chloride solution, ammonium citrate solution and plain steel
bar 12 mm in diameter. The chemical content of the cement and calcium stearate
used in the study is shown in Table 1. Physical tests including specific gravity,
fineness modulus, volume weight, sieve analysis, and clay content were performed
on the materials of crushed stone and sand used. The specific gravity, fineness
modulus, volume weight and clay content are 2.65, 2.68, 1.49 ton/m3, 1.13% for
sand and 2.61, 6.47, 1.51 ton/m3, 0.75% respectively. The maximum aggregate
used is 20 mm. Table 2 shows the grading of fine and coarse aggregate. Three
concrete strengths were designed and used as shown in Table 3 and, for each of
these, three standard cylinder molds of 150 mm diameter and 300 mm height, and
three prism molds of 100, 100, and 200 mm were used.
Table 4 shows the variables used in this study. The designation C with two
digits indicates the concrete and its strength, SP means superplasticizer, the three-
digit number after SP represents the percentage contents of superplasticizer by
cement weight, CST is the abbreviation for calcium stearate. The three-digit
number after CST is the content of calcium stearate as a percentage of cement
weight. The calcium stearate contents for SCC 20 MPa are 0, 0.28, 1.43 and 2.85%,
for SCC 30 MPa are 0, 0.24, 1.20, 2.40%, and for SCC 40 MPa are 0, 0.19, 0.93
and 1.865% by weight of cement. A cylindrical specimen with diameter 150 mm
and height 300 mm is used for a compressive strength test at 28 days. Another type
of specimen used for the corrosion test is a beam with dimensions 100 mm x 100
mm x 200 mm. Three specimens each are used for the compressive strength and
corrosion tests.
concrete without superplasticizer and calcium stearate, and code number 2 means
concrete with superplasticizer and without calcium stearate. Code numbers 3, 4,
and 5 are concrete with supplementary superplasticizer and calcium stearate in the
doses listed in Table 2.
Figure 9 shows that the compressive strength of SCC is greater than that of
conventional concrete. This is because the concrete mix proportions in SCC have a
lower water–cement ratio. The low water content causes low pore and capillary
values in the hardening concrete. The hardened concrete formed is denser and
contains fewer capillaries.
SCC with calcium stearate has a compressive strength that tends to be the same
for the 20 MPa quality concrete and tends to fall for the concrete qualities of 30 MPa
and 40 MPa when compared with the SCC concrete without calcium stearate. This is
caused by the formation of material from the reaction of the stearate and calcium
hydroxide. Calcium hydroxide is the residual reaction between C3S and water. This
reaction can be seen in the chemical equations/formulas (2) and (3). The result of this
reaction is a material that coats the capillary surface like a wax. This material has a
weak bond when compared with the calcium silicate hydrate bond. Finally, this
material leads to a decrease of the concrete’s compressive strength.
The compressive strength of SCC without and with calcium stearate is higher
than that of conventional concrete. The increases in compressive strength of SCC
20, 30, and 40 MPa with calcium stearate, compared with conventional concrete,
are 28, 31, 28, and 37%; 16, 8, 10, and 3%; and 20, 14, 6 and -2% respectively.
2C3S + 6H → C3S2H3 + 3Ca(OH)2 (2)
Calcium silicate hydrate
Ca(OH)2 + RCOOH → Ca+COOR- + H2O (3)
Calcium hydroxide(lime)+ stearate → insoluble calcium stearate + water [27].
Table 5. Results of compressive strength test.
Code Specimen Compressive Improved Concrete
no. strength (MPa) compressive grade
designation strength (%) (MPa)
1 C20-SP0.00-CST0.00 19.49
2 C20-SP0.25-CST0.00 24.98 28
3 C20-SP0.25-CST0.28 25.54 32 20
4 C20-SP0.25-CST1.43 24.98 28
5 C20-SP0.25-CST2.85 26.65 37
1 C30-SP0.00-CST0.00 29.75
2 C30-SP0.25-CST0.00 34.42 16
3 C30-SP0.25-CST0.24 32.01 8 30
4 C30-SP0.25-CST1.20 32.75 10
5 C30-SP0.25-CST2.40 30.72 3
1 C40-SP0.00-CST0.00 45.27
2 C40-SP0.25-CST0.00 54.32 20
3 C40-SP0.25-CST0.19 51.50 14 40
4 C40-SP0.25-CST0.93 48.10 6
5 C40-SP0.25-CST1.86 44.14 -2
60
40
30
20
20 MPa
10 30 MPa
40 MPa
0
1 2 3 4 5
Code number
Fig. 9. Compressive strength of concrete 20, 30, 40 MPa.
From Fig. 9, it can be concluded that calcium stearate can be safely used in SCC
with a content of 10 kg per cubic metre of concrete. This can be seen from the fact
that the average compressive strength of concrete without superplasticizer and
calcium stearate was 19.49, 29.75, and 45.27 MPa, while for the SCC with 10 kg/m3
calcium stearate content the values were 26.65, 30.72, and 44.14 MPa for the
concrete qualities of 20, 30, and 40 MPa, respectively. The compressive strength
of SCC concrete with 10 kg/m3 calcium stearate content is still higher than concrete
without superplasticizer and calcium stearate.
water is not able to penetrate into the concrete capillaries without specific
hydrostatic pressure [43].
14
20 MPa
12
30 MPa
10 40 MPa
Corrosion (%)
0
1 2 3 4 5
Code number
Fig. 10. Corrosion of steel bar in concrete 20, 30 and 40 MPa.
4. Conclusions
The effect of using calcium stearate in SCC together with its compressive strength
and corrosion resistance have been discussed in detail. The findings can be
summarized as follows:
Calcium stearate used in SCC has a good effect on the compressive strength and
resistance to corrosion attack by chloride ions.
SCC has better resistance to corrosion attacks by chloride ions compared with
conventional concrete.
The corrosion attack declined by around 29, 46, 86 and 86% for SCC 20 MPa
with calcium stearate content of 0, 0.28, 2.43, and 2.85% respectively; by around
23, 27, 34, and 65% for SCC 30 MPa with calcium stearate content of 0, 0.24,
1.20 and 2.40% respectively; and by around 7, 46, 62 and 63% for SCC 40 MPa
with calcium stearate content of 0, 0.19, 0.93, 1.86%, respectively, compared
with conventional concrete.
The improvements in the compressive strength of SCC 20, 30 and 40 MPa
without and with calcium stearate are 28, 31, 28, and 37%; 16, 8, 10 and 3%; and
20, 14, 6 and -2%, respectively, compared with conventional concrete.
The use of 10 kg/m3 of calcium stearate in SCC 20 and 30 MPa is still structurally
safe because the compressive strength is still greater when compared with
conventional concrete with the same cement content. But in the SCC 40 MPa
with 10 kg/m3 calcium stearate, the compressive strength is a little lower than
that of conventional concrete.
An investigation has been made of the effects of forebody and afterbody shapes
of a series of projectiles on the aerodynamic characteristics at Mach numbers
from 1.6 to 5. This is done using analytical methods combined with semi-
empirical design curves. Some concluding observations from the investigation
are given below.
Acknowledgements
This research is funded by Jenderal Soedirman University through a research grant
with the International Research Collaboration scheme year 2018. PT. Sika Nusa
Pratama Indonesia is grateful acknowledged for giving us the opportunity to use
Viscocrete 1003 as a superplasticizer in the concrete.
Nomenclatures
Abbreviations
C Concrete
CST Calcium stearate
Lt Litre
SNI Standar Nasional Indonesia
SP Superplasticizer
s/a Sand per aggregate
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