Variables Unidades Valor Unidades Valor Unidades Valor: Calculo de Propiedades Dela Mezcla

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CALCULO DE PROPIEDADES DELA MEZCLA

Variables Unidades Valor Unidades Valor Unidades Valor


T ºF 89.96361 K 305.352 R 549.6336
(ºC)/5=(ºF−32)/
P psia 456.2866 kPa 3145.996 psia 456.2866
F molar lbmol/h 4000 kgmol/h 1814.368 lbmol/h 4000
Ts ºF 77 K 298.15 R 536.67
Ps psia 14.7 kPa 101.3533 psia 14.7
R psiaft3/lbm 10.73159 kJ/kmol.K 8.31432 psiaft3/lbm 10.73159
Ta ºF 77 K 298.15 R 536.67
gc ft/s2 32.16 m/s2 m/s2 9.81

Calculos de fase por Rachford-Rice 1952

𝑓_((𝑛_𝑣 ) )=∑1_(𝑖=1)^𝑛▒(𝑍_𝑖∗(𝑘_𝑖−1))/(𝑛_𝑣 〖 (𝑘 〗 _𝑖−1)+1)


〖𝑓 ^´ 〗 _((𝑛_𝑣 ) )=−∑1_(𝑖=1)^𝑛▒(𝑍_𝑖∗ 〖 (𝑘_𝑖−1) 〗 ^2)/[ 〖

𝐾_𝑖=𝑃_(𝑐,𝑖)/𝑃 𝑒𝑥𝑝[5,37(1+𝜔_𝑖 )(1−𝑇_(𝑐,𝑖)/𝑇)]


Cálculos de fase
Nº Comps. zi zi norm MW i Pci, psia Tci, R ωi Zc
1 Propane 0.5 0.5 44.10 617.37 665.82 0.1524 0.2768
2 n-Butane 0.5 0.5 58.12 550.65 765.36 0.2010 0.2738
3 0 0 0 0.00 0.00 0.00 0.0000 0.0000
4 0 0 0 0.00 0.00 0.00 0.0000 0.0000
5 0 0 0 0.00 0.00 0.00 0.0000 0.0000
6 0 0 0 0.00 0.00 0.00 0.0000 0.0000
7 0 0 0 0.00 0.00 0.00 0.0000 0.0000
8 0 0 0 0.00 0.00 0.00 0.0000 0.0000
9 0 0 0 0.00 0.00 0.00 0.0000 0.0000
10 0 0 0 0.00 0.00 0.00 0.0000 0.0000
11 0 0 0 0.00 0.00 0.00 0.0000 0.0000
12 0 0 0 0.00 0.00 0.00 0.0000 0.0000
Total 1 1

Calculo de propiedades aparentes de la mezcla 𝑀=∑_(𝑖=1)^𝑁▒ 〖𝑦 _𝑖 𝑀_𝑖 〗


Vapores
Comps. yi MW a Psci, psia Tsci, R ωi Zc Pci, kPa
Propane 0 0.00 0.00 0.00 0.00 0.00 0.00
n-Butane 0 0.00 0.00 0.00 0.00 0.00 0.00
0 0 0.00 0.00 0.00 0.00 0.00 0.00
0 0 0.00 0.00 0.00 0.00 0.00 0.00
0 0 0.00 0.00 0.00 0.00 0.00 0.00
0 0 0.00 0.00 0.00 0.00 0.00 0.00
0 0 0.00 0.00 0.00 0.00 0.00 0.00
0 0 0.00 0.00 0.00 0.00 0.00 0.00
0 0 0.00 0.00 0.00 0.00 0.00 0.00
0 0 0.00 0.00 0.00 0.00 0.00 0.00
0 0 0.00 0.00 0.00 0.00 0.00 0.00
0 0 0.00 0.00 0.00 0.00 0.00 0.00
Total 0 0 0 0 0 0 0

Propiedades adicionales
Ecuaciones
Variables Unidades Valor Unidades Valor
𝑇_𝑠𝑟=𝑇/𝑇_𝑠𝑐 𝑇_𝑠𝑟=𝑇/𝑇_𝑠𝑐
R kJ/kmol.K 8.31432 psia.ft3/lb 10.73159
Tsr - #DIV/0!
𝑃_𝑠𝑟=𝑃/𝑃_𝑠𝑐 𝑃_𝑠𝑟=𝑃/𝑃_𝑠𝑐
Psr - #DIV/0!
ρg mas kg/m3 (MW 0 lb/ft3 0
𝜌_𝑔=𝑃𝑀𝑊/𝑅𝑇 ρ_g=(PMW_a)/RT
ρg mol kmol/m3 1.239169 lbmol/ft3 0.077357
Viscosidad
X 5.293922
μ_g= 〖 10 〗 ^(−4) Kexp[X(ρ_g/62,4)^Y ] ρ_s=(1/((RT_c)
Y 1.341216
K 159.6635
K=((9,4+0,02∗MW) T^1,5)/(209+19∗MW+T)
ug cP 0.015966
Viscosidadlb/ft.s 1.073E-05 X=3,5+986/T+0,01∗MW
Y=2,4−0,2∗X

Calculo de propiedades termodinamicas

Comps. yi xi MW i Hiform kJ/kmol a b c


Propane 0 0.5 44.10 -103890 39.4889 0.395 0.002114
n-Butane 0 0.5 58.12 -126190 67.721 0.008541 0.003277
0 0 0 0.00 0 0 0 0
0 0 0 0.00 0 0 0 0
0 0 0 0.00 0 0 0 0
0 0 0 0.00 0 0 0 0
0 0 0 0.00 0 0 0 0
0 0 0 0.00 0 0 0 0
0 0 0 0.00 0 0 0 0
0 0 0 0.00 0 0 0 0
0 0 0 0.00 0 0 0 0
0 0 0 0.00 0 0 0 0
Total 0 1

Variables T P Fmolar Fvol ρmas μ H


89.96361 456.2866 4000 1.720143 33.01438 7.939E-05 -49188.15

Variables Unidades Total Vapor Liquido Corrientes T1 ºF


Frac vap - 0 0 1 1 90
T ºF 89.96361 0 89.96361 2 89.99727
P psia 456.2866 0 456.2866 3 89.99727
Fmolar lbmol/h 4000 0 4000 4 89.97906
Fvol ft3/s 1.720143 0 1.720143 5 89.97906
ρmas lb/ft3 33.01438 0 33.01438 6 89.97906
μ lb/ft.s 7.939E-05 0 7.939E-05 7 89.96997
H btu/lbmol -49188.15 0 -49188.15 8 89.96997
ρmol lbmol/ft3 0.645941 0 0.645941 9 89.96361
μ cP 0.118146 0 0.118146 10 89.96361
MW 51.11 0 51.1105 0 11
Frac vol 0 1 -49188.15 12

Propiedades estandar y referencia


Variables Unidades Valor Unidades Valor Unidades Valor
Ts ºF 77 K 298.15 R 536.67
Ps psia 14.7 kPa 101.3533 psia 14.7
R gases psiaft3/lbm 10.73159 R gases 8.31432 psiaft3/lbm 10.73159
Ta ºF 77 K 298.15 R 536.67
gc ft/s2 32.16 m/s2 9.81

Nº Tag Nº Especificaciones de la tuberia ASME 36.10M


D Externo Espesor D interno
Cédula DN in Material
ft in ft
1 tuberia 40 4 0.375 0.237 0.3355
2 codo 40 4 0.375 0.237 0.3355
3 tuberia 40 4 0.375 0.237 0.3355
4 valvula 40 4 0.375 0.237 0.3355
5 codo 40 4 0.375 0.237 0.3355
6 tuberia 40 4 0.375 0.237 0.3355
7 codo 40 4 0.375 0.237 0.3355
8 tuberia 40 4 0.375 0.237 0.3355
9 valvula 40 4 0.375 0.237 0.3355

Tipo Le/D DN mm DN   pulg fT


Válvula de 340
Válvula de 150 15 0.5 0.027
Válvula de 8 20 0.75 0.025
Válvula de 35 25 1 0.023
Válvula de 160 32 1.25 0.022
Válvula de 900 40 1.5 0.021
Válvula de v 100 50 2 0.019
Válvula de v 150 65.8 2,5-3 0.018
Válvula de 45 100 4 0.017
Válvula de 35 125 5 0.016
Válvula de 25 150 6 0.015
Válvula de 420 200.25 8 a 10 0.014
Válvula de 75 300-400 12 a 16 0.013
Codo están 30 450-600 18-24 0.012
Codo a 90º 20
Codo rosca 50
Codo están 16
Codo rosca 26
Vuelta cerr 50
Te estándar 20
Te estándar 60
Comps. MW i Pci, kPa
Propane 44.097 4256.66
Conversion de unidades n-Butane 58.124 3796.62
0 0
(ºC)/5=(ºF−32)/9=(R−491,67)/9=(K−273,15)/5
0 0
Presion 0 0 0
μ 0 0 0
Entalpia 0 0 0
Entalpia 0 0 0
Fmol 0 0 0
0 0
0 0
Rice 1952 Frac. molar 0 0
𝑦_𝑖=𝑥_𝑖 𝐾_𝑖
(𝑍_𝑖∗ 〖 (𝑘_𝑖−1)
(𝑛_𝑣 ^2)/[ 〖𝑛 _𝑣 (𝑘 〗) )/
〗)_𝑛=𝑛_𝑣−𝑓_((𝑛_𝑣 〖𝑓 ^´ 〗 𝑥_𝑖=𝑧_𝑖/(𝑛_𝑣
_𝑖−1)+1]^2 _((𝑛_𝑣 ) ) 𝐾_𝑖+𝑛_𝑙 )

2.842117
(nv)n -4.380953 n vapor n líquido (nv)n -10.08405 n vapor
1+𝜔_𝑖 )(1−𝑇_(𝑐,𝑖)/𝑇)]
nv -1.538836 0 1 nv -4.380953 0
Ki Wilson f(nv) f´(nv) xi yi f(nv) f´(nv) xi
0.37 -0.160486 -0.051511 0.5 0 -0.083926 -0.014087 0.5
0.10 -0.189033 -0.071467 0.5 0 -0.091122 -0.016606 0.5
0.00 0 0 0 0 0 0 0
0.00 0 0 0 0 0 0 0
0.00 0 0 0 0 0 0 0
0.00 0 0 0 0 0 0 0
0.00 0 0 0 0 0 0 0
0.00 0 0 0 0 0 0 0
0.00 0 0 0 0 0 0 0
0.00 0 0 0 0 0 0 0
0.00 0 0 0 0 0 0 0
0.00 0 0 0 0 0 0 0
-0.349519 -0.122978 1 0 -0.175047 -0.030693 1

∑_(𝑖=1)^𝑁▒ 〖𝑦 _𝑖 𝑀_𝑖 〗 𝑀=∑_(𝑖=1)^𝑁▒ 〖


Líquidos
Tci, K Comps. xi MW a Psci, psia Tsci, R ωi Zc
0.00 Propane 0.5 22.05 308.69 332.91 0.08 0.14
0.00 n-Butane 0.5 29.06 275.33 382.68 0.10 0.14
0.00 0 0 0.00 0.00 0.00 0.00 0.00
0.00 0 0 0.00 0.00 0.00 0.00 0.00
0.00 0 0 0.00 0.00 0.00 0.00 0.00
0.00 0 0 0.00 0.00 0.00 0.00 0.00
0.00 0 0 0.00 0.00 0.00 0.00 0.00
0.00 0 0 0.00 0.00 0.00 0.00 0.00
0.00 0 0 0.00 0.00 0.00 0.00 0.00
0.00 0 0 0.00 0.00 0.00 0.00 0.00
0.00 0 0 0.00 0.00 0.00 0.00 0.00
0.00 0 0 0.00 0.00 0.00 0.00 0.00
0 Total 51.11 584.01 715.5873 0.1767 0.275329

Variables Unidades Valor Unidades Valor Letsou-Stiel


𝑇_𝑠𝑟=𝑇/𝑇_𝑠𝑐
R kJ/kmol.K 8.31432 psia.ft3/lb 10.73159 Tc Liq K 397.5485
Tsr - 0.768087 Pc liq atm 39.73985
𝑃_𝑠𝑟=𝑃/𝑃_𝑠𝑐Psr - 0.781296 MW liq 51.11
ρl mas kg/m3 528.8408 lb/ft3 33.01438 ε 0.032571
ρl mol kmol/m3 10.34701 lbmol/ft3 0.645941 Tr 0.768087
με 0 0.0032
ρ_s=(1/((RT_c)/P_c )) 〖 Z_RA 〗 ^(1+(1−T_r )^(2/7) ) με 1 0.003668
μL cP 0.118146
lb/ft.s 7.939E-05

Ecuaciones para entalpía

𝐻=∑1▒ 〖𝑦 _𝑖 𝐻_𝑖^𝐼𝐺 〗⟹𝑑𝑜𝑛𝑑𝑒⟹𝐻 _𝑖^𝐼𝐺=∫2_(25º𝐶)^𝑇▒ 〖𝐶 _𝑝^𝑖𝑔 𝑑𝑇 〗 +𝐻_𝑖^𝑓𝑜𝑟(25º𝐶) =𝐻_𝑖^𝐼𝐺(𝑇)


𝑆^𝐼𝐺=∑1▒ 〖𝑦 _𝑖 𝑆_+
−𝐻_𝑖^𝐼𝐺(25º𝐶)

𝐻_𝑖^𝐼𝐺(∗) =(𝑎+𝑏𝑇+𝑐𝑇^2+𝑑𝑇^3+𝑒𝑇^4+𝑓𝑇^5 ) 〖𝑀𝑊〗 _𝑖


Vapores Liquidos
Tstn Tsist K R gases
298.15 305.352 8.31432
d e f g Hi (kJ/kmol)Hi (kJ/kmol) Hi (kJ/kmol)Hi (kJ/kmol)
3.965E-07 -6.67E-10 1.679E-13 1 15470.1 16014.0 0.0 15470.05 16014.02
-1.11E-06 1.766E-10 -6.4E-15 1 19386.7 20099.3 0.0 19386.71 20099.28
0 0 0 0 0.0 0.0 0.0 0 0
0 0 0 0 0.0 0.0 0.0 0 0
0 0 0 0 0.0 0.0 0.0 0 0
0 0 0 0 0.0 0.0 0.0 0 0
0 0 0 0 0.0 0.0 0.0 0 0
0 0 0 0 0.0 0.0 0.0 0 0
0 0 0 0 0.0 0.0 0.0 0 0
0 0 0 0 0.0 0.0 0.0 0 0
0 0 0 0 0.0 0.0 0.0 0 0
0 0 0 0 0.0 0.0 0.0 0 0
Hid (kJ/kmol) 0.0 Hid (kJ/kmol)
Hid (btu/lbmol) 0 Hid (btu/lbmol)

ρmol μ MW
0.645941 0.118146 51.11

P1 psia F molar F vol ft3/s ρ lb/ft3 μ1 lb/ft.s H btu/lbmol


500 4000 1.720235 33.01262 7.938E-05 -49187.38
498.7998 4000 1.720228 33.01275 7.938E-05 -49187.44
496.7483 4000 1.720228 33.01275 7.938E-05 -49187.44
490.1135 4000 1.720182 33.01363 7.938E-05 -49187.82
466.8637 4000 1.720182 33.01363 7.938E-05 -49187.82
464.8122 4000 1.720182 33.01363 7.938E-05 -49187.82
461.2899 4000 1.720159 33.01407 7.939E-05 -49188
459.2385 4000 1.720159 33.01407 7.939E-05 -49188
456.8337 4000 1.720143 33.01438 7.939E-05 -49188.15
456.2866 4000 1.720143 33.01438 7.939E-05 -49188.15

L
E
𝐸
𝜃=𝑎𝑠𝑒𝑛 ( )
𝜃=𝑎𝑠𝑒𝑛(𝐸/𝐿)
𝐿
215.5188
𝜃
Geometria de la tuberia Variables termodinámicas Propiedades de transpo
ε L ft Elev ϴ T1 ºF P1 psia F molar F vol ft3/s ρ lb/ft3
0.00015 15 15 90 90 500 4000 1.720235 33.01262
0.00015 0 0 0 89.99727 498.7998 4000 1.720228 33.01275
0.00015 100 0 0 89.99727 496.7483 4000 1.720228 33.01275
0.00015 0 0 0 89.97906 490.1135 4000 1.720182 33.01363
0.00015 0 0 0 89.97906 466.8637 4000 1.720182 33.01363
0.00015 50 50 90 89.97906 464.8122 4000 1.720182 33.01363
0.00015 0 0 0 89.96997 461.2899 4000 1.720159 33.01407
0.00015 35 0 0 89.96997 459.2385 4000 1.720159 33.01407
0.00015 0 0 0 89.96361 456.8337 4000 1.720143 33.01438
Tci, K Vc m3/kmol ωi Zc Hiform kJ/kmol Comps. zi
369.89801 0.2 0.1524 0.276815 -103890 C3 0.5
425.199005 0.25499 0.201 0.273843 -126190 nC4 0.5
0 0 0 0 0
0 0 0 0 0
0 0 0 0 0
0 0 0 0 0
0 0 0 0 0
0 0 0 0 0
0 0 0 0 0
0 0 0 0 0
0 0 0 0 0
0 0 0 0 0

n líquido
1
yi
0
0
0
0
0
0
0
0
0
0
0
0
0

𝑀=∑_(𝑖=1)^𝑁▒ 〖𝑦 _𝑖 𝑀_𝑖 〗
Algoritmo para calculo de fase
Pci, kPa Tci, K
2128.33 184.95
1898.31 212.60
0.00 0.00
0.00 0.00
0.00 0.00
0.00 0.00
0.00 0.00
0.00 0.00
0.00 0.00
0.00 0.00
0.00 0.00
0.00 0.00
4026.64014 397.5485

Eucaciones para entropía Eucaciones para cap

𝑆^𝐼𝐺=∑1▒
𝐻_𝑖^𝐼𝐺(𝑇) 〖𝑦 _𝑖 𝑆_𝑖^𝐼𝐺
−𝐻_𝑖^𝐼𝐺(25º𝐶) +𝐻_𝑖^𝑓𝑜𝑟(25º𝐶) 𝐶_(𝑃_𝑖)^𝐼𝐺=(𝑏+2𝑐𝑇+3𝑑𝑇
〗−𝑅∑ 1▒ 〖𝑦 _𝑖 𝑙𝑛𝑦_𝑖 〗⟹𝑑𝑜𝑛𝑑𝑒⟹𝑆 _𝑖^𝐼𝐺=𝑆_𝑖^𝐼𝐺(25º𝐶) +∫2_(25º𝐶)^𝑇▒ 〖 (𝐶_𝑝^𝑖𝑔)/𝑇 𝑑𝑇 〗

𝑆_𝑖^𝐼𝐺=(𝑏𝑙𝑛(𝑇)+2𝑐𝑇+3/2 𝑑𝑇^2+4/3 𝑒𝑇^3+5/4 𝑓𝑇^4+𝑔) 〖𝑀𝑊〗 _𝑖 𝐶_𝑃^𝐼𝐺=∑1▒

Vapores Liquidos
T inicial K Tsist K R gases Tsist K
298.15 305.352 8.31432 305.352
Hi (kJ/kmol) So kJ/kmol.K Sid kJ/kmolSo kJ/kmol.K Sid kJ/kmol.K Cpi kJ/kmo
-51673.019 202.1 0 0 202.0971 -2.881524 103.9301
-62738.716 168.7 0 0 168.651 -2.881524 87.20701
0 0.0 0 0 0 0 0
0 0.0 0 0 0 0 0
0 0.0 0 0 0 0 0
0 0.0 0 0 0 0 0
0 0.0 0 0 0 0 0
0 0.0 0 0 0 0 0
0 0.0 0 0 0 0 0
0 0.0 0 0 0 0 0
0 0.0 0 0 0 0 0
0 0.0 0 0 0 0 0
-114411.7 Sid kJ/kmol 0 Sid kJ/kmol 191.1371 Cpid kJ/km
-49188.146 Sid btu/lbm 0.0 Sid btu/lbm 45.7 Cpid btu/lb
Moody

1/√(𝑓_𝑇𝑢𝑟𝑏 )=1,74−2𝑙𝑜𝑔(2𝜀/𝑑+18,7/(𝑅𝑒√(𝑓_𝑇𝑢𝑟𝑏 ))

Panhandle B
Weymouth
𝑓=1/94 (𝑃_𝑏/(𝑣𝜌𝑇_𝑏 ))^0,04
𝐴=(𝜋𝑑^2)/4𝑣=𝐹_𝑣𝑜𝑙/𝐴 𝑣=100/√𝜌 𝑅𝑒=𝜌𝑣𝐷/𝜇 𝑓=1/(71,6𝑑^0,33 )
Propiedades de transporte fluidos Factor de fricción y coeficiente de resistencia de tubos y
μ1 lb/ft.s H btu/lbmol A1 ft2 v1 ft/s v1er ft/s Re f f* f**
7.9375E-05 -49187.38 0.088405 19.45865 17.40444 2715184 0.016493 7.786561 7.786553
7.9377E-05 -49187.44 0.088405 19.45857 2715146
7.9377E-05 -49187.44 0.088405 19.45857 17.4044 2715146 0.016494 7.786502 7.786552
7.9384E-05 -49187.82 0.088405 19.45805 2714892
7.9384E-05 -49187.82 0.088405 19.45805 2714892
7.9384E-05 -49187.82 0.088405 19.45805 17.40417 2714892 0.016494 7.786498 7.786548
7.9388E-05 -49188 0.088405 19.4578 2714765
7.9388E-05 -49188 0.088405 19.4578 17.40406 2714765 0.017081 7.651409 7.787398
7.939E-05 -49188.15 0.088405 19.45762 2714676
para calculo de fase
Eucaciones para capacidad calorífica
(𝑃_𝑖)^𝐼𝐺=(𝑏+2𝑐𝑇+3𝑑𝑇^2+4𝑒𝑇^3+5𝑓𝑇^4
(𝐶_𝑝^𝑖𝑔)/𝑇 𝑑𝑇 〗 ) 〖𝑀𝑊〗 _𝑖

𝐶_𝑃^𝐼𝐺=∑1▒ 〖𝑦 _𝑖 𝐶_(𝑃_𝑖)^𝐼𝐺 〗

Cp kJ/kmol.K

0
0
(𝑑𝑃/𝑑𝐿)_(𝑓𝑟𝑖𝑐.)=−(𝑓𝜌𝑣^2)/(2𝑔_𝑐 𝑑_𝑖 144)

𝑑+18,7/(𝑅𝑒√(𝑓_𝑇𝑢𝑟𝑏 ))) (𝑑𝑃/𝑑𝐿)_(𝑎𝑐𝑐.)=−(𝜌𝑣_1 (𝑣_1−𝑣_2 ))/(144𝑔_𝑐 𝑑𝐿)

(𝑑𝑃/𝑑𝐿)_(𝑒𝑙𝑒𝑣.)=−𝜌𝑔𝑠𝑒𝑛(𝜃)/(𝑔_𝑐 144)
Weymouth
𝑓=1/(71,6𝑑^0,33 ) (𝑑𝑃/𝑑𝐿)_(𝑎𝑐𝑐𝑒𝑠𝑜.)=−(𝐾𝜌𝑣^2)/(2𝑔_𝑐𝑃_2−𝑃_1=[−(𝑓𝜌𝑣^2)/(2𝑔_𝑐
𝑑_𝑖 144𝐿) 𝑑_𝑖 144)]𝐿

resistencia de tubos y accesoriosPerdida de carga durante el transporte T ambientePresión P2


Δ Kacce ΔPf psi ΔPe psi ΔPa psi ΔPacc psi Ta F P2 psia
8.22E-06 0.995186 0.204952571 3.215E-05 77 498.7998
0.51 2.051506 77 496.7483
-4.98E-05 6.634647 0 0.000214 77 490.1135
5.78 23.24978 77 466.8637
0.51 2.051451 77 464.8122
-4.98E-05 3.317239 0.204958849 0.000107 77 461.2899
0.51 2.051424 77 459.2385
-0.135989 2.404753 0 7.483E-05 77 456.8337
0.136 0.547041 77 456.2866
150 Temperatura (ºF) -
400 Presión (psia) -
5000 Flujo molar (lbmol/h)
5000
1 D. nominal 4 pul L = 1000 ft 2
𝐻_1 Cedula 40 E = 0 ft 𝐻_2
𝐻 2 𝐹 𝑚𝑜𝑙
𝐻 1 𝐹 𝑚𝑜𝑙 𝐹_𝑚𝑜𝑙
𝐹_𝑚𝑜𝑙
𝑄𝑄
𝐻_2=(𝐹_(𝑚𝑜𝑙,1) 𝐻_1−𝑄)/𝐹_(𝑚𝑜𝑙,2)
𝑐 𝑑_𝑖 144)]𝐿
Ideal 𝐴_𝑠=𝜋𝐷𝐿 𝑄=𝑈𝐴(𝑇_𝑏−𝑇_𝑎 ) 𝐹_(𝑚𝑜𝑙,1) 𝐻_1=𝐹_(𝑚𝑜𝑙,2) 𝐻_2+𝑄
Balance de energia o calor perdido o ganado Variables y propiedades de transporte
U A ft2 Q btu/h Q1 btu/h Q2 btu/h H2 btu/lbmol T2 ºF P2 psia F molar
1 17.67146 229.729 -2E+08 -2E+08 -49187.44 89.99727 498.7998 4000
1 0 0 -2E+08 -2E+08 -49187.44 89.99727 496.7483 4000
1 117.8097 1531.205 -2E+08 -2E+08 -49187.82 89.97906 490.1135 4000
1 0 0 -2E+08 -2E+08 -49187.82 89.97906 466.8637 4000
1 0 0 -2E+08 -2E+08 -49187.82 89.97906 464.8122 4000
1 58.90486 764.5297 -2E+08 -2E+08 -49188 89.96997 461.2899 4000
1 0 0 -2E+08 -2E+08 -49188 89.96997 459.2385 4000
1 41.2334 534.7959 -2E+08 -2E+08 -49188.15 89.96361 456.8337 4000
1 0 0 -2E+08 -2E+08 -49188.15 89.96361 456.2866 4000
es de transporte
H
F vol ft3/s ρ2 lb/ft3 μ2 lb/ft.s A2 ft2 v2 ft/s v2er ft/s
btu/lbmol
1.720228 33.01275 7.9376519E-05 -49187.44 0.088405 19.45857
1.720228 33.01275 7.9376519E-05 -49187.44 0.088405 19.45857
1.720182 33.01363 7.9383952E-05 -49187.82 0.088405 19.45805
1.720182 33.01363 7.9383952E-05 -49187.82 0.088405 19.45805
1.720182 33.01363 7.9383952E-05 -49187.82 0.088405 19.45805
1.720159 33.01407 7.9387664E-05 -49188 0.088405 19.4578
1.720159 33.01407 7.9387664E-05 -49188 0.088405 19.4578
1.720143 33.01438 7.939026E-05 -49188.15 0.088405 19.45762
1.720143 33.01438 7.939026E-05 -49188.15 0.088405 19.45762
Propiedades de las sustancias puras para el sistema de unidades internacional
1 2 3 4 5 6 7 8
Propiedades fisicas
Componentes Fórmula quTBP K ρliqi kg/m3Peso molecTc K Pc kPa Vc m3/kmo
Methane CH4 111.625 299.39401 16.0429 190.69901 4640.6802 0.0989999
Ethane C2H6 184.55 355.68301 30.069901 305.42801 4883.8501 0.148
Propane C3H8 231.048 506.67801 44.097 369.89801 4256.6602 0.2
i-Butane C4H10 261.42001 561.966 58.124001 408.09601 3647.6201 0.263
n-Butane C4H10 272.64801 583.22302 58.124001 425.19901 3796.6201 0.25499
i-Pentane C5H12 301.02802 623.44202 72.151001 460.39801 3333.5901 0.30799
n-Pentane C5H12 309.20901 629.729 72.151001 469.60001 3375.1201 0.31099
n-Hexane C6H14 341.88 662.664 86.177902 507.89801 3031.6201 0.368
n-Heptane C7H16 371.57901 686.815 100.205 540.15802 2736.78 0.42598
n-Octane C8H18 398.82001 705.37701 114.232 568.59802 2496.6201 0.486
n-Nonane C9H20 423.96701 720.24701 128.259 594.59802 2300.0701 0.54299
n-Decane C10H22 447.29901 732.72101 142.285 617.59802 2107.55 0.60197
n-C11 C11H24 469.04001 742.84601 156.313 638.29901 1964.9301 0.66
n-C12 C12H26 489.42801 751.14502 170.339 658.29901 1829.92 0.71297
n-C13 C13H28 508.57901 758.81403 184.367 675.79901 1723.53 0.77999
n-C14 C14H30 526.65802 762.91302 198.38 694 1620.1801 0.82999
n-C15 C15H32 543.76801 770.40503 212.41 707 1516.8101 0.87998
n-C16 C16H34 559.94 775.48102 226.429 717 1420.5601 0.93997
n-C17 C17H36 575.29901 780.19202 240.457 733.37 1316.9 1.00581
n-C18 C18H38 589.85901 784.09302 254.479 745.26001 1213.47 1.0700001
n-C19 C19H40 603.79901 787.591 268.51001 755.92902 1116.95 1.13
n-C20 C20H42 616.92902 790.66901 282.54001 768 1160 1.1900001
n-C21 C21H44 629.65002 794.302 296.58301 778 1110 1.2447701
n-C22 C22H46 641.76001 796.75201 310.58801 787 1060 1.3011301
n-C23 C23H48 653.36902 799.90601 324.60901 796 1020 1.35604
n-C24 C24H50 664.42902 801.35901 338.63901 804 980 1.4111201
n-C25 C25H52 675.039 803.414 352.67001 812 950 1.46473
n-C26 C26H54 685.36902 805.36902 366.69 819 910 1.5182101
n-C27 C27H56 695.26001 807.12701 380.72 826 883 1.5707
n-C28 C28H58 704.76001 808.35901 394.73901 832 850 1.6222399
n-C29 C29H60 713.92902 810.341 408.76901 838 826 1.6730601
n-C30 C30H62 722.86902 811.89801 422.79901 863 868 1.7235301
22-Mpropane C5H12 282.64801 595.59302 72.151001 433.77802 3198.8201 0.303
2-Mpentane C6H14 333.41101 656.50702 86.177902 497.49701 3010.3601 0.36636
3-Mpentane C6H14 336.42001 667.68402 86.177902 504.44901 3123.8401 0.36636
22-Mbutane C6H14 322.88101 652.565 86.177902 504.44901 3880.6201 0.35899
23-Mbutane C6H14 331.12701 665.16803 86.177902 499.98001 3126.8701 0.358
2-Mhexane C7H16 363.19901 681.539 100.205 530.36902 2733.6201 0.421
3-Mhexane C7H16 364.99701 690.20001 100.205 535.25 2813.79 0.404
3-Epentane C7H16 366.62201 701.16803 100.205 540.64001 2890.8 0.416
22-Mpentane C7H16 352.341 676.966 100.205 520.5 2773.26 0.416
23-Mpentane C7H16 362.92801 698.04602 100.205 537.34802 2908.02 0.393
24-Mpentane C7H16 353.64301 675.99402 100.205 519.789 2736.78 0.418
33-Mpentane C7H16 359.20901 696.32703 100.205 536.39801 2945.51 0.414
223-Mbutane C7H16 354.026 693.25 100.205 531.16901 2953.6201 0.398
2-Mheptane C8H18 390.80301 700.82001 114.232 559.638 2484.3701 0.488
3-Mheptane C8H18 392.082 708.55603 114.232 563.66901 2546.29 0.46399
4-Mheptane C8H18 390.86401 707.49103 114.232 561.73901 2542.1201 0.476
3-Ehexane C8H18 391.69 716.46503 114.232 565.48901 2608.1001 0.455
22-Mhexane C8H18 379.992 698.39301 114.232 549.86902 2529.0701 0.47799
23-Mhexane C8H18 388.76001 715.013 114.232 563.48901 2628.3701 0.46799
24-Mhexane C8H18 382.582 703.263 114.232 553.52002 2556.3701 0.472
25-Mhexane C8H18 382.25601 696.67102 114.232 550.05902 2486.51 0.48199
33-Mhexane C8H18 385.12201 712.84802 114.232 562.02002 2653.6201 0.44299
34-Mhexane C8H18 390.88 721.95801 114.232 568.84802 2692.1201 0.46599
Cyclopropane C3H6 240.371 420.54001 42.080601 397.811 5495.0801 0.17069
Cyclobutane C4H8 285.66101 698.39301 56.1077 459.927 4984.8901 0.21013
Cyclopentane C5H10 322.39801 748.87402 70.135002 511.60001 4508.9502 0.25999
Cyclohexane C6H12 353.88 781.82202 84.160004 553.20001 4053 0.30799
1Mcycpentene C6H10 347 784.52002 82.150002 542 3770 0.311199
3Mcycpentene C6H10 343.20001 758.58002 82.150002 535.70001 4019.96 0.2985
Cycloheptane C7H14 391.95001 813.91901 98.189003 604.20001 3810 0.35299
Cyclooctane C8H16 424.311 838.57001 112.208 647.20001 3560 0.40999
Cyclononane C9H18 451.539 852.74902 126.236 644.26001 3171.5701 0.51217
Cyclodecane C10H20 475.371 860.02002 140.26801 667.039 2964.6201 0.5691
Mcyclopentan C6H12 344.95901 752.065 84.161903 532.70001 3789.55 0.319
Ecyclopentan C7H14 376.617 769.565 98.189003 569.52002 3397.6201 0.37446
Mcyclohexane C7H14 374.07901 772.427 98.189003 572.09802 3475.3701 0.368
Ecyclohexane C8H16 404.944 790.67902 112.208 609.26001 3033.6201 0.44828
Ecycheptane C9H18 436.483 816.27301 126.236 654.26001 2938.53 0.472
Mcycoctane C9H18 435.14801 837.078 126.236 658.15002 3029.54 0.46726
Ethylene C2H4 169.399 383.22601 28.053801 282.35901 5031.79 0.12894
Propene C3H6 225.399 520.95502 42.080601 365 4620.4102 0.18095
Propadiene C3H4 238.69901 655.59302 40.0648 393.14801 5471.54 0.162
1-Butene C4H8 266.89801 593.789 56.1077 419.60001 4022.6001 0.23995
cis2-Butene C4H8 276.867 625.953 56.1077 435.578 4205.77 0.23394
tr2-Butene C4H8 274.02701 608.68402 56.1077 428.62701 4102.3501 0.23815
i-Butene C4H8 266.29901 592.79303 56.1077 417.89801 4002.3301 0.23894
12-Butadiene C4H6 283 650.70001 54.091801 443.69901 4498.8301 0.21897
13-Butadiene C4H6 268.70001 619.74402 54.091801 425 4326.5601 0.221
Cyclobutene C4H6 275.79901 710.34802 54.09 446.29901 5270 0.1955
2E1C4= C6H12 337.79901 694.06403 84.160004 510.39801 3270 0.3535
1-Pentene C5H10 303.09601 638.72302 70.135002 464.69901 3528.7 0.3
3M1C5= C6H12 327.29901 672.35101 84.160004 495.29901 3270 0.3465
Cyclopentene C5H8 317.38 776.51599 68.118401 507 4801.9902 0.245
1-Hexene C6H12 336.60001 671.65302 84.161903 501.99799 3171.3701 0.34999
1-Heptene C7H14 366.79901 695.60602 98.189003 537.20001 2837.1001 0.43999
1-Octene C8H16 394.39801 713.56702 112.208 566.59802 2624.3101 0.46399
1-Nonene C9H18 420.039 732.06403 126.236 592.039 2344.1201 0.5831
1-Decene C10H20 443.75 743.62903 140.246 614.81702 2206.3101 0.6478
Benzene C6H6 353.23901 882.19 78.110001 562.09802 4924.3901 0.25999
Toluene C7H8 383.79901 870.04401 92.1408 591.79901 4100.04 0.316
o-Xylene C8H10 417.57501 883.14502 106.166 630.37201 3732.8101 0.36912
m-Xylene C8H10 412.26501 866.88202 106.166 617.04901 3541.1201 0.37573
p-Xylene C8H10 411.51001 864.229 106.166 616.26001 3510.79 0.37906
E-Benzene C8H10 409.35001 870.03302 106.166 617.09802 3607.1201 0.374
n-PBenzene C9H12 432.38901 864.75702 120.194 638.37701 3199.8401 0.43999
Cumene C9H12 425.561 864.75702 120.194 631.15002 3208.8101 0.42763
14-EBenzene C10H14 456.93701 864.75702 134.222 657.96002 2802.6201 0.47999
1M2-EBenzene C9H12 438.32501 883.14502 120.194 650.927 3039.8701 0.45763
1M3-EBenzene C9H12 434.47601 867.414 120.194 637.039 2837.1201 0.48765
1M4-EBenzene C9H12 435.16101 863.70203 120.194 640.37201 2938.53 0.47264
123-MBenzene C9H12 449.26501 897.60602 120.194 664.52802 3454.26 0.435
124-MBenzene C9H12 442.5 879.69702 120.194 649.09802 3232.26 0.43
135-MBenzene C9H12 437.89401 867.94702 120.194 637.36102 3126.75 0.43288
n-BBenzene C10H14 456.45401 863.17401 134.222 660.539 2886.8101 0.4968
i-BBenzene C10H14 445.93701 856.87201 134.222 650.37201 3049.8701 0.47837
sec-BBenzene C10H14 446.483 865.328 134.222 664.539 2950.8701 0.47837
tert-Bbenzen C10H14 442.29901 869.89203 134.222 659.815 2964.6201 0.46077
o-Cymene C10H14 451.328 880.36102 134.222 669.81702 2895.78 0.47837
m-Cymene C10H14 448.22601 864.65802 134.222 666.20502 2938.53 0.47837
p-Cymene C10H14 450.27701 859.96002 134.222 650 2730 0.47837
Styrene C8H8 418.30801 908.83002 104.152 636 3840 0.351999
Acetylene C2H2 189.35001 417.05301 26.038 308.32001 6139.1001 0.11296
M-Acetylene C3H4 249.94 620.53601 40.0648 402.39001 5627.6001 0.164
VnylAcetlen C4H4 278.25 688.43201 52.076 451.99799 4860 0.21796
DMAcetylene C4H6 300.13 695.84302 54.091499 473.20001 4870 0.221
EAcetylene C4H6 281.22 659.28802 54.091801 443.20001 4950 0.222
Biacetylene C4H2 283.5 717.26001 50.060001 476.99701 5860 0.1835
3-M-1-Butyne C5H8 299.5 598.73688 68.120003 476 4210 0.271499
1-Pentyne C5H8 313.29901 694.89001 68.120003 493.49701 4050 0.277999
2-Pentyne C5H8 329.20001 715.26501 68.120003 522 4230 0.2775
1-Hexyne C6H10 344.5 719.96002 82.150002 527 3670 0.333499
1-Heptyne C7H12 372.89801 736.84601 96.169701 559.70001 3200 0.389499
1-Octyne C8H14 399.39801 749.84003 110.196 586.90002 2960 0.445499
1-Nonyne C9H16 423 760.30902 124.23 610.79901 2660 0.5015
1-Decyne C10H18 447.20001 768.82202 138.24001 632.5 2430 0.5575
3-Hexyne C6H10 354.35001 727.10303 82.145401 544 3530 0.331
2-Hexyne C6H10 357.67001 736.58197 82.145401 549 3530 0.331
Urea CH4N2O 973.15002 1335 60.055901 0.001 20 6.6700001
Carbon C 973.15002 1642.0601 12.0108 0.001 100 0
Ammonia NH3 239.69901 616.07001 17.030001 405.54901 11276.9 0.0803999
Hydrogen H2 20.5548 69.8591 2.016 33.44 1315.5 0.0515
H2O H2O 373.14801 997.98602 18.0151 647.29901 22120 0.0571
Helium He 4.20999 124.064 4.0029802 5.19 226.97 0.0573
Argon Ar 87.2994 1370.1801 39.948002 150.707 4863.6001 0.0749
Nitrogen N2 77.3498 806.37402 28.013 126.194 3394.3701 0.09
Oxygen O2 90.1996 1137.6801 32 154.77 5080.02 0.0732
Oxido de nitrogeno NO 121.4 71.322701 30.006001 180 6470 0.0577
NO2 NO2 294.29901 1469.76 46.006001 430.99701 10000 0.0807
SO2 SO2 263.20001 1395.5601 64.063004 430.79901 7870 0.12217
CO CO 81.6996 799.388 28.0109 132.94901 3498.75 0.0892999
CO2 CO2 194.59801 825.33502 44.009701 304.10001 7370 0.0939
Mercury Hg 629.729 13503.2 200.589 1735 160800 0.05635
H2S H2S 213.498 788.40802 34.076 373.60001 9007.79 0.0979999
COS COS 223 1015.4 60.069901 378.79901 6179.8101 0.142
CS2 CS2 319.35901 1269.3101 76.130501 552 7903.3901 0.172
NaOH NaOH 661.40997 1782.3101 39.997002 767.52002 1015.5 0.2
Silane H4Si 161 582.62097 32.117298 269.70001 4840 0.1327
Cloruro de hidrogenoHCl 188.10001 870.33002 36.4608 324.70001 8300 0.0808999
M-Mercaptan CH4S 279.09601 863.19202 48.1068 469.99701 7234.6001 0.14496
Glycine C2H5NO2 699 1479.786 75.0672 1021 6740 0.234
HF HF 293 984.14301 20.006001 461 6470 0.0692
Dextrose C6H12O6 617 1180.91 180.158 755 4820 0.414
MEAmine C2H7NO 443.49701 1016.97 61.0839 612 4450 0.19596
DEAmine C4H11NO2 542.15002 1095 105.138 715.26001 3272.8701 0.37656
TEAmine C6H15NO3 633.14801 1124 149.19 787.427 2447.6201 0.44001
DGAmine C4H11NO2 494.29901 1057 105.138 675.70001 3770 0.326
MDEAmine C5H13NO2 520.40002 1040 119.16 677 3700 0.31334
Aniline C6H7N 457.60001 1024.41 93.1287 699 5310 0.27399
Pyrrole C4H5N 401.99701 973.48901 67.091003 639.79901 7250 0.224
DEGlycol C4H10O3 518.15002 1120.66 106.122 744.59802 4599.9902 0.312
Methanol CH4O 337.79901 795.71997 32.041901 512.59802 7376.4502 0.127
Ethanol C2H6O 351.39801 795.97998 46.069901 513.90002 6147 0.16708
1-Propanol C3H8O 370.29901 803.99902 60.096001 536.79901 5170 0.21897
1-Butanol C4H10O 390.89801 813.86902 74.123001 563.09802 4420 0.275
1-Pentanol C5H12O 411.10001 819.53003 88.150002 588.20001 3910 0.326
EGlycol C2H6O2 470.39801 1110.71 62.069 702 6515.1802 0.186
TEGlycol C6H14O4 550.40002 1128.45 150.16901 727 1418.55 0.446
Glycerol C3H8O3 562 1260.78 92.095001 725 6670 0.25499
Furfurol C5H6O2 443.10001 1134.86 98.0998 632 5350 0.263
Acetone C3H6O 329.20001 790 58.080002 508.10001 4700 0.209
Ketene C2H2O 231.998 678.90802 42.037701 370 6500 0.14496
Furfural C5H4O2 434.85001 1153.9399 96.0858 657 5512.1001 0.252
Formaldehyde CH2O 252.998 752.44501 30.025801 407 6590 0.10497
CCl4 CCl4 349.89801 1601.28 153.82201 556.40002 4559.9902 0.2759
Chloroform CHCl3 334.29901 1498.17 119.375 536.40002 5370 0.2389
BenzylCl C7H7Cl 452.54999 1106.011 126.585 686 3910 0.36
Cl2 Cl2 239.19901 1561.319 70.905701 416.89801 7740 0.1238
F2 F2 85 1500 37.997002 144.3 5220 0.0662999
VinylCl C2H3Cl 259.79901 919.25702 62.492001 425 5150 0.179
AcryloNitril C3H3N 350.5 805 53.063801 536 4559.9902 0.20995
Phenol C6H6O 455 1055.9301 94.112801 694.20001 6120 0.229
TAME C6H14O 359.45001 777.52002 102.18 536.828 3114.03 0.3785
ETBE C6H14O 346.25 762.552 102.18 517.11401 3114.03 0.3785
MTBE C5H12O 328.29901 745.83502 88.150002 496.39801 3370 0.33
Acetal C6H14O2 376.75 830.776 118.176 541 2980 0.402
Furan C4H4O 304.5 938 68.0746 490.20001 5500 0.21796
Trioxane C3H6O3 387.64801 1174.6801 90.0784 604 5820 0.224
9 10 11 12 13 14 15 16 17 18
Constantes para entalpia
Acentricity Zc Hform (25 Ca b c d e f
0.0114984 0.2897619 -74900 -12.98 2.36459 -0.002132 5.662E-06 -3.72E-09 8.609E-13
0.0986 0.2846351 -84738 -1.7675 1.1429 -0.000324 4.243E-06 -3.39E-09 8.821E-13
0.1524 0.2768154 -103890 39.4889 0.395 0.0021141 3.965E-07 -6.67E-10 1.679E-13
0.18479 0.2827329 -134590 30.903 0.1533 0.0026348 7.272E-08 -7.28E-10 2.367E-13
0.201 0.2738428 -126190 67.721 0.0085406 0.003277 -1.11E-06 1.766E-10 -6.4E-15
0.22224 0.2682185 -154590 64.25 -0.131798 0.003541 -1.33E-06 2.514E-10 -1.3E-14
0.25389 0.2688319 -146490 63.198 -0.011702 0.0033164 -1.17E-06 1.996E-10 -8.66E-15
0.3007 0.2641918 -167290 74.513 -0.096697 0.0034765 -1.32E-06 2.524E-10 -1.35E-14
0.34979 0.2595862 -187890 71.41 -0.096895 0.003473 -1.33E-06 2.558E-10 -1.38E-14
0.4018 0.2566591 -208590 126.507 -0.2701 0.0039983 -1.97E-06 6.228E-10 -9.38E-14
0.44549 0.2526287 -229190 4.979E-09 -0.06529 0.0034029 -1.25E-06 2.01E-10 -2.24E-23
0.48848 0.2470701 -249790 7.335E-09 -0.055614 0.0033767 -1.24E-06 1.987E-10 -3.7E-23
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19

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