Dolomite, Dolomitic Limestone, & Carey Dried Stone: Material Safety Data Sheet

Dolomite
MATERIAL SAFETY DATA SHEET

Dolomite, Dolomitic Limestone, & Carey Dried Stone
MSDS prepared by: Mgr. Of Technical Services October 17, 2005
National Lime & Stone Phone: 419-422-4341

551 Lake Cascade Pky Emergency: 419-396-7671
PO Box 120
Findlay, OH 45839
SECTION I – PRODUCTION IDENTIFICATION

NLS Products: 10; 10 40; 10 50; 10BB; 11 11P; 12; 12 50; 12BB; 20; 20 40;
20 50; 20BB; 30; 30 50: 6X16; 6X16BB; 60; 60 50; 80; 80 50;
DLP; DMI; DMI 50; DMIBB; PDL 50; PDLBB
Trade Name & Synonyms: Dolomite, Limestone, Ag Lime
Chemical Name & Synonyms Dolomitic Limestone
Chemical Family Alkaline Earth Carbonate
Formula CaCO3 – MgCO3
CAS # 16389-88-1, 1317-65-3, 471-34-1 and 546-93-0
SECTION II – HAZARDOUS INGREDIENTS

Composition varies, may contain quartz.
Dolomitic Limestone is not listed on the NTP, IARC, or OSHA lists of carcinogens, but crystalline silica, a
component of this product, is listed. IARC has determined that there is sufficient evidence of carcinogenity to
experimental animals exposed to crystalline silica and limited evidence for carcinogenity to humans. “Limited
evidence” means that a casual relationship is possible; however, other explanations such as chance, bias or
confounding factors cannot adequately be excluded.
SECTION III – PHYSICAL DATA
Boiling point: Decomposes 1100 – 1700° F

Specific gravity: 2.7 – 2.9
% volatile by volume: NA
Vapor pressure: NA
Vapor density: NA
Solubility in water: Negligible

Evaporation rate: NA
Appearance and odor: White to gray solid odorless
Page 1 of 3
Dolomite
SECTION IV – FIRE AND EXPLOSION HAZARD DATA
Flash point: NA
Flammable limits: Not flammable
Extinguishing media: None required
Special fire fighting procedures: None required
Unusual fire and explosion hazards: When heated at 1700° F or more for prolonged periods,
dolomitic limestone decomposes into dolomitic quicklime
(CaOMgO) releasing carbon dioxide (decomposition can
begin at 1100°F).
SECTION V – HEALTH HAZARD DATA
Threshold limit value: Exposure limits vary with the % quartz dust. Refer to ACGIH
and MSHA for current TLV’s and TWA’s.
Effects of overexposure: Exposure to dust may irritate respiratory system, eyes or skin.
Emergency and first aid procedures: Dust in eyes – flush with clear water. Dust on previously
irritated skin – wash with soap and water. Dust in throat and
nasal passages should clear spontaneously. Contact a
physician if irritation persists.
SECTION VI – REACTIVITY DATA

Stability: Unstable - reacts with acids evolving CO2. Stable if no acids
are present.
Incompatibility: Contact with acids.
Hazardous decomposition products: When heated at 1100 - 1700° F, dolomitic limestone
decomposes into dolomitic quicklime releasing carbon dioxide
gas.
Hazardous polymerization: Will not occur.
SECTION VII – SPILL OR LEAK PROCEDURES
Steps to be taken if material is

spilled or released: Spilled materials, where dust is generated, may overexpose
clean-up personnel to respirable dust. Use of respiratory
protective equipment may be necessary. Dolomitic limestone
may be wetted with water to control dusting.
Waste disposal method: Pick up and reuse clean materials. Dispose of waste materials
only in accordance with applicable federal, state, and local
laws and regulations.
Page 2 of 3
Dolomite
SECTION VIII – SPECIAL PROTECTION INFORMATION
Respiration protection: NIOSH-MSHA approved dust respirators for conditions where

dust levels may exceed exposure limits.
Ventilation: As required to maintain exposures below TLV’s. Vent dust to
collector.
Eye protection: Dust goggles should be worn when visibly dusty conditions
exist.
SPECIAL PRECAUTIONS
No special precautions required. Respirable dust levels should be monitored regularly. May cause pitting of
aluminum.
This information relates only to the specific material designated and may not be valid for such material used in
combination with any other materials or in any process. Such information is, to the best of National Lime and Stone
Company’s knowledge and belief, accurate and reliable as of the date indicated. However, no representation,
warranty, or guarantee is made as to its accuracy, reliability or completeness. It is the users responsibility to satisfy
himself as to the suitableness and completeness of such information for his own particular use. Also, the
suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance
requirements.
NATIONAL LIME & STONE COMPANY MAKES NO WARRANTY OF MERCHANTABILITY OR OF

FITNESS FOR ANY PARTICULAR PURPOSE. THE DETERMINATION OF PRODUCT SUITABILITY
FOR ANY PARTICULAR USE IS THE SOLE RESPONSIBILITY OF THE PURCHASER AND USER.
This Product is NOT intended to be used as a food source, component or ingredient. It is NOT produced
in compliance with state or federal regulations governing products consumed or intended for
consumption by humans or animals and should not be used for such purposes.
IN THE EVENT OF BREACH OF ANY WARRANTY OF ANY TYPE, THE SOLE REMEDY OF THE
PURCHASER AND/OR USER SHALL BE REPLACEMENT OF THE PRODUCT PURCHASED. UNDER NO
CIRCUMSTANCES WILL SELLER BE LIABLE FOR DAMAGES INCLUDING INCIDENTAL OR
CONSEQUENTIAL DAMAGES, REGARDLESS OF THE LEGAL THEORY UPON WHICH A CLAIM MAY
BE BASED
Page 3 of 3

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Dolomite

MATERIAL SAFETY DATA SHEET

MSDS prepared by: Mgr. Of Technical Services October 17, 2005

National Lime & Stone Phone: 419-422-4341

SECTION I – PRODUCTION IDENTIFICATION

Trade Name & Synonyms: Dolomite, Limestone, Ag Lime

Chemical Name & Synonyms Dolomitic Limestone

Chemical Family Alkaline Earth Carbonate

Formula CaCO3 – MgCO3

CAS # 16389-88-1, 1317-65-3, 471-34-1 and 546-93-0

SECTION II – HAZARDOUS INGREDIENTS

SECTION III – PHYSICAL DATA

Boiling point: Decomposes 1100 – 1700° F

Solubility in water: Negligible

SECTION IV – FIRE AND EXPLOSION HAZARD DATA

SECTION V – HEALTH HAZARD DATA

SECTION VI – REACTIVITY DATA

SECTION VII – SPILL OR LEAK PROCEDURES

Steps to be taken if material is

SECTION VIII – SPECIAL PROTECTION INFORMATION

Respiration protection: NIOSH-MSHA approved dust respirators for conditions where

NATIONAL LIME & STONE COMPANY MAKES NO WARRANTY OF MERCHANTABILITY OR OF

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