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Tugas 1 PSPK

The document provides the component continuity equations for: 1) A CSTR reactor with simultaneous first-order reactions. The equations relate the inflow and outflow of components to the rate of formation and rate of change within the reactor. 2) A CSTR reactor with a reversible first-order reaction. The equations are similar but also include the reverse reaction rate. 3) A tubular reactor with consecutive first-order reactions occurring along the length. The equations relate the flow of components into and out of infinitesimal reactor sections to the formation and change within each section.

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Aknasasia Virginia Krisanti
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356 views3 pages

Tugas 1 PSPK

The document provides the component continuity equations for: 1) A CSTR reactor with simultaneous first-order reactions. The equations relate the inflow and outflow of components to the rate of formation and rate of change within the reactor. 2) A CSTR reactor with a reversible first-order reaction. The equations are similar but also include the reverse reaction rate. 3) A tubular reactor with consecutive first-order reactions occurring along the length. The equations relate the flow of components into and out of infinitesimal reactor sections to the formation and change within each section.

Uploaded by

Aknasasia Virginia Krisanti
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as DOCX, PDF, TXT or read online on Scribd
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1. Write the component continuity equations describing the CSTR of example 2.

3 with :

a. Simultaneous reactions (first-order, isothermal)


K1 K2

A B A C

b. Reversible (first-order, isothermal)


K1

A B
K2

Penyelesaian :

F0, ρ0,

CA0, CB0
F, ρ,
V, ρ, CA, CB
CA, CB

a. Untuk reaksi simultan


- General component continuity equation

flow of moles flow of moles rate of formation rate of change


of jth of jth of mole of mole
[ ]−[ ]+[ ]=[ ]
component component of jth component of jth component
into system out of system from chemical reaction inside system

Component j into system : Fo.Cj0


Component j out system : F.Cj
Rate of formation by reaction : A = - k1.V.CA – k2.V.CA
B = k1.V.CA
C = k2..V.CA
d(Cj. V)
Rate of change inside system : dt

- Continuity for each component


d(CA. V)
A  Fo.CA0 - F.CA + (- k1.V.CA – k2.V.CA) = dt
d(CB. V)
B  Fo.CB0 - F.CB + k1.V.CA = dt
d(CC. V)
C  Fo.CC0 - F.CC + k2.V.CA = dt
b. Untuk reaksi reversibel
- General component continuity equation

flow of moles flow of moles rate of formation rate of change


of j of j of mole of mole
[ ]−[ ]+[ ]=[ ]
component component of j component of j component
into system out of system from chemical reaction inside system

Component j into system : Fo.Cj0


Component j out system : F.Cj
Rate of formation by reaction : A = - k1.V.CA + k2.V.CB
B = k1.V.CA - k2.V.CB
d(Cj. V)
Rate of change inside system : dt

- Continuity for each component


d(CA. V)
A  Fo.CA0 - F.CA + (- k1.V.CA + k2.V.CB) = dt
d(CB. V)
B  Fo.CB0 - F.CB + (k1.V.CA - k2.V.CB) = dt

2. Write the component continuity equations for a tubular reactor as in example 2.5 with
consecutive reactions occurring:
K1 K2

A B C

Penyelesaian :

dz

CA0(t) v(t,z) CAL(t)

z=0 z z+dz z=L

- General component continuity equation

molar flow of j
molar flow of j rate of formation time rate of
leaving system of j
[ into boundary ] − [ ]+[ ] = [ change of j ]
at boundary inside system inside system
at z
z + dz
∂Cj
Enter boundary z : A.v.Cj + (A.-Dj )
∂z
∂ ∂Cj ∂ ∂Cj
Out of boundary z+dz : A.v.Cj +[∂z (A. v. Cj )] 𝑑𝑧-(A.Dj )- [∂z (A. Dj ) ]dz
∂z ∂z

Rate of formation inside system : A = -k1.CA.A.dz


B = k1.CA.A.dz- k2.CB.A.dz
C = k2.CB.A.dz
∂
Time rate of change inside system : (A. Cj. dz )
∂t

- Continuity for each component


∂ ∂ ∂CA ∂
A− (A. v. CA )dz + (A. DA )dz - k1.CA.A.dz = (A. CA . dz )
∂z ∂z ∂z ∂t
∂ ∂ ∂CB ∂
B  − ∂z (A. v. CB )dz + ∂z (A. DB )dz + k1.CA.A.dz- k2.CB.A.dz = ∂t (A. CB . dz )
∂z
∂ ∂ ∂CC ∂
C  − ∂z (A. v. CC )dz + ∂z (A. DC )dz + k2.CB.A.dz = ∂t (A. CC . dz )
∂z

After dividing by A.dz, equations above become

∂ ∂ ∂CA ∂
A  − ∂z (v. CA ) + ∂z (DA ) - k1.CA = ∂t (CA )
∂z
∂ ∂ ∂CB ∂
B  − ∂z (v. CB ) + ∂z (DB ) + k1.CA - k2.CB = ∂t (CB )
∂z
∂ ∂ ∂CC ∂
C− (v. CC ) + (DC ) + k2.CB = (CC )
∂z ∂z ∂z ∂t

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