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Tugas 1 PSPK

The document provides the component continuity equations for: 1) A CSTR reactor with simultaneous first-order reactions. The equations relate the inflow and outflow of components to the rate of formation and rate of change within the reactor. 2) A CSTR reactor with a reversible first-order reaction. The equations are similar but also include the reverse reaction rate. 3) A tubular reactor with consecutive first-order reactions occurring along the length. The equations relate the flow of components into and out of infinitesimal reactor sections to the formation and change within each section.
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0% found this document useful (0 votes)
348 views3 pages

Tugas 1 PSPK

The document provides the component continuity equations for: 1) A CSTR reactor with simultaneous first-order reactions. The equations relate the inflow and outflow of components to the rate of formation and rate of change within the reactor. 2) A CSTR reactor with a reversible first-order reaction. The equations are similar but also include the reverse reaction rate. 3) A tubular reactor with consecutive first-order reactions occurring along the length. The equations relate the flow of components into and out of infinitesimal reactor sections to the formation and change within each section.
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1. Write the component continuity equations describing the CSTR of example 2.

3 with :

a. Simultaneous reactions (first-order, isothermal)


K1 K2

A B A C

b. Reversible (first-order, isothermal)


K1

A B
K2

Penyelesaian :

F0, ρ0,

CA0, CB0
F, ρ,
V, ρ, CA, CB
CA, CB

a. Untuk reaksi simultan


- General component continuity equation

flow of moles flow of moles rate of formation rate of change


of jth of jth of mole of mole
[ ]−[ ]+[ ]=[ ]
component component of jth component of jth component
into system out of system from chemical reaction inside system

Component j into system : Fo.Cj0


Component j out system : F.Cj
Rate of formation by reaction : A = - k1.V.CA – k2.V.CA
B = k1.V.CA
C = k2..V.CA
d(Cj. V)
Rate of change inside system : dt

- Continuity for each component


d(CA. V)
A  Fo.CA0 - F.CA + (- k1.V.CA – k2.V.CA) = dt
d(CB. V)
B  Fo.CB0 - F.CB + k1.V.CA = dt
d(CC. V)
C  Fo.CC0 - F.CC + k2.V.CA = dt
b. Untuk reaksi reversibel
- General component continuity equation

flow of moles flow of moles rate of formation rate of change


of j of j of mole of mole
[ ]−[ ]+[ ]=[ ]
component component of j component of j component
into system out of system from chemical reaction inside system

Component j into system : Fo.Cj0


Component j out system : F.Cj
Rate of formation by reaction : A = - k1.V.CA + k2.V.CB
B = k1.V.CA - k2.V.CB
d(Cj. V)
Rate of change inside system : dt

- Continuity for each component


d(CA. V)
A  Fo.CA0 - F.CA + (- k1.V.CA + k2.V.CB) = dt
d(CB. V)
B  Fo.CB0 - F.CB + (k1.V.CA - k2.V.CB) = dt

2. Write the component continuity equations for a tubular reactor as in example 2.5 with
consecutive reactions occurring:
K1 K2

A B C

Penyelesaian :

dz

CA0(t) v(t,z) CAL(t)

z=0 z z+dz z=L

- General component continuity equation

molar flow of j
molar flow of j rate of formation time rate of
leaving system of j
[ into boundary ] − [ ]+[ ] = [ change of j ]
at boundary inside system inside system
at z
z + dz
∂Cj
Enter boundary z : A.v.Cj + (A.-Dj )
∂z
∂ ∂Cj ∂ ∂Cj
Out of boundary z+dz : A.v.Cj +[∂z (A. v. Cj )] 𝑑𝑧-(A.Dj )- [∂z (A. Dj ) ]dz
∂z ∂z

Rate of formation inside system : A = -k1.CA.A.dz


B = k1.CA.A.dz- k2.CB.A.dz
C = k2.CB.A.dz

Time rate of change inside system : (A. Cj. dz )
∂t

- Continuity for each component


∂ ∂ ∂CA ∂
A− (A. v. CA )dz + (A. DA )dz - k1.CA.A.dz = (A. CA . dz )
∂z ∂z ∂z ∂t
∂ ∂ ∂CB ∂
B  − ∂z (A. v. CB )dz + ∂z (A. DB )dz + k1.CA.A.dz- k2.CB.A.dz = ∂t (A. CB . dz )
∂z
∂ ∂ ∂CC ∂
C  − ∂z (A. v. CC )dz + ∂z (A. DC )dz + k2.CB.A.dz = ∂t (A. CC . dz )
∂z

After dividing by A.dz, equations above become

∂ ∂ ∂CA ∂
A  − ∂z (v. CA ) + ∂z (DA ) - k1.CA = ∂t (CA )
∂z
∂ ∂ ∂CB ∂
B  − ∂z (v. CB ) + ∂z (DB ) + k1.CA - k2.CB = ∂t (CB )
∂z
∂ ∂ ∂CC ∂
C− (v. CC ) + (DC ) + k2.CB = (CC )
∂z ∂z ∂z ∂t

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