Pharmaceutical organic chemistry -2

Sl No Questions Ans Chapter title/content Difficulty*

1 Molecule must have _____ π electrons to be b Benzene and its d
aromatic compound derivatives
a) 2n+2
b) 4n+2
c) 6n+2
d) 8n+2
2 Cyclopentadienyl cation is a Benzene and its s
a) Aromatic derivatives
b) Not aromatic
c) Contains Five π electrons
d) Heterocycle

3 Electrophiles are c Benzene and its md

a) Rich in electrons derivatives
b) Neutral
c) More affinity to nucleas
d) Less affinity to nucleas

4 Catalyst used in Friedal-crafts alkylation is b Benzene and its d

a) Ammonium chloride derivatives
b) Aluminium chloride
c) Calcium chloride
d) Sodium chloride

5 Kolbe reaction is characteristic reaction for c Benzene and its md

a) Carboxylic acids derivatives
b) Amines
c) Phenols
d) Alcohols

6 Reimer-Tiemann reaction is characteristic c Benzene and its md

reaction for derivatives
a) Carboxylic acids
b) Amines
c) Phenols
d) Alcohols

7 Which of the following is weakly activating d Benzene and its md

group derivatives
a)-F
b) -Br
c) -NH2
d) -C2H5
8 In mechanism of electrophilic aromatic a Benzene and its md
substitution reaction, intermediate formed is derivatives
a) Carbocation
b) Carbanion
c) Neutral
d) Basic

9 In mechanism of electrophilic aromatic a Benzene and its s

substitution reaction derivatives
a) Ist step is rate determining step
b) IInd step is slow step
c) IInd step is rate determining step
d) Ist step is Fast step

10 Electron releasing group in electrophilic a Benzene and its s

aromatic substitution reaction derivatives
a) Stabilizes Carbocation
b) Destabilizes Carbocation
c) Deactivates ring
d) Do not have any effect

11 Chloro group is b Benzene and its s

a) Electron withdrawing by resonance effect derivatives
b) Electron withdrawing by inductive effect
c) Electron withdrawing by both inductive and
resonance effect
d) Electron donating by both inductive and
resonance effect
12 Toluene undergoes electrophilic aromatic c Benzene and its md
substitution reaction to give derivatives
a) Only para substituted product
b) Only ortho substituted product
c)Both para and ortho substituted product
d) Meta substituted product

13 Nitrobenzene undergoes electrophilic d Benzene and its md

aromatic substitution reaction to give derivatives
a) Only para substituted product
b) Only ortho substituted product
c) Both para and ortho substituted product
d) Meta substituted product

14 Chlorobenzene undergoes electrophilic c Benzene and its md

aromatic substitution reaction to give derivatives
a) Only para substituted product
b) Only ortho substituted product
c)Both para and ortho substituted product
d) Meta substituted product
14 In case of carbocation intermediate in d Benzene and its s
electrophilic aromatic substitution of aniline, derivatives
stable resonace structure has
a) Pentet electrons
b) hextet electrons
c) heptet electrons
d) octet electrons
15 Iodobenzene undergoes electrophilic aromatic c Benzene and its md
substitution reaction to give derivatives
a) Only para substituted product
b) Only ortho substituted product
c) Both para and ortho substituted product
d) Meta substituted product

16 Protonated dimethylaniline undergoes d Benzene and its s

electrophilic aromatic substitution reaction to derivatives
give
a) Only para substituted product
b) Only ortho substituted product
c) Both para and ortho substituted product
d) Meta substituted product
17 Benzaldehyde undergoes nitration reaction to d Benzene and its s
give derivatives
a) Only para substituted product
b) Only ortho substituted product
c) Both para and ortho substituted product
d) Meta substituted product

18 Acetanilide undergoes nitration reaction to c Benzene and its s

give derivatives
a) Only para substituted product
b) Only ortho substituted product
c) Both para and ortho substituted product
d) Meta substituted product

19 4- methyl acetanilide undergoes bromination a Benzene and its s

gives chief product i.e., derivatives
a) 2-bromo-4- methyl acetanilide
b) 3-bromo-4- methyl acetanilide
c) 5-bromo-4- methyl acetanilide
d) 2,3-dibromo-4- methyl acetanilide

20 4-hydroxy toluene on nitration gives _______ b Benzene and its s

as chief product derivatives
a) 2-Nitro-4-hydroxy toluene
b) 3-Nitro-4-hydroxy toluene
c) 2,6-Dinitro-4-hydroxy toluene
d) 3,5-Dinitro-4-hydroxy toluene
21 What is the name of C6H5-CH2 group? c Benzene and its s
a) aryl derivatives
b) arenyl
c) benzyl
d) phenyl

22 Which will not result in a reaction? c Benzene and its d

a) C6H5OH + Br2 derivatives
b) C6H5OH + NaOH
c) C6H5OH + Na2CO3
d) C6H5OH + HNO3/H2SO4

23 Which of the following represents the best d Benzene and its md

reagent(s) for the electrophilic nitration of derivatives
benzene?
a) NO2
b) HNO2
c) HNO3
d) H2SO4, HNO3

24 Predict the major product when nitrobenzene c Benzene and its d

reacts with methyl chloride in presence of derivatives
aluminium chloride
a) nitrobenzene
b) o-nitrotoluene and p-nitrotoluene
c) m-nitrotoluene
d) chlorobenzene
25 Predict the major product when toluene c Benzene and its s
reacts with methyl chloride in presence of derivatives
aluminium chloride
a) o-chlorotoluene and p-chlorotoluene
b) m-chlorotoluene
c) o-dimethylbenzene and p-dimethylbenzene
d) m-dimethylbenzene
26 Aldehyde group in benzaldehyde is b Benzene and its s
a) ortho and para directing derivatives
b) meta directing
c) para directing
d) ortho directing

27 Bromine group in bromobenzene is a Benzene and its s

a) ortho and para directing derivatives
b) meta directing
c) para directing
d) ortho directing
28 Which of the following statements is incorrect Benzene and its s
for aromatic compounds c derivatives
a) Are planar
b) Have 4n+2 π-electrons
c) Have 4n π-electrons
d) Are cyclic

29 When considering electrophilic aromatic a Benzene and its s

substitution reactions electron donating derivatives
subsituents (e.g. methoxy) are described as
a) ortho/para directing and activating
b) ortho/para directing and deactivating
c) meta directing and activating
d) meta directing and deactivating
30 How many pairs of degenerate π molecular d Benzene and its s
orbitals are found in benzene? derivatives
a) 6
b) 5
c) 4
d) 2

31 Chemically DDT is a Benzene and its s

a) dichlorodiphenyltrichloroethane derivatives
b) dichloroethane
c) trichloroethane
d) dichloropropane
e) trichlorobutane

32 Saccharine is a derivative of a Benzene and its s

a) benzothiazole derivatives
b) benzotriazole
c) benzimidazole
d) benzoxazole

33 Saccharine is used as b Benzene and its md

a) preservative derivatives
b) artificial sweetener
c) flavouring agent
d) colouring agent

34 Chloramine is used as c Benzene and its md

a) preservative derivatives
b) artificial sweetener
c) disinfectant
d) flavouring agent
35 Alcohols can be converted into carboxylic a Aromatic acids md
acids by
a) oxidation
b) Reduction
c) Hydrolysis
d) Eliminatione

36 Alkyl halides can be converted in to carboxylic c Aromatic acids s

acid by
a) oxidation
b) Reduction
c) via grignard reagent
d) Hydrolysis

37 Carboxylic acids can be converted in primary b Aromatic acids s

alcohol by
a) Oxidation using KMNO4
b) Reduction using LiAlH4
c)Hydrolysis using NaOH
d) Ester formation

38 Carboxylic acids are more acidic than alcohols b Aromatic acids s

due to
a) Resonance stabilization of conjugate base
of acid is small
b) Resonance stabilization of conjugate base
of acid is large
c) Resonance stabilization of acid is small
d) Resonance stabilization of acid is large
39 Which of the following statement is TRUE a Aromatic acids s
a) α-Chlorobutyric acid is as strong as
chloroacetic acid
b) α-Chlorobutyric acid is less strong as
chloroacetic acid
c)Trifluroacetic acid is weak acid
d) Electron withdrawing group decreases
acidity
40 Effect of ortho-OCH3 group on acidity of b Aromatic acids md
benzoic acid
a) Increases
b) Decreases
c) No effect
d) Strongly increases

`41 Effect of ortho-NO2 group on acidity of a Aromatic acids md

benzoic acid
a) Increases
b) Decreases
c) No effect
d) Strongly increases
42 Phenol can be converted to p- & o- b Phenols s
Hydroxyphenyl ethyl ketone by
a) Riemen-Tiemann reaction
b) Fries rearrangement
c) Claisens rearrangement
d) Kolbe reaction

43 Phenol can be converted into salicylaldehyde a Phenols s

by
a) Riemen-Tiemann reaction
b) Fries rearrangement
c) Claisens rearrangement
d) Kolbe reaction

44 Benzyl Phenyl ether is obtained from benzyl d Phenols s

bromide and phenol in the presence of
catalyst
a) Con HCl
b) Con H2SO4
c) Aq HNO3
d) aq. NaOH
45 Carbonation of grignard reagent leads to b Aromatic acids s
synthesis of
a) Alkyl halide
b) Carboxylic acid
c) Aldehyde
d) Ketone

46 Acyl chloride can be synthesised from c Aromatic acids s

carboxylic acid using
a) HCl
b) NaCl
c) SOCl2
d) KCl

47 Catalyst used in Friedal-crafts alkylation is Benzene and its

a) Ammonium chloride derivatives
b) Aluminium chloride
c) Calcium chloride
d) Sodium chloride

48 Which of the following is O-hydroxy phenol a Phenols s

a) Catechol
b) Resorcinol
c) Hydroquinone
d) Cresol
49 Which of the following is p-hydroxy phenol c Phenols s
a) Catechol
b) Resorcinol
c) Hydroquinone
d) Cresol

50 Which of the following is m-hydroxy phenol b Phenols s

a) Catechol
b) Resorcinol
c) Hydroquinone
d) Cresol

51 Which of the following is 3-methyl phenol d Phenols s

a) Catechol
b) Resorcinol
c) Hydroquinone
d) Cresol

52 Phenol is soluble in a Phenols s

a) Aq NaOH
b) Aq NaHCO3
c) Aq HCl
d) None

53 Catalyst used in Friedal-crafts alkylation is Benzene and its

a) Ammonium chloride derivatives
b) Aluminium chloride
c) Calcium chloride
d) Sodium chloride

54 Anisole can be synthesised from phenol using a Phenols s

a) Methyl sulfate and NaOH
b) Methyl sulfate and HCl
c) Methyl acetate and NaOH
d) Methyl acetate and HCl

55 Which of the following functional groups can't d Benzene and its s

accommodate +ve charge in electrophilic derivatives
aromatic substitution reaction
a) NH2
b) OH
c) Cl
d) NO2
56 Which of the following is secondary amine b Aromatic amines m
a) Aniline
b) N-Methylaniline
c) N,N-Dimethylaniline
d) Trimethylaniline

57 Which of the following catalyst used to reduce c Aromatic amines s

nitro group to amine
a) LiAlH4
b) NaBH4
c) Sn, HCl
d) KMNO4

58 Benzaldehyde is converted to benzylamine by b Aromatic amines s

a) Reduction
b) Reductive amination
c) Oxidation
d) Amination

59 Hofmann degradation of amides gives a Aromatic amines m

a) Primary amine
b) Secondary amine
c) Tertiary amine
d) Quaternary amine

60 Intermediate formed in Hofmann degradation a Aromatic amines s

is
a) Isocyanate
b) Isothiocyanate
c) Imine
d) Amine

61 Hofmann elimination of quaternary b Aromatic amines s

ammonium salts gives
a) Alkane
b) Alkene
c) Alkyne
d) Alkyl halide

62 Reduced basicity of aniline is due to a Aromatic amines s

a) Larger resonance stabilisation of aniline
b) Larger resonance stabilisation of its
cojugate acid
c) Resonance effect
d) Inductive effect
63 Effect of halogens on basicity of aniline b Aromatic amines d
a) Increases
b) Decreases
c) No effect
d) Strongly increases

64 2-pentyltrimethyl ammonium ion by hofmann a Aromatic amines s

elimination gives____ as chief product
a) 1-Pentene
b) 2-Pentene
c) 3-Pentene
d) Both a) and B)

65 A reaction of N-methylaniline with nitrous acid b Aromatic amines s

gives
a) Diazonium salt
b) N-Nitroso-N-methylaniline
c) P-nitroso-N-methylaniline
d) No reaction

66 The amine ‘A’ when treated with nitrous acid c Aromatic amines s
gives yellow oily substance. The amine A is
a) Triethylamine
b) Trimethylamine
c) Aniline
d) methylphenylamine

67 The reaction of aniline with chloroform under d Aromatic amines s

alkaline conditions leads to the formation of
a) Phenyl isonitrile
b) Phenyl isocyanate
c) Phenyl cyanate
d)Phenyl cyanide

68 Which of the following statements about c Aromatic amines s

primary amines is ‘False‘?
a) Alkyl amines are stronger bases than aryl
amines
b) Alkyl amines react with nitrous acid to
produce alcohols
c) Aryl amines react with nitrous acid to
produce phenols
d) Alkyl amines are stronger bases than
ammonia
69 Which of the following compound will not d Aromatic amines s
undergo azo coupling reaction with benzene
diazonium chloride?
a) Aniline
b) Phenol
c) Anisole
d) Nitrobenzene
70 Aromatic amine are b Aromatic amines md
a) acidic in nature
b) basic in nature
c) neutral compounds
d) amphoteric compounds

71 In conversion of Benzene diazonium salt to a Aromatic amines s

Fluorobenzene, the catalyst used is
a) HBF4
b) KF
c) Trifluoroacetic acid
d) CuF

72 In conversion of o-toluidine to o-cresol, the a Aromatic amines s

catalyst used is
a) NaNO2, H2SO4
b) HNO3
c) NaNO2
d) NaNO2, KCl

73 Iodobenzene can be synthesized from aniline b Aromatic amines s

via.,
a) Grignard reagent
b) Diazonium salt
c) using KI
d) Using Iodine

74 In conversion of Benzene diazonium salt to b amines s

Fluorobenzene, the catalyst used is
a) Br2
b) CuBr
c) HBr
d) Bromine water

75 In conversion of Benzene diazonium salt to b amines s

Cyanobenzene, the catalyst used is
a) HCN
b) CuCN
c) LiAlH4
d) Cyanoacetic acid

76 In conversion of 2,4-dichloroBenzene b amines s

diazonium salt to 2,4-dichlorbenzene, the
catalyst used is
a) NaOH
b) H3PO2
c) HCl
d) KOH
77 Product of Hofmann elimination reaction is c amines s
a) Primary amine
b) Secondary amine
c) Teriary amine
d) ammonia

78 Catalyst used in Hofmann rearrangement b amines s

reaction is
a) NaBr
b) NaOBr
c) HCl
d) NaCl

79 Intermediate formed in Hofmann a amines s

rearrangement reaction is
a) Isocyanate
b) Cyanide
c) Cyanate
d) Isothocyanate

80 Product of Hofmann rearrangement reaction a Amines s

is
a) Primary amine
b) Secondary amine
c) Teriary amine
d) Amide
81 Hofmann rearragement reaction is also called c Amines s
as
a) Migration to electron deficient carbon
b) Migration to electron rich carbon
c) Migration to electron deficient nitrogen
d) Migration to electron rich nitrogen

82 Sterochemistry in Hofmann rearragement b amines s

reaction is
a) Inverstion of configuration
b) Retention of configuration
c) No sterochemistry is observed
d) None

83 In orientation of Hofmann elimination b amines s

reaction of quaternary salts, E2 transition
state observed is
a) Carbocation like
b) Carbanion like
c) Alkene characte
d) Alkane character
84 In orientation of Hofmann elimination amines
reaction of quaternary salts, E2 transition
state observed is
a) Carbocation like
b) Carbanion like
c) Alkene characte
d) Alkane character
85 Fats and oils are a Fats and oils m
a) Esters
b) Amides
c) Carboxylic acids
d) Phenols

86 Soaps are prepared by hydroysis of c Fats and oils m

trigylcerides using
a) HCl
b) H2SO4
c) NaOH
d) H2O

87 Example of drying oil is c Fats and oils s

a) Coconut oil
b) Castor oil
c) Linseed oil
d) Olive oil

88 Which of the below fatty acid is example of b Fats and oils m

unsaturated fatty acid
a) Myristic acid
b) Oleic acid
c) Palmitic acid
d) Stearic acid

89 Which of the following statement is TRUE b Fats and oils s

a) Fats and oils soluble in water
b) Fats and oils contain both polar and non
polar group
c) Fats and oils are salts of carboxylic acids
d) Fats and oils are amides of fatty acids

90 Saponification value of oil is more than 2 b Fats and oils s

indicates
a) Oil is fress
b) Oil is deteroriated
c) It has no effect on oil
d) Oil contain more unsaturated fatty acid
91 Fats and oils are c Fats and oils s
a) monoesters of glycerol
b) diesters of glycerol
c) triesters of glycerol
d) triesters of glycol

92 Sodium and potassium salts of fatty acids are d Fats and oils m
called
a) Protein
b) Terpenes
c) Carbohydrates
d) Soaps

93 Oleic acid is a fatty acid containing d Fats and oils s

a) 12 carbons
b) 14 carbons
c) 16 carbons
d) 18 carbons

94 Liquid oils can be converted to solid fats by b Fats and oils s

a) Hydrolysis
b) Hydrogenation
c) Saponification
d) oxidation of double bond.

95 Partial hydrolgenation of vegetable oils in the a Fats and oils s

presence of Ni catalyst at 200 °C gives
a) Vanaspati ghee
b) Margarine
c) Both of these
d) Non of these

96 Synthetic detergents can be represented by Fats and oils

the following general formula
a) RONa
b) ROSO3Na
c) RCOONa
d) RCOOH

97 Alkaline hydrolysis of fats and oils is called a Fats and oils m

a) Saponification
b) Fermentation
c) Diazotisation
d) Rancidification
98 The degree of unsaturation of fat can be a Fats and oils m
determined by mean of its a) Iodine value
b) Saponification value
c) Ester value
d) Acetyl value

99 stearic acid is a fatty acid containing d Fats and oils s

a) 12 carbons
b) 14 carbons
c) 16 carbons
d) 18 carbons

100 Palmitic acid is a fatty acid containing c Fats and oils s

a) 12 carbons
b) 14 carbons
c) 16 carbons
d) 18 carbons

101 Melting point of Oleic acid is d Fats and oils s

a) 58 °C
b) 63 °C
c) 70 °C
d) 4 °C

102 Naphthalene undegoes oxidation with a Polynuclear s

Na2Cr2O7/H2SO4 to form Hydrocarbons
a) Phthalic acid
b) Benzoic acid
c) Teraline
d) Phenyl acetic acid

103 Napthalene undegoes nitration with a Polynuclear s

HNO3/H2SO4 at 60 °C to give mainly Hydrocarbons
a) 1-Nitronapthalene
b) 1,2-Nitronapthalene
c) 2-Nitronapthalene
d) 2,5-Nitronapthalene

104 Which of the following is starting material in a Polynuclear s

Haworth synthesis of naphthalene Hydrocarbons
a) succininc anhydride
b) Phthalic anhydride
c) acetic anhydride
d) None of the above
105 Which of the following statement is TRUE in d Polynuclear s
electrophilic aromatic substitution of Hydrocarbons
napthalene
a) α-Product forms
b) β-product forms
c) Both α & β product forms
d) α product always predominates depending
on condition
106 Nitration of naphthalene molecule at room a Polynuclear s
temperature gives Hydrocarbons
a) 1-nitronaphthalene
b) 2-nitronaphthalene
c) 4-nitronaphthalene
d) 8-nitronaphthalene

107 Naphthalene on oxidation with c Polynuclear s

CrO3/CH3COOH gives Hydrocarbons
a) 1,2-Naphthoquinone
b) 1,3-Naphthoquinone
c) 1,4-Naphthoquinone
d) No reaction

108 Naphthalene on oxidation with V2O5 gives b Polynuclear s

a) Succinic anhydride Hydrocarbons
b) Phthalic anhydride
c) Acetic anhydride
d) No reaction

109 β-Napthalenediazonium chloride converted to a Polynuclear s

naphthalene in presence of Hydrocarbons
a) H3PO2
b) CuBr
c) CuCN
d) HCl

110 All carbon atoms in naphthalene are b Polynuclear s

a) Sp hybridised Hydrocarbons
b) sp2 hybridised
c) sp3 hybidised
d) None of the above

111 Anthracene on bromination in presence of a Polynuclear s

Br2/CCl4 gives Hydrocarbons
a) 9-Bromoanthracene
b) 1-Bromoanthracene
c) 2-Bromoanthracene
d) 4-Bromoanthracene
112 Anthracene on sulphonation in presence of b Polynuclear s
Con H2SO4 at high temperature gives Hydrocarbons
a) 1-Anthracenesulfonic acid
b) 2-Anthracenesulfonic acid
c) 4-Anthracenesulfonic acid
d) 9-Anthracenesulfonic acid

113 Anthracene on sulphonation in presence of a Polynuclear s

Con H2SO4 at low temperature gives Hydrocarbons
a) 1-Anthracenesulfonic acid
b) 2-Anthracenesulfonic acid
c) 4-Anthracenesulfonic acid
d) 9-Anthracenesulfonic acid

114 Anthracene on oxidation in presence of a Polynuclear s

Na2Cr2O7 /Con H2SO4 gives Hydrocarbons
a) 9,10 Anthraquinone
b) 9,10 Dihydroanthracene
c) 1,4 Anthraquinone
d) 1,4 Dihydroanthracene

115 Anthracene on reduction in presence of H2 b Polynuclear s

/Pd-C gives Hydrocarbons
a) 9,10 Anthraquinone
b) 9,10 Dihydroanthracene
c) 1,4 Anthraquinone
d) 1,4 Dihydroanthracene

116 Starting materials for synthesis of c Polynuclear s

phenanthrene are Hydrocarbons
a) Naphthalene & acetic anhydride
b) Naphthalene & phthalic anhydride
c) Naphthalene & succinic anhydride
d) Naphthalene & benzene

117 Friedel-crafts acylation of phenanthrene gives c Polynuclear s

a) 1-acetylphenanthrene Hydrocarbons
b) 4-acetylphenanthrene
c) 9-acetylphenanthrene
d) 10-acetylphenanthrene

118 Cyclopropane is synthesised from b Cycloalkanes s

a) 2 moles of ethyl chloride
b) 1,3-Dichloropropane
c) Calcium adipate
d) Diethyl adipate
119 Cyclopropane on oxidation with conc H2SO4 b Cycloalkanes s
gives
a) Isopropyl alcohol
b) n-Propyl alcohol
c) Butanol
d) Epoxide

120 Cyclopropane on reduction with conc with c Cycloalkanes m

Ni/H2 at 80 °C gives
a) Ethane
b) Butane
c) Propane
d) Pentane

121 Cyclopropane on halogenation with Cl2/FeCl3 c Cycloalkanes m

gives
a) 1,1-Dichloropropane
b) 1,2-Dichloropropane
c) 1,3-Dichloropropane
d) 1,2,3-Trichloropropane

122 According to Baeyer strain theory, Heat of b Cycloalkanes m

combustion of the cycloalkanes
a) Increases as the ring size increases
b) Decreases as the ring size increases
c) No change in Heat of combustion
d) None of the above

123 According to Baeyer strain theory, which of c Cycloalkanes m

the following cycloalkane is stable
a) Cyclopropane
b) Cyclobutane
c) Cyclopentane
d) Cyclohexane

124 According to Baeyer strain theory, which of a Cycloalkanes m

the following conformer of cycloalkane is
more stable
a) Chair form
b) Boat form
c) Twist-chair form
d) Twist-boat form
125 According to Baeyer strain theory, which of a Cycloalkanes s
the following statement is TRUE
a) Lesser potential energy in Chair form
compare to other conformers
b) Larger potential energy in Chair form than
boat form
c)Larger potential energy in twist-boat form
than boat form
d) Both chair and boat form have similar
potential energy
126 Cycloalkanes are associated with the general d Cycloalkanes m
formula
a) CnH2n+2
b) CnH2(n+2)
c) CnH2n+1-r
d) CnH2(n+1-r)
127 Identify the incorrect statement regarding b Cycloalkanes s
cycloalkanes
a) These have sp3 hybridized carbons
b) These have tetrahedral bond angles
c) Stability of the cycloalkanes varies directly
with their respective size
d) These undergo nucleophilic substitution
reactions
128 Identify the compound with the highest ring b Cycloalkanes s
strain
a) Cyclohexane
b) Cyclopropane
c) Cyclobutane
d) Cyclopentane
129 Which among the following compounds a Cycloalkanes s
explodes on contact with oxygen
a) Cyclopropane
b) Cyclobutane
c) Cyclopentane
d) Cyclohexane

130 Identify the alicyclic hydrocarbon which is Cycloalkanes

highly flammable
a) Cycloheptane
b) Cyclopentane
c) Cyclopropane
d) Cyclooctane
131 Identify the incorrect statement regarding c Cycloalkanes m
cyclohexane:
a) It is non-polar
b) It serves as an organic solvent
c) It a hydrophilic hydrocarbon
d) It is commercially used for variety of
applications
132 Cycloalkanes have the same molecular b Cycloalkanes m
formula as
a) Alkanes
b) Alkenes
c) Akynes
d) Cycloalkenes
133 Which of the following cycloalkane is most b Cycloalkanes s
reactive?
a) Cyclohexane
b) Cyclopropane
c) Cyclobutane
 d) Cyclopentane

134 Which of the following molecules will a Cycloalkanes s

decolorise bromine in carbon tetrachloride
most readily?
a) 1,2-Dimethylcyclopropane
b) 1,2-Dimethylcyclobutane
c) Cylcopentane
d) Cyclohexane
135 Cyclobutane reacts with hydrogen in the a Cycloalkanes s
presence of nickel catalyst at 200 °C to give
a) Butane
b) 1-Butene
c) 2-Butene
d) None of these

136 The bond angle between carbon atoms in a Cycloalkanes m

cyclohexane is
a) 109° 28'
b) 60°
c) 90°
d)120°
137 The bond angle between carbon atoms in b Cycloalkanes m
cyclopropane is
a) 109° 28'
b) 60°
c) 90°
d)120°
138 The bond angle between carbon atoms in c Cycloalkanes m
cyclobutane is
a) 109° 28'
b) 60°
c) 90°
d)120°
139 The most stable conformation of cyclohexane c Cycloalkanes s
is the
a) Haworth form
b) Boat form
c) Chair form
d)Newman form
140 Which of the following statement is false c Cycloalkanes s
about cyclohexane?
a) It is a saturated cyclic hydrocarbon
b) All C-C-C bond angles are 109° 28'
c) Unstable, strained compound
d)Exist in chair-form and boat-form