THERMOCHEMISTRY Page # 23

Exercise - III Subjective Level-I

Heat of reaction & it's type 9. The heat of reaction ½H2(g) + ½Cl2(g)  HCl
1. For urea NH2CONH2(S) ; f H°298 = –333.5 kJ/mol. (g) at 27° C is –22.1 k cal. Calculate the heat of
Find f U°298 of urea. reaction at 77°C. The molar heat capacities at
constant pressure at 27° for hydrogen, chlorine & HCl
are 6.82, 7.70 & 6.80 cal mol–1 respectively.
2. On the basis of following data,
Evaluate the standard enthalpy of formation of
tungsten carbide (WC) 10. Calculate the enthalpy change when infinitely
3 dilute solutions of CaCl2 and Na2CO3 are mixed Hf
(i) W(s) + O2(g) WO3(s) rH° = – 837 for Ca2+ (aq), CO32– (aq) and CaCO3 (s) are –129.80,
2
kJ/mol –161.65, –288.5 kcal mol–1 respectively.
5
(ii) WC(s) + O2(g) WO3 (s) + CO2(g)
2
rH° = – 1196 kJ/mol
11. The enthalpies of neutralization of NaOH & NH4OH
(iii) C(graphite) + O2(g) CO2(g) rH° = –
by HCl are –13680 calories and –12270cal respectively.
393.5 kJ/mol
What would be the enthalpy change if one gram
equivalent of NaOH is added to one gram equivalent
3. Calculate r H° for Fe2O 3(s) + 3CO(g) of NH4Cl in solution? Assume that NH4OH and NaCl are
2Fe(s) + 3CO2(g) quantitatively obtained.
Given : fH° (Fe2O3) = –822.2 kJ/mol
fH° (CO, g) = –110.5 kJ/mol, fH° (CO2, g) 12. The heat of solution of anhydrous CuSO4 is –15.9
= – 393.5 kJ/mol kcal and that of CuSO4. 5H2O is 2.8 kcal. Calculate
the heat of hydration of CuSO4

4. The standard heats of formation of CH4(g), CO2(g)

and H2O(l ) are –76.2, –398.8, –241.6 kJ mol–1. 13. The standard enthalpy of neutralization of KOH
Calculate amount of heat evolved by burning 1 m3 of with (a) HCN (b) HCl in dilute solution is –2480 cal.
methane measured at 1 atm & 273 K. geq–1 and –13.68 kcal geq–1 respectively. Find the
enthalpy of dissociation of HCN at the same
5. A cylinder of gas supplied by a company contains
temperature.
14 kg of butane. The heat of combustion of butane is
2658 kJ/mol. A normal family requires 20 MJ of energy
per day for cooking. If the cylinder lasts for 26 days, 14. If the enthalpy of formation of HCl (g) and Cl–
what percentage of gas is wasted due to inefficient (aq) are –92.3 kJ/mole and –167.44 kJ/mol, find the
combustion. enthalpy of solution of hydrogen chloride gas.

6. A cylinder of gas is assumed to contain 11.2 kg of Calorimeter

butane. If a normal family needs 20,000 kJ of energy
per day for cooking, how long will the cylinder last if 15. 0.16 g of methane was subjected to combustion
the enthalpy of combustion, H = –2658 kJ/mole for at 27° C in a bomb calorimeter. The temperature of
butane. calorimeter system (including water) was found to
rise by 0.5°C. Calculate the heat of combustion of
methane at (i) constant volume (ii) constant pressure.
7. The molar enthalpy of vaporization of benzene at The thermal capacity of calorimeter system is 17.7
its boiling point (353 K) is 30.84 kJ mol–1 What is the kJK–1 (R = 8.313 mol–1K–1)
molar internal energy change ? For how long would a
12 volt source need to supply a 0.5 A current in order
to vaporise 7.8 g of the sample at its boiling point ? 16. 1.00 l sample of a mixture of CH4(g) & O2(g)
measured at 25° C & 740 torr was allowed to react at
constant pressure in a calorimeter which together
8. When 12.0 g of carbon reacted with oxygen to with its contents had a heat capacity of 1260 cal/K.
form CO & CO2 at 25°C & constant pressure, 75.0 The complete combustion of the methane to CO2 &
kcal of heat was liberated and no carbon remained. H2O caused a temperature rise in the calorimeter of
Calculate the mass of oxygen which reacted. 0.667 K. What was the mole percent of CH4 in the
H0f (CO 2 ) = –95 kcal mol–1, H0f (CO) = –24 kcal mol– original mixture ? H°comb(CH4) = –215 kcal mol–1.
1
.

394 - Rajeev Gandhi Nagar Kota, Ph. No. 0744-2209671, 93141-87482, 93527-21564
IVRS No. 0744-2439051, 0744-2439052, 0744-2439053 www.motioniitjee.com, [email protected]
 Page # 24 THERMOCHEMISTRY
17. A quantity of 1.92 of methanol was burnt in a 24. Using the given data calculate enthalpy of
constant pressure calorimeter. The temperature of formation of acetone (g). [All values in kJ mol–1]
water increased by 4.2°C. If the quantity of water binding energy of ; C – H = 413.4 ; C – C = 347.0 ;
surrounding the inner vessel was 2000 ml and the C = O = 728.0 ; O = O = 495.0 ; H – H = 435.8
heat capacity of the inner vessel was 2.02 kJ/°C. ; Hsub of C = 718.4
Calculate the heat of combustion of methanol.
[Specific heat of capacity of H2O = 4.18 J/g°C]
25. Find the enthalpy of S – S bond from the following
Bond energy data.
18. The enthalpy of dissociation of PH3 is 954 kJ/mol (i) C2H5 – S – C2H5(g) H0f  –147.2 kJ / mol
and that of P2H4 is 1.48 M J mol–1. What is the bond (ii) C2H5 – S – S – C2H5(g) H0f  –201.9 kJ / mol
enthalpy of the P – P bond ? (iii) S (g) Hf0  222.8 kJ / mol

19. Using the bond enthalpy data given below, Resonance Energy
calculate the enthalpy change for the reaction. 26. The enthalpy of formation of ethane, ethylene
C2H4(g) + H2(g)  C2H6 (g) and benzene from the gaseous atoms are –2839.2, –
Data : 2275.2 and –5506 KJ mol–1 respectively. Calculate the
Bond C–C C=C C–H H–H resonance energy of benzene. The bond enthalpy of
C – H bond is given as equal to +410.87 KJ/mol.
Bond Enthalpy 336.81 kJ/mol 606.68 kJ/mol 410.87
kJ/mol 431.79 kJ/mol
27. Calculate the heat of combustion of methyl alcohol
at 298 K from the following data
20. The enthalpy change for the following process at Bond C–H C–O O–H O=O C=O
25°C and under constant pressure at 1 atm are as Energy kJ mol–1 414 351.5 464.5 494 711
follows : Resonance energy of CO2 = –143 kJ mol–1
CH4(g)  C(g) + 4H(g) rH = 396 kcal/mole Latent heat of vaporisation of methyl alcohol = 35.5
C2H6(g)  2C(g) + 6H(g) rH = 676 kcal/mole kJ mol–1
Calculate C – C bond energy in C2H6 & heat of formation Latent heat of vaporisation of water = 40.6 kJ mol–1.
of C2H6 (g)
Given : subC(s) = 171.8 kcal/mole Born Haber cycle
28. Calculate the electron gain enthalpy of fluorine
B.E. (H – H) = 104.1 kcal/mole
atom using the following data. Make Born – Haber's
cycle. All the values are in kJ mol–1 at 25°C. Hdiss (F2)
21. The polymersiation of ethylene to linear = 160, H0f (NaF(s)) = –571, I.E.
polyethylene is represented by the reaction nCH2 = [Na(g)] = 494, Hvap [Na(s)] = 101. Lattice energy of
CH2  (–CH2 – CH2)n where n has a large integral NaF(s) = –894.
value. Given that the average enthalpies of bond
dissociation for C = C & C – C at 298 K are +590 & 29. Cesium chloride is formed according to the
+331 kJ mol–1 respectively. Calculate the enthalpy of following equation
polymerisation per mole of ethylene at 298 K. Cs(s) + 0.5 Cl2(g)  CsCl(s).
The enthalpy of sublimation of Cs, enthalpy of
22. From the following data : Enthalpy of formation dissociation of chlorine, ionization energy of Cs &
of CH3CN = 87.86 kJ/mol, Enthalpy of formation of electron gain enthalpy of chlorine are 81.2, 243.0,
C2H6 = –83.68 kJ/mol 375.7 and –348.3 kJ mol–1. The energy change
Enthalpy of sublimation of graphite = 719.65 kJ/mol involved in the formation of CsCl is –388.6 kJ mol–1.
Calculate the lattice energy of CsCl.
Enthalpy of dissociation of nitrogen = 945.58 kJ/mol;
Enthalpy of dissociation of H2 = 435.14 kJ/mol
30. The Born-Haber cycle for rubidium chloride (RbCl)
C – H bond enthalpy = 414.22 kJ/mol
is given below (the energies are in kcal mol–1)
Calculate the (i) C–C ; (ii) C  N

23. The heat of combustion of acetylene is 312 kcal.

If heat of formation of CO2 & H2O are –94.38 & –68.38
kcal respectively, calculate C  C bond energy. Given
that heat of atomisation of C is 150 kcal and H – H
bond energy and C – H bond energy are 103 kcal and
93.64 k cal respectively. Find the value of X.

394 - Rajeev Gandhi Nagar Kota, Ph. No. 0744-2209671, 93141-87482, 93527-21564
IVRS No. 0744-2439051, 0744-2439052, 0744-2439053 www.motioniitjee.com, [email protected]