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The document summarizes vapor-liquid equilibrium calculations for a mixture of four hydrocarbon components (ethane, propane, n-butane, and 2-methyl propane) at different temperatures and pressures. It provides equations, constants, and calculations of vapor pressures, mole fractions in the vapor and liquid phases, and phase amounts. The key information includes component properties, equilibrium conditions, equations used, and results of mole fraction and phase calculations.

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0% found this document useful (0 votes)
133 views4 pages

10 1-1

The document summarizes vapor-liquid equilibrium calculations for a mixture of four hydrocarbon components (ethane, propane, n-butane, and 2-methyl propane) at different temperatures and pressures. It provides equations, constants, and calculations of vapor pressures, mole fractions in the vapor and liquid phases, and phase amounts. The key information includes component properties, equilibrium conditions, equations used, and results of mole fraction and phase calculations.

Uploaded by

KathrynaDenaga
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as XLSX, PDF, TXT or read online on Scribd
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Component A B Pvap xi yi

Ethane 817.08 4.402229 41.67193 0.05 0.416719


Propane 1051.38 4.517190 8.64864 0.10 0.172973
n-Butane 1267.56 4.617679 2.001168 0.40 0.160093
2-Methyl Propane 1183.44 4.474013 2.780159 0.45 0.250214
SUM 1

Tbp (K) 293.6617 P (bar) 5.00

Equations used:

�_𝑖 𝑃_𝑖^𝑣𝑎𝑝=𝑦_𝑖 𝑃 𝑦_𝑖=(�_𝑖 𝑃_𝑖^𝑣𝑎𝑝)/𝑃

4_(𝑖=1)^𝑐▒ 〖� _� �_�^��� 〗 =∑_(�=1)^�▒ 〖� _𝑖 𝑃=𝑃 〗

log_10 〖
〖�^𝑣𝑎𝑝=−𝐴/𝑇+� 〗
𝑃^𝑣𝑎𝑝= 〖 10 〗 ^((−𝐴/𝑇+�) )
Component A B Pvap yi xi
Ethane 817.08 4.402229 47.71215 0.05 0.00524
Propane 1051.38 4.517190 10.29414 0.10 0.048571
n-Butane 1267.56 4.617679 2.468761 0.40 0.810123
2-Methyl Propane 1183.44 4.474013 3.382307 0.45 0.665226
SUM 1.529161

Tdp (K) 300 P (bar) 5.00

Equations used:
�_𝑖 𝑃_𝑖^𝑣𝑎𝑝=𝑦_𝑖 𝑃 �_𝑖=(𝑦_𝑖 𝑃)/(𝑃_𝑖^𝑣𝑎𝑝 )

4_(𝑖=1)^𝑐▒ 〖� _� �_�^��� 〗 =∑_(�=1)^�▒ 〖� _𝑖 𝑃=𝑃 〗

log_10 〖
〖�^𝑣𝑎𝑝=−𝐴/𝑇+� 〗 〖 10 〗 ^((−𝐴/𝑇+�) )
𝑃^𝑣𝑎𝑝=
Component A B Pvap K
Ethane 817.08 4.402229 50.76862 0.098486 yE 0.231537
Propane 1051.38 4.517190 11.15036 0.448416 yP 0.19224
n-Butane 1267.56 4.617679 2.718396 1.83932 yB 0.231193
2-Methyl Propane 1183.44 4.474013 3.700585 1.351138 yMP 0.34503

T (K) 303.0 L 0.869234


P (bar) 5.0 V 0.130766

Eq 1 1
Eq 2 1
Eq 3 0.050001
Eq 4 0.1
Eq 5 0.4
Eq 6 0.449999
xE 0.022691
xP 0.086124
xB 0.425395
xMP 0.46579

L+V 1

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