Section X

Soaps and Hand Cleaners

266
 Soaps and Hand Cleaners 267

Antibacterial Handwash
A premium liquid cleansing system that leaves a long lasting
soft and smooth after-feel.
Inaredlents:
Water
wf%
44.3
Ammonium Lauryl Sulfate(28%) 23.0
Sodium Laureth-2 Sulfate(26%) 21.5
Promidium CO 3.5
Monateric LMAB 3.0
Phospholipid CDM 2.5
Pricerine 9083 1.0
Triclosan 0.2
Monamate RMEA-40 0.7
Disodium EDTA 0.2
Cutric Acid 0.1
Procedure:
With stirring, combine all ingredients except Triclosan. Heat
mixture to 55C and add Triclosan. While cooling, add color and
fragrance. Adjust the pH to 6 with citric acid.
Typical Properties:
Appearance: Clear Liquid
Solids(%): 18
Viscosity (cP) @ 25C: 5400
Formula F-858

p e a r Antibacterial Hand Wash

Inuredients:
Part 1:
m
Ethanol(95%) 63.0
Hydroxyethyl Cellulose 1.0
Part 2:
Propylene Glycol 5.0
Phospholipid CDM 3.0
Part 3:
Water 28.0
Procedure:
Blend hydroxyethyl cellulose and ethanol with high speed
agitation. Separately, mix Phospholipid CDM, propylene glycol
and water. Add part 1 to part 2. Mix until uniform. Add water,
color and fragrance. Package.
Typical Propertie.:
Appearance: Clear colorless liquid
pH: 6.0
Formula F-853
SOURCE: Mona Industries, Inc.: Formulas F-858 and F-853
268 Cosmetic and Toiletty Formulations

Clear Liauid Hand SoaD with Sumended Mineral Oil Beads

Inqredient:
DI Water
rn
68.00
Carbopol ETD 2020 0.90
Glycerin 2.00
Triethanolamine 0.20
Ammonium lauryl sulfate (30%) 20.00
Lauryl ether sulfosuccinate (40%) 2.00
Disodium EDTA 0.10
Propylene glycol 2.00
Triclosan 0.50
DMDM hydantoin 0.70
Triethanolamine 0.60
Cocamidopropyl betaine (35%) 2.00
Mineral oil beads 1.00
Physical Properties:
Brookfield RVT Viscosity-20 rpm: 5,000 CP
Product pH: 5.0-6.0
Product Clarity/Appearance: Clear
Procedure:
1. Using moderate agitation (800 rpm) provided by a Lightnin'
Mixer or similar variable speed unit and an impeller suit-
able for general mixing and blending operations, disperse
or screen the Carbopol polymer into the DI water. Mix the
slurry for approximately 15 minutes or until the slurry
is homogeneous. Heating the water to 40-50C will increase
the wetting and dispersability of the Carbopol ETD polymers.
2. With minimal agitation to avoid excessive air entrapment,
add in the glycerin, TEA, lauryl sulfate, sulfosuccinate,
and the EDTA.
3. Premix the propylene glycol and the triclosan. Add the
mixture.
4. Continue agitation and add the DMDM hydantoin followed by
the triethanolamine and the cocamidopropyl betaine sur-
factant. Add the mineral oil beads with reduced agitation
to avoid breaking the beads.
5. Add color and fragrance, as desired.
SOURCE: BFGoodrich Co.: Formulation HIT-410
 Soaps and Hand Cleaners 269

d-Limonene Hand Soap

Starting formulation for a hand soap containing d-Limonene
as a grease cutter.
Inuredients: Wt%
Phase A:
Water, DI 77.40
Carbopol 1382 1.00
Triethanolamine 99% 1.50
Phase B:
Sulfochem ES-2 5.10
Phase C:
d-Limonene 15.00
Blending Procedure:
Charge water and begin vigorous agitation. Add the Carbopol
1382 and mix. After adequate mixing, add the TEA-99 (Note: This
will form a thick gel.) To this, add the Sulfochem ES-2 and mix
until homogeneous. Add the d-Limonene. Adjust the pH up with
TEA and down with citric.
Formulation No. F1027

d-Limonene Hand Soap

Starting formulation for a hand soap containing d-Limonene
as a grease cutter.
Inuredients: Wt%
Phase A:
Water, DI 73.40
Carbopol 1382 1.00
Triethanolamine 99% 1.50
Phase B:
Sulfochem ES-2 5.10
Amidex 0 2.00
Neodol 91-8 2.00
Phase C:
d-Limonene 15.00
Blending Procedure:
Charge water and begin vigorous agitation. Add the Carbopol
1382 and mix. After adequate mixing, add the TEA-99. (Note:
This will form a thick gel.) To this, add the Sulfochem ES-2,
Amidex 0, and the Neodol 91-8, and mix until homogenous. Add
the d-Limonene. Adjust the pH up with TEA and down with citric.
Formulation No. F1028
SOURCE: Chemron Corp.: Suggested Formulations
270 Cosmetic and Toiletry Formulations

d-Limonene Waterless Hand Cleaner

Ingredient: wt%
DI water 69.85
Carbopol ETD 2001 0.35
d-Limonene 25.00
Propylene glycol 1.00
Glycerin 2.00
C12-15 linear alcohol, 7 moles EO 0.50
Germaben IIE 1.00
Sodium hydroxide (18%) 0.30
Pumice* 10.00
Physical Properties:
Brookfield RVT Viscosity, 20 rpm: 35,000 CP
*addition of pumice may increase viscosity
Product pH: 5.5-5.8
Product Clarity/Appearance: Thick, white, creamy emulsion
Procedure:
1. Using moderate agitation (800 rpm) provided by a Lightnin'
Mixer or similar variable speed unit and an impeller suit-
able for general mixing and blending operations, disperse
or screen the Carbopol polymer into the DI water. Mix the
slurry for approximately 15 minutes or until the slurry is
homogeneous. Heating the water to 40-50C will increase the
wetting and dispersability of the Carbopol ETD polymers.
2. Using moderate agitation, add the d-Limonene to the polymer
dispersion and mix for 10 minutes.
3. Premix the propylene glycol, glycerin, alcohol ethoxylate
and preservative together. Add to the solvent/water mixture
4 . Add the sodium hydroxide to the formulation-check the pH
frequently-until pH 5.8 is achieved. For best results, keep
pH under 6.0.
5. Add the pumice, or other abrasive, as desired.
6. Add color and fragrance, as desired.
SOURCE: BFGoodrich Co.: Formulation HIT-400
 Soaps and Hand Cleaners 271

d-Limonene Waterless Hand Cleaner

Inuredient:
d-Limonene
!mi
25.00
Pemulen TR-1 0.20
Deionized water 70.10
Propylene glycol 1.00
Glycerin 2.00
C12-15 linear alcohol, 7 moles EO 0.50
Germaben IIE 1.00
Sodium hydroxide (18%) 0.20
Pumice 10.00
Physical Properties:
Brookfield RVT Viscosity 20 rpm: 11,400 CP
Product pH: 5.8
Product Clarity/Appearance: Opaque

d-Limonene Waterless Hand Cleaner

Insredient: Wt$
d-limonene 25.00
Pemulen TR-2 0.20
Deionized water 70.10
Propylene glycol 1.00
G1ycerin 2.00
(212-15 linear alcohol, 7 moles EO 0.50
Germaben IIE 1.00
Sodium hydroxide (18%) 0.20
Pumice 10.00
Physical Properties:
Brookfield RVT Viscosity 20 rpm: 6,500 CP
Product pH: 5.8
Product Clarity/Appearance: Opaque
Procedure:
1. Use a Lightnin' Mixer or similar variable speed unit and an
impeller suitable for general mixing and blending operations.
Add the Pemulen polymer into the vortex of the rapidly agit-
ating d-limonene (800 rpm). Allow to mix until homogeneous
and free of polymer lumps.
2. Using moderate agitation, add the deionized water to the oil
phase and mix for 10 minutes.
3 . Premix the propylene glycol, glycerin, alcohol ethoxylate
and preservative together. Add to the solvent/water mixture.
4. Add the sodium hydroxide to the formulation-check the pH
frequently-until pH 5 . 8 is achieved. For best results keep
pH under 6.0.
5. Add the pumice, or other abrasive, as desired.
6 . Add color and fragrance, as desired.
SOURCE: BFGoodrich Co.: Formulation HIT-401
272 Cosmetic and Toiletry Formulations

Emollient Liauid Soap [With Conditioner1

Insredients/CTFA Name: Wt%
Deionized Water 49.00
Schercoquat DAS/Quaternium-61 3.00
Schercotaine CAB-G/Cocamidopropyl Betaine 10.00
Schercopol DOS-70/Dioctyl Sodium Sulfosuccinate 15.00
Rhodacal A246/L/Sodium C14-16 Olefin Sulfonate 16.50
Schercomid AME-70/Acetamide MEA 3.00
Glycerine 1.50
Schercemol DISD/Diisostearyl Dilinoleate 1.00
Germaben I1 1.00
Procedure:
Dissolve Schercoquat DAS in water at room temperature (or
with gentle heat to 40C). Add the rest of the ingredients one
by one, mixing well after each addition.
Formula SK 134

Liauid Hand SoaD

(Pearlescent)
Inqredients/CTFA Name: wt%
Water (Deionized) 51.8
Dowicil-200/Quaternium-15 0.2
Schercoquat IAS (90%)/Isostearamidopropyl Ethyldimonium
Ethosulfate) 1.0
Schercotaine CAB-G (45%)/Cocamidopropyl Betaine 10.0
Schercomid SLM-LC/Lauramide DEA 1.0
Ethylene Glycol Monostearate/Glycol Stearate 1.0
Stepanol WA Paste (30%)/Sodium Lauryl Sulfate 35.0
Fragrance q.s.

Procedure:
1. Heat water to 45-50C. With stirring add Dowicil-200 and Scher-
coquat IAS. Mix to dissolve.
2. Add Schercotaine CAB-G.
3. Dissolve (melt) EGMS in Schercomid SLM-LC, then add to above.
4 . Add Stepanol WA Paste.
5. When uniform, cool and add fragrance.
Specifications:
Activity, %: 18
Viscosity @ 25C*: 4,000-6,000 cps
pH @ 25C: 8.0
*To increase viscosity, decrease 9; amide.
*To decrease viscosity, increase % amide.
Formula SO-021
SOURCE: Scher Chemicals, Inc.: Suggested Formulations
 Soaps and Hand Cleaners 273

Hand Sanitizinu Gel

Insredient: Wt%
DI water 38.75
Carbopol ETD 2001 0.20
Propylene glycol 0.50
Ethano1 60.00
PEG-60 almond glycerides 0.30
Triisopropanolamine 0.25
Physical properties:
Brookfield RVT Viscosity-20 rpm: 7,000 cp
% Transmission 420nm: 95-97
(Brinkman Colorimeter)
pH range: 7.3-7.6

Hand Sanitizinu Gel

Insredient:
DI Water
rn
38.65
Carbopol Ultrez 10 0.30
Propylene glycol 0.50
Ethano1 60.00
PEG-60 almond glycerides 0.30
Triisopropanolamine 0.25
Physical Properties:
Brookfield RVT Viscosity-20'rpm: 11,000 cp
% Transmission 420nm: 92-94
(Brinkmam Colorimeter)
pH range: 7.3-7.6
Procedure:
1. Using moderate agitation (800 rpm) provided by a Lightnin'
Mixer or similar variable speed unit and an impeller suit-
able for general mixing and blending operations, disperse
or screen the Carbopol polymer into the DI water. Mix the
slurry for approximately 15 minutes or until the slurry is
homogeneous. Heating the water to 40-50C will increase the
wetting and dispersability of the Carbopol ETD polymers.
2. Slowly add the ethanol with gentle mixing. Allow as much
air to escape as possible before proceeding.
3. Add the PEG-60 almond glycerides with gentle mixing.
4. Add the triisopropanolamine with gentle sweeping motion to
minimize air entrapment. Mix until uniform.
5. Add dye or fragrance if desired.
SOURCE: BFGoodrich Co.: Formulation HIT-420
274 Cosmetic and Toiletty Formulations

Nand Sanitizins Gel (Continuedl

Insredient: Wt%
DI water 38.55
Carbopol ETD-2020 0.40
Propylene glycol 0.50
Ethano1 60.00
PEG-60 almond glycerides 0.30
Triisopropanolamine 0.25
Phyeical Properties:
Brookfield RVT Viscosity-20 rpm: 7,000 cp
% Transmission 420 nm: 96-98
(Brinkman Colorimeter)
pH range: 7.3-7.6
Procedure:
1. Using moderate agitation (800 rpm) provided by a Lightnin'
Mixer or similar variable speed unit and an impeller suit-
able for general mixing and blending operations, disperse or
screen the Carbopol polymer into the DI water. Mix the slurry
for approximately 15 minutes or until the slurry is homogene-
ous. Heating the water to 40-50C will increase the wetting and
dispersability of the Carbopol ETD polymers.
2. Slowly add the ethanol with gentle mixing. Allow as much air
to escape as possible before proceeding.
3 . Add the PEG-60 almond glycerides with gentle mixing.
4. Add the triisopropanolamine with gentle sweeping motion to
minimize air entrapment. Mix until uniform.
5 . Add dye or fragrance if desired.

SOURCE: BFGoodrich Co.: Formulation HIT-420

 Soaps and Hand Cleaners 275

Liquid Hand Soar,

Starting formulation for a mild hand soap.
Insredients: Wt%
Sulfochem B-209 28.00
Water, soft 70.81
Fragrance 0.10
NaC 1 typical: 1.00
Citric acid typical: 0.09
Preservatives q.s.
Blending Procedure:
Charge water into mixing vessel and add remaining ingredients
in order listed. Mix until homogeneous.
Typical Physical Properties:
Viscosity: 5,000-7,000 cps
pH: 7.0-7.5
Formulation No. E3128

Liquid Hand SoaD

Starting formulation for a mild hand soap
Inaredients: wt%
Sulfochem B-2090P 29.00
Water, soft 70.04
Fragrance 0.15
NaC 1 typical: 0.75
Citric acid typical: 0.06
Preservatives q.s.
Blenaing Procedure:
Charge water into mixing vessel and add remaining ingredients
in order listed. Mix until homogeneous.
Typical Physical Properties:
Viscosity: 5,000-7,500 cps
pH: 7.0-7.5
Formulation No. E3133
SOURCE: Chemron Corp.: Suggested Formulations
276 Cosmetic and Toiletry Formulations

Liauid Soar,
with a pearl-lustre effect, 14.6% active ingredient
ReciDe: Wt%
A Hostapon SCID/Sodium Cocoyl Isethionate 4.00
B Water 53.90
C Genapol ZRO liquid/Sodium Laureth Sulfate 30.00
Fragrance 0.30
Genapol PGL/Glycol Distearate, Cocamide MEA,
PPG-4 Deceth-4 4.00
Dyestuff solution q.s.
Preservative q.s.
Genagen CAB/Cocamidopropyl Betaine 6.00
D Sodium chloride 1.80
Procedure:
1. Dissolve A in B at approx. 60C.
2. Cool 1 to approx. 35C.
3. Stir the components of C one after another into 2.
4. If necessary adjust the pH.
5. Finally adjust the viscosity with D.
Formula A II/1033

Liauid Soar,
clear, 9.6% active ingredient
ReciDe:
20.00
w
A Genapol LRO liquid/Sodium Laureth Sulfate
B HOStaDUr SAS 60/Sodium C14-17 Sec Alkyl Sulfonate 5.00
G e n a g k CA-050/PEG-5 Cocamide 1.00
Fragrance 0.30
Water 72.60
Dyestuff solution q.s.
Preservative q.s.
C Tylose H 100000 yp/Hydroxyethyl Cellulose 1.10

Procedure:
1. Stir the components of B one after another into A.
2. Add C to 1 while stirring continuously until a homogeneous
product free of lumps has been obtained.
Formula A II/1019
SOURCE: Woechet Aktiengesellschaft: Guide Recipe8
 Soaps and Hand Cleaners 277

Mild Hand Cleanser

Raw Materials: Wt%

Mackanate LO-Special (Disodium Lauryl Sulfosuccinate) 83.0
Mackamide PKM (Palmkernelamide MEAI- 4.0
-..
Mackernium 007 (Polyquaternium 7) ' 0.8
Mackstat DM (DMDM Hydantoin) qs
Water, Fragrance qs to 100.0
Procedure:
1. Add Mackamide PKM to Mackanate LO-Special.
2. Heat to 70C.
3. Blend until homogeneous.
4. Dissolve Mackernium 007 in water and add to product.
5. Blend until completely homogeneous.
6. Cool to 50C with mild agitation.
7. Add Mackstat DM and Fragrance.
8. Cool with continuous agitation.

Facial Cleanser
Raw Materials: Wt%
Mackanate LO-Special (Disodium Lauryl Sulfosuccinate) 88.0
Cetyl Alcohol 2.0
Brij 52 2.0
Mackstat DM (DMDM Hydantoin) qs
Water, Dye, Fragrance qs to 100.0
Solids, %: 40.0 (+-1.0)
pH (as is): 5.5-6.0
Appearance: Pearly Cream
Procedure:
1. Add Cetyl Alcohol, Brij 52, and water to Mackanate LO-Special.
2. Heat to 70C.
3. Blend until homogeneous.
4. Adjust pH to 5.0-6.0 with Sodium Hydroxide.
5. Cool to 50C and add Mackstat DM and Fragrance.
6. Adjugt solids to 40.0 (+-1.0)% at this point.
7. Cool to room temperature.
SOURCE: McIntyre Group Ltd.: Personal Care Formulary: Formulas
278 Cosmetic and Toiletly Formulations

Mineral Spirits Waterless Hand Cleaner

Insredient: wtg
DI water 64.90
Carbopol ETD 2001 0.30
Mineral Spirits 30.00
Propylene glycol 1.00
G1ycerin 2.00
C12-15 linear alcohol, 7 moles EO 0.50
Germaben IIE 1.00
Sodium hydroxide (18%) 0.30
Pumice* 10.00
Physical Properties:
Brookfield RVT Viscosity, 20 rpm: 45,000 CP
*addition of pumice may increase viscosity
Product pH: 5.5-5.8
Product Clarity/Appearance: Thick, white, creamy emulsion
Procedure:
1. Using moderate agitation (800 rpm) provided by a Lightnin'
Mixer or similar variable speed unit and an impeller suit-
able for general mixing and blending operations, disperse
or screen the Carbopol polymer into the DI water. Mix the
slurry for approximately 15 minutes or until the slurry is
homogeneous. Heating the water to 40-50C will increase the
wetting and dispersability of the Carbopol ETD polymers.
2. Using moderate agitation, add the mineral spirits to the
polymer dispersion and mix for 10 minutes.
3 . Premix the propylene glycol, glycerin, alcohol ethoxylate
and preservative together. Add to the solvent/water
mixture.
4. Add the sodium hydroxide to the formulation-check the pH
frequently-until pH 5.8 is acheived. For best results keep
pH under 6.0.
5. Add the pumice, or other abrasive, as desired.
6 . Mix color and fragrance, as desired.

SOURCE: BFGoodrich Co.: Formulation HIT-402

 Soaps and Hand Cleaners 279

Mineral SDirits Waterless Hand Cleaner

Inuredient: wt%
Mineral Spirits 25.00
Pemulen TR-1 0.20
Deionized water 70.10
Propylene glycol 1.00
Glycerin 2.00
C12-15 linear alcohol, 7 moles EO 0.50
Germaben IIE 1.00
Sodium hydroxide (18%) 0.20
Pumice 10.00
Physical Propertieo:
Brookfield RVT Viscosity-20 rpm: 11,500 CP
Product pH: 5.8
Product Clarity/Appearance: Opaque

Mineral SDirits Waterless Hand Cleaner

Inqredient:
Mineral SDirits 25.00
Pemulen TR-2 0.20
Deionized water 70.10
Propylene glycol 1.00
G1ycerin 2.00
C12-15 linear alcohol, 7 moles EO 0.50
Germaben IIE 1.00
Sodium hydroxide (18%) 0.20
Pumice 10.00

Physical Properties:
Brookfield RVT Viscosity-20 rpm: 7,200 CP
Product pH: 5.8
Product Clarity/Appearance: Opaque
Procedure:
1. Use a Lightnin' Mixer or similar variable speed unit and an
impeller suitable for general mixing and blending operations.
Add the Pemulen polymer into the vortex of the rapidly agit-
ating mineral spirits (800 rpm). Allow to mix until homogene-
ous and free of polymer lumps.
2. Using moderate agitation, add the deionized water to the oil
phase and mix for 10 minutes.
3 . Premix the propylene glycol, glycerin, alcohol ethoxylate
and preservative together. Add to the solvent/water mixture.
4 . Add the sodium hydroxide to the formulation-check the pH
frequently-until pH 5.8 is achieved. For best results keep
pH under 6.0.
5. Add the pumice, or other abrasive, as desired.
6 . Add color and fragrance, as desired.
SOURCE: BFGoodrich Co.: Formulation HIT-403