Simple Aid For Teaching The Theory Atomic Structure: Hung-Cheh Chiang and Ching-Hwei Tseng
Simple Aid For Teaching The Theory Atomic Structure: Hung-Cheh Chiang and Ching-Hwei Tseng
Simple Aid For Teaching The Theory Atomic Structure: Hung-Cheh Chiang and Ching-Hwei Tseng
of Atomic Structure
Hung-cheh Chiang and Ching-Hwei Tseng
Institute of Chemistry, National Taiwan Normal University
No. 88 Sec. 5, Roosevelt Rd., Taipei, Taiwan, Republic of China
In the course of both high school and undergraduate college Example: 24Cr
chemistry, students are often puzzled by the theory of atomic The student would choose the fourth card, because 24 is
structure. In order to help them learn this more easily, we have smaller than the 36 required by the fifth card. There are 18
designed a simple demonstration to show the Pauli exclusion electrons on the fourth card, thus the remaining six electrons
principle, Hund's rule, quantum numbers, electronic energy of Cr will distribute themselves in the fourth energy level ac-
levels, and electron configurations. The exercise involves cording to the rules. Rule one
hanging valence electrons (represented by pieces of rubber)
onto a game hoard which depicts the energy sequence of a ns < (n - 2)f < (n - l)d < np
given atom. translates to
<
4s < 2f 3d < 4p
Materials
Because 2f does not exist, the six electrons would be dis-
1 wooden plate (60 cm X 40 cm X 1cm) tributed into the lowest available levels; two being placed in
33 iron nails (1.5cm in length) the 4s level and the remaining four into the 3d level.
2 rubber tubes of different colors (16 cm X 1em), cut these into
1-cm pieces, yielding 16 pieces of each color Thus, the configuration of 2aCr is shown to be (Ar)4s23d4
I blank index cards (see Fig. 3). With this the instructor can speak to the special
stability of a half-filled sublevel and can show the students
Set-Up that, with 3d sublevels close to those of the 4s sublevel, the
The game board, or orbital plate, is cut from a piece of wood. effect is large enough to allow "promotion" of a 4s electron to
I t is labeled as indicated in Figure 1, where n is the principal the 3d sublevel, giving Cr five 3d electrons. Thus, the accepted
quantum number, s, p, d , and f are the suborbits, and the configuration of 24Cr should he shown to be (Ar)4s'3d5.
number in parentheses after the suborbital designation in-
dicates the angular momentum quantum number. The spin
quantum number will be designated by using differently
colored pieces of rubber tubing which should be cut as de-
scribed above.
Hammer the nails (which will be used as holders for elec-
trons) into position as noted. Each suborhit should have the .....
number of electron nails that corresponds to the maximum
number of electrons that can be held in that suhorbit.
Seven index cards should be labeled as shown in Figure 2.
..... .. ---dm plot.
These n-value cards will provide the players with standard
information about the principal quantum numbers. Figure 1. Construction of the game board.
The Rules
Remember that the goal of this exercise is to fill out the
game hoard with cards and pieces of tubing so that it provides
a visual representation of the electron configuration within
the atom. Total the number of electrons within the given atom
Figure 2. The seven index cards representing the principal quantum num
and compare to the electron totals on the n-value cards. The
n-value card with a total that is either less than or equal to the
number of electrons in the atom of interest is then chosen and
hung onto the upper left nail.
If the number of electrons is equal to the n-value card, you
are done. If i t is not, determine how many more electrons are
present. Take that number of pieces of cut rubber tubing and
hane them. as re~resentativesof valence electrons. on the nails
accirding to the following energy sequence. US; differently
colored nieces of tuhine to renresent electrons with opposite
spin. he energy sequence ofthe sublevels with the &me n -
value is: NOTE: Tho o
rqremts ~ I K ~ I
ns < (n - 2)f < (n - l)d < np of r u m r tubing
if n < 6, then (n - 2)f is absent
if n < 4, both (n - l)d and (n - 2)f are absent Figure 3. The completed g m e board for &r.