Activated Sludge
Activated Sludge
Activated Sludge
1
6/28/2013
Speaker
2
6/28/2013
Activated Sludge
Process Control
Jeanette Brown
Presentation Outline
• Definitions
• Description of the activated sludge
process
• Process Control
• Troubleshooting
3
6/28/2013
Definitions
• Heterotrophic-derive carbon for cell growth
and energy from organic compounds
• Autotrophic-derive carbon for cell growth
and energy from inorganic compounds
– Nitrification-converting ammonia nitrogen to
nitrate nitrogen
Definitions
• Aerobic-aerated with DO ~ 2mg/L
• SRT-The average time suspended solids
are retained in a biological waste
treatment system
• F:M-the loading rate expressed as pounds
of BOD5 per pound of mixed liquor volatile
suspended solids per day
4
6/28/2013
SC
Receiving
Secondary Disinfection
Water
Secondary Treatment
• Biological wastewater treatment that
generally removes at least 85% of BOD
and suspended solids.
• <30 mg/L BOD and TSS
• Two types
– Biofilms (Attached Growth) (Fixed Film)
• Trickling filters
• Rotating Biological Contactors
– Suspended Growth
• Activated Sludge
5
6/28/2013
6
6/28/2013
Classification of Activated
Sludge Processes
• The activated-sludge process is often
classified on the basis of loading rate
– may be expressed as a volumetric loading
rate, SRT, or F:M
• Classified as
– High rate
– Conventional
– Low rate
7
6/28/2013
Basic Components
• Single or multiple biological reactors (aeration
tanks).
• Aeration source to provide
– Oxygen
– Mixing
• Clarifier(s)
• Collection and delivery mechanism for RAS
• Means of removing excess solids (WAS)
O2 + Pollutants + Microorganisms
BOD5
RAS (microorganisms)
WAS
8
6/28/2013
NBOD
BOD, mg/l
TBOD
CBOD
days
Process
• Remove carbonaceous BOD
• Remove carbonaceous BOD and oxidize
ammonia (nitrify)
• Design is based on
– Length of time the solids are kept within the process;
solids retention time (SRT)
– Amount of food provided to the bacteria; food to
microorganism ratio (F/M)
– Hydraulic retention time
9
6/28/2013
Basic Process
• Organic matter is the carbon and energy
source for cell growth
• Carbon is converted to cell tissue, water,
oxidized products mainly CO2
• Contents of aeration tank is MLSS,
MLVSS
Microbiology and
Biochemistry
• Activated sludge process is a big biochemical
factory
– Bacteria
– Fungi
– Protozoa
– Rotifers
– Nematodes
• Bacteria are the significant organisms for
consuming organic matter
10
6/28/2013
Microbiology and
Biochemistry
• Predominant species of microorganisms
depends on
– Characteristics of the influent wastewater
– Environmental conditions
– Process design
– Plant operation
Microbiology and
Biochemistry
• A successful plant depends on cultivating
a biological community that will
– remove and consume (assimilate) waste
material,
– Flocculate together
– Settle well to produce a concentrated solids
for recycling
– Produce a clear effluent
11
6/28/2013
Microbiology and
Biochemistry
• Two general types of microorganisms
– Floc formers
– Filament formers
• Floc formers
– Clump together
– Form gelatinous floc which is heavy enough to settle
• Filament formers
– Stringy, threadlike structures
– Light-weight, doesn’t settle
Microbiology and
Biochemistry
• Activated sludge process uses
– Heterotrophic bacteria for carbonaceous BOD
removal
• Organisms that use organic carbon for the
formation of cell tissue
• Organic matter + oxygen +nutrients + C2H7O2N
(microorganisms) C2H7O2N (new
microorganisms) + CO2 + H2O
12
6/28/2013
Nutrients
O2
Nutrients
O2
13
6/28/2013
Solids Separation
• An important feature of the activated-
sludge microbial system is its ability to
separate by gravity under quiescent
conditions.
• This property is achieved by
– selecting the culture that settles,
– recycling the settled sludge, and
– operating the process under loading conditions
that will select for a flocculent culture.
Process Control
14
6/28/2013
Process Control
• Need to provide sufficient nutrients and food
• Need to keep a balance population of bacteria and
protozoa
• Need to provide sufficient oxygen
• Need to provide mixing
O2 + Pollutants + Microorganisms
RAS (microorganisms)
WAS
15
6/28/2013
Balanced Population
• RAS
– Source of microorganisms to aeration tanks
– Typically 30 to 50% Q
• WAS
– Removal of excess organisms
16
6/28/2013
Aeration
• Aeration consumes
50%-65% of net
power demand for
treatment
• Important to select
design that meets
mixing and oxygen
requirements at
lowest cost possible
17
6/28/2013
MLSS
• MLSS-concentration of suspended solids
in activated-sludge mixed liquor,
expressed in milligrams per liter (mg/L)
– Typically 1500 to 3500 mg/L
– Plant specific
– Can be measured in-situ
MLVSS
• MLVSS-the fraction of the suspended
solids in activated-sludge mixed liquor
– that can be driven off by combustion at 550
°C (1022 °F);
– indicates the concentration of microorganisms
available for biological oxidation
• Not an exact measurement because dead cells are
also volatile
18
6/28/2013
SRT
• SRT = Solids under aeration divided by
the solids leaving the system.
– For BOD removal, typically 3 to 5 days
– For nitrogen removal, greater than 6 days.
19
6/28/2013
SRT(MCRT)-US Units
Solids Under Aeration = Vaer (million gallons) x 8.34
lbs/million gallons-mg/L x MLSS, mg/L
SRT(MCRT)-SI Units
Therefore;
SRT =[Vaer (m3/d) x MLSS, g/m3 (mg/L) x kg/1000 g]/[Qwas m3/d x Cwas,
g/m3 (mg/L) x kg/1000 g] + [Q, m3/d x TSSeff, g/m3 (mg/L) x kg/1000 g]
20
6/28/2013
Example
• Given:
– Vaer = 1.4 million gallons (5,300 m3)
– Q = 3.1 MGD (11,735 m3/d)
– MLSS = 2650 mg/L
– Qwas = 70,000 gpd (265 m3/d)
– TSSeff = 20 mg/L
– WAS =RAS = 5960 mg/L
Example-US Units
• Solids under aeration = (1.4 million gallons x
8.34 lbs/million gallons-mg/L x 2650 mg/L) =
30,941 lbs
• Solids leaving system = (0.07 million gallons x
8.34 lbs/million gallons-mg/L x 5960 mg/L) + (3.1
million gallons/d x 8.34 lbs/million gallons-mg/L x
20 mg/L) = 3997 lbs/day
21
6/28/2013
Example-SI Units
• Solids under aeration = (5300 m3 x 2650 g/m3 x
kg/1000 g = 14,045 kg
• Solids leaving system = [(265 m3/d x 5960 g/m3
x kg/1000 g)] + [(11,735 m3/d x 20 g/m3) x
kg/1000 g] = 1814 kg/day
Process Control
Calculations
• F/M Ratio
– Food to microorganism ratio
– Mass of food entering biological reactors, lbs
(kg) BOD
– Mass of microorganisms in the biological
reactors, lbs (kg) MLVSS
– MLVSS typically is 80% of the MLSS
22
6/28/2013
23
6/28/2013
24
6/28/2013
210 ml
• SVI = ml/MLSS,g
• SVI = 210 ml/2.2 g = 95
(2200 mg = 2.2 g)
25
6/28/2013
26
6/28/2013
WAS Rate
SRT = lbs (kg) of solids biological system
WAS, lbs/d (kg/d) + TSSEff, lbs/d (kg/d)
WAS Rate
27
6/28/2013
28
6/28/2013
Process Control-Microbiology
• Indicator microorganism
– Amoeba
– Flagellates
– Motile ciliates
– Stalked ciliates
– Rotifers
– Nematodes
29
6/28/2013
Stalked Ciliates
30
6/28/2013
Stalked Ciliates
Rotifers
31
6/28/2013
Filamentous
Nematodes/Worms
32
6/28/2013
Water Bears
Control Strategies
• Operators have a preferred method for
calculating the amount of solids to waste
to maintain an optimum solids inventory.
– What is right for one plant may not be right for
another
– Strategies include F:M, constant MLSS or
SRT
33
6/28/2013
Control Strategies
• F:M Control
– Wasting rates determined by F:M will depend
on the variations of influent BOD,
• Constant MLSS
– wasting rates determined for a constant
MLSS will depend on changes in activated-
sludge growth rate (resulting from influent
variations). Easiest control strategy for small
treatment plants
Control Strategies
• SRT control is most often the method
chosen for municipal WWTPs.
– For a given target SRT, the same portion of
activated-sludge inventory is wasted every
day regardless of the variations occurring in
the influent wastewater.
– For example, if you set a target SRT of 10
days, you will waste 10% of the MLSS every
day.
34
6/28/2013
Control Strategies
• SRT Control-
– Easier for operators to maintain a constant
SRT than a constant F:M or MLSS.
– Gives operators more control and the process
more stability when the SRT method is used.
– Choose the one that is easiest for you and
gives the best performance, but be open to
changes
Solids Separation
• Clarifiers are part of the activated sludge
process
• Need to understand and manage clarifier
performance to ensure permit compliance
• Need to understand relationship of RAS
flow to clarifiers performance
35
6/28/2013
Solids Separation
• There are five parameters that will have
the most influence over the performance
of a well-designed secondary clarifier:
– 1) MLSS concentration in the flow to the
clarifier,
– 2) wastewater flow,
– 3) RAS flow,
– 4) surface area of the clarifier, and
– 5) settleability of the activated sludge
Secondary Clarifiers
• Typically circular
• Have lower detention times
than primary because
solids are biological-1 to 2
hours
• Overflow rates at ADF =
800 gpd/ft2
• With BNR =600 gpd/ft2
• SLR = 30 lbs/d/ft2
• With BNR =20 lbs/d/ft2
36
6/28/2013
• Example:
A = 7,000 ft2 (650 m2) (Per unit)
Q=5,500,000 gal/d (20,820m3.d) ((Per unit)
SOR = (5,500,000 gal.d)/ 7,000 ft2 = 785 gal/ft2.day
SOR = (20,820 m3d)/ 650 m2 = 32 m3/m2.day
37
6/28/2013
SLR Example
• Q = 18.2 MGD (68894 m3.d)
• R = 7.7 MGD (29148 m3.d)
• MLSS = 3350 mg/L, (g/m3)
• A = 39,978 ft2 ( 3714 m2)
38
6/28/2013
190.0
180.0
170.0
Average Monthly
Influent BOD5
mg/L
160.0 (mg/l)
Average Monthly
150.0 Influent TSS
(mg/l)
140.0
130.0
October-06 February-08 July-09 November-10
Time
39
6/28/2013
Troubleshooting
Gathering Information
• Gathering information is a basic
troubleshooting task that requires
knowledge of
– the specific plant,
– waste constituents received, and
– specific processes.
40
6/28/2013
Gathering Information
• The following guidelines will assist in
gathering information:
– Determine whether a problem exists or the
test results are in error.
– Find out when the problem was first observed
and what was done about it.
– Examine the biomass with a microscope to
evaluate the state of the microorganisms,their
diversity, motility, and numbers.
Gathering Information
– Determine whether the operation of the plant
contributes to the problem. Check the
upstream unit for contributory problems,
including the sewer system and recycle
streams.
– Complete flow and mass-balance analysis.
Check each unit process separately because
one weak process can overload the whole
plant.
41
6/28/2013
Gathering Information
– Use a quality assurance program to improve
the accuracy of test results.
– Check for pipeline leaks that can divert flows,
including chemicals.
– Check for changes in treatment chemicals.
– Ensure that air-delivery systems work.
– Determine whether mechanical or electrical
failures are causing problems
Gathering Information
– Check for such failures when problems occur.
• A brief power outage can stop equipment,
requiring manual restart.
– Separate the symptoms from the problem.
• Listen to everyone’s observations but mistrust
everyone’s interpretation.
• Identify the root cause, not the symptom.
• Things are not always as they first appear; do not
be too quick to jump to conclusions.
42
6/28/2013
Effective Troubleshooting
• To troubleshoot effectively,
– operators must determine the probable cause
of a problem and
– select one or more corrective measures to
restore the process to full efficiency with the
least adverse effect on the final effluent
quality and at the lowest cost.
Effective Troubleshooting
• An operator needs
– thorough knowledge of the plant’s activated-
sludge process
– familiarity with influent wastewater
characteristics, plant flow rates and patterns,
– design and actual loading parameters,
– performance of the overall plant and individual
processes, and
– current maintenance procedures
43
6/28/2013
Effective Troubleshooting
• When a problem or situation arises, first
evaluate the problem and determine if it
fits into one or a combination of the
following areas:
– Hydraulic,
– Mechanical, and/or
– Process.
Hydraulic
• Hydraulic problems are easy to detect
because of solids washout at the
secondary clarifiers. These problems can
be the result of several conditions.
– rainstorms. This is especially true if the
treatment facility is served from combined
sewers.
– not enough tanks in service because of
maintenance or repairs.
44
6/28/2013
Mechanical
• Mechanical problems can result in an
effluent violation if it is not corrected or
noticed immediately.
• Problems may include failure of:
– clarifier collector mechanism,
– return activated-sludge (RAS) pump,
– blower, or mechanical aerator
Process
• Process problems are typically the most
difficult to identify and correct.
• It is important to maintain good records.
– can see warning signs of an impending
problem
– change in influent characteristics could result
in a change in settling characteristics.
45
6/28/2013
Process
– In-plant sidestream changes,
– differences in dissolved oxygen
concentrations, and other parameters and
– plant conditions are important aspects that an
operator must know to effectively troubleshoot
a treatment facility.
• Good plant records will help to determine
and correct the problem.
Microscopy
• Another excellent process troubleshooting
mechanism is microscopic examination
– can determine the condition of the activated-
sludge process by knowing and determining
the predominance of various microorganisms.
– microscopic examination of the mixed liquor
will help identify the presence and type of
filamentous organisms present in the facility,
which in turn will help determine the best
course of action to correct a process problem
46
6/28/2013
Troubleshooting Skills
• Troubleshooting requires several skills,
including
– investigative thinking and
– logical use of all tools available to help solve a
problem.
• It is important when troubleshooting not to
make more than one change at a time.
Troubleshooting Skills
• If multiple changes are made at once, it is
difficult, if not impossible, to identify which
process change was the most effective.
• Always remember that the activated-
sludge system is a biological process so
most responses will not be noticed
immediately. It may take days or weeks
before a process improvement can be
seen.
47
6/28/2013
Keys to Successful
Troubleshooting
• The following seven areas are critical for
narrowing the search for solutions to most
problems:
– Thorough knowledge of the process being
evaluated.
– Thorough knowledge of all plant flow patterns,
including sidestreams.
– Thorough knowledge of the plant’s design
parameters and how actual loadings compare
to design values.
Keys to Successful
Troubleshooting
– Thorough knowledge of all maintenance
procedures, including equipment maintenance
considerations and staff responsibilities.
– Thorough knowledge of how to recognize an
abnormal condition.
– Thorough knowledge of what alternatives are
available when trouble develops.
– Thorough knowledge of the amounts and
characteristics of any industrial waste that
may be discharged to the plant.
48
6/28/2013
Laboratory Testing
• Several simple laboratory tests that can
help solve or troubleshoot operational
problems include
– the mixed liquor settleability test,
– sludge volume index (SVI),
– mixed liquor respiration rate,
– dissolved oxygen (DO) measurement, and
– sludge blanket level
Settleability Test
49
6/28/2013
Operational Problems
• The following are some common
operational problems:
– Foaming in bioreactors
– Solids Washout
• Hydraulics
• Solids loading
– Bulking
Foaming
• Stiff white billowing foam, indicating a
young sludge (low SRT) is found in either
new or underloaded plants.
– MLSS concentration is too low and the F:M is
too high.
• The foam may consist of detergents or
proteins that cannot be converted to food
by bacteria that grow in the mixed liquor at
a high F:M.
50
6/28/2013
Causes-white foam
• Causes include:
– Problem with RAS flow
– Low MLSS resulting from process startup or
excessive sludge wasting
– presence of a toxic or inhibiting material,
– abnormally low or high pHs or insufficient DO
– nutrient deficiencies,
– activated-sludge biomass in the secondary
clarifier effluent
51
6/28/2013
Brown Foam
• Greasy dark-tan
foam typically
caused by
Nocardia.
• Can be caused by
operating at a
high SRT
• Trapped surfaces
and recycle add
to the problem
Nocardia Foam
• Once established, Nocardia foaming can
be extremely difficult to eliminate because
– Foam is difficult to break with water sprays.
– Foam typically does not respond to chemical
antifoamants.
52
6/28/2013
Nocardia Foam
– Chlorinating RAS, although often helpful,
does not eliminate Nocardia because most of
it is in the floc and not exposed to chlorine.
– Increased wasting has its limitations because
Foam is not wasted with the WAS.
– Even if foam and scum are removed from the
process, they can cause problems in
downstream units such as digesters and also
can be recycled with decant or supernatant to
the activated-sludge process.
53
6/28/2013
Filamentous Bulking
• Filamentous Bulking can be caused by:
– Low-DO concentrations in biological reactors,
– Insufficient nutrients,
– Improper pH—either too low or widely
varying,
– Warm wastewater temperature,
– Widely varying organic loading,
– Industrial wastes with high BOD and low
nutrients (N and P)
54
6/28/2013
Filamentous Bulking
– High influent sulfide concentrations that cause
the filamentous microorganism Thiothrix to
grow
– Very low F:M, allowing Nocardia
predominance,
– Massive amounts of filaments present in
influent wastewater or recycle streams
55
6/28/2013
56
6/28/2013
Non-filamentous Bulking
• Non-filamentous bulking may be caused
by:
– Improper organic loading—either too high or
too low F:M,
– Over aeration, and
– Toxics.
57
6/28/2013
Summary
• Need to understand the activated sludge
process and how it works at your plant
• Good process control requires good
laboratory data and instrumentation
• Troubleshooting is a complex process
especially with process problems
• More detailed information in MOP-11
58
6/28/2013
Questions?
59