O Ring Material Guide
O Ring Material Guide
O Ring Material Guide
Material Guide
Content
A Introduction 3
B Elastomers 3
B.1 Application parameters of elastomers . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
C Materials 26
C.1 Standard materials . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 26
1
Material Guide
A Introduction
Equipment manufacturers and end users expect sealing On the basis of many years of experience in the
systems to operate leak free and to maintain long service manufacture and application of sealing systems we can
life. Reliability is crucial to effective low maintenance cost offer a large variety of different high-quality materials.
operations. To find the perfect sealing solution in each
individual case both material performance and seal This catalogue provides the necessary support for the
design are critically important. right material selection.
B Elastomers
One of the main used material groups for sealings are the The following tables provide a summary of the various
elastomers. They show good properties like elasticity or elastomer material groups. We can offer a large number
good chemical compatibility. of materials within each group.
Table I Elastomers
Designation Trade Name* Abbreviation
ISO 1629 ASTM 1418 B+S
Acrylonitrile–Butadiene Rubber Europrene NBR NBR N
(Nitrile Rubber) Krynac
Nipol N
Perbunan NT
Breon
Hydrogenated Acrylonitrile–Butadiene Rubber Therban HNBR HNBR H
Zetpol
Polyacrylate Rubber Noxtite ACM ACM A
Hytemp
Nipol AR
Chloroprene Rubber Baypren CR CR WC
Neoprene
Ethylene Propylene Diene Rubber Dutral EPDM EPDM E
Keltan
Vistalon
Buna EP
Silicone Rubber Elastoseal VMQ VMQ S
Rhodorsil
Silastic
Silopren
Fluorosilicone Rubber Silastic FVMQ FVMQ F
Tetrafluorethylene–Propylene Copolymer Elastomer Aflas FEPM TFE / P** WT
Butyl Rubber Esso Butyl IIR IIR WI
Styrene–Butadiene Rubber Buna S SBR SBR WB
Europrene
Polysar S
3
Material Guide
Table II The most important types of synthetic rubber, their grouping and abbreviations
Chemical name Abbreviation
DIN / ISO 1629 ASTM D - 1418
M - Group
(saturated carbon molecules in main macro-molecule-chain)
- Polyacrylate Rubber ACM ACM
- Ethylene Acrylate Rubber AEM
- Chlorosulphonated Polyethylene Rubber CSM CSM
- Ethylene Propylene Diene Rubber EPDM EPDM
- Ethylene Propylene Rubber EPM EPM
- Fluorocarbon Rubber FKM FKM
- Perfluoro Rubber FFKM FFKM
O - Group
(with oxygen molecules in the main macro-molecule chain)
- Epichlorohydrin Rubber CO CO
- Epichlorohydrin Copolymer Rubber ECO ECO
R - Group
(unsaturated hydrogene carbon chain)
- Chloroprene Rubber CR CR
- Butyl Rubber IIR IIR
- Nitrile Butadiene Rubber NBR NBR
- Natural Rubber NR NR
- Styrene Butadiene Rubber SBR SBR
- Hydrogenated Nitrile Butadiene Rubber HNBR HNBR
Q - Group
(with Silicone in the main chain)
- Fluorosilicone Rubber FVMQ FVMQ
- Methyl Vinyl Silicone Rubber VMQ VMQ
U - Group
(with carbon, oxygen and nitrogen in the main chain)
- Polyester Urethane AU AU
- Polyether Urethane EU EU
225
200
175
150
125
100
75
0
0 20 40 60 80 120 140 160
5
Material Guide
B.1.3. General field of application FKM is known especially for its non-flammability, low gas
permeability and excellent resistance to ozone,
Elastomer materials are used to cover a large number of weathering and aging.
fields of application. Details regarding resistance in The operating temperatures of the Fluorocarbon Rubber
special media are shown in chapter “B.1.4 Chemical range between -20 °C and +200 °C (for a short period
compatibility”, page 9. of time up to +230 °C). Suitable formulated FKM can be
used down to -35 °C. FKM is also often used with mineral
The various elastomers can be characterised as follows: based oils and greases at high temperatures.
NBR (Nitrile Butadiene Rubber): EPDM (Ethylene Propylene Diene Rubber)
The properties of the Nitrile Rubber depend mainly on the
EPDM shows good heat, ozone and aging resistance. In
ACN content which ranges between 18% and 50%. In
addition they also exhibit high levels of elasticity, good low
general they show good mechanical properties. The
temperature behaviour as well as good insulating
operating temperatures range between -30 °C and
properties.
+100 °C (for a short period of time up to +120 °C).
The operating temperatures of applications for EPDM
Suitable formulated NBR can be used down to -60 °C.
range between -45 °C and +150 °C (for a short period
NBR is mostly used with mineral based oils and greases.
of time up to +175 °C). With sulphur cured types the
FKM (Fluorocarbon Rubber) range is reduced to -45 °C and +120 °C (for short period
of time up to +150 °C).
Depending on structure and fluorine content FKM EPDM can often be found in applications with brake fluids
materials can differ with regards to their chemical (based on glycol) and hot water.
resistance and cold-flexibility.
HNBR (Hydrogenated Nitrile Butadiene Rubber) Applications for FFKM can be mostly found in the chemical
and process industries and in all applications with either
HNBR is made via selective hydrogenation of the NBR aggressive environments or high temperatures.
butadiene groups. The properties of the HNBR rubber
depend on the ACN content which ranges between 18%
and 50% as well as on the degree of saturation. HNBR
shows good mechanical properties.
The operating temperature of HNBR ranges between
-30 °C and +140 °C (for a short period of time up to
+160 °C) in contact with mineral oils and greases.
Special types can be used down to -40 °C. B.1.4 Chemical compatibility
Q (Silicone Rubber) It is important to recognise that when using this guide, the
ratings shown are based on published data and
Silicone rubber shows excellent heat resistance, cold
immersion tests. These tests are conducted under
flexibility, dielectric properties and especially good
laboratory conditions and may not represent adequately
resistance against oxygen and ozone.
the conditions in the field. Relative short term laboratory
Depending on the material the operating temperatures
tests may not pick up all the additives and impurities
ranges between -60 °C and +200 °C (for a short period
which may exist in long term service applications.
of time even up to +230 °C). Special types can be used
down to -90 °C. There are also some types with narrow Care must be taken to ensure that all aspects of the
temperature ranges. Silicone is often used in the medical- application are considered carefully before a material is
and food industry. selected. For example at elevated temperatures some
aggressive fluids can cause a much more marked effect
CR (Chloroprene Rubber)
on an elastomer than at room temperature.
In general the CR materials show relatively good
Physical properties as well as fluid compatibility need to
resistances to ozone, weathering, chemicals and aging.
be considered. Compression set, hardness, abrasion
Also they show good non-flammability, good mechanical
resistance and thermal expansion can influence the
properties and cold flexibility.
suitability of a material for a particular application.
The operating temperatures range between -40 °C and
+100 °C (for a short period of time up to +120 °C). It is recommended that users conduct their own tests to
Special types can be used down to -55 °C. confirm the suitability of the selected material for each
CR materials are found in sealing applications such as application.
refrigerants, for outdoor applications and in the glue
industry. Our experienced technical staff can be consulted for
further information on specific applications.
ACM (Polyacrylate Rubber)
Rating system
ACM shows excellent resistance to ozone, weathering
and hot air, although it shows only a medium physical A Very good suitability
strength, low elasticity and a relatively limited low Elastomer shows little or no effect from exposure.
temperature capability. Little effect on performance and physical
The operating temperatures range from -20 °C and properties. Very good resistance.
+150 °C (for a short period of time up to +175 °C). B Good suitability.
Special types can be used down to -35 °C. Some effects from exposure with some loss of
ACM-materials are mainly used in automotive physical properties. Some chemical swelling.
applications which require special resistance to lubricants
containing many additives (incl. sulphur) at high C Limited suitability.
temperatures. Significant swell and loss of physical properties after
exposure. Additional tests should be done.
FFKM (Perfluoro Rubber)
U The elastomer is unsuitable for application in this
Perfluoroelastomers show broad chemical resistance media.
similar to PTFE as well as good heat resistance. They show
low swelling with almost all media. — Insufficient information available for service in this
Depending on the material the operating temperatures media.
range between -25 °C and +240 °C. Special types can
be used up to +325 °C.
7
Material Guide
FVMQ
HNBR
EPDM
A
VMQ
ACM
FKM
NBR
AU
Chemical
CR
Allyl Alcohol
U U A A B U B B U
(2-Propene-1-ol)
FVMQ
HNBR
EPDM
VMQ
ACM
FKM
NBR
Allyl Chloride
AU
Chemical
CR
- U U U - - U U A
(3-Chloro-1-Propene)
Acet Aldehyde U U - B U U U U -
Allyl Ketone U U C A U U U U B
Acet Amide - - A A U A A A B
Aluminium Acetate U U B A U U B B U
Acetyl Acetone U U U A U U U U U
Aluminium Bromide A U A A A A A A A
Acetyl Chloride U U U U A A U U U
Aluminium Fluoride - U A A A A A A B
Acetic Acid C U B A C C C C B
Aluminium Nitrate U U A A A - A A B
Acetic Acid Chloride U U U U A A U U U
FVMQ
FVMQ
HNBR
HNBR
EPDM
EPDM
VMQ
VMQ
ACM
ACM
FKM
FKM
NBR
NBR
AU
AU
Chemical Chemical
CR
CR
Ammonium Chloride ASTM Test Fuel B U U U U A A A A U
- - A A - - A A -
Solution
ASTM Test Fuel C U U U U A B B B U
Ammonium Fluoride U U B A B B A A A
ASTM-Oil IRM 902 A B B U A A A A B
Ammonium Hydroxide U U A A U - U U -
ASTM-Oil IRM 903 A B U U A A A A B
Ammonium Hydroxide
U U A A U - U U -
Solution ASTM-Oil No.1 A B B U A A A A A
Ammonium Nitrate ASTM-Oil No.2 A B B U A A A A B
U - A A - - A A -
Solution
ASTM-Oil No.3 A B U U A A A A B
Ammonium Nitrite - - B A - - A A B
ATM-Brake Fluid
Ammonium Phosphate, U U B A U A U U A
- - A A - - A A A (Glycolbased)
monobasic, etc.
Automatic-Transmission
Ammonium Sulfate U A B U A A A A B
U U A A U B A A B Fluid
Solution
Ammonium
- B - A - - A A A
Thiocyanate
Amyl Acetate U U U A U U U U U
B
Amyl Alcohol U U B A B B B B U
Amyl Borate - - A U - - A A -
FVMQ
HNBR
EPDM
VMQ
ACM
FKM
NBR
Amyl Chloride U U U U A B U U U
AU
Chemical
CR
Amyl Naphtalene U U U U A A U U U
Barium Carbonate - A - A A A A A A
Anderol L-774 A U U U A A A A U
Barium Chloride
U A A A A A A A A
Aniline Chlorohydrate U U B B B B B B U Solution
9
Material Guide
FVMQ
FVMQ
HNBR
HNBR
EPDM
EPDM
VMQ
VMQ
ACM
ACM
FKM
FKM
NBR
NBR
AU
AU
Chemical Chemical
CR
CR
Benzine 50 / Butane A B B U A A A A U
U U U U B B U U U
Benzene 50
1-Butanethiol U - U U A U U U U
Benzine 60 /
U U U U B B U U U Butanole U U B B A A A A B
Benzene 40
Benzine 70 / Butantriol A B B A A A A A A
U U U U A A B B U
Benzene 30
Butene U B U U A B B B U
Benzine 80 /
U U U U A A B B U Buthylphenol U U U U B - U U U
Benzene 20
Butter B B B B A A A A B
Benzoic Acid, Solution B U B B A A B B B
Buttermilk U A A A A A A A A
Benzol (Benzene) U U U U B B U U U
Butyl Acetate U U U b U U U U U
Benzophenone U U - B A A - - -
Butyl Acrylate U - U U U U U U -
Benzyl Alcohol U U B B A B U U B
Butyl Alcohol U U B A A A A A B
Benzyl Chloride U U U U A A U U U
Butyl Amine U U U - U U U U C
Biphenyl U - U U A B U U U
Butyl Benzoate U - U A A A U U -
Bitumen U B U U A A U U U
Butyl Carbitol U - C A C U U U U
Black Liquor U U B B B - B B -
Butyl Cellosolve U U C A U U C C -
Blast Furnace Gas B U U U A B U U A
Butyl Diglycol - - - A A - A A -
Bleach Solution U U U A A B U U U
Butyl Ether U U U U U U U U U
Bleaching Powder
U U B A A B C C B
Solution Butyl Phthalate U U U A U A U U A
Boiler Feed Water U U C A B B B B C Butyl Pyrocatechol U - - B A B U U -
Bone Oil A A U U A A A A U Butyl Stearate - A U U A B B B B
Borax (Sodiumborate) A U B A A A B B A Butylene b B C U A A A A U
Borax Solutions U U U A B B B B B Butyraldehyd U - U B U U U U U
Boric Acid U B B A A A A A A Butyric Acid U U C U A B B B U
Brake Fluids Butyric Acid Butyl Ester U - U B B B U U -
U U B A U U U U U
(based on glycol ether)
Brake Fluids
- A B - A - A A -
(based on mineral oil)
Bromine U U U U B B U U U
Bromine Solution in
C
U U U U A B U U U
Water
Bromine Vapour U U U U B B U U U
FVMQ
HNBR
EPDM
VMQ
ACM
FKM
NBR
AU
Bromobenzene U U U U A B U U U Chemical
CR
FVMQ
FVMQ
HNBR
HNBR
EPDM
EPDM
VMQ
VMQ
ACM
ACM
FKM
FKM
NBR
NBR
AU
AU
Chemical Chemical
CR
CR
Calcium Carbonate Cellulose Acetat - A U B U - A A A
U U A A A A A A A
Slurry
Chile Salpetre
U B B A A A B B B
Calcium Chloride B B A A A A A A A (Sodium Nitrate)
Cellulose U B B B U B B B B Coca-Cola U B B A B A A A A
11
Material Guide
FVMQ
HNBR
EPDM
VMQ
ACM
FKM
NBR
AU
Chemical
CR
FVMQ
Cocoa Butter - B B U A B A A C
HNBR
EPDM
VMQ
ACM
FKM
NBR
AU
Chemical
CR
Coconut grease A B B U A A A A A
Coffee U U A A A A A A A Decalin
B U U U A A U U U
(Decahydronaphtalene)
Coffee Extract U U A A A A A A A
Decane A U U U A A A A B
Coke Oven Gas U U U U A B U U B
Dextrin U U A A A A A A A
Copper Acetate
U U C B U U U U U
Solution Dextrose B B - A A A A A A
3,1-Dichloropropene - U U U - - U U A
Dichloro Iso-Propylene
U B U U U U U U U
Ether
FVMQ
FVMQ
HNBR
HNBR
EPDM
EPDM
VMQ
VMQ
ACM
ACM
FKM
FKM
NBR
NBR
AU
AU
Chemical Chemical
CR
CR
Dicyclo Hexyl Amine U U U U U U U U U Dimethylbutane A - B U A A A A U
Divinyl Benzene U U U U A B U U U
Diethylene Glycol U U A A A A A A B
DMT (Dimethyl
Diethylene Triamine U U U A U U U U U U U U A A B U U U
Terephthalate)
Diglycolic Acid U - B A A U U U U
DNCB
U U U U A B U U U
Dihexyl Phthalic Acid (Dinitrochlorobenzene)
U - U - U - U U U
Ester
Dodecanol - - A B A - B B -
1,4-Dihydroxybenzene B - U B U B U U U
Domestic Fuel Oils A A B U A A A A U
Dihydroxy Tartaric Acid Dowtherm A U U U U A B U U U
U U A B A A A A A
(Tartaric Acid)
Dowtherm E U U U U A B U U U
Di-Isobutyl Ketone U U U A U U U U U
Di-Isobutylene U U U U A C B B U
Di-Isooctyl Sebacate U U U B B U U U U
Di-Isopropyl Benzene U U U U A A U U U E
Di-Isopropyl Ketone U U U A U U U U U
Dimethyl Amine U U U B U U U U U
FVMQ
HNBR
EPDM
VMQ
ACM
FKM
NBR
Dimethyl Aniline U U U B U U U U U
AU
Chemical
CR
13
Material Guide
FVMQ
FVMQ
HNBR
HNBR
EPDM
EPDM
VMQ
VMQ
ACM
ACM
FKM
FKM
NBR
NBR
AU
AU
Chemical Chemical
CR
CR
Ethyl Acrylate U U U - U U U U U Ferric Nitrates B B A A A A A A B
Freon 152 a - - A A U - A A -
Freon 21 U B B U U B U U U
F Freon 218 - - A A A - A A -
Freon 22 B U A A U U U U U
Freon 31 - B A A U B U U U
FVMQ
HNBR
EPDM
VMQ
ACM
FKM
NBR
AU
Chemical Freon 32 - B A A U B A A U
CR
FVMQ
FVMQ
HNBR
HNBR
EPDM
EPDM
VMQ
VMQ
ACM
ACM
FKM
FKM
NBR
NBR
AU
AU
Chemical Chemical
CR
CR
Freon C318 - - A A B B A A U Glucose solution U U A A A A A A A
Freon TA - A A A U - A A A Glycerol U U A A A A A A A
Furfurylalcohol - C - - - - - - -
H
G
FVMQ
HNBR
EPDM
VMQ
ACM
FKM
NBR
AU
Chemical CR
FVMQ
HNBR
EPDM
VMQ
HEF-3 U U U U A B B B U
ACM
FKM
NBR
AU
Chemical
CR
Helium Gas A A A A A A A A A
Gallic Acid U U B B A A A A A
Heptane A B B U A A A A C
Gas Oil A A B U A A A A B
A/
Gasoline / Alcohol Mix U U U U B U b B U Hexa Fluoro Silicic Acid U U B B - B B U
B
15
Material Guide
FVMQ
FVMQ
HNBR
HNBR
EPDM
EPDM
VMQ
VMQ
ACM
ACM
FKM
FKM
NBR
NBR
AU
AU
Chemical Chemical
CR
CR
Hexene A B B U A A B B U Iso-Butyl Methyl Ketone U U U A U U U U U
Hexyl Alcohol U U B B A B A A B Iso-Butylene U U U U A A A A U
Hydrazine C U B A C B B B U Iso-Butyraldehyde U U U A U U U U U
Hydrazine Hydrate C U B A C B B B U Iso-Cyanate - - - A - - - - -
Hydrobromic Acid U U U A A C U U U
Iso-Dodecane U U B U A A A A U
Hydrochlorique Acid
U U U B A U U U U Iso-Octane A B B U A A A A U
(Muriatic Acid) 37%
Hydrogen Sulfide U U B A A U C C U
Hydrogen, Gas B A A A A C A A C J
Hydrogene Bromide,
U U U U A U U U B
anhydrous
FVMQ
HNBR
EPDM
VMQ
ACM
FKM
NBR
Hydrogensulfite Leach B U B A A - U U -
AU
Chemical
CR
Hydroquinone B - U B U B U U U
Jet Fuel JP3 B B U U A A A A U
Hydroxy Acetic Acid U U U A U U U U B
Jet Fuel JP4 B B U U A B A A U
Hydroxyl Amine - - - A A A A A A
Jet Fuel JP5 B B U U A B A A U
Hydroxyl Amine Sulfate - - B A A A A A A
Jet Fuel JP6 B B U U A B A A U
Hypochlorous Acid U - U B A - U U -
JP3 (Fuel) U B U U A A A A U
JP4 (Fuel) U B U U A B A A U
I JP5 (Fuel) U B U U A B A A U
JP6 (Fuel) B B U U A B A A U
JPX (Fuel) - - B U U U A A U
FVMQ
HNBR
EPDM
VMQ
ACM
FKM
NBR
AU
Chemical
CR
Ink A A A A B A A A A
Iodine - - U B A A B B - K
Iodine tincture U U B B A B B B B
Iodoform - - - A A - - - -
FVMQ
HNBR
EPDM
VMQ
ACM
FKM
NBR
AU
Chemical
CR
Iodoform - - - A A - - - -
Iso-Butane A A U U A A A A U Kerosene C B U U A b A A U
FVMQ
HNBR
EPDM
VMQ
ACM
FKM
NBR
AU
Chemical
CR
Magnesium Hydroxide
FVMQ
HNBR
EPDM
U U B A B B B B B
VMQ
ACM (Solution)
FKM
NBR
AU
Chemical
CR
Magnesium Silicate
Lactams U U C U U U U U U A A A A A A A A A
(Talcum)
Lactic Acid U B A B A A B B B Magnesium Sulfate
U U A A A A A A A
(Epson Salts)
Lanolin A A B U A A A A B
Maleic Acid C C B A A b B B C
Latex U U A A A A A A A
Maleic Anhydride U - U U B - U U -
Laughing Gas (N2O) A A A B A A A A A
Malic Acid U U B B A A A A B
Lavender Oil B U U U A B B B U
Margarine A B B U A A A A B
Lead Acetate Salt
U U U A U U C C U
Solution Mayonaise - U U U U U A A A
Lead Arsenate - A - A - - A A A Menthol U U B B A U B B U
Lead Nitrate - U B A A A A A B Mercaptans U U U A U U U U U
Lead Nitrate Solution - - A A - A A A B Mercuric Chloride
- - A A A A A A A
Solution
Lead Sulfate U A A A A A B B B
Mercury A A A A A A A A A
Lemon Juice U - B A A - A A A
Mercury Nitrate - - A A - - A A A
Ligroin - B B U A A A A U
Liqueurs B B A A A A A A A Methane A U B U A B A A B
Methyl Acetate U U B B U U U U U
Methyl Acetoacetate U U C B U U U U U
Methyl Acrylate U U U B U U U U U
M Methyl Alcohol U U B A U A B B A
Methyl Amine U U U A U U U U U
FVMQ
HNBR
EPDM
Methyl Aniline U U U B B - U U -
VMQ
ACM
FKM
NBR
AU
Chemical
CR
Methyl Bromide U U U U A A U U U
Machinery Oil
A A B U A A A A B Methyl Butyl Ketone U U U A U U U U U
(mineral)
Methyl Carbonate U U U U U B U U U
Maganese Chloride
U U A A A A A A A
(Solution) Methyl Cellosolve U U U B U U U U U
Magnesium Acetate Methyl Cellulose U B B B B U B B B
U U U A U U U U U
Solution
Methyl Chloride U U U U B B U U U
Magnesium Chloride
- U A A A A A A A
Solution Methyl Cyclopentane U U U U B B U U U
17
Material Guide
FVMQ
HNBR
EPDM
VMQ
ACM
FKM
NBR
AU
Chemical
CR
Methyl Ethyl Ketone U U U B U U U U U
FVMQ
HNBR
EPDM
VMQ
ACM
FKM
NBR
AU
Chemical
CR
Methyl Formate - - U B U - U U -
Monoethanol Amine U U U B U U U U U
Mononitro Chloro
U U U U A A U U U
O
Benzene
Morpholine U U C B - - U U U
FVMQ
HNBR
EPDM
VMQ
ACM
FKM
NBR
AU
U U - B A - U U U
(Hydrochloric Acid)
Octadecane B B B U A A A A U
Muriatic Acid (HCl),
U U B A A - B B B
diluted Octal U B U B B C U U C
FVMQ
FVMQ
HNBR
HNBR
EPDM
EPDM
VMQ
VMQ
ACM
ACM
FKM
FKM
NBR
NBR
AU
AU
Chemical Chemical
CR
CR
Octane U U U U A B B B U Phenol C U U U B - U U U
Pine Oil A A U U A A B B U
Pineapple Juice U U A A A A A A A
P Pinene U B B U A B B B U
Piperidine U U U U U U U U U
FVMQ
HNBR
EPDM
Polyvinyl Acetates - - B A U - - - -
VMQ
ACM
FKM
NBR
AU
Chemical
CR
Potassium Acetate U B B A B U B B U
Palm Kernel Oil A - A U A - A A -
Potassium Aluminium
- - - A - - - - -
Palm Oil A A U U A A A A U Sulfat
19
Material Guide
FVMQ
HNBR
EPDM
VMQ
ACM
FKM
NBR
AU
Chemical
CR
FVMQ
Potassium Hypochlorite
HNBR
EPDM
VMQ
U U - B A B B B B
ACM
FKM
NBR
(Javelle Water)
AU
Chemical
CR
Potassium Iodide U U B A A A A A A
Rapeseed Oil B B B U A B B B U
Potassium Nitrate C C B A A A B B A
Roast Gas (dry) A - B A A A A A A
Potassium Perchlorate U U B A A - U U -
Rosin (Colophony) U U A A A A A A A
Potassium
- - B A U U B B -
Perfluoroacetate
Potassium
C B B A A U U U U
Permanganate
S
Potassium Persulfate U U B A A U U U U
Potassium Phosphate - - - A A - A A U
FVMQ
HNBR
EPDM
VMQ
ACM
FKM
NBR
AU
Potassium Sulfate U C B A A B A A B Chemical
CR
Potassium Sulfite U C A A A A A A A Salicylic Acid - A A A A - B B -
Propanol U U A A A A B B B Sewage - - B A A A A A A
Sodium Bisulfate
U U A A A A A A A
Solution
Sodium Bisulfite
U U A A A A A A A
Solution
Sodium Carbonate
U U A A A A A A A
(Soda Ash)
FVMQ
FVMQ
HNBR
HNBR
EPDM
EPDM
VMQ
VMQ
ACM
ACM
FKM
FKM
NBR
NBR
AU
AU
Chemical Chemical
CR
CR
Sodium Carbonate Starch B B A A A A A A A
- - A A A A A A A
Solution
Stearic Acid A A B B A A B B B
Sodium Chlorate U B B A A U B B U
Stoddard Solvent A A B U A A A A U
Sodium Chloride
U U A A A A A A A Styrene U U U U A C U U U
(Common Salt)
Succinic Acid U U B A A - A A A
Sodium Chloride
- - A A A - A A -
Solution Sucrose Sap U U B A A A A A A
Sodium Chlorite - - U A A - U U - Sugar Solutions U U B A A A A A A
Sodium Cyanide Sulphur U - A A A B U U B
- - A A - - B B A
Solution
Sulphur Hexafluoride
B - A A B B B B -
Sodium Dichromate U U A A A - B B B (SF6)
Sodium Phosphate - - B A A - A A U
Sodium Silicate
Solution
- - A A A - A A - T
Sodium Sulfate
U U B A A A B B A
(Glauber’s Salts) FVMQ
HNBR
EPDM
VMQ
ACM
FKM
NBR
Sodium Sulfhydrate
AU
Chemical
CR
U - A A A A A A A
Solution
Talcum - A - A A A A A A
Sodium Sulphide U U B A A A B B B
Tallow U B B B A U A A B
Sodium Sulphite
U U A A A A A A A
Solution Tannins U B B B A A B B B
21
Material Guide
FVMQ
HNBR
EPDM
VMQ
ACM
FKM
NBR
AU
Chemical
CR
Titanium Tetrachloride U U B B B B B B U
FVMQ
HNBR
EPDM
VMQ
ACM
FKM
NBR
AU
Toluene (Toluol) U U U U B B U U U Chemical
CR
Town Gas U U U U A B B B B Vaseline B B B U A A A A B
Trichloro Benzene U U U - A U - - U
Trichloro Ethane U U U U A B U U U
Trichloro Ethyl
Phosphate
- - U - U - U U -
W
Trichloro Ethylene U U U U B B U U U
Trichloroacetic Acid U U U B U U B B B
FVMQ
HNBR
EPDM
VMQ
ACM
FKM
NBR
Chemical AU
CR
Tricresyl Phosphate U U U B B B U U U
Water 135 °C U U C A C A C U U
Water 80 °C U U B A B A A B B
HNBR
EPDM
VMQ
ACM
FKM
NBR
AU
FVMQ
HNBR
EPDM
VMQ
ACM
FKM
NBR
AU
Chemical
CR
Wine + Whiskey U U A A A A A A A
Wood Spirit U U U B U U U U -
X
FVMQ
HNBR
EPDM
VMQ
ACM
FKM
NBR
AU
Chemical
CR
Xenon A A A A A A A A A
Xylene (Xylol) U U U U B U U U U
Xylidines
U U U B U U U U U
(aromatic Amines)
Y
FVMQ
HNBR
EPDM
VMQ
ACM
FKM
NBR
AU
Chemical
CR
Yeast B U A A A A A A A
Z
FVMQ
HNBR
EPDM
VMQ
ACM
FKM
NBR
AU
Chemical
CR
Zeolites - - A A A - A A -
Zinc Acetate U U B A U U B B U
Zinc Sulfate U U A A A A A A A
23
Material Guide
ACS Polymers exposed to French Standard AFNOR - Analysis of dispensing ACS 3 certified test
Licensing drinking water XP P41-250, part 1-3 according ”Synoptic (Accréditation de laboratories in
Documents” conformité France:
- Storage test (microbe sanitaire) Paris / Vandoevre /
analysis) Lille
BAM Seals for the use in gas - reactive behaviour with BAM BAM, Berlin
recommendation or oxygen fittings lubricants (Bundesanstalt für
- limits for pressure and Materialforschung
temperature und -prüfung)
(DIN 4060)
- seals and components
BfR Polymers exposed to BfR Guidelines - Chemical and physical tests BfR BAM, Berlin
Recommendation food (“Polymers exposed to - Biological tests (Bundesamt für HY
(former: BgVV) food”) various - Sterilisation tests Risikobewertung) (Hygiene-Institut,
paragraphs, depending - Taste tests Gelsenkirchen)
on the application of the
seal
DVGW Seals for processing BfR Guidelines Various classifications and DVGW, Bonn Environmental
Release for storage and distribution (“Polymers exposed to tests - depending on the (Deutscher Verein Hygiene Institute,
drinking water of drinking water food”) application des Gas- und Gelsenkirchen
Wasserfaches e.V.) TZW, Karlsruhe
DVGW W270 Materials exposed to DVGW, Microbiological DVGM, Bonn TZW, Karlsruhe
recommendation drinking water worksheet W 270 testing:reproduction of (Deutscher Verein HY (Hygiene
microorganisms on materials des Gas- und Institution),
Wasserfaches) Gelsenkirchen
FDA Materials for food and “White List” (Register of - Component test according FDA In house or
guideline pharmaceutical permitted dispensing “White List” (Food and Drug external
components) according - Extended for foods Administration) laboratories
to 21. CFR Part containing water or oil
177.2600 Extraction test for
polar / non polar solvents
International Applications for military Various military - Depending on application Various test
Military Releases devices specifications and and specification laboratories
standards depending on
the application
KTW Polymers exposed to BfR Guidelines - Extraction test DVGW, Bonn Environmental
certificate drinking water, (“Polymers exposed to - Odour- and taste test (Deutscher Verein Hygiene Institute,
Cold- warm- and hot food”) - Register of permitted des Gas- und Gelsenkirchen
water part 1.3.13 components Wasserfaches e.V.) TZW, Karlsruhe
BAM, Berlin
NSF Food and Sanitary NSF Standard criteria Depending on application: NSF NSF, USA
Release - Test of components (National Sani- UL, USA
- Test of component group tation Foundation)
- Physical and chemical
Material tests
- Toxicological and micro
biological tests
USP For medical and Different specifications: Depending on specification: USP Different test
examination pharmaceutical use USP Class I to VI, - intracutaneous reactive tests (United States laboratories
USP Class 26 - systemic Injections Pharmacopeia,
- muscle implantations USA)
WRAS Polymers exposed to British Standard - Dispensing test WRAS Various accredited
Release drinking water BS 6920 - Microbe test (Water Regulations test laboratories in
(former: WRC) BS 2494 - Extraction test Advisory Scheme) England
- Hot water test
25
Material Guide
C Materials
The following tables show the most important materials materials with institutional approvals in the main are
for different applications. Apart from this we offer further listed in one chapter even if they are used for special
numerous materials for special applications. Please industrial applications.
contact your local B+S company.
Due to the different conditions in the field, e. g. different
The listed materials are structured according to their main media, the given material properties could be affected
purpose. Owing to the versatility of the materials exact and changed. Tests should be done for each application.
organisation is not possible. Therefore for example
Elongation at break DIN 53 504 % > 200 > 150 > 100
ASTM D 412
Compression set 24h / 100 °C DIN ISO 815B % < 25 < 30 < 30
ASTM D 395B
Elongation at break DIN 53 504 % > 150 > 125 > 125
ASTM D 412
27
Material Guide
Elongation at break DIN 53 504 % > 125 > 125 > 120 > 100
ASTM D 412
Compression set 24h / 175 °C DIN ISO 815B % < 20 < 20 < 20 < 20
ASTM D 395B
Change of tensile strength % max -25 max -25 max -25 max -25
Change of elongation at break % max -25 max -25 max -25 max -25
Change of volume % max +10 max +10 max +10 max +10
Temperature range -18 °C to -18 °C to -18 °C to -15 °C to
Maximum and minimum operating temperatures +200 °C +200 °C +200 °C +200 °C
depend on the specific application criteria.
HNBR 70 HNBR 75
Shore A Shore A
partially saturated partially saturated
29
Material Guide
31
Material Guide
33
Material Guide
35
Material Guide
37
Material Guide
Light
D.2 Storage and shelf life Elastomeric seals should be protected from light sources,
in particular direct sunlight or strong artificial light with an
Seals and bearings are often stored as spare parts for ultraviolet content. The individual storage bags offer the
prolonged periods. Most rubbers change in physical best protection as long as they are UV resistant.
properties during storage and ultimately become It is advisable to cover any windows of storage rooms with
unserviceable due, e.g., to excessive hardening, a red or orange coating or screen.
softening, cracking, crazing or other surface
degradation. These changes may be the result of
particular factors or combination of factors, such as the Radiation
action of deformation, oxygen, ozone, light, heat,
humidity or oils and solvents. Precaution should be taken to protect stored articles from
all sources of ionising radiation likely to cause damage
With a few simple precautions, the shelf life of these to stored articles.
products can be considerably lengthened.
Elastomeric materials should, wherever possible, be Rubber details and components less than 1.5 mm thick
stored in a relaxed condition free from tension, are liable to be more seriously affected by oxidation
compression or other deformation. Where articles are degradation even when stored in satisfactory conditions
packed in a strain-free condition they should be stored in as recommended. Therefore they may be inspected and
their original packaging. tested more frequently than it is mentioned above.
Contact with liquid and semi-solid materials Rubber details / seals in assembled components
Elastomeric seals should not be allowed to come into It is recommended that the units should be exercised at
contact with solvents, oils, greases or any other semi-solid least every six months and that the maximum period a
materials at any time during storage, unless so packed by rubber detail be allowed to remain assembled within a
the manufacturer. stored unit, without inspection, be a total of the initial
period stated above and the extension period. Naturally
this will depend on the design of the unit concerned.
Contact with metal and non-metals
Direct contact with certain metals, e.g. manganese, iron
and particularly copper and its alloys, e.g. brass and
compounds of these materials are known to have
deleterious effects on some rubbers. Elastomeric seals
should not be stored in contact with such metals.
Because of possible transfer of plasticisers or other
ingredients, rubbers must not be stored in contact with
PVC. Different rubbers should preferably be separated
from each other.
Cleaning
Where necessary, cleaning should be carried out with the
aid of soap and water or methylated spirits. Water should
not, however, be permitted to come into contact with
fabric reinforced components, bonded seals (because of
corrosion) or polyurethane rubbers. Disinfectants or
other organic solvents as well as sharp-edged objects
must not be used. The articles should be dried at room
temperature and not placed near a source of heat.
39
Material Guide
Notes
41
Material Guide
For all other countries in Europe, Africa and the Near East, please contact:
Busak+Shamban S.A. Division R.G. Export. Route Sous-Riette 29, 1023 Crissier, Switzerland Tel: 41 21 6314111, Fax 41 21 6314145
www.trelleborg.com