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Miller Indices in Hexagonal Crystal System

The document discusses Miller-Bravais indices for describing planes and directions in hexagonal crystal systems. It notes that hexagonal crystals use a 4-index notation where the first three indices describe the basal plane and the fourth represents the c-axis perpendicular to the basal plane. This allows for equivalent planes and directions to be grouped together despite the hexagonal symmetry. Examples are given of how planes and directions are represented using intercepts and the 4-index notation, and how the indices transform between the standard 3-index and 4-index forms.

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Shubham Kumbhar
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666 views12 pages

Miller Indices in Hexagonal Crystal System

The document discusses Miller-Bravais indices for describing planes and directions in hexagonal crystal systems. It notes that hexagonal crystals use a 4-index notation where the first three indices describe the basal plane and the fourth represents the c-axis perpendicular to the basal plane. This allows for equivalent planes and directions to be grouped together despite the hexagonal symmetry. Examples are given of how planes and directions are represented using intercepts and the 4-index notation, and how the indices transform between the standard 3-index and 4-index forms.

Uploaded by

Shubham Kumbhar
Copyright
© © All Rights Reserved
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Miller Indices in Hexagonal

crystal system
Hexagonal crystals → Miller-Bravais Indices

 Directions and planes in hexagonal lattices and crystals are designated by the
4-index Miller-Bravais notation
 In the four index notation:
 the first three indices are a symmetrically related set on the basal plane
 the third index is a redundant one (which can be derived from the first two)
and is introduced to make sure that members of a family of directions or planes
have a set of numbers which are identical
 this is because in 2D two indices suffice to describe a lattice (or crystal)
 the fourth index represents the ‘c’ axis ( to the basal plane)
 Hence the first three indices in a hexagonal lattice can be permuted to get the
different members of a family; while, the fourth index is kept separate.
Related to ‘l’ index

Related to ‘k’ index


Related to ‘i’ index

Related to ‘h’ index


Hexagonal crystals → Miller-Bravais Indices

a3 Intercepts → 1 1 - ½ 
Plane → (1 12 0)
(h k i l)
i = (h + k)

a2

a1
The use of the 4 index notation is to bring out the equivalence between
crystallographically equivalent planes and directions (as will become clear in coming slides)
Examples to show the utility of the 4 index notation
a3

a2
Obviously the ‘green’ and
‘blue’ planes belong to the
same family and first three
indices have the same set of
numbers (as brought out by the
a1 Miller-Bravais system)

Intercepts → 1 -1   Intercepts →  1 -1 
Miller → (1 1 0 ) Miller → (0 1 0)
Miller-Bravais → (1 1 0 0 ) Miller-Bravais → (0 11 0)
Examples to show the utility of the 4 index notation

a3

a2

Intercepts → 1 -2 -2  a1 Intercepts → 1 1 - ½ 

Plane → (2 11 0 ) Plane → (1 12 0)


Intercepts → 1 1 - ½ 1
Plane → (1 12 1)

Intercepts → 1   1 1
Plane → (1 01 1)
Directions
 One has to be careful in determining directions in the Miller-Bravais system.
 Basis vectors a1, a2 & a3 are symmetrically related by a six fold axis.
 The 3rd index is redundant and is included to bring out the equality between equivalent directions (like
in the case of planes).
 In the drawing of the directions we use an additional guide hexagon 3 times the unit basis vectors (a i).

Guide Hexagon
Directions Drawing the [1120] direction
• Trace a path along the basis vectors as required by the direction. In the current example move
1unit along a1, 1unit along a2 and 2 units along a3.
• Directions are projected onto the basis vectors to determine the components and hence the Miller-
Bravais indices can be determined as in the table.

a1 a2 a3
Projections a/2 a/2 −a

Normalized wrt LP 1/2 1/2 −1

Factorization 1 1 −2

Indices [1 1 2 0]
We do similar exercises to draw other directions as well

Drawing the [101 0] direction


Some important directions
Transformation between 3-index [UVW] and 4-index [uvtw] notations

U  u t V  v t W w

1 1
u  (2U  V ) v  (2V  U ) t  (u  v) w W
3 3

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