Scaling in Boilers

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Home / Applications / Process water / Boiler feed water / Scaling

Boiler scale is caused by impurities being precipitated out of the water directly on heat transfer surfaces or
by suspended matter in water settling out on the metal and becoming hard and adherent. Evaporation in a
boiler causes impurities to concentrate. This interferes with heat transfers and may cause hot spots.
Leading to local overheating. Scaling mechanism is the exceeding of the solubility limits of mineral
substances due to elevated temperature and solids concentration at the tube/water interface. The
deposition of crystalline precipitates on the walls of the boiler interferes with heat transfer and may cause
hot spots, leading to local overheating. The less heat they conduct, the more dangerous they are.

Common feed water contaminants that can form boiler deposits include calcium, magnesium, iron,
aluminum, and silica. Scale is formed by salts that have limited solubility but are not totally insoluble in
boiler water. These salts reach the deposit site in a soluble form and precipitate.
The values corresponding to their thermal conductivity are:

Steel 15 kcal/m2.h per degree C


CaSO4 1-2 kcal/m2.h per degree C
CaCO3 0.5-1 kcal/m2.h per degree C
SiO2 0.2-0.5 kcal/m2.h per degree C

Scaling is mainly due to the presence of calcium and


magnesium salts (carbonates or sulphates), which are less
soluble hot than cold, or to the presence of too high
concentration of silica in relation to the alkalinity of the
water in the boiler.
A carbonate deposit is usually granular and sometimes of
a very porous nature. The crystals of calcium carbonate
are large but usually are matted together with finely divided
particles of other materials so that the scale looks dense
and uniform. Dropping it in a solution of acid can easily
identify a carbonate deposit. Bubbles of carbon dioxide will
effervesce from the scale.
A sulphate deposit is much harder and more dense than
a carbonate deposit because the crystals are smaller and
cement together tighter. A Sulphate deposit is brittle, does
not pulverize easily, and does not effervesce when
dropped into acid.
A high silica deposit is very hard, resembling porcelain.
The crystal of silica are extremely small, forming a very
dense and impervious scale. This scale is extremely brittle
and very difficult to pulverize. It is not soluble in
hydrochloric acid and is usually very light coloured.
Iron deposits, due either to corrosion or iron
contamination in the water, are very dark coloured. Iron
deposits in boilers are most often magnetic. They are
soluble in hot acid giving a dark brown coloured solution.

If unchecked, scaling causes progressive lowering of the boiler efficiency by heat retardation, acting as an
insulator. Eventually, scale built-up will cause the tube to overheat and rupture.

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