Magic Quack SDS Sheet 7-19-18

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SAFETY DATA SHEET

1. Identification
Product number 1000037655
Product identifier 10 OZ MAGIC QUACK DECOY RESTORER 12PK
Company information J. SCOTT HARRISON & CO. INC
9400 MANOR ROAD
LEAWOOD, KS 66206 United States
Company phone General Assistance 1-913-481-9554
Emergency telephone US 1-866-836-8855
Emergency telephone outside 1-952-852-4646
US
Version # 01
Recommended use CLEANER
Recommended restrictions None known.

2. Hazard(s) identification
Physical hazards Flammable aerosols Category 1
Health hazards Skin corrosion/irritation Category 2
Reproductive toxicity (fertility) Category 2
Specific target organ toxicity, single exposure Category 3 narcotic effects
Specific target organ toxicity, repeated Category 2
exposure
Aspiration hazard Category 1
OSHA defined hazards Not classified.

Label elements

Signal word Danger


Hazard statement Extremely flammable aerosol. May be fatal if swallowed and enters airways. Causes skin irritation.
May cause drowsiness or dizziness. Suspected of damaging fertility. May cause damage to
organs through prolonged or repeated exposure.
Precautionary statement
Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not
spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn,
even after use. Do not breathe mist or vapor. Wash thoroughly after handling. Use only outdoors
or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face
protection.
Response If swallowed: Immediately call a poison center/doctor. Do NOT induce vomiting. If on skin: Wash
with plenty of water. If inhaled: Remove person to fresh air and keep comfortable for breathing. If
exposed or concerned: Get medical advice/attention. Call a poison center/doctor if you feel
unwell. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and
wash before reuse.
Storage Store in a well-ventilated place. Keep container tightly closed. Store locked up. Protect from
sunlight. Do not expose to temperatures exceeding 50°C/122°F.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Environmental hazards Hazardous to the aquatic environment, acute Category 2
hazard
Hazardous to the aquatic environment, Category 2
long-term hazard

Product name: 10 OZ MAGIC QUACK DECOY RESTORER 12PK SDS US

Product #: 1000037655 Version #: 01 Issue date: 06-19-2018 1 / 10


Hazard(s) not otherwise None known.
classified (HNOC)
Supplemental information None.

3. Composition/information on ingredients
Mixtures
Chemical name Common name and synonyms CAS number %
2-Methylpentane 107-83-5 20 - 40
Butane 106-97-8 20 - 40
n-Hexane 110-54-3 20 - 40
Propane 74-98-6 10 - 20
Other components below reportable levels 2.5 - 10
*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.

4. First-aid measures
Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON
CENTER or doctor/physician if you feel unwell.
Skin contact Remove contaminated clothing. Wash with plenty of soap and water. If skin irritation occurs: Get
medical advice/attention. Wash contaminated clothing before reuse.
Eye contact Rinse with water. Get medical attention if irritation develops and persists.
Ingestion Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If
vomiting occurs, keep head low so that stomach content doesn't get into the lungs.
Most important Aspiration may cause pulmonary edema and pneumonitis. May cause drowsiness and dizziness.
symptoms/effects, acute and Headache. Nausea, vomiting. Skin irritation. May cause redness and pain. Prolonged exposure
delayed may cause chronic effects.
Indication of immediate Provide general supportive measures and treat symptomatically. Keep victim under observation.
medical attention and special Symptoms may be delayed.
treatment needed
General information IF exposed or concerned: Get medical advice/attention. If you feel unwell, seek medical advice
(show the label where possible). Ensure that medical personnel are aware of the material(s)
involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in
attendance.

5. Fire-fighting measures
Suitable extinguishing media Foam. Powder. Carbon dioxide (CO2).
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media
Specific hazards arising from Contents under pressure. Pressurized container may explode when exposed to heat or flame.
the chemical During fire, gases hazardous to health may be formed.
Special protective equipment Firefighters must use standard protective equipment including flame retardant coat, helmet with
and precautions for firefighters face shield, gloves, rubber boots, and in enclosed spaces, SCBA.
Fire fighting Move containers from fire area if you can do so without risk. Containers should be cooled with
equipment/instructions water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose
holder or monitor nozzles, if possible. If not, withdraw and let fire burn out.
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. Move
containers from fire area if you can do so without risk. In the event of fire and/or explosion do not
breathe fumes.
General fire hazards Extremely flammable aerosol.

6. Accidental release measures


Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear
protective equipment and appropriate protective equipment and clothing during clean-up. Do not breathe mist or vapor. Do
emergency procedures not touch damaged containers or spilled material unless wearing appropriate protective clothing.
Ventilate closed spaces before entering them. Local authorities should be advised if significant
spillages cannot be contained. For personal protection, see section 8 of the SDS.

Product name: 10 OZ MAGIC QUACK DECOY RESTORER 12PK SDS US

Product #: 1000037655 Version #: 01 Issue date: 06-19-2018 2 / 10


Methods and materials for Refer to attached safety data sheets and/or instructions for use. Stop leak if you can do so without
containment and cleaning up risk. Move the cylinder to a safe and open area if the leak is irreparable. Eliminate all ignition
sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood,
paper, oil, etc.) away from spilled material. Prevent entry into waterways, sewer, basements or
confined areas. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or
earth and place into containers. Following product recovery, flush area with water.

Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination. For waste disposal, see section 13 of the SDS.
Environmental precautions Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all
environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into
drains, water courses or onto the ground.

7. Handling and storage


Precautions for safe handling Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Pressurized container: Do not pierce or burn, even after use. Do not use if spray
button is missing or defective. Do not spray on a naked flame or any other incandescent material.
Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill,
grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment used
when handling the product must be grounded. Do not re-use empty containers. Do not breathe
mist or vapor. Avoid contact with eyes, skin, and clothing. Pregnant or breastfeeding women must
not handle this product. Should be handled in closed systems, if possible. Use only in
well-ventilated areas. Wear appropriate personal protective equipment. Wash hands thoroughly
after handling. Avoid release to the environment. Observe good industrial hygiene practices.
Conditions for safe storage, Level 3 Aerosol.
including any incompatibilities
Store locked up. Pressurized container. Protect from sunlight and do not expose to temperatures
exceeding 50°C/122 °F. Do not puncture, incinerate or crush. Do not handle or store near an open
flame, heat or other sources of ignition. This material can accumulate static charge which may
cause spark and become an ignition source. Store away from incompatible materials (see Section
10 of the SDS).

8. Exposure controls/personal protection


Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components Type Value
n-Hexane (CAS 110-54-3) PEL 1800 mg/m3
500 ppm
Propane (CAS 74-98-6) PEL 1800 mg/m3
1000 ppm
US. ACGIH Threshold Limit Values
Components Type Value
2-Methylpentane (CAS STEL 1000 ppm
107-83-5)
TWA 500 ppm
Butane (CAS 106-97-8) STEL 1000 ppm
n-Hexane (CAS 110-54-3) TWA 50 ppm
US. NIOSH: Pocket Guide to Chemical Hazards
Components Type Value
Butane (CAS 106-97-8) TWA 1900 mg/m3
800 ppm
n-Hexane (CAS 110-54-3) TWA 180 mg/m3
50 ppm
Propane (CAS 74-98-6) TWA 1800 mg/m3
1000 ppm

Product name: 10 OZ MAGIC QUACK DECOY RESTORER 12PK SDS US

Product #: 1000037655 Version #: 01 Issue date: 06-19-2018 3 / 10


Biological limit values
ACGIH Biological Exposure Indices
Components Value Determinant Specimen Sampling Time
n-Hexane (CAS 110-54-3) 0.4 mg/l 2,5-Hexanedio Urine *
n, without
hydrolysis
* - For sampling details, please see the source document.
Exposure guidelines
US - California OELs: Skin designation
n-Hexane (CAS 110-54-3) Can be absorbed through the skin.
US ACGIH Threshold Limit Values: Skin designation
n-Hexane (CAS 110-54-3) Can be absorbed through the skin.
Appropriate engineering Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
controls should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level. Eye
wash facilities and emergency shower must be available when handling this product.
Individual protection measures, such as personal protective equipment
Eye/face protection Chemical respirator with organic vapor cartridge and full facepiece.
Skin protection
Hand protection Wear appropriate chemical resistant gloves. Suitable gloves can be recommended by the glove
supplier.
Other Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.
Respiratory protection Chemical respirator with organic vapor cartridge and full facepiece.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene Observe any medical surveillance requirements. When using do not smoke. Always observe good
considerations personal hygiene measures, such as washing after handling the material and before eating,
drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove
contaminants.

9. Physical and chemical properties


Appearance
Physical state Gas.
Form Aerosol.
Color Not available.
Odor Not available.
Odor threshold Not available.
pH Not available.
Melting point/freezing point Not available.
Initial boiling point and boiling 8.82 °F (-12.88 °C) estimated
range
Flash point -156.0 °F (-104.4 °C) PROPELLANT estimated
Evaporation rate Not available.
Flammability (solid, gas) Not applicable.
Upper/lower flammability or explosive limits
Flammability limit - lower Not available.
(%)
Flammability limit - upper 7.7 % estimated
(%)
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure 30 - 50 psig @70F estimated
65 - 85 psig @130F estimated
Vapor density Not available.

Product name: 10 OZ MAGIC QUACK DECOY RESTORER 12PK SDS US

Product #: 1000037655 Version #: 01 Issue date: 06-19-2018 4 / 10


Relative density Not available.
Solubility(ies)
Solubility (water) Not available.
Partition coefficient Not available.
(n-octanol/water)
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not available.
Other information
Explosive properties Not explosive.
Oxidizing properties Not oxidizing.
Percent volatile 40 % estimated
Specific gravity 0.642 estimated

10. Stability and reactivity


Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous Hazardous polymerization does not occur.
reactions
Conditions to avoid Avoid temperatures exceeding the flash point. Contact with incompatible materials.
Incompatible materials Strong oxidizing agents. Nitrates. Fluorine. Chlorine.
Hazardous decomposition No hazardous decomposition products are known.
products

11. Toxicological information


Information on likely routes of exposure
Inhalation May cause damage to organs through prolonged or repeated exposure by inhalation. May cause
drowsiness and dizziness. Headache. Nausea, vomiting.
Skin contact Causes skin irritation.
Eye contact Direct contact with eyes may cause temporary irritation.
Ingestion Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious
chemical pneumonia.
Symptoms related to the Aspiration may cause pulmonary edema and pneumonitis. May cause drowsiness and dizziness.
physical, chemical and Headache. Nausea, vomiting. Skin irritation. May cause redness and pain.
toxicological characteristics
Information on toxicological effects
Acute toxicity May be fatal if swallowed and enters airways. Narcotic effects.
Components Species Test Results
Butane (CAS 106-97-8)
Acute
Inhalation
LC50 Mouse 1237 mg/l, 120 Minutes
52 %, 120 Minutes
Rat 1355 mg/l
n-Hexane (CAS 110-54-3)
Acute
Dermal
LD50 Rabbit > 2000 mg/kg, 4 Hours
> 5 ml/kg, 4 Hours
Inhalation
LC50 Rat > 5000 ppm, 24 Hours
> 31.86 mg/l

Product name: 10 OZ MAGIC QUACK DECOY RESTORER 12PK SDS US

Product #: 1000037655 Version #: 01 Issue date: 06-19-2018 5 / 10


Components Species Test Results
73860 ppm, 4 Hours
Oral
LD50 Rat 24 ml/kg
24 g/kg
Wistar rat 49 g/kg
Propane (CAS 74-98-6)
Acute
Inhalation
LC50 Mouse 1237 mg/l, 120 Minutes
52 %, 120 Minutes
Rat 1355 mg/l
658 mg/l/4h

* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation Causes skin irritation.
Serious eye damage/eye Direct contact with eyes may cause temporary irritation.
irritation
Respiratory or skin sensitization
Respiratory sensitization Not a respiratory sensitizer.
Skin sensitization This product is not expected to cause skin sensitization.
Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
IARC Monographs. Overall Evaluation of Carcinogenicity
Not listed.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not regulated.
US. National Toxicology Program (NTP) Report on Carcinogens
Not listed.
Reproductive toxicity Suspected of damaging fertility.
Specific target organ toxicity - May cause drowsiness and dizziness.
single exposure
Specific target organ toxicity - May cause damage to organs through prolonged or repeated exposure.
repeated exposure
Aspiration hazard May be fatal if swallowed and enters airways.
Chronic effects May cause damage to organs through prolonged or repeated exposure.

12. Ecological information


Ecotoxicity Toxic to aquatic life with long lasting effects.
Components Species Test Results
n-Hexane (CAS 110-54-3)
Aquatic
Fish LC50 Fathead minnow (Pimephales promelas) 2.101 - 2.981 mg/l, 96 hours

* Estimates for product may be based on additional component data not shown.
Persistence and degradability No data is available on the degradability of this product.
Bioaccumulative potential
Partition coefficient n-octanol / water (log Kow)
2-Methylpentane 3.74
Butane 2.89
n-Hexane 3.9
Propane 2.36

Product name: 10 OZ MAGIC QUACK DECOY RESTORER 12PK SDS US

Product #: 1000037655 Version #: 01 Issue date: 06-19-2018 6 / 10


Mobility in soil No data available.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.

13. Disposal considerations


Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents
under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into
sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used
container. Dispose of contents/container in accordance with local/regional/national/international
regulations.
Local disposal regulations Dispose in accordance with all applicable regulations.
Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues / unused Dispose of in accordance with local regulations. Empty containers or liners may retain some
products product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal. Do not re-use empty containers.

14. Transport information


DOT
UN number UN1950
UN proper shipping name Aerosols, flammable, (each not exceeding 1 L capacity)
Transport hazard class(es)
Class 2.1
Subsidiary risk -
Label(s) 2.1
Packing group Not applicable.
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
Special provisions N82
Packaging exceptions 306
Packaging non bulk None
Packaging bulk None
This product meets the exception requirements of section 173.306 as a limited quantity and may be shipped as a limited quantity.
Until 12/31/2020, the "Consumer Commodity - ORM-D" marking may still be used in place of the new limited quantity diamond
mark for packages of UN 1950 Aerosols. Limited quantities require the limited quantity diamond mark on cartons after 12/31/20
and may be used now in place of the "Consumer Commodity ORM-D" marking.
IATA
UN number UN1950
UN proper shipping name Aerosols, flammable
Transport hazard class(es)
Class 2.1
Subsidiary risk -
Label(s) 2.1
Packing group Not applicable.
Environmental hazards Yes
ERG Code 10L
Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Read safety
instructions, SDS and emergency procedures before handling.
Other information
Passenger and cargo Allowed with restrictions.
aircraft
Cargo aircraft only Allowed with restrictions.
Packaging Exceptions LTD QTY
IMDG
UN number UN1950
UN proper shipping name AEROSOLS
Transport hazard class(es)
Class 2.1
Subsidiary risk -
Label(s) None
Product name: 10 OZ MAGIC QUACK DECOY RESTORER 12PK SDS US

Product #: 1000037655 Version #: 01 Issue date: 06-19-2018 7 / 10


Packing group Not applicable.
Environmental hazards
Marine pollutant Yes
EmS F-D, S-U
Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Read safety
instructions, SDS and emergency procedures before handling.
Packaging Exceptions LTD QTY
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78 and
the IBC Code
DOT

IATA; IMDG

Marine pollutant

General information DOT Regulated Marine Pollutant. IMDG Regulated Marine Pollutant.

15. Regulatory information


US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
n-Hexane (CAS 110-54-3) Listed.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not regulated.

Product name: 10 OZ MAGIC QUACK DECOY RESTORER 12PK SDS US

Product #: 1000037655 Version #: 01 Issue date: 06-19-2018 8 / 10


Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - Yes
Delayed Hazard - Yes
Fire Hazard - Yes
Pressure Hazard - Yes
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous No
chemical
SARA 313 (TRI reporting)
Chemical name CAS number % by wt.
n-Hexane 110-54-3 20 - 40
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
n-Hexane (CAS 110-54-3)
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Butane (CAS 106-97-8)
Propane (CAS 74-98-6)
Safe Drinking Water Act Not regulated.
(SDWA)
US state regulations
US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100)
Not listed.
US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd.
(a))
Butane (CAS 106-97-8)
n-Hexane (CAS 110-54-3)
US. Massachusetts RTK - Substance List
2-Methylpentane (CAS 107-83-5)
Butane (CAS 106-97-8)
n-Hexane (CAS 110-54-3)
Propane (CAS 74-98-6)
US. New Jersey Worker and Community Right-to-Know Act
2-Methylpentane (CAS 107-83-5)
Butane (CAS 106-97-8)
n-Hexane (CAS 110-54-3)
Propane (CAS 74-98-6)
US. Pennsylvania Worker and Community Right-to-Know Law
2-Methylpentane (CAS 107-83-5)
Butane (CAS 106-97-8)
n-Hexane (CAS 110-54-3)
Propane (CAS 74-98-6)
US. Rhode Island RTK
Butane (CAS 106-97-8)
n-Hexane (CAS 110-54-3)
Propane (CAS 74-98-6)
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain
any chemicals currently listed as carcinogens or reproductive toxins.
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australia Australian Inventory of Chemical Substances (AICS) Yes
Canada Domestic Substances List (DSL) Yes
Canada Non-Domestic Substances List (NDSL) No
China Inventory of Existing Chemical Substances in China (IECSC) Yes
Europe European Inventory of Existing Commercial Chemical No
Substances (EINECS)

Product name: 10 OZ MAGIC QUACK DECOY RESTORER 12PK SDS US

Product #: 1000037655 Version #: 01 Issue date: 06-19-2018 9 / 10


Country(s) or region Inventory name On inventory (yes/no)*
Europe European List of Notified Chemical Substances (ELINCS) No
Japan Inventory of Existing and New Chemical Substances (ENCS) No
Korea Existing Chemicals List (ECL) Yes
New Zealand New Zealand Inventory Yes
Philippines Philippine Inventory of Chemicals and Chemical Substances Yes
(PICCS)
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).

16. Other information, including date of preparation or last revision


Issue date 06-19-2018
Version # 01
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
Revision information Product and Company Identification: Product and Company Identification

Product name: 10 OZ MAGIC QUACK DECOY RESTORER 12PK SDS US

Product #: 1000037655 Version #: 01 Issue date: 06-19-2018 10 / 10

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