F5S Chemistry Revision Worksheet (6)– Double decomposition

4g of marble chip is added to 1M 50cm 3 HCl and the rate of reaction is measured, with the acid being 25 oC.
(a) Write balanced chemical equation for the reaction occurring. ____________________________________________________________________________
(b) Write the ionic equation of the reaction. ____________________________________________________________________________________________
(c) State three methods of monitoring the rate of reaction.
__________________________________________________________________________________________________________________________________________
__________________________________________________________________________________________________________________________________________
____________________________________________________________________________________________________________
(d) One of the methods involves the use of graduated gas syringe, while the other requires the use of electronic balance. Draw the two apparatus required.

(e) Which of the reactants is in excess? Show by calculation. (f) Calculate the maximum volume of CO2 that can be collected at r.t.p..

(g) A student monitors the rate by measuring the volume of CO2 formed along time. Sketch a graph of volume of CO2 collected against time of reaction.
(h) For each of the following cases, copy the graph in (g) and sketch a new line to represent the effect of the changing conditions.
Original condition: Effect on rate Reason for Effect on volume of Time required to form Sketch Graph
4g of marble chip + 1M 50cm3 HCl + 25oC. effect on rate CO2(g) formed all CO2
1. 4g of marble chip + 1M 50cm3 HCl + 15oC.

2. 4g of marble chip + 1M 50cm 3 HCl + 50oC.

3. 4g of marble powder + 1M 50cm 3 HCl + 25oC.

4. 1g of marble chip + 1M 50cm 3 HCl + 25oC.

5. 6g of marble chip + 1M 50cm 3 HCl + 25oC.

6. 6g of marble powder + 1M 50cm3 HCl + 25oC.

7. 4g of marble chip + 2M 50cm 3 HCl + 25oC.

8. 4g of marble chip + 0.5M 50cm 3 HCl + 25oC.

9. 4g of marble chip + 1M 25cm 3 HCl + 25oC.

2.
Draw the energy profile for an exothermic reaction. Mark the activation energy Draw the energy profile for an endothermic reaction. Mark the activation energy
without catalyst with Ea and the activation energy with catalyst with Ea’. without catalyst with Ea and the activation energy with catalyst with Ea’.

3. State collision theory.

__________________________________________________________________________________________________________________________________________
__________________________________________________________________________________________________________________________________________
4. State the five factors affecting the rate of reaction and explain with kinetic theory.

Factors Explanation, using kinetic theory

1. Major Reason
___________________________________________________________________________________________________________________________
___________________________________________________________________________________________________________________________
Minor Reason
___________________________________________________________________________________________________________________________

2.
___________________________________________________________________________________________________________________________
___________________________________________________________________________________________________________________________

3.
___________________________________________________________________________________________________________________________
___________________________________________________________________________________________________________________________

4.
___________________________________________________________________________________________________________________________
___________________________________________________________________________________________________________________________

5.
___________________________________________________________________________________________________________________________
___________________________________________________________________________________________________________________________

5. Draw the Maxwell Boltzmann Distribution curve to show the effect of the following changes on the rate of reaction.
(a) increases temperature from T1 to T2 (b) Decreases temperature from T 1 to T2 (c) Addition of catalyst
6. The reaction between sodium thiosulphate and hydrochloric acid can be used to study the effect temperature or concentration on rate of reaction. A student
uses this method.
 Place 20cm3 of sodium thiosulphate solution and 20cm3 of water in a conical flask
 Add 10cm3 of dilute hydrochloric acid to the flask
 Place the flask on a piece of paper marked with a black X
 Time how long it takes before the X can no longer be seen

Before, starting the experiment, the student considers the risk to her of sulphur dioxide escaping from the flask.
(a) Draw the apparatus required. (2) (b) Write the chemical equation and ionic equation of the reaction between the two solutions. (2)

(c) Using the following information, explain whether any sulphur dioxide escapes from the flask. (3)
Solubility of SO2 at room temperature = 100g /dm3
Concentration of sodium thiosulphate solution =
0.300mol/dm3
Volume of sodium thiosulphate solution = 20cm3
Volume of water = 20cm3
Volume of hydrochloric acid = 10cm3

(d) Is it necessary to perform the experiment in fume cupboard? (1)_________________________________________________________________________

(e) At what point in the experiment should the student have started a timer? (1) _______________________________________________________________
She repeats the experiment to study the effect of temperature on rate of reaction.
(f) State two variables that have to be kept constant so that the determination is valid. (2) _______________________________________________________

(g) She records the time for the cross to disappear and plotted these data against temperature, as shown on the graph on the left.
She then calculates the rate at different temperature and plot the graph on the right.

(h) For the graph on the left, the result at (14, 42) is anomalous. Explain one mistake the student may have made to cause this anomalous result. (1)
_____________________________________________________________________________________________________________________________
(i) For the graph on the right, suggest two reasons why the results are least accurate at higher temperatures. (2)
_____________________________________________________________________________________________________________________________
_____________________________________________________________________________________________________________________________
(j) There are two reasons why rate of reaction increases with temperature. Explain the major reason. (2)
_____________________________________________________________________________________________________________________________
_____________________________________________________________________________________________________________________________
(k) Another student uses the same reaction to study the effect of changing concentration of the sodium thiosulphate solution on the rate of reaction. Give two
variables that the student must control in this investigation to obtain valid results. (2)
7. Five sets of experiment were carried out to study the rate of reaction of excess limestone with nitric acid.
Test Temperature (OC) Chemicals used
1 25 limestone chips + 100cm3 of 1M nitric acid
2 25 limestone chips + 200cm3 of 1M nitric acid
3 25 limestone chips + 100cm3 of 2M nitric acid
4 15 limestone chips + 100cm3 of 1M nitric acid
5 25 Powdered limestone + 200cm3 of 1M nitric acid

The volume of gas given off was measured over time for test 1 and a graph was then plotted as shown below.
(a) Write a chemical equation for the reaction.
(b) Draw a labeled set-up for the experiment.
(c) How long did it take for the reaction in test 1 to complete?
(d) What is the final volume of gas collected?
(e) Draw your expected graphs for tests 2, 3, 4 and 5 on the same graph. Explain your answer.

___________________________________________________________________________
___________________________________________________________________________
___________________________________________________________________________
___________________________________________________________________________
___________________________________________________________________________
___________________________________________________________________________
___________________________________________________________________________
___________________________________________________________________________
___________________________________________________________________________
___________________________________________________________________________
___________________________________________________________________________
___________________________________________________________________________
1. When manganese(IV) oxide is used in the decomposition of 2. Which of the following property can be measured to 3. At the beginning of a reaction, the rate is
potassium chlorate(V) to prepare O2(g) , the enthalpy change for the determine the rate of chemical reaction? A. largest and remain constant
decomposition of potassium chlorate(V) A. change in mass B. smallest then increases
A. changes from exothermic to endothermic B. change in colour C. largest then decreases
B. becomes more exothermic C. change in pressure D. the same as the final rate
C. becomes more endothermic D. all of the above depending on the reaction
D. stays the same

4. The energy barrier that must be overcome for the forward reaction to occur is called the (1) and iit is the difference between (2).
A B C D
1 Enthalpy change Enthalpy change Activation energy Activation energy
2 I and II I and III I and II I and III

5. Given that A + B  C + D ∆H = +947.7kJ. In the this reaction, energy is (1) the surroundings because the bonds in the products contain (2) energy than the reactants.
A B C D
1 Released to Absorbed from Released to Absorbed from
2 Less kinetic More kinetic Less potential More potential

6. Given that 2C2H2(g) + 3H2(g)  C2H4(g) + C2H6(g) ∆H = -486.4kJ, which represents the energy changes for both catalyzed and uncatalyzed reactions?
A B C D