Metallic Bonding: Positive Metal Ions and The Delocalised Electrons

Metallic bonding
Metals consist of giant lattices of metal ions in a sea of delocalised electrons
Definition: A metallic bond is the electrostatic force of attraction between the

positive metal ions and the delocalised electrons
sodium
The positive ions are formed when the outer electrons become detached from the atom , leaving a
positive ion behind. The electrons that leave the atom, join in the sea of delocalised electrons. The
metal ions are arranged in a lattice
Metals have high melting points because the strong electrostatic forces between positive ions
and sea of delocalised electrons require a lot of energy to break
The three main factors that affect the strength of a metallic bond are:
1. Number of protons/ Strength of nuclear attraction.
The more protons the stronger the bond
2. Number of delocalised electrons per atom (the outer shell electrons are delocalised)
The more delocalised electrons the stronger the bond
3. Size of ion.
The smaller the ion, the stronger the bond.
Example
Mg has stronger metallic bonding than Na and hence a higher
melting point. The Metallic bonding gets stronger because in Mg
there are more electrons in the outer shell that are released to the
sea of electrons. The Mg ion is also smaller and has one more
proton. There is therefore a stronger electrostatic attraction
between the positive metal ions and the delocalised electrons
and higher energy is needed to break bonds.
magnesium
Conductivity of electricity
Metals can conduct electricity well because the delocalised valence electrons can move throughout the
structure in all directions.
Conductivity of heat
Metals can conduct heat well. There is a strong connection between a metal’s ability to conduct heat and
electricity. This suggests the delocalised valence electrons are mainly responsible for conducting heat
through a metal. Energy is conducted through a metal by more energetic electrons colliding and passing on
their energy to less energetic electrons
Malleability and Ductility

A malleable material is one that may be beaten or pressed into new shapes. A ductile material is one
that can be drawn into wires and made thinner through stretching .
Metals are malleable and ductile because the positive ions in the lattice are all identical. So the
planes of ions can slide easily over one another. The attractive forces in the lattice are the same
whichever ions are adjacent
N Goalby chemrevise.org 1
Metallic Crystals
The metal cations are held in place by a sea of

delocalised electrons. The cations are packed as
closely as possible.
Typical properties of metals
• High melting points (metallic bonding is a

strong type of bonding)
• Malleable
• Conductors of electricity (the delocalised
electrons will flow when a potential difference
is applied across it)
• Shiny (due to delocalised electrons causing
light to be reflected)
Metallic bonding Questions
1) Describe the bonding in a metal

Describe the crystal structure of a metal (use a diagram to show the structure)
2 Draw diagrams that show how the particles are arranged in a crystal of sodium and aluminium. You
should identify the particles and show a minimum of six particles in a two-dimensional diagrams.
3) Explain why Metallic substances:
i) usually have high melting and boiling points
ii) can conduct electricity
iii) are malleable and ductile
4) What 3 factors affect the strength of a metallic bond?
5) a) Explain why the melting point of potassium is lower than that of sodium.
b) Explain why the melting point of magnesium is higher than that of sodium.
c) Explain why the melting point of aluminium is higher than the melting point of sodium.
6) Suggest a reason why aluminium is a better conductor of electricity than magnesium.
7) Silver and sodium chloride melt at similar temperatures. Describe the physical properties of silver
which are different from those of sodium chloride and, in each case, explain why the property of silver is
different from that of sodium chloride.
8) Find out about the different structures that exist in different metals and describe the different
structures
Metallic Lattices
Some of the simplest crystal structures are those of metals where all particles are identical.
There are three major types of metallic lattice. Two of these involve the close packing of particles; the
third involves cubic packing of particles :
Almost all metals crystallise in one or more of these systems. The close packed structures account for
about 50 metals; cubic packing accounts for about 20 metals.
HEXAGONAL CLOSE PACKING (HCP)

CLOSE PACKING
CUBIC CLOSE PACKING (CCP)
CUBIC PACKING BODY CENTRED CUBIC (BCC)
There is no obvious relationship between structural type and position in the periodic table.
In the both close packed arrangements a given sphere has 12 other spheres in contact with it. It is said to
have 12 co-ordination or a co-ordination number of 12.
Hexagonal Close Packing (HCP)
A In hexagonal close packing

the metal ions are arranged in A
layers. The second layer (B) sits
in the holes above the first
B layer(A). B
The pattern continues ABABAB
A
A
Mg, Zn, Cd all have HCP structures

This is unit-cell
representation for
The unit-cell representation is hexagonal close
defined as the simplest repeating packing
unit of the lattice which displays
the full symmetry of the crystal
Cubic Close Packing CCP
A
C
In Cubic Close Packing the layer
are arranged differently from C
hexagonal close packing. The
second layer (B) sits in the holes
B above the first layer(A)in the same
way but the third layer does not sit
B
above the first. The third layer is
displaced over and is called layer
A (C).
The pattern continues A
ABCABCABC
This is unit-cell representation for

cubic close packing. This packing is
also called face centred cubic
packing. You can see there are
particles at the centre of each face of
the unit cell.
Cu, Ag, Au, Al, Pb all have CCP packing
In body centred packing each sphere is in contact with 8

others and is said to have 8 co-ordination or a co-
ordination number of 8.
Examples: Group1 metals

many transition metals

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Metallic bonding

Metals consist of giant lattices of metal ions in a sea of delocalised electrons

Definition: A metallic bond is the electrostatic force of attraction between the

Malleability and Ductility

The metal cations are held in place by a sea of

Typical properties of metals

• High melting points (metallic bonding is a

Metallic bonding Questions

1) Describe the bonding in a metal

3) Explain why Metallic substances:

i) usually have high melting and boiling points

ii) can conduct electricity

iii) are malleable and ductile

4) What 3 factors affect the strength of a metallic bond?

6) Suggest a reason why aluminium is a better conductor of electricity than magnesium.

HEXAGONAL CLOSE PACKING (HCP)

CUBIC PACKING BODY CENTRED CUBIC (BCC)

Hexagonal Close Packing (HCP)

A In hexagonal close packing

Mg, Zn, Cd all have HCP structures

This is unit-cell representation for

Cu, Ag, Au, Al, Pb all have CCP packing

In body centred packing each sphere is in contact with 8

Examples: Group1 metals

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