Geology of The Kitsault Molybdenum Deposit, British Columbia
Geology of The Kitsault Molybdenum Deposit, British Columbia
Geology of The Kitsault Molybdenum Deposit, British Columbia
Abstract
0361-0128/85/377/57-1552.50 57
58 ROGER C. STEININGER
EXPLANATION
Hazelton
Formation• Alice
ArmIntrusives
Bowser
LakeGroup • Basalt
Flow
Coastal
Plutonic ScaleI:250•000
Complex
FIG. l. Geology of the Alice Arm area and location of the Kitsault deposit.
lesser amounts of quartz monzonite are common. swarm,there may be ten to hundredsof dikes per
Wanlesset al. (1966) reported a 47 _ 1.2-m.y. date kilometer, but between swarms,lamprophyresare
for a quartz monzonite along Observatory Inlet, rare if not absent.Individual dikes vary in thickness
whereas dates from 79 to 40 m.y. from intrusive from a few centimeters to 30 m, with the majority
bodiesalongthe easternmarginof the complexhave being i to 3 m thick. Strikesof N 35 ø E to N 80 ø
been reported (Wheeler and Gabrielse,1972). In- E anddipswithin 10ø of verticalare common.These
trusionsalongthe easternmargin of the CoastPlu- swarms seem to center on the earlier intrusive
tonic Complexhave produceda hornfelsaureolein eventsin the region, and particularlyon the Alice
the Bowser Lake and Hazelton Formations as much Arm Intrusives.
as 1.5 km outward from the contact. Numerous Recent plateau-type olivine basalt
Adjacent on the eastto the CoastPlutonit Com- flows,cinder cones,and feeder dikes occurthrough-
plex are a group of 50 to 55-m.y.-old intrusions, out the area. Age dates indicate that this igneous
principallystockswith associated
molybdenite,that activity is approximatelyone million yearsold.
have been referred to as the Alice Arm Intrusives
(Carter, 1981). A commonfeatureof theseintrusions Kitsault Geology
is that the oldest phase is the most marie and the The Upper Jurassicto Lower CretaceousBowser
later phasesare more siliceous,principally quartz LakeGroup(Richards,1983) hoststhe EarlyTertiary
monzonite. Molybdenite related to the Lime Creek Lime Creek Intrusive Complex. The oldest recog-
Intrusive Complex is the best known and highest nizedmemberof the Complexis the EastLobe (Fig.
grade of this group. Other significantmineralized 2), whichis succeededby the Borderstock,Southern
systemsinclude BoundyCreek, Bell Moly, Tidewa- stock, Central stock,and NortheastPorphyry and
ter, and Ajax (Dak Biver). The other membersof Intramineral dikes. Mineralization is related to the
the Alice Arm Intrusivecontainvisiblemolybdenite lasttwo phasesof the Lime CreekIntrusiveComplex.
but in amounts that cannot be considered mineral Postmineralization lamprophyredikes and basalt
resourcesat the present time. flows are commonin and near the deposit.
West-central British Columbia and southeast At Kitsault the Bowser Lake Group consistsof
Alaskaare characterizedby numerous35-m.y.-old interbeddedargilliteandgraywackewith minorcon-
lamprophyredike swarms.Smith (1973) suggests glomerateand limestone.Individual beds vary in
that these dikes are chemicallysimilarto vogesite thickness from a few centimeters to several meters.
and spessartitebut are petrographicallyclassifiedas Regionally,the BowserLake Group hasa northwest
odinitc or spessartite.Most of the lamprophyres strikeand a steepnortheastdip, althoughthis trend
occur in northeast-trendingdike swarmsa few kilo- is interruptedby small-scale
folds.Typical graywacke
meterswide and severalkilometerslong. Within a at Kitsaultconsistsof 40 percentangularchert and
EXPLANATION
N ::!!• Central
Stock
?.'• Southern
Stock
XxX•1Border Stock
".•"--•EaslLobe
•-• Hornfels
•Bowser LakeGroup
(%)
Plagioclase 55 51 55 42 45 41 38
An Ana,Anas Ana6 Anas Anas An34
Alkali feldspar 2 11 12 23 21 22
Quartz 9 17 14 21 23 30
Biotite 10 16 14 10 6 6 36
Amphibole 19 1 2 3 26
Sphene 1 1 1 1 1 tr
Apatite I 1 tr 1 tr tr
Zircon tr tr tr tr tr tr
Monazite tr tr tr tr tr
Opaques 3 2 2 2 1 1
that the 53-m.y. date reflectsthe age of mineraliza- alaskites because of their lack of marlcs. However,
tion, whereasthe older datesrepresentthe period becausethe aplitic texture is most common,aplite
of intrusiveactivity. is a more suitableterm, althougha completerange
Aplite: Numerous aplite dikes are common of texturesfrom felsite to pegmatitecan be found.
throughoutthe Lime Creek Intrusive Complexand Labeling these units "dikes" is also a misnomer,
in particular in the northern and western portions sincetheir form varies from irregular pods to true
(Figs.3 and 4). Thesedikeswere previouslycalled through-going dikelikebodies.The aplitephasecuts
ppm
Rb/K20 68 43 35 46 42 54 52 53
Na•O + R20 1.20 2.69 2.65 2.98 4.42 3.55 3.69 3.05
CaO
105,200
E
Line
of
section •
EXPLANATION
Lamprophyre Dikes
Intromineral Dikes ond
• Northeost
Porphyry
Stock
J---'---1
Aplite
• Centrol
Stock
•.,• Southern
Stock
¾•-• BorderStock
."_.•
: Hornfels
150
METERS
FIG. 3. Generalizedgeologyof the northern part of the Lime Creek Intrusive Complex.
the Central and Border stocksand is cut by the portionof the complexandhasbeenintersected by
Intramineral dikes, thus placing its apparent age only a few drill holes.Its true distributionis imper-
between the Central stock and the Northeast Por- fectly known. The Intramineral dikes occur as a
phyry, althoughit maybe a late differentiatedphase series of dikes that appear to be related to the
of the Central stock. NortheastPorphyry for the following reasons:(1)
The chemistry of the aplite is summarizedin their mineralogicaland chemicalsimilarity(Tables
Table 3. One of its distinctive characteristics is 2 and 3), (2) similarityof relative age relationships
disseminatedmolybdenitethat appearsto be a pri- with respectto molybdenummineralization,(3) the
mary rock-formingmineral.Alsopresentare incipi- abundance of Intramineral dikes near the Northeast
ent quartz veinsthat appearto have crystallizedas Porphyry and their decreasein abundanceaway
part of the magma. The presence of these two from the stock, and (4) the lack of crosscutting
featuressuggests that the aplite is a transitionphase relationships
betweenthe two units.
between a true igneousstageand the first hydro- Carter (1981) reportsa date of 53.7 _ 1.7 m.y.
thermal event. Mineralogically,the aplite has an for the Intramineraldikesand 48.3 _ 1.6 m.y. for
equigranular texture, composed of plagioclase, the NortheastPorphyry.Sincehis descriptionsug-
quartz, alkali feldspar,and minor biotite. geststhat both rocksare altered, it is possiblethat
Northeast Porphyry and Intramineral dikes: The both dateswere reset by hydrothermalevents.
NortheastPorphyry and related Intramineral dikes Petrographicand mineralogicsummariesfor both
are the youngestrecognizedmembersof the Lime unitsare presentedin Tables2 and 3. The distinctive
Creek Intrusive Complex. The NortheastPorphyry characteristic of the Intramineral dikes and Northeast
forms a stocklikebody at depth in the northeast Porphyryis their texture. Theserocksare the only
EXPLANATION
Lomprophyre Dikes
IntrominerolDikesand
Northeast Porphyry Stock
Aplite
Central
Stock
Southern
Stock
Hornfels
150 METERS
I
•800
Hydrothermal and Thermal Alteration
Associatedwith the intrusionof the early members
of the Lime Creek Complexis a contactmetamorphic
1800 zone of hornfels in the argillite and graywacke.
Hydrothermal alteration associatedwith the miner-
alization can be subdivided into a central silicified
zone that is surroundedby a zone of potassium
1600
silicate(potassic)alteration.Outward from the po-
tassic zone is a weakly developed phyllic zone.
Argillic and propylitic alterationsexistperipheralto
1400 % the phyllic zonebut are weakly developedbecause
j . they are superimposed uponthe hornfels.Generally,
the higher temperature assemblages(i.e., silicic,
potassic, andphyllic)occurasveinenvelopes.Except
1200
in areaswhere a stockworkof veins has developed
and the alteration envelopesoverlap, argillic and
propylitic alterationare commonperipheral to the
• I000 higher temperaturealterationenvelopes.
I•.
I•.
Thermal metamorphism
8OO
Thermal metamorphismis expressedasa hornfels
aureole that extendsup to 750 m away from the
intrusivecontact(Fig. 7). This aureoleis developed
in argillitesandgraywackes that are regionallymeta-
6OO morphosed to a chlorite-sericite-epidote-albite
greenschistfacies assemblage(Woodcock, 1964).
Superimposedupon the inner part of the hornfels
4OO
aureoleis a later hydrothermaloverprint.The horn-
fels itself can be subdivided into an outer weak
albite-epidotehornfelsfacies(with incipientsericite-
chlorite), a central pale-brownbiotite zone, and an
2OO inner brown biotite zone (Kamilli, 1977).
Severalmineralogicchangescan be documented
e--........
proceedingfrom the outer limit of hornfelsinward
to the stockcontact(Fig. 7). Biotite in the outer
o iI i •
2
;.
5
Cu ;4 •5 zone first appearsas pale-brown,fine-grainedmica
STOCK replacingsericite.Towardthe stock,biotite increases
FIG. 6. Minor element trends within the Lime Creek ]nttusiYe
in abundance and size and darkens to brown or
Complex. Stocknumberssameas Figure ,5. green brown before being bleachedby the hydro-
thermal overprint. Sedimentarycarbon and chert
grain boundariesdisappeartoward the intrusive
Structure
contact. Feldspar and quartz appear to be more
Geologicsections,as illustratedin Figure 4, sug- resistantto contactmetamorphiceffects,remaining
gest that the entire Lime Creek Complexis tilted assharplydefinedgrainsmuchcloserto the igneous
to the southwest.Since the youngestintrusionsare contact, but eventually they, too, lose their grain
in the northern part of the complex, they have edgeboundaries andbecomeirregularshapes.Feld-
caused a doming and tilting that produced the sparbecomesincreasinglycloudedby fine-grained
presentgeometry.The NortheastPorphyry,which allophanebut eventuallyis completelydestroyed
is the youngestknownintrusion,alsoappearsto be leavingonly cloudyrelics.
tilted, suggesting
either a later intrusionor a regional The hydrothermaloverprint is characterizedby
deformation. severalmineralogicalchanges.Sericite is coarser,
Generally,all knownfaultsconsistof gougeand segregated in patcheswith chloriteandcalcite,and
broken rock zonesup to a few meters wide with appears to be replacing metamorphic biotite.
minor normal displacement.Even though most of Bleachedzonesoccuradjacentto veinsand consist
the faultsare postmineral,little deformationof the of pale-greenchlorite, sericite,and calcite.Epidote
orebodyis known.Mostfaultsstrikenortheastand in veinsandasmatrixreplacementsis mostabundant
dip northwest,a trend that was also followedby toward the inner part of the hornfelsaureole.The
late veinsand lamprophyredikes. assemblagechlorite, calcite, epidote, and sericite
KITSAULT MOLYBDENUM DEPOSIT 65
EXPLANATION
: Sedimentary
carbon
chert edges d•soppeor
Plogioclosetwinning begins
to disappear end quartz feld-
spar edges disappear.
..... Chert becomes indistinct
METERS ' "' '"'•"•;•]•';:;'
;;•" ' ----• Quartz-feldsp.r
bec
....
I I I indistinct
probablyrepresentsthe propylitic zone associated ized by white clay, which is generallya combination
with hydrothermal alteration.Sincethe hydrothermal of sericiteand kaolin group minerals.Both of these
fluidswere attackinga refractorymetamorphicrock, layered silicatesreplace plagioclaseand marlcsbut
the developmentof low-temperaturehydrothermal have little or no effect on quartz and alkali feldspar.
alterationwasinhibited,thereforeproducingonly a Phyllic: Phyllic alteration occurs as envelopes
poorly developedpropyliticzone. associatedwith quartz-pyrite-scheeliteveins in a
zone that is peripheralto, and partly superimposed
Hydrothermal alteration upon, the hangingwall of the orebody(Figs. 8 and
Propylitic:Propylitic alteration is commonpe- 9). These envelopesare dark siliceouszones that
ripheral to higher temperaturevein alterationen- are seldommore than a few millimeterswide. Pyrite
velopeswithin the orebody and superimposedon and scheeliteare so erratically distributed in the
the hornfelsaureole.Propyliticalterationof hornfels veinsthat in placesthey appearto be barren quartz
is describedin the precedingsection.Within the veins.
intrusiverocks,the mostabundantpropyliticalter- Within the phyllic envelopes,the rock is com-
ation minerals are sericite and carbonate and minor pletely replacedby a fine-grainedmixtureof quartz,
chlorite and epidote. Generally, plagioclaseis re- sericite, and/or pyrite. This alteration affects all
placed by sericite and carbonate. The sericite is igneousminerals except primary quartz, although
actually a fine-grainedwhite mica that may be quartz overgrowthshave been observed.
paragonite.Biotite is commonlyreplacedby a mix- Potassic:Potassicalteration (K-feldspathization),
ture of chlorite,sericite,opaques,and epidote.The i.e., alkalifeldsparreplacementwith minorsecondary
other primary igneousminerals,quartz and alkali biotite, occursas envelopesalong the marginsof
feldspar,appear to be unaffectedby this type of barren quartz veins. With increasingalteration in-
alteration. tensity the color changesfrom a vivid pink, to a
Argillic: Argillicalterationis commonthroughout light pinkishtint, to white in the pervasivezones.
the orebody,generallyas isolatedpatchesbetween Plagioclase is the firstmineralreplaced,followedby
highertemperaturealterationtypes,althoughthere biotite. The last stage of this alteration was the
is a slight increasein intensity of this type of developmentof secondaryrims on primary alkali
alterationtoward the outer marginof the ore zone feldspar grains. Although plagioclaseis replaced
and in one strong zone in the west part of the first, most patchesof potassicalteration contain at
orebody.This latter area appearsto be fault related least a few remnants of unaltered or sericitized
andischaracterized by greenclaywhichisa mixture plagioclase.Secondarybiotite occursas small unal-
of montmorillonite and sericite.Fault-relatedargil- tered anhedralgrainsscatteredthroughoutthe more
lizationis superimposed uponthe earlierhydrother- intenselyfeldspathizedrock. Where primary and
mal alteration and may represent the alteration secondarybiotite are in closeproximity,the former
relatedto the waninghydrothermalfluids. is propylitically altered whereas the later is unal-
Typical argillic alterationassociatedwith the mo- tered, suggesting that propyliticalterationpreceded
lybdenum-bearing hydrothermalstagesis character- potassicalteration.
66 ROGER C. STEININGER
Line of Section
105,200E
EXPLANATION
•0 I 5'0MoS2
• Phylhc
•'• Feldspathizalion
•_:•:• Silicificafion
.... Hornfels- Stock
Contacl
150
I METERS
FIG. 8. Generalized plan of hydrothermal alteration.
• $
6lOrn-
phyry and related Intramineral dikestook place and
wasfollowedby stageII mineralizationwhich again
consisted,ofthree types of veins similar to those of
stageI. No apparentdifferencehasbeen identified
in the order, style, or characteristics
between these
two stagesof mineralizationexceptfor the crosscut-
:505 m-
ting relationshipsof the Intramineral dikes.
Next camethe emplacementof the third vein set
EXPLANATION
(stageIII) startingwith quartz veins with associated
potassicalterationenvelopesfollowed by quartz-
• •0.1% MoS2
molybdeniteveins that are characteristicallywide
• Phyllic with ribbonsof molybdenite.Theseveinsare cut by
•,• Feldspathization quartz-pyriteveinswith or without scheelite.
o 15o METERS
_-_--_-•Silicification FollowingstageIII mineralizationare polymetallic
I I I I .... sulfideveinsof stageIV which are characterizedby
Central Stock
Contact
through-goingquartz veins that may containone or
FiG. 9. Generalized hydrothermal alteration distribution more of the following minerals:sphalerite,galena,
along section 105,200 east. chalcopyrite,lead-bismuthsulphosalts,tetrahedrite,
KITSAULT MOLYBDENUMDEPOSIT 67
StageIV mineralization
Carbonate
Quartz-polymetallic
StageIII mineralization
Quartz-pyrite-sc
Quartz-bandedmolybdenite
Quartz
Quartz-pyrite-scheelite
StageII mineralization Quartz-molybdenite
Quartz
Lime
Creek
Stage I mineralization
Quartz-pyrite-sc
Quartz-molybdenite
Quartz
Intrusive
Central stock--aplites (53.3 __-1.4 m.y.)
Complex
Southern stock
Border stock
East Lobe
Line
of
Section
105,200
E
EXPLANATION
>0 I MoS2
• Quartz-pyrde
veining
• Quartz-molybdenite
stockwork
i•.• Quartz
veining
.... Hornfels- Stock
Contact
forminglocalizedpodsthat are not continuousover nite zone(Figs.12 and 13). Informationis sketchy
greatdistances.With depth eventhe 0.20 percent aboutpyritedistribution,but it probablyoccursin
MoS2 zone becomes less continuous. As shown on a shellthat mimicsthe shapeof the molybdenite
the crosssection(Fig. 13), the boundariesof the zoneandmayaverageapproximately 1 percent.
0.10 percent zone are generally regular, whereas Pyrrhotite:Pyrrhotiteis mostabundantlydissem-
the 0.20 percentand0.30 percentzonesare erratic inatedthroughthehornfelsaureolesurrounding the
and sinuous.Mineable reservesare placedat 115 LimeCreekIntrusiveComplexandprobablyformed
milliontonsof 0.19 percentMoS2(AMAX, 1982). duringmetamorphism. Rarequartz-pyrrhotiteveins
Pyrite: Pyrite is commonlyfound in quartz veins, are scatteredthroughoutthe Kitsaultdeposit,both
asfracturecoatings,disseminated in intrusiverocks, within the molybdenitezone and within the barren
andaserraticallydistributedclotsandaggregates in central zone. Also presentin the hornfelsaureole
polymetallicveins.Within quartz veinsand as frac- are isolated1- to 10-cm-widequartz-pyrrhotite
and
ture coatings,individualdisseminated grainsvary in pyrrhotiteveinsthat appearto predatethe thermal
size from less than 0.05 mm to as much as 3 ram. metamorphism andhavea moreregionalextentthan
Aggregatesof pyrite up to 2 cm wide are most do the other pyrrhotiteveins.
commonin the polymetallicveins. Pyrite is most Scheelite:Scheelitecommonlyoccursin quartz-
abundanton the hanging-wall
sideof the molybde- pyrite veinson the hanging-wall sideof the molyb-
denitc zone (Figs. 10 and 11). Individual scheelite
grainsare generallylessthan 2 mm across,have an
N averagesize of approximately1 mm, and are errat-
305
EXPLANATION
>0.1% Mo S2
i[•T'-•T• Quortz
- pyriteveining METERS
• Quortz -molybdenite
stockwork
610m .610m
305 305 m
EXPLANATION
• (0.10
%MoS2
• ß OJO-O.19
%MoS
2
• 0,20-0.29%MoS2
•:•'••0 30%MoS
2
o 15o METERS
L I I J
removedlarge portionsof the Lime Creek Intrusive Holland, P. T., 1976, Lead at Kitsault: Golden, Colorado, Climax
Complexand its related mineralization. MolybdenumCo., unpub.rept. May 24, 1976, 8 p.
Kamilli, D., 1977, Mineralogic changesin contact aureoles
Acknowledgments around selected molybdenum-bearingintrusions: Golden,
Colorado,ClimaxMolybdenumCo., unpub. rept. December,
The understanding of Kitsaultgeologyhasevolved 1977, 125 p.
throughthe studiesof numerousgeologists employed Richards,T., 1983, Cretaceous-Tertiarymineralization across
the Skeenaarch, westcentralBritishColumbialabs.I:Canadian
by Kennecottand Climax.Of particularnote are the Mining Metallurgy Bull., v. 76, no. 857, p. 46.
studiesby R. J. Woodcock,Robert Galbraith, David Smith, J. G., 1973, A Tertiary lamprophyre dike province in
Giles, and Nick Carter. The work done by William southeasternAlaska:CanadianJour. Earth Sci., v. 10, p. 408-
Duncan while employed by Climax Molybdenum 420.
Corporation of British Columbia deservesspecial Wanless, R. K., Stevens, R. D., Lachance, G. R., and Edmonds,
C. M., 1966, Age determinationsand geologicalstudies,K-
acknowledgment. His four yearsof effort from 1974 Ar isotopic ages, Report 7: Canada Geol. Survey Paper 66-
through1978 were instrumentalin developingmany 17, 120 p.
of the recent geologicconceptsabout the deposit. Wheeler, J. O., and Gabrielse, H., 1972, The Cordilleran
Bill'sindividualwork is an exampleof true dedication structuralprovince: Geol. Assoc.Canada Spec. Paper 11, p.
1-81.
to the geologicunderstandingof an orebody. To White, W. H., Bookstrom, A. A., Kamilli, R. J., Ganster, M. W.,
date, the mostauthoritativepublicationshave been Smith, R. P., Ranta, D. E., and Steininger, R. C., 1981,
Carter (1981) and Woodcock and Carter (1976). Character and origin of Climax-type molybdenumdeposits:
Thanksare due to AMAX for permissionto publish ECON. GEOL. 75TH ANNIV. VOL., p. 270-316.
this paper. Woodcock,J. R., 1964, Geologyand geochemistry of Alice Arm
molybdenumdeposits:Kitsault,B.C., BearCreek Mining Co.
June15, July 17, 1984 unpub.CoordinatingUnit rept., June29, 1964, 169 p.
Woodcock,J. R., and Carter, N. C., 1976, Geologyand geo-
REFERENCES chemistryof the Alice Arm molybdenumdeposits:Canadian
Inst. Mining Metallurgy Spec.Vol. 15, p. 462-475.
AMAX, 1982, Annual report: Greenwich,Connecticut,36 p. Wray, W. B., Jr., 1972, Molybdenum ore potential area south
Carter, N. C., 1981, Porphyrycopperm•dmolybdenumdeposits, of Lime Creek deposits,Kitsault, B. C., British Columbia
west central British Columbia,B.C.: CanadaMinistry Energy, Molybdenum Ltd.: Kennecott Geol. ResearchDiv., unpub.
Mines PetroleumResources,Bull. 64, 150 p. rept. April, 1972, 80 p.