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24-10-17 - Assignment 3 Question Pool

This document contains an assignment of 11 questions for a general chemistry course covering topics in inorganic chemistry, radial wave functions, and radial distribution functions. The questions assess understanding of crystal field stabilization energies; spin magnetic moments; coordination numbers; identifying optical isomers of coordination complexes; identifying structures with octahedral geometry; calculating photon emission rates; determining location uncertainties from momentum uncertainties; calculating force constants from energy level differences; identifying radial distribution function values; determining orbital angular momentum and node numbers; relating vibrational frequencies between hydrogen and tritium molecules; and calculating electron binding energies from photoelectron experiments.

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98 views1 page

24-10-17 - Assignment 3 Question Pool

This document contains an assignment of 11 questions for a general chemistry course covering topics in inorganic chemistry, radial wave functions, and radial distribution functions. The questions assess understanding of crystal field stabilization energies; spin magnetic moments; coordination numbers; identifying optical isomers of coordination complexes; identifying structures with octahedral geometry; calculating photon emission rates; determining location uncertainties from momentum uncertainties; calculating force constants from energy level differences; identifying radial distribution function values; determining orbital angular momentum and node numbers; relating vibrational frequencies between hydrogen and tritium molecules; and calculating electron binding energies from photoelectron experiments.

Uploaded by

PranavSharma
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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GENERAL CHEMISTRY (CHEM F111)

I semester 2017-2018
Assignment 3- Question pool based on Lectures 21 to Lecture 26
(Portion covered: Inorganic Chemistry and Radial wave functions, Radial
distribution functions etc.)

1. Calculate the crystal field stabilization energy of [NiCl4]2- ion in terms of Δo.

2. Which of following pair may have spin only magnetic moment value 4.90 B.M.?
(A) [Mn(H2O)6]3+ and [Cr(H2O)6]2+ (B) [Fe(H2O)6]3+ and [Cr(H2O)6]2+
(C) [Cr(H2O)6]3+ and [Mn(H2O)6]2+ (D) [Fe(H2O)6]3+ and [Mn(H2O)6]3+

3. Number of O and N coordination respectively in [Fe(EDTA]4- are ___ & ___

4. Draw the structures of the following and identify which of them will have optical isomers?
[A] - cis-[Co(en)2Cl2] [B] - trans-[Co(en)2Cl2]
[C] - mer-[Co(H2O)3Cl3] [D] - [Co(ox)3]3+

5. From the following complexes, the one with regular octahedron structure is
(A) CrF2 (B) [Cu(NH3)6]2+ (C) [TiF4(Cl)2]2- (D) MnF2

6. How many photons does a monochromatic (single frequency) infrared rangefinder of


power 1 mW and wavelength 1000 nm emit in 0.1 s?

7. The speed of a certain electron is 995 km s−1. If the uncertainty in its momentum is to be
reduced to 0.0010 per cent, what uncertainty in its location must be tolerated?

8. For a certain harmonic oscillator of effective mass 2.88 × 10−25 kg, the difference in
adjacent energy levels is 3.17 zJ. Calculate the force constant of the oscillator.

9. At what radius in the H atom does the radial distribution function of the ground state have
(a) 50 per cent of its maximum value.

10. What is the orbital angular momentum of an electron in the orbitals (A) 2p and (B) 3d.
Give the numbers of angular and radial nodes in each case.

11. The vibrational frequency of H2 is 131.9 THz. What is the vibrational frequency of T 2 (T
=3H, Tritium)?

12. In an X-ray photoelectron experiment, a photon of wavelength 121 pm ejects an electron


from the inner shell of an atom and it emerges with a speed of 56.9 Mm s−1. Calculate the
binding energy of the electron.

END

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