Product Name: CAT DEO 15W-40 (DIESEL ENGINE OIL)

Revision Date: 12 Oct 2012

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MATERIAL SAFETY DATA SHEET

SECTION 1 PRODUCT AND COMPANY IDENTIFICATION

PRODUCT
Product Name: CAT DEO 15W-40 (DIESEL ENGINE OIL)
Product Description: Base Oil and Additives
Product Code: 478669-00, 97X127
Intended Use: Engine oil

COMPANY IDENTIFICATION
Supplier: EXXON MOBIL CORPORATION
3225 GALLOWS RD.
FAIRFAX, VA. 22037 USA
24 Hour Health Emergency 609-737-4411
Transportation Emergency Phone 800-424-9300
ExxonMobil Transportation No. 281-834-3296
Product Technical Information 800-662-4525, 800-947-9147
MSDS Internet Address http://www.exxon.com, http://www.mobil.com

SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS

Reportable Hazardous Substance(s) or Complex Substance(s)

Name CAS# Concentration*
ZINC DITHIOPHOSPHATE 68649-42-3 1 - 2.5%

* All concentrations are percent by weight unless material is a gas. Gas concentrations are in percent by volume.

SECTION 3 HAZARDS IDENTIFICATION

This material is not considered to be hazardous according to regulatory guidelines (see (M)SDS Section 15).

POTENTIAL HEALTH EFFECTS

Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure
injection under skin may cause serious damage.

NFPA Hazard ID: Health: 0 Flammability: 1 Reactivity: 0

HMIS Hazard ID: Health: 0 Flammability: 1 Reactivity: 0
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NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert
advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary
from person to person.

SECTION 4 FIRST AID MEASURES

INHALATION
Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use
adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek
immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use
mouth-to-mouth resuscitation.

SKIN CONTACT
Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the
body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by
a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be
minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent
of injury.

EYE CONTACT
Flush thoroughly with water. If irritation occurs, get medical assistance.

INGESTION
First aid is normally not required. Seek medical attention if discomfort occurs.

SECTION 5 FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA
Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish
flames.

Inappropriate Extinguishing Media: Straight Streams of Water

FIRE FIGHTING
Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering streams,
sewers, or drinking water supply. Firefighters should use standard protective equipment and in enclosed
spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to
protect personnel.

Hazardous Combustion Products: Smoke, Fume, Aldehydes, Sulfur oxides, Incomplete combustion
products, Oxides of carbon

FLAMMABILITY PROPERTIES
Flash Point [Method]: >215°C (419°F) [ASTM D-92]
Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0
Autoignition Temperature: N/D
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SECTION 6 ACCIDENTAL RELEASE MEASURES

NOTIFICATION PROCEDURES
In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable
regulations. US regulations require reporting releases of this material to the environment which exceed the
applicable reportable quantity or oil spills which could reach any waterway including intermittent dry creeks. The
National Response Center can be reached at (800)424-8802.

PROTECTIVE MEASURES
Avoid contact with spilled material. See Section 5 for fire fighting information. See the Hazard Identification
Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum
requirements for personal protective equipment. Additional protective measures may be necessary, depending
on the specific circumstances and/or the expert judgment of the emergency responders. For emergency
responders: Respiratory protection: respiratory protection will be necessary only in special cases, e.g.,
formation of mists. Half-face or full-face respirator with filter(s) for dust/organic vapor or Self Contained
Breathing Apparatus (SCBA) can be used depending on the size of spill and potential level of exposure. If the
exposure cannot be completely characterized or an oxygen deficient atmosphere is possible or anticipated,
SCBA is recommended. Work gloves that are resistant to hydrocarbons are recommended. Gloves made of
polyvinyl acetate (PVA) are not water-resistant and are not suitable for emergency use. Chemical goggles are
recommended if splashes or contact with eyes is possible. Small spills: normal antistatic work clothes are
usually adequate. Large spills: full body suit of chemical resistant, antistatic material is recommended.

SPILL MANAGEMENT
Land Spill: Stop leak if you can do it without risk. Recover by pumping or with suitable absorbent.

Water Spill: Stop leak if you can do it without risk. Confine the spill immediately with booms. Warn other
shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist
before using dispersants.

Water spill and land spill recommendations are based on the most likely spill scenario for this material;
however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction
and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be
consulted. Note: Local regulations may prescribe or limit action to be taken.

ENVIRONMENTAL PRECAUTIONS
Large Spills: Dike far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways,
sewers, basements or confined areas.

SECTION 7 HANDLING AND STORAGE

HANDLING
Avoid contact with used product. Prevent small spills and leakage to avoid slip hazard. Material can
accumulate static charges which may cause an electrical spark (ignition source). When the material is handled
in bulk, an electrical spark could ignite any flammable vapors from liquids or residues that may be present (e.g.,
during switch-loading operations). Use proper bonding and/or ground procedures. However, bonding and
grounds may not eliminate the hazard from static accumulation. Consult local applicable standards for
guidance. Additional references include American Petroleum Institute 2003 (Protection Against Ignitions
Arising out of Static, Lightning and Stray Currents) or National Fire Protection Agency 77 (Recommended
Practice on Static Electricity) or CENELEC CLC/TR 50404 (Electrostatics - Code of practice for the avoidance
Product Name: CAT DEO 15W-40 (DIESEL ENGINE OIL)
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of hazards due to static electricity).

Static Accumulator: This material is a static accumulator.

STORAGE
The container choice, for example storage vessel, may effect static accumulation and dissipation. Do not store
in open or unlabelled containers.

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION

EXPOSURE LIMIT VALUES

Exposure limits/standards for materials that can be formed when handling this product: When mists/aerosols
can occur the following are recommended: 5 mg/m³ - ACGIH TLV (inhalable fraction), 5 mg/m³ - OSHA PEL.

NOTE: Limits/standards shown for guidance only. Follow applicable regulations.

ENGINEERING CONTROLS

The level of protection and types of controls necessary will vary depending upon potential exposure conditions.
Control measures to consider:
No special requirements under ordinary conditions of use and with adequate ventilation.

PERSONAL PROTECTION

Personal protective equipment selections vary based on potential exposure conditions such as applications,
handling practices, concentration and ventilation. Information on the selection of protective equipment for use
with this material, as provided below, is based upon intended, normal usage.

Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a

level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator
selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of
respirators to be considered for this material include:
No special requirements under ordinary conditions of use and with adequate ventilation.

For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode.
Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate,
gas/vapor warning properties are poor, or if air purifying filter capacity/rating may be exceeded.

Hand Protection: Any specific glove information provided is based on published literature and glove
manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions.
Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use
conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material
include:
No protection is ordinarily required under normal conditions of use.

Eye Protection: If contact is likely, safety glasses with side shields are recommended.
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Skin and Body Protection: Any specific clothing information provided is based on published literature or
manufacturer data. The types of clothing to be considered for this material include:
No skin protection is ordinarily required under normal conditions of use. In accordance with good
industrial hygiene practices, precautions should be taken to avoid skin contact.

Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after
handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned.
Practice good housekeeping.

ENVIRONMENTAL CONTROLS
Comply with applicable environmental regulations limiting discharge to air, water and
soil. Protect the environment by applying appropriate control measures to prevent or limit
emissions.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Note: Physical and chemical properties are provided for safety, health and environmental considerations only
and may not fully represent product specifications. Contact the Supplier for additional information.

GENERAL INFORMATION
Physical State: Liquid
Color: Amber
Odor: Characteristic
Odor Threshold: N/D

IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION

Relative Density (at 15 °C): 0.826
Flash Point [Method]: >215°C (419°F) [ASTM D-92]
Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0
Autoignition Temperature: N/D
Boiling Point / Range: > 316°C (600°F)
Vapor Density (Air = 1): N/D
Vapor Pressure: [N/D at 20 °C]
Evaporation Rate (n-butyl acetate = 1): N/D
pH: N/A
Log Pow (n-Octanol/Water Partition Coefficient): > 3.5
Solubility in Water: Negligible
Viscosity: 115.5 cSt (115.5 mm2/sec) at 40 °C | 15 cSt (15 mm2/sec) at 100°C
Oxidizing Properties: See Hazards Identification Section.

OTHER INFORMATION
Freezing Point: N/D
Melting Point: N/A
Pour Point: < -27°C (-17°F)
DMSO Extract (mineral oil only), IP-346: < 3 %wt

SECTION 10 STABILITY AND REACTIVITY

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STABILITY: Material is stable under normal conditions.

CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition.

MATERIALS TO AVOID: Strong oxidizers

HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures.

HAZARDOUS POLYMERIZATION: Will not occur.

SECTION 11 TOXICOLOGICAL INFORMATION

ACUTE TOXICITY
Route of Exposure Conclusion / Remarks
Inhalation
Toxicity (Rat): LC50 > 5000 mg/m3 Minimally Toxic. Based on test data for structurally similar
materials.
Irritation: No end point data. Negligible hazard at ambient/normal handling temperatures.
Based on assessment of the components.

Ingestion
Toxicity (Rat): LD50 > 5000 mg/kg Minimally Toxic. Based on test data for structurally similar
materials.

Skin
Toxicity (Rabbit): LD50 > 5000 mg/kg Minimally Toxic. Based on test data for structurally similar
materials.
Irritation (Rabbit): Data available. Negligible irritation to skin at ambient temperatures. Based on test
data for structurally similar materials.

Eye
Irritation (Rabbit): Data available. May cause mild, short-lasting discomfort to eyes. Based on test
data for structurally similar materials.

CHRONIC/OTHER EFFECTS
For the product itself:
Diesel engine oils: Not carcinogenic in animals tests. Used and unused diesel engine oils did not produce any
carcinogenic effects in chronic mouse skin painting studies.
Oils that are used in gasoline engines may become hazardous and display the following properties:
Carcinogenic in animal tests. Caused mutations in vitro. Possible allergen and photoallergen. Contains
polycyclic aromatic compounds (PAC) from combustion products of gasoline and/or thermal degradation
products.

Contains:
Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified
Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung
non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitizing in test
animals.

Additional information is available by request.

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The following ingredients are cited on the lists below: None.

--REGULATORY LISTS SEARCHED--

1 = NTP CARC 3 = IARC 1 5 = IARC 2B
2 = NTP SUS 4 = IARC 2A 6 = OSHA CARC

SECTION 12 ECOLOGICAL INFORMATION

The information given is based on data available for the material, the components of the material, and similar materials.

ECOTOXICITY
Material -- Not expected to be harmful to aquatic organisms.

MOBILITY
Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to
partition to sediment and wastewater solids.

PERSISTENCE AND DEGRADABILITY

Biodegradation:
Base oil component -- Expected to be inherently biodegradable

BIOACCUMULATION POTENTIAL
Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may
reduce the bioconcentration or limit bioavailability.

SECTION 13 DISPOSAL CONSIDERATIONS

Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable
laws and regulations, and material characteristics at time of disposal.

DISPOSAL RECOMMENDATIONS
Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised
incineration at very high temperatures to prevent formation of undesirable combustion products. Protect the
environment. Dispose of used oil at designated sites. Minimize skin contact. Do not mix used oils with solvents,
brake fluids or coolants.

REGULATORY DISPOSAL INFORMATION

RCRA Information: The unused product, in our opinion, is not specifically listed by the EPA as a hazardous
waste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed as hazardous wastes. It
does not exhibit the hazardous characteristics of ignitability, corrositivity or reactivity and is not formulated with
contaminants as determined by the Toxicity Characteristic Leaching Procedure (TCLP). However, used
Product Name: CAT DEO 15W-40 (DIESEL ENGINE OIL)
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product may be regulated.

Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and
can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be
completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken
for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with
governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE
SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION.
THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.

SECTION 14 TRANSPORT INFORMATION

LAND (DOT): Not Regulated for Land Transport

LAND (TDG): Not Regulated for Land Transport

SEA (IMDG): Not Regulated for Sea Transport according to IMDG-Code

AIR (IATA): Not Regulated for Air Transport

SECTION 15 REGULATORY INFORMATION

OSHA HAZARD COMMUNICATION STANDARD: When used for its intended purposes, this material is not classified
as hazardous in accordance with OSHA 29 CFR 1910.1200.

Complies with the following national/regional chemical inventory requirements:: TSCA

EPCRA

Chemical Name CAS Number Typical Value Component TPQ Product TPQ
PHOSPHORUS 7723-14-0 0.143971 %weight 100 LBS 69458.29 LBS

SARA (311/312) REPORTABLE HAZARD CATEGORIES: None.

SARA (313) TOXIC RELEASE INVENTORY:

Chemical Name CAS Number Typical Value

ZINC DITHIOPHOSPHATE 68649-42-3 1 - 2.5%

The following ingredients are cited on the lists below:

Chemical Name CAS Number List Citations

DIPHENYLAMINE 122-39-4 18
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PHOSPHORUS 7723-14-0 1, 4
ZINC DITHIOPHOSPHATE 68649-42-3 13, 15, 17

--REGULATORY LISTS SEARCHED--

1 = ACGIH ALL 6 = TSCA 5a2 11 = CA P65 REPRO 16 = MN RTK
2 = ACGIH A1 7 = TSCA 5e 12 = CA RTK 17 = NJ RTK
3 = ACGIH A2 8 = TSCA 6 13 = IL RTK 18 = PA RTK
4 = OSHA Z 9 = TSCA 12b 14 = LA RTK 19 = RI RTK
5 = TSCA 4 10 = CA P65 CARC 15 = MI 293

Code key: CARC=Carcinogen; REPRO=Reproductive

SECTION 16 OTHER INFORMATION

N/D = Not determined, N/A = Not applicable

THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS:

Revision Changes:
Section 06: Notification Procedures - Header was modified.
Section 13: Disposal Considerations - Disposal Recommendations was modified.
Section 10 Stability and Reactivity - Header was modified.
Section 13: Disposal Recommendations - Note was modified.
Section 13: Empty Container Warning was modified.
Section 09: Phys/Chem Properties Note was modified.
Section 09: Boiling Point C(F) was modified.
Section 08: Comply with applicable regulations phrase was modified.
Section 08: Personal Protection was modified.
Section 08: Hand Protection was modified.
Section 09: Vapor Pressure was modified.
Section 07: Handling and Storage - Handling was modified.
Section 07: Handling and Storage - Storage Phrases was modified.
Hazard Identification: Health Hazards was modified.
Section 11: Dermal Lethality Test Data was modified.
Section 11: Oral Lethality Test Data was modified.
Section 11: Inhalation Lethality Test Data was modified.
Section 05: Hazardous Combustion Products was modified.
Section 06: Accidental Release - Spill Management - Water was modified.
Section 09: Relative Density - Header was modified.
Section 09: Flash Point C(F) was modified.
Section 09: Viscosity was modified.
Section 09: Viscosity was modified.
Section 14: Sea (IMDG) - Header was modified.
Section 14: Air (IATA) - Header was modified.
Section 14: LAND (TDG) - Header was modified.
Section 14: LAND (DOT) - Header was modified.
Composition: Component table was modified.
Section 15: List Citations Table was modified.
Section 15: List Citation Table - Header was modified.
Section 14: LAND (DOT) - Default was modified.
Section 14: LAND (TDG) Default was modified.
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Section 14: Sea (IMDG) - Default was modified.
Section 14: Air (IATA) - Default was modified.
Section 15: National Chemical Inventory Listing - Header was modified.
Section 15: SARA (313) TOXIC RELEASE INVENTORY - Table was modified.
Section 16: Code to MHCs was modified.
Section 15: Community RTK - Header was modified.
Section 08: Exposure limits/standards was modified.
Hazard Identification: OSHA - May be Hazardous Statement was modified.
Section 06: Notification Procedures was modified.
Section 09: Oxidizing Properties was modified.
Section 01: Company Contact Methods Sorted by Priority was modified.
Section 06: Protective Measures was added.
Section 06: Accidental Release - Protective Measures - Header was added.
Section 15: Community RTK - CAS - Header was added.
Section 15: Community RTK - Component TPQ - Header was added.
Section 15: Community RTK - Chemical Name - Header was added.
Section 15: Community RTK - Product RQ - Header was added.
Section 15: Community RTK Table was added.
Section 15: Community RTK - Typical Value - Header was added.
Section 08: Exposure Limit Values - Header was added.
Section 15: TSCA Class 2 Statement was deleted.
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The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief,
accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most
current available from ExxonMobil. The information and recommendations are offered for the user's consideration and
examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer
repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is
included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to
handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law,
re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used
for convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any
affiliates in which they directly or indirectly hold any interest.

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Internal Use Only

MHC: 0B, 0B, 0, 0, 0, 0 PPEC: A

DGN: 2026963XUS (543511)

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Copyright 2002 Exxon Mobil Corporation, All rights reserved