Polyhalite Characteristics April 2016
Polyhalite Characteristics April 2016
Polyhalite Characteristics April 2016
THE ER
FE R TIL IZ
April 2016
INDEX
INTRODUCING POLY4
INTRODUCING POLY4 3
Our product 4
Crush strength 13
Spreader testing 14
Salt index 15
Solubility 16
Soil pH 20
Carbon footprint 22
2
INTRODUCING
INTRODUCING POLY4
POLY4
POLY4 is the trademark name of all polyhalite
products from Sirius Minerals. Polyhalite is a naturally
occurring, evaporite mineral formed from the dried-
up bed of an ancient sea or ocean. Chemically, it is a
hydrated potassium, calcium, magnesium sulphate salt
with the chemical formula:
K 2SO4.MgSO4.2CaSO4.2H2O.
PRODUCT CHARACTERISTICS
NUTRIENT RELEASE IN SOIL
3
INTRODUCING POLY4 THE FUTURE OF FERTILIZER
OUR PRODUCT
INTRODUCING POLY4
K Mg
PRODUCT CHARACTERISTICS
S Ca
POLY4’s low chloride levels are ideal for sensitive crops and
the product has also been granted authorisation for use in
organic systems, certified by the Soil Association and Organic
NUTRIENT RELEASE IN SOIL
4
INTRODUCING POLY4 THE FUTURE OF FERTILIZER
INTRODUCING POLY4
The major purpose of all fertilizers is to bridge the gap between crop
demand and nutrient deficiencies in the soil. Sirius Minerals’ global
agronomy programme provides technical and commercial validation
of POLY4’s use as an effective fertilizer — suitable for high value or
broad acre crops — with its supply of four essential nutrients.
PRODUCT CHARACTERISTICS
important to soil structure and drainage. The addition of magnesium
benefits the critical physiological and biochemical processes which
are important to high crop productivity.
6
POLY4 PRODUCT
INTRODUCING POLY4
CHARACTERISTICS
Data on the physical and chemical characteristics
of POLY4 is summarised for a range of properties
including label declared analysis, caking potential,
critical relative humidity, crush strength, spreading
performance, salt index and solubility in water.
PRODUCT CHARACTERISTICS
NUTRIENT RELEASE IN SOIL
7
POLY4 PRODUCT CHARACTERISTICS
NUTRIENT CONTENT
INTRODUCING POLY4
POLY4’s four macro nutrients, as stated on its label, are 14% K 2O,
17% CaO, 6% MgO and 48% SO3. POLY4 contains very low levels of
chloride, with a typical halite content of 3.07%1.
FIGURE 1 70
Nutrient content
of major potash
fertilizers
60
50
Nutrient content in %
40
30
20
NUTRIENT RELEASE IN SOIL
10
0
POLY4 Potassium Muriate of Sulphate of Sulphate of
Nitrate (NOP) Potash (MOP) Potash Magnesium Potash (SOP)
(SOP-M)
1
SGS France Analysis (Nov 2014), 95% confidence interval for potassium, magnesium, calcium, sulphur and chloride.
8
POLY4 PRODUCT CHARACTERISTICS
INTRODUCING POLY4
POLY4 is compatible for blending and can improve shelf life
PRODUCT CHARACTERISTICS
substantial effect on caking propensity. Furthermore, adding POLY4
into blends as a K source shows a reduction in caking propensity.
TABLE 1
KEY DIFFERENCE 20:10:10 BLEND COMPOSITION EJECTION PRESSURE (KPA) Caking propensity
of 20:10:10 blends
with different N
N source AN + DAP + POLY4 + MOP 56.8 and K source2
9
POLY4 PRODUCT CHARACTERISTICS
The results show that POLY4 has a lower propensity for caking, thus
extending the overall shelf life of the blend when compared to MOP.
FIGURE 2
POLY4 + AN 20:10:10 POLY4 + Urea 20:10:10
PRODUCT CHARACTERISTICS
Compression 90
curves of 20:10:10 80
NPK blends made
Compression Load (psi)
with POLY4 or 70
MOP and different
N fertilizers 60
50
40
30
20
10
0
1 10 100 1000 10000
Test time (seconds)
NUTRIENT RELEASE IN SOIL
70
60
50
40
30
20
10
0
1 10 100 1000 10000
Test time (seconds)
Walker G.M., Holland C.R. Ahmad, M.N., Fox J.N. and Kells A.G. (1999). Granular Fertilizer Agglomeration in Accelerated Caking Tests. Ind. Eng. Chem.
3
10
POLY4 PRODUCT CHARACTERISTICS
TABLE 2
KEY DIFFERENCE 20:10:10 BLEND COMPOSITION APPROXIMATE STORAGE LIFE (MONTHS) Approximate
INTRODUCING POLY4
storage life of
20:10:10 blends
N source AN + DAP + MOP + POLY4 23 with different N
and K sources4
AN + AS + DAP + POLY4 15
PRODUCT CHARACTERISTICS
1 Calcium ammonimum nitrate Limited compatibility
There are no incompatibilities with using POLY4 amongst the product tests. Our tests show
that POLY4 was chemically safe and only has minor caking with some fertilizers after 17
months in storage.
4
University of Limerick (2015). 5EFMA (2006) Compatibility triangle shown with results from University of Limerick. 6POLY4 compatibility based on caking
propensity and approximate storage life from accelerated caking testing
11
POLY4 PRODUCT CHARACTERISTICS
5
NUTRIENT RELEASE IN SOIL
4
3
2
1
0
0 10 20 30 40 50 60 70 80 90
Relative humidity (%)
7
Clayton, W.E. (1984). Humidity Factors Affecting Storage and Handling of Fertilizers. International Fertilizer Development Center.
8
University of Limerick (2015)
12
POLY4 PRODUCT CHARACTERISTICS
CRUSH STRENGTH
INTRODUCING POLY4
POLY4 has a crush strength of 5.5kgf
PRODUCT CHARACTERISTICS
9.2 FIGURE 5
8.9 Crush strength of
POLY4 and other
fertilizers10
6.2
Crush Strength (kgf)
5.9
5.5
3 kgf
crush
9
UN Fertilizer Manual (1998). 10Current formulations as of July 2015 tested by University of Limerick and Mars Minerals. 11Ammonimum nitrate.
12
Diammonium nitrate. 13Kieserite. 14Muriate of potash
13
POLY4 PRODUCT CHARACTERISTICS
SPREADER TESTING
INTRODUCING POLY4
POLY4 is suitable for use in spreaders at typical distances for fertilizer application
Fertilizer is often applied to fields using mechanical spreaders to ensure an even distribution of
the required nutrients. Ineffective spreading leads to uneven fertilizer application, resulting in
strips of nutrient-deficient crops and a subsequent loss of farmer income.
POLY4 granules were tested using spreading machinery15 set to a spreading width of 24m and
36m, a typical distance for fertilizer application. Figure 6 shows the results of the spreader
testing to be within the 20% tolerance limits, outside which striping manifests within a crop.
POLY4’s quality spread pattern reduces the risk of expensive corrective action.
PRODUCT CHARACTERISTICS
FIGURE 6 180
Spreading results 160
of POLY4 granules 140
Relative contents (%)
at 24m (upper)
and 36m (lower) 120
100
80
60
40
20
0
15 10 5 0 5 10 15
Distance from centre (m)
180
160
140
Relative contents (%)
NUTRIENT RELEASE IN SOIL
120
100
80
60
40
20
0
20 10 0 10 20
Distance from centre (m)
15
SCS Spreader & Sprayer Testing Ltd. (UK) (2013)
14
POLY4 PRODUCT CHARACTERISTICS
SALT INDEX
INTRODUCING POLY4
POLY4 has a salt index of 76
PRODUCT CHARACTERISTICS
from seven independent laboratories show a lower salt index
for POLY4 than MOP, SOP and SOP-M (Figure 7).
76±15
Salt index
The ratio of the increase in osmotic pressure produced by a fertilizer to that produced by the same weight of sodium nitrate multiplied by 100 to give
16
whole numbers is called the “salt index” or SI (Rader, L.F., Jr., White, L.M., and Whittaker, C.W. (1943) The Salt Index – a measure of the effect of fertilizers
on the concentration of the soil solution. Soil Science, V.55, No. 3, pp. 201–218.) 17Jackson W.L. (1958). Soil Chemical Analysis, Prentice Hall, Englewood
Cliffs, NJ. 18Salt index is average of results from in 2013 from Thornton Laboratories, Spectrum Analytic Inc., Southern jesting, Midwest Laboratories, 15
University of Florida, University of São Paulo and Shandong Agricultural University
POLY4 PRODUCT CHARACTERISTICS
SOLUBILITY
INTRODUCING POLY4
TABLE 3 All fertilizers are characterised by their FERTILIZER SOLUBILITY AT 25°C (g/l)
Summary of
commercial solubility in water at a given temperature.
fertilizer solubility POLY4 27
at 25°C19–24
The solubility of POLY4, determined in a AS 750
standard test over a range of temperatures19,
MOP 264
is compared to the water solubility reported
for common fertilizers in Figure 8. The SOP 120
water solubility of POLY4 is 27 g/l at 25°C Urea 1200
corresponding to the amount of POLY4 that
Gypsum 2.55
would dissolve in the plough layer of a moist,
PRODUCT CHARACTERISTICS
10
NUTRIENT RELEASE IN SOIL
1
0 5 10 15 20 25 30 35
Temperature (°C)
‘SGS’, France (2013), 20Elam, M., S. Ben-Ari, and H. Megan. (1995). The dissolution of different types of potassium fertilizers suitable for fertigation.
19
Sohnel, O., and P. Novotny (1986). Densities of aqueous solutions of inorganic substances. Elsevier, Amsterdam. 22“IUPAC (2014). IUPAC-NIST Solubility
21
Database. Available online at http://srdata.nist.gov/solubility/index.aspx [Accessed on November 2015]” 23American Chemical Society (2006). Reagent
16 chemicals: specifications and procedures: American Chemical Society specifications, official from January 1, 2006. Oxford University Press. p. 242. ISBN
0-8412-3945-2. 24S. Gangolli (1999). The Dictionary of Substances and Their Effects: C. Royal Society of Chemistry. p. 71. ISBN 0-85404-813-8.
POLY4 PRODUCT CHARACTERISTICS
Dissolution rate characterises the transition of a solid fertilizer into a solution. Figure 9 shows
INTRODUCING POLY4
POLY4 in comparison to MOP, SOP and SOP-M at 20˚C. POLY4’s dissolution rate was similar
to MOP, but slightly faster than SOP during the first 15 minutes.
Since POLY4 is a mineral, dissolution results in simultaneous nutrient release. Both tests
demonstrated that all nutrients are available, with near full dissolution of its nutrient content
within six hours (Figure 10).
Crops benefit from this characteristic as nutrients are delivered at a pace that is more
compatible with their metabolic requirements.
PRODUCT CHARACTERISTICS
time compared to
SOP-M other potassium-
% dissolved
60 based fertilizers25
at concentrations
of 10g/l
40
20
0
0 20 40 60 80 100 120
Time (mins)
100 K2O
FIGURE 10
SO3 Dissolution
80 MgO pattern of the
% nutrients in solution
nutrients in POLY4
CaO over time at 20˚26
60
20
0
0 6 12 18 24 30 36
Hours
25
‘SGS’, France (2013)(experiment using agitation)
26
Elam, M., S. Ben-Ari, and H. Megan. (1995). The dissolution of different types of potassium fertilizers suitable for fertigation.
17
18
INTRODUCING POLY4 PRODUCT CHARACTERISTICS NUTRIENT RELEASE IN SOIL
POLY4 NUTRIENT
INTRODUCING POLY4
RELEASE IN SOIL
The most compelling evidence for nutrient release of
fertilizer in soil is the extent and efficiency of plant
nutrient uptake. Agronomic studies confirm that the
nutrients from POLY4 are readily available to a crop and
that nutrient uptake generally increases with higher
application rates, particularly on nutrient deficient soils.
PRODUCT CHARACTERISTICS
NUTRIENT RELEASE IN SOIL
19
POLY4 NUTRIENT RELEASE IN SOIL
SOIL pH
INTRODUCING POLY4
Maintenance of soil pH, within suitable limits, is important for optimum nutrient availability and
therefore plant growth (Figure 11). POLY4 has no expected effect on soil pH levels unless
there are reducing conditions. For example, when sulphates are reduced to elemental sulphur
or in soils with significant aluminium levels that can exchange with the cations and, upon
release into the soil solution, enter into chemical reactions that affect pH.
Nitrogen
PRODUCT CHARACTERISTICS
Phosphorus
Potassium
Sulphur
Calcium
Magnesium
Iron
Manganese
Boron
Copper and zinc
Molybdenum
4.0 4.5 5.0 5.5 6.0 6.5 7.0 7.5 8.0 8.5 9.0 9.5 10.0
6.5
soil pH as shown in Figure 12; none of the
soil pH values are significantly different from 6.0
27
Lucas, R.E. and Davis, J.F. (1961) Relationships between pH values of organic soils and availabilities of 12 plant nutrients. Soil Science. 92: 177–182.
28
University of Warwick (2014), University of Florida (2015)
20
POLY4 NUTRIENT RELEASE IN SOIL
INTRODUCING POLY4
POLY4’s effect on soil EC is limited
Fertilizers are soluble salts which can increase soil water salinity thereby
increasing soil EC. In our studies, POLY4 and other fertilizers increased
soil EC (as measured after harvest at the higher application rates), but in
no instances were the increases sufficient to cause crop damage.
PRODUCT CHARACTERISTICS
Corn
(3.2) FIGURE 13
Soybean Wheat Barley The effect of
Cabbage Tomato (5.5) (7.6) (10) POLY4 on soil
(2.8) (3.5) EC for studies
conducted on
Corn a range of salt
sensitive crops29–34
Post POLY4
Cabbage trial soil EC
10% Yield
Impediment
Soybean Threshold
0 1 2 3 4 5 6 7 8 9 10
Soil EC (ds/m)
29
Corn 300kg K2O/ha Sichuan University (2014), 30Tomato 175kg K2O/ha University of Florida (2014), 31Cabbage 200kg K2O/ha University of Florida (2013),
32
Soybean 250kg K2O/ha University of Florida (2013), 33Wheat 80kg K2O/ha SGS 2015, 34FAO Irrigation & Drainage paper 61 (2002)
21
POLY4 NUTRIENT RELEASE IN SOIL
CARBON FOOTPRINT
INTRODUCING POLY4
POLY4’s embedded CO2 emissions (CO2e) are low compared with other fertilizers
The world’s population is predicted to hit 9 billion by 205035. Over the next 35 years more
food needs to be produced than has been to date in human history. In addition, new wealthy
economies are emerging which demand more protein rich and higher quality diets. Sustaining
increased livestock herds requires greater efficiency from grain production and arable land.
This requires farmers and food producers to use balanced fertilization to increase yields.
The situation has become even more challenging as there is increasingly less farm land
available to grow the required crops. Application of fertilizer will form an integral part in
satisfying this increased demand for food.
FIGURE 14
Embedded -6%
fertilizer CO2 for as a significant source of greenhouse gases 1,999
a UK wheat and
potato fertilizer (GHG)36 and so with increased use there becomes 1,878
plan38–41
an ever increasing need to improve the use
Wheat 713
efficiency of applied fertilizers and to use fertilizer 679
species with lower GHG contributions.
Figure 14 shows a comparison between a standard and POLY4 fertilizer plan of embedded
CO2 emissions. The low GWP of POLY4 translates into a 6% decrease in CO2 emissions
compared to a standard plan.
35
Food Matters; Towards a Strategy for the 21st Century. The Cabinet Office Strategy Unit; July 2008. 36Sam Wood and Annette Cowie. A Review of
Greenhouse Gas Emission Factors for Fertiliser Production. Research and Development Division, State Forests of New South Wales. Cooperative
Research Centre for Greenhouse Accounting. June 2004. 37Demand for fertiliser and associated environmental impacts, Wiltshire, J., Ricardo-AEA Ltd,
22 Gemini Building, Harwell, Didcot, UK,(2014). 38CO2 emissions are estimated during fertilizer production. 39Fertilizer plan normalised for spreading and yield
differences. 40Standard fertilizer plan contains Urea, TSP, MOP, AS and Kieserite. 41POLY4 fertilizer plan contains Urea, TSP, MOP and POLY4.
NOTES