Assignment 1 PDF
Assignment 1 PDF
Assignment 1 PDF
ASSIGNMENT 1
QUESTION 1
a) Relative volatility is defined as
y1 x1
12
y 2 x2
For binary system that obeys modified Raoult’s law, prove that the relative volatility at x1 =
0 and x1 = 1 are as follow:
b) For a binary system of acetone(1) and methanol(2) at 320.15 K, the activity coefficients
are correlated by the following equations:
1 1 P2sat
x1 1 - ln
2 0.98 P1sat
(5 marks)
QUESTION 2
A stream containing a mixture of pentane(1), n-hexane(2) and heptane(3) with flow rate of
80 kmol/h, 100 kmol/h and 120 kmol/h, respectively is fed to a flash separator operating at
350 K and 1.2 bar. By assuming Raoult’s law, determine the flow rates of vapor and liquid
formed and its compositions. The Antoine parameters for each component are given in the
following table.
(20 marks)
th
Date of submission: 10 April 2017