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Tutorial 6

This document provides instructions for 4 thermodynamics problems involving estimating fugacities and fugacity coefficients for various chemical systems: 1. Estimate the fugacity of SO2 at 600K and 300 bar using equation 11.67. 2. Estimate the fugacity of isobutylene at 280oC and 20 bar using equation 11.68. 3. Determine the fugacity and fugacity coefficient for isobutane at 40oC and pressures of 2 bar, 5.28 bar, and 8 bar using equations involving the fugacity coefficient, saturated liquid fugacity, and molar volume. 4. Estimate the fugacities and fugacity coefficients for a ethylene/pro

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242 views1 page

Tutorial 6

This document provides instructions for 4 thermodynamics problems involving estimating fugacities and fugacity coefficients for various chemical systems: 1. Estimate the fugacity of SO2 at 600K and 300 bar using equation 11.67. 2. Estimate the fugacity of isobutylene at 280oC and 20 bar using equation 11.68. 3. Determine the fugacity and fugacity coefficient for isobutane at 40oC and pressures of 2 bar, 5.28 bar, and 8 bar using equations involving the fugacity coefficient, saturated liquid fugacity, and molar volume. 4. Estimate the fugacities and fugacity coefficients for a ethylene/pro

Uploaded by

Ereen
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Faculty of Chemical Engineering CPE553 Chemical Engineering Thermodynamics

TUTORIAL 6

1. Determine good estimates of the fugacity for SO2 at 600K and 300 bar by using eqn. (11.67).

2. Estimate the fugacity of isobutylene as a gas at 280oC (553.15 K) and 20 bar by using eqn.
(11.68).

3. Determine the fugacity and fugacity coefficient for isobutane at 40oC (313.15 K) and pressure
of 2 bar, 5.28 bar and 8 bar. The saturation pressure of isobutane at 40oC (313.15 K) is 5.28
bar.
Given the fugacity coefficient for vapor phase, fugacity for liquid phase and molar volume of
saturated liquid are:

 Pr 
  exp  B 0
 B1  
 Tr 
V sat  P  Pi sat 
fi   P exp
i
sat sat
i
RT
1Tr 2/7
V sat  Vc Z c

4. For the system ethylene(1)/propylene(2) as a gas, estimate fˆ1 , fˆ2 , ˆ1 , and ˆ2 at t/T = 150oC
/423.15 K, P = 30 bar and y1 = 0.35
(a) Through application of eq. (11.63)
(b) Assuming that the mixture is an ideal solution

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