SAFETY DATA SHEET

SikaGrout®-212 SR

Version Revision Date: SDS Number:

1.2 10/18/2017 100000004574

SECTION 1. IDENTIFICATION

Product name : SikaGrout®-212 SR

Manufacturer or supplier's details

Company name : 601, avenue Delmar
Canada
Pointe-Claire, QC H9R 4A9
Sika Canada Inc.
www.sika.ca

Telephone : (514) 697-2610 / 1 (800) 933-7452

Telefax : (514) 694-2792

Health and Safety Services’s : [email protected]

e-mail address

Emergency telephone : CANUTEC (collect) (613) 996-6666 (24 hours)

Recommended use of the chemical and restrictions on use

For further information, refer to product data sheet.

SECTION 2. HAZARDS IDENTIFICATION

GHS Classification
Skin corrosion : Category 1C

Serious eye damage : Category 1

Skin sensitization : Category 1

Carcinogenicity (Inhalation) : Category 1A

Specific target organ system- : Category 3 (Respiratory system)

ic toxicity - single exposure

Specific target organ system- : Category 1 (Lungs)

ic toxicity - repeated expo-
sure

GHS label elements

Hazard pictograms :

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SAFETY DATA SHEET

SikaGrout®-212 SR

Version Revision Date: SDS Number:

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Signal Word : Danger

Hazard Statements : H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H335 May cause respiratory irritation.
H350i May cause cancer by inhalation.
H372 Causes damage to organs (Lungs) through prolonged or
repeated exposure.

Precautionary Statements : Prevention:

P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read
and understood.
P260 Do not breathe dust/ fume/ gas/ mist/ vapors/ spray.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing must not be allowed out of
the workplace.
P280 Wear protective gloves/ protective clothing/ eye protection/
face protection.
Response:
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT
induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately
all contaminated clothing. Rinse skin with water.
P304 + P340 + P310 IF INHALED: Remove person to fresh air
and keep comfortable for breathing. Immediately call a POISON
CENTER/doctor.
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Immediately call a POISON
CENTER/doctor.
P308 + P313 IF exposed or concerned: Get medical advice/
attention.
P333 + P313 If skin irritation or rash occurs: Get medical advice/
attention.
P362 + P364 Take off contaminated clothing and wash it before
reuse.
Storage:
P403 + P233 Store in a well-ventilated place. Keep container
tightly closed.
P405 Store locked up.
Disposal:
P501 Dispose of contents/ container to an approved waste dis-
posal plant.

Other hazards
None known.

Supplemental information
If product is in liquid or paste form, physical or health hazards listed related to dust are not con-
sidered significant. However, product may contain substances that could be potential hazards if
caused to become airborne due to grinding, sanding or other abrasive processes.

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SAFETY DATA SHEET

SikaGrout®-212 SR

Version Revision Date: SDS Number:

1.2 10/18/2017 100000004574

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Hazardous ingredients
Chemical name CAS-No. Concentration (% w/w)
Quartz (SiO2) 14808-60-7 >= 30 - < 40
Portland cement 65997-15-1 >= 30 - < 40
calcium oxide 1305-78-8 >= 1 - < 2
Quartz (SiO2) <5µm 14808-60-7 >= 0 - < 1

SECTION 4. FIRST AID MEASURES

General advice : Move out of dangerous area.

Consult a physician.
Show this material safety data sheet to the doctor in attend-
ance.

If inhaled : Move to fresh air.

Consult a physician after significant exposure.

In case of skin contact : Take off contaminated clothing and shoes immediately.
Wash off with soap and plenty of water.
Immediate medical treatment is necessary as untreated
wounds from corrosion of the skin heal slowly and with difficul-
ty.

In case of eye contact : Small amounts splashed into eyes can cause irreversible tis-
sue damage and blindness.
In the case of contact with eyes, rinse immediately with plenty
of water and seek medical advice.
Continue rinsing eyes during transport to hospital.
Remove contact lenses.
Keep eye wide open while rinsing.

If swallowed : Clean mouth with water and drink afterwards plenty of water.
Do not induce vomiting without medical advice.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
Take victim immediately to hospital.

Most important symptoms : Health injuries may be delayed.

and effects, both acute and corrosive effects
delayed irritant effects
sensitizing effects
carcinogenic effects
Cough
Respiratory disorder
Allergic reactions
Dermatitis
See Section 11 for more detailed information on health effects
and symptoms.
May cause an allergic skin reaction.
Causes serious eye damage.

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SikaGrout®-212 SR

Version Revision Date: SDS Number:

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May cause respiratory irritation.

May cause cancer by inhalation.
Causes damage to organs through prolonged or repeated
exposure.
Causes severe burns.

Notes to physician : Treat symptomatically.

SECTION 5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : Use extinguishing measures that are appropriate to local cir-
cumstances and the surrounding environment.

Further information : Collect contaminated fire extinguishing water separately. This

must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.

Special protective equipment : In the event of fire, wear self-contained breathing apparatus.
for fire-fighters

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protec- : Use personal protective equipment.

tive equipment and emer- Avoid breathing dust.
gency procedures Deny access to unprotected persons.

Environmental precautions : Do not flush into surface water or sanitary sewer system.
If the product contaminates rivers and lakes or drains inform
respective authorities.
Local authorities should be advised if significant spillages
cannot be contained.

Methods and materials for : Pick up and arrange disposal without creating dust.
containment and cleaning up Keep in suitable, closed containers for disposal.

SECTION 7. HANDLING AND STORAGE

Advice on protection against : Avoid dust formation. Provide appropriate exhaust ventilation
fire and explosion at places where dust is formed.

Advice on safe handling : Avoid formation of respirable particles.

Avoid exceeding the given occupational exposure limits (see
section 8).
Do not get in eyes, on skin, or on clothing.
For personal protection see section 8.
Persons with a history of skin sensitization problems or asth-
ma, allergies, chronic or recurrent respiratory disease should
not be employed in any process in which this mixture is being
used.
Smoking, eating and drinking should be prohibited in the ap-

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SAFETY DATA SHEET

SikaGrout®-212 SR

Version Revision Date: SDS Number:

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plication area.
Follow standard hygiene measures when handling chemical
products.

Conditions for safe storage : Prevent unauthorized access.

Store in original container.
Keep in a well-ventilated place.
Observe label precautions.
Store in accordance with local regulations.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Ingredients with workplace control parameters

Ingredients CAS-No. Value type Control parame- Basis
(Form of ters / Permissible
exposure) concentration
Quartz (SiO2) 14808-60-7 TWA (Res- 0.1 mg/m3 CA ON OEL
pirable frac-
tion)
TWA (Res- 0.025 mg/m3 CA AB OEL
pirable par-
ticulates)
TWAEV 0.1 mg/m3 CA QC OEL
(respirable
dust)
TWA (Res- 0.025 mg/m3 CA BC OEL
pirable) (Silica)
TWA (Res- 0.025 mg/m3 ACGIH
pirable frac- (Silica)
tion)
Portland cement 65997-15-1 TWA 10 mg/m3 CA AB OEL
TWAEV 5 mg/m3 CA QC OEL
(respirable
dust)
TWAEV (to- 10 mg/m3 CA QC OEL
tal dust)
TWA (Res- 1 mg/m3 CA BC OEL
pirable)
TWA (Res- 1 mg/m3 ACGIH
pirable frac-
tion)
aluminium oxide 1344-28-1 TWA 10 mg/m3 CA AB OEL
TWA (Res- 1 mg/m3 CA BC OEL
pirable)
TWAEV (to- 10 mg/m3 CA QC OEL
tal dust) (Aluminum)
TWA (Res- 1 mg/m3 ACGIH
pirable frac-
tion)
Limestone 1317-65-3 TWA 10 mg/m3 CA AB OEL
STEL 20 mg/m3 CA BC OEL
TWAEV (to- 10 mg/m3 CA QC OEL

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tal dust)
TWA (Total 10 mg/m3 CA BC OEL
dust)
TWA (respir- 3 mg/m3 CA BC OEL
able dust
fraction)
diiron trioxide 1309-37-1 TWA (Res- 5 mg/m3 CA AB OEL
pirable)
TWA 5 mg/m3 CA BC OEL
(Fumes) (Iron)
TWA (Dust) 5 mg/m3 CA BC OEL
(Iron)
STEL 10 mg/m3 CA BC OEL
(Fumes) (Iron)
TWAEV 5 mg/m3 CA QC OEL
(fume and (Iron)
dust)
TWA (Res- 5 mg/m3 ACGIH
pirable frac-
tion)
gypsum (containing less than 13397-24-5 TWA 10 mg/m3 CA AB OEL
2% free crystalline silica in the
respirable fraction)
STEL 20 mg/m3 CA BC OEL
TWAEV 5 mg/m3 CA QC OEL
(respirable
dust)
TWAEV (to- 10 mg/m3 CA QC OEL
tal dust)
TWA (Total 10 mg/m3 CA BC OEL
dust)
TWA (respir- 3 mg/m3 CA BC OEL
able dust
fraction)
TWA (Inhal- 10 mg/m3 ACGIH
able fraction) (Calcium)
TWA (Inhal- 10 mg/m3 ACGIH
able fraction) (Calcium)
magnesium oxide 1309-48-4 TWA (Inhal- 10 mg/m3 CA BC OEL
able fume) (Magnesium)
TWA (Res- 3 mg/m3 CA BC OEL
pirable dust (Magnesium)
and fume)
STEL (Res- 10 mg/m3 CA BC OEL
pirable dust (Magnesium)
and fume)
TWA 10 mg/m3 CA AB OEL
(Fumes)
TWAEV 10 mg/m3 CA QC OEL
(Fumes) (Magnesium)
TWA (Inhal- 10 mg/m3 CA BC OEL
able fume) (Magnesium)
TWA (Res- 3 mg/m3 CA BC OEL

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pirable dust (Magnesium)

and fume)
STEL (Res- 10 mg/m3 CA BC OEL
pirable dust (Magnesium)
and fume)
TWAEV 10 mg/m3 CA QC OEL
(Fumes) (Magnesium)
TWA (Inhal- 10 mg/m3 ACGIH
able fraction)
calcium oxide 1305-78-8 TWA 2 mg/m3 CA AB OEL
TWA 2 mg/m3 CA BC OEL
TWAEV 2 mg/m3 CA QC OEL
TWA 2 mg/m3 ACGIH
Quartz (SiO2) <5µm 14808-60-7 TWA (Res- 0.1 mg/m3 CA ON OEL
pirable frac-
tion)
TWA (Res- 0.025 mg/m3 CA AB OEL
pirable par-
ticulates)
TWAEV 0.1 mg/m3 CA QC OEL
(respirable
dust)
TWA (Res- 0.025 mg/m3 CA BC OEL
pirable) (Silica)
TWA (Res- 0.025 mg/m3 ACGIH
pirable frac- (Silica)
tion)
Engineering measures : Use of adequate ventilation should be sufficient to control
worker exposure to airborne contaminants. If the use of this
product generates dust, fumes, gas, vapor or mist, use pro-
cess enclosures, local exhaust ventilation or other engineer-
ing controls to keep worker exposure below any recommend-
ed or statutory limits.

Personal protective equipment

Respiratory protection : Use a properly fitted NIOSH approved air-purifying or air-fed
respirator complying with an approved standard if a risk as-
sessment indicates this is necessary.

The filter class for the respirator must be suitable for the max-
imum expected contaminant concentration
(gas/vapor/aerosol/particulates) that may arise when han-
dling the product. If this concentration is exceeded, self-
contained breathing apparatus must be used.

Hand protection

Remarks : Chemical-resistant, impervious gloves complying with an

approved standard should be worn at all times when handling
chemical products if a risk assessment indicates this is nec-
essary.

Eye protection : Safety eyewear complying with an approved standard should

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SAFETY DATA SHEET

SikaGrout®-212 SR

Version Revision Date: SDS Number:

1.2 10/18/2017 100000004574

be used when a risk assessment indicates this is necessary.

Skin and body protection : Choose body protection in relation to its type, to the concen-
tration and amount of dangerous substances, and to the spe-
cific work-place.

Hygiene measures : Avoid contact with skin, eyes and clothing.

Wash hands before breaks and immediately after handling
the product.
Remove contaminated clothing and protective equipment
before entering eating areas.
Wash thoroughly after handling.
Avoid breathing dust.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : powder

Color : gray

Odor : none

Odor Threshold : No data available

pH : Not applicable

Melting point/range / Freezing : No data available

point

Boiling point/boiling range : No data available

Flash point : Not applicable

Evaporation rate : No data available

Flammability (solid, gas) : No data available

Upper explosion limit : No data available

Lower explosion limit : No data available

Vapor pressure : No data available

Relative vapor density : No data available

Density : Not applicable

Solubility(ies)
Water solubility : insoluble

Partition coefficient: n- : No data available

octanol/water

Autoignition temperature : No data available

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SAFETY DATA SHEET

SikaGrout®-212 SR

Version Revision Date: SDS Number:

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Decomposition temperature : No data available

Viscosity
Viscosity, dynamic : No data available

Viscosity, kinematic : not determined

Explosive properties : No data available

Molecular weight : No data available

SECTION 10. STABILITY AND REACTIVITY

Reactivity : No dangerous reaction known under conditions of normal use.

Chemical stability : The product is chemically stable.

Possibility of hazardous reac- : Stable under recommended storage conditions.

tions

Conditions to avoid : No data available

Incompatible materials : No data available

No decomposition if stored and applied as directed.

SECTION 11. TOXICOLOGICAL INFORMATION

Acute toxicity
Not classified based on available information.
Skin corrosion/irritation
Causes severe burns.
Serious eye damage/eye irritation
Causes serious eye damage.
Respiratory or skin sensitization
Skin sensitization: May cause an allergic skin reaction.
Respiratory sensitization: Not classified based on available information.
Germ cell mutagenicity
Not classified based on available information.
Carcinogenicity
May cause cancer by inhalation.
IARC Group 1: Carcinogenic to humans

Quartz (SiO2) 14808-60-7

Quartz (SiO2) <5µm 14808-60-7

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NTP Known to be human carcinogen

Quartz (SiO2) 14808-60-7

Quartz (SiO2) <5µm 14808-60-7

Reproductive toxicity
Not classified based on available information.
STOT-single exposure
May cause respiratory irritation.
STOT-repeated exposure
Causes damage to organs (Lungs) through prolonged or repeated exposure.
Aspiration toxicity
Not classified based on available information.

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity
No data available
Persistence and degradability
No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Other adverse effects

Product:
Additional ecological infor- : Do not empty into drains; dispose of this material and its con-
mation tainer in a safe way.

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues : Disposal of this product, solutions and any by-products should
at all times comply with the requirements of environmental
protection and waste disposal legislation and any regional
local authority requirements.

Contaminated packaging : Empty containers should be taken to an approved waste han-

dling site for recycling or disposal.

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Version Revision Date: SDS Number:

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SECTION 14. TRANSPORT INFORMATION

Domestic regulation
TDG (road/train)
Not dangerous goods
International Regulations
IATA-DGR
Not dangerous goods
IMDG-Code
Not dangerous goods
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.

SECTION 15. REGULATORY INFORMATION

Canadian lists
No substances are subject to a Significant New Activity Notification.

SECTION 16. OTHER INFORMATION

Revision Date : 10/18/2017

Prepared by : R & D of Sika Canada Inc.
Notice to Reader:
The information contained in this Material Safety Data Sheet applies only to the actual Sika Can-
ada product identified and described herein. This information is not intended to address, nor does
it address the use or application of the identified Sika product in combination with any other mate-
rial, product or process. All of the information set forth herein is based on technical data regarding
the identified product that Sika believes to be reliable as of the date hereof. Prior to each use of
any Sika product, the user must always read and follow the warnings and instructions on the
product's current Product Data Sheet, product label and Material Safety Data Sheet for each Sika
product, which are available at web site and/or telephone number listed.

SIKA MAKES NO WARRANTIES EXPRESS OR IMPLIED AND ASSUMES NO LIABILITY

ARISING FROM THIS INFORMATION OR ITS USE. SIKA SHALL NOT BE LIABLE UNDER
ANY LEGAL THEORY FOR SPECIAL OR CONSEQUENTIAL DAMAGES AND SHALL NOT BE
RESPONSIBLE FOR THE USE OF THIS PRODUCT IN A MANNER TO INFRINGE ON ANY
PATENT OR ANY OTHER INTELLECTUAL PROPERTY RIGHTS HELD BY OTHERS.
All sales of Sika products are subject to its current terms and conditions of sale available at
www.sika.ca or 514-697-2610.
Full text of other abbreviations
ADR Accord européen relatif au transport international des marchandises
Dangereuses par Route
CAS Chemical Abstracts Service
DNEL Derived no-effect level
EC50 Half maximal effective concentration

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SikaGrout®-212 SR

Version Revision Date: SDS Number:

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GHS Globally Harmonized System

IATA International Air Transport Association
IMDG International Maritime Code for Dangerous Goods
LD50 Median lethal dosis (the amount of a material, given all at once, which
causes the death of 50% (one half) of a group of test animals)
LC50 Median lethal concentration (concentrations of the chemical in air that
kills 50% of the test animals during the observation period)
MARPOL International Convention for the Prevention of Pollution from Ships, 1973
as modified by the Protocol of 1978
OEL Occupational Exposure Limit
PBT Persistent, bioaccumulative and toxic
PNEC Predicted no effect concentration
REACH Regulation (EC) No 1907/2006 of the European Parliament and of the
Council of 18 December 2006 concerning the Registration, Evaluation,
Authorisation and Restriction of Chemicals (REACH), establishing a
European Chemicals Agency
SVHC Substances of Very High Concern
vPvB Very persistent and very bioaccumulative

CA / Z8

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